Thermodynamic assessment of geothermal energy use in hydrogen production

In this study, geothermal-based hydrogen production methods, and their technologies and application possibilities are discussed in detail. A high-temperature electrolysis (HTE) process coupled with and powered by a geothermal source is considered for a case study, and its thermodynamic analysis through energy and exergy is conducted for performance evaluation purposes. In this regard, overall energy and exergy efficiencies of the geothermal-based hydrogen production process for this HTE are found to be 87% and 86%, respectively.     

Economics of hydrogen production and liquefaction by geothermal energy

Seven models are considered for the production and liquefaction of hydrogen by geothermal energy. In these models, we use electrolysis and high-temperature steam electrolysis processes for hydrogen production, a binary power plant for geothermal power production, and a pre-cooled Linde–Hampson cycle for hydrogen liquefaction. Also, an absorption cooling system is used for the pre-cooling of hydrogen before the liquefaction process. A methodology is developed for the economic analysis of the models. It is estimated that the cost of hydrogen production and liquefaction ranges between 0.979 $/kg H₂ and 2.615 $/kg H₂ depending on the model. The effect of geothermal water temperature on the cost of hydrogen production and liquefaction is investigated. The results show that the cost of hydrogen production and liquefaction decreases as the geothermal water temperature increases. Also, capital costs for the models involving hydrogen liquefaction are greater than those for the models involving hydrogen production only.     

Thermodynamic analysis of models used in hydrogen production by geothermal energy

Four models are developed for the use of geothermal energy for hydrogen production. These include using geothermal work output as the work input for an electrolysis process (Case 1); using part of geothermal heat to produce work for electrolysis process and part of geothermal heat in an electrolysis process to preheat the water (Case 2), using geothermal heat to preheat water in a high-temperature electrolysis process (Case 3), and using part of geothermal work for electrolysis and the remaining part for liquefaction (Case 4). These models are studied thermodynamically, and both reversible and actual (irreversible) operation of the models are considered. The effect of geothermal water temperature on the amount of hydrogen production per unit mass of geothermal water is investigated for all four models, and the results are compared. The results show that as the temperature of geothermal water increases the amount of hydrogen production increases. Also, 1.34 g of hydrogen may be produced by one kg of geothermal water at 200 °C in the reversible operation for Case 1. The corresponding values are 1.42, 1.91, and 1.22 in Case 2, Case 3, and Case 4, respectively. Greater amounts of hydrogen may be produced in Case 3 compared to other cases. Case 2 performs better than Case 1 because of the enhanced use of geothermal resource in the process. Case 4 allows both hydrogen production and liquefaction using the same geothermal resource, and provides a good solution for the remote geothermal resources. A comparison of hydrogen production values in the reversible and irreversible conditions reveal that the second-law efficiencies of the models are 28.5%, 29.9%, 37.2%, and 16.1% in Case 1, Case 2, Case 3, and Case 4, respectively.     

Ranking locations for producing hydrogen using geothermal energy in Afghanistan

Geothermal energy is a type of renewable energy with high availability and independence from climatic and atmospheric conditions. It has been shown that geothermal energy is technically, economically and environmentally more suitable for hydrogen production than other renewable sources. Hydrogen has wide applications in many fields including cooling, oil, gas, petrochemical, nuclear, and energy industries. Afghanistan has significant potential in geothermal power generation and also several hydrogen-consuming industries that provide opportunities for geothermal-based hydrogen production. This study attempted to find suitable locations for the construction of geothermal power plant for hydrogen production in Afghanistan. Given the multitude of criteria involved in the choice of location, evaluations and comparisons were performed using multi-criteria decision-making methods. Nine criteria were used to evaluate 17 Afghanistan provinces in terms of suitability for geothermal-based hydrogen production. The SWARA (Stepwise Weight Assessment Ratio Analysis) method was used to weight the criteria and then the ARAS (Additive Ratio Assessment) method was used to rank the provinces. The results were validated. The results showed that Sari pul, Balkh and Herat are the most suitable Afghanistan provinces and Zabul, Ghor and Kandahar are the least suitable Afghanistan provinces for geothermal-based hydrogen production. The three methods produced almost identical rankings with only minor differences in the overall ranking of some provinces.     

Heat transfer problems for the production of hydrogen from geothermal energy

Electrolysis at low temperature is currently used to produce Hydrogen. From a thermodynamic point of view, it is possible to improve the performance of electrolysis while functioning at high temperature (high temperature electrolysis: HTE). That makes it possible to reduce energy consumption but requires a part of the energy necessary for the dissociation of water to be in the form of thermal energy.

A collaboration between France and Iceland aims at studying and then validating the possibilities of producing hydrogen with HTE coupled with a geothermal source. The influence of the exit temperature on the cost of energy consumption of the drilling well is detailed.

To vaporize the water to the electrolyser, it should be possible to use the same technology currently used in the Icelandic geothermal context for producing electricity by using a steam turbine cycle. For heating the steam up to the temperature needed at the entrance of the electrolyser three kinds of heat exchangers could be used, according to specific temperature intervals.     

Assessment of geothermal energy use with thermoelectric generator for hydrogen production

In this work, a new model for producing hydrogen from a low enthalpy geothermal source was presented. Thermal energy from geothermal sources can be converted into electric power by using thermoelectric modules instead of Organic Rankine Cycle (ORC) machines, especially for low geothermal temperatures. This electrical energy uses the water electrolysis process to produce hydrogen. Simulation and experiments for the thermoelectric module in this system were undertaken to assess the efficiency of these models. TRNSYS software is used to simulate the system in Hammam Righa spa, the temperature of this spring is 70 °C. Obtained results reveal that in hammam righa spa in Algeria, 0.5652 Kg hydrogen per square meter of thermoelectric generator (TEG) can be produced in one year.     

The exploitation of hydrogen sulfide for hydrogen production in geothermal areas

Hydrogen is a valuable energy resource and it is widespread in nature. As a matter of fact, researches on hydrogen production are currently experiencing an increasing interest from scientists around the world since this resource is clean and renewable. Several methods of producing hydrogen have been developed in industrialized countries such as the United States of America and Germany.This paper is interested in the process by which hydrogen sulfide of geothermal areas is exploited for hydrogen production. In fact, research advances in this field have concluded that hydrogen sulfide of geothermal resources can contribute significantly and economically in the process of hydrogen generation.The present paper was principally conducted from a literature study and a synthesis of works achieved in recent years in order to highlight the various aspects of hydrogen production from hydrogen sulfide and particularly to study the possibility of the exploitation of Algeria’s thermal resources in this field.     

Domestic hydrogen production using renewable energy

A brief review shows that domestic production of hydrogen to fuel a car is feasible by using various means. Among these, the solar––photovoltaic electricity––electrolysis process seems to be the most practical if a renewable energy source is to be used. A simplified model has been developed to determine and optimize the thermal and economical performance of domestic photovoltaic-electrolyzer systems, either with fixed or sun tracking panels using annual total solar radiation on a horizontal surface and climatic data. Twelve locations in the United Sates from four climatic zones (tropical-sub tropical, dry, temperate, cool snow-forest) have been selected. Simulations have been carried out to produce data for hydrogen production for these various locations and the resulting data have been correlated to obtain hydrogen production in kg/kW_p/year photovoltaic system as a function of total annual solar radiation on horizontal surface. The economical feasibility has been studied by taking the photovoltaic and electrolyzer systems' price as variable parameters. It is assumed that the necessary capital is 100% borrowed from a financial institution to pay back in monthly installments. It has been found that the hydrogen production with fixed photovoltaic panels varies from 26 to 42 kg/kW_p/year and the cost from 25 to 268 $/GJ.     

Exploring the feasibility of green hydrogen production using excess energy from a country-scale 100% solar-wind renewable energy system

When planning large-scale 100% renewable energy systems (RES) for the year 2050, the system capacity is usually oversized for better supply-demand matching of electrical energy since solar and wind resources are highly intermittent. This causes excessive excess energy that is typically dissipated, curtailed, or sold directly. The public literature shows a lack of studies on the feasibility of using this excess for country-scale co-generation. This study presents the first investigation of utilizing this excess to generate green hydrogen gas. The concept is demonstrated for Jordan using three solar photovoltaic (PV), wind, and hybrid PV-wind RESs, all equipped with Lithium-Ion battery energy storage systems (ESSs), for hydrogen production using a polymer electrolyte membrane (PEM) system. The results show that the PV-based system has the highest demand-supply fraction (>99%). However, the wind-based system is more favorable economically, with installed RES, ESS, and PEM capacities of only 23.88 GW, 2542 GWh, and 20.66 GW. It also shows the highest hydrogen annual production rate (172.1 × 10³ tons) and the lowest hydrogen cost (1.082 USD/kg). The three systems were a better option than selling excess energy directly, where they ensure annual incomes up to 2.68 billion USD while having payback periods of as low as 1.78 years. Furthermore, the hydrogen cost does not exceed 2.03 USD/kg, which is significantly lower than the expected cost of hydrogen (3 USD/kg) produced using energy from fossil fuel-based systems in 2050.     

Modelling of hydrogen production from hydrogen sulfide in geothermal power plants

Geothermal power plants emit high amount of hydrogen sulfide (H₂S). The presence of H₂S in the air, water, soils and vegetation is one of the main environmental concerns for geothermal fields. There is an increasing interest in developing suitable methods and technologies to produce hydrogen from H₂S as promising alternative solution for energy requirements. In the present study, the AMIS technology is the invention of a proprietary technology (AMIS^® - acronym for “Abatement of Mercury and Hydrogen Sulfide” in Italian language) for the abatement of hydrogen sulphide and mercury emission, is primarily employed to produce hydrogen from H₂S. A proton exchange membrane (PEM) electrolyzer operates at 150 °C with gaseous H₂S sulfur dimer in the anode compartment and hydrogen gas in the cathode compartment. Thermodynamic calculations of electrolysis process are made and parametric studies are undertaken by changing several parameters of the process. Also, energy and exergy efficiencies of the process are calculated as % 27.8 and % 57.1 at 150 °C inlet temperature of H₂S, respectively.     

Exergoeconomic analysis of a hybrid copper-chlorine cycle driven by geothermal energy for hydrogen production

In this study, we conduct an exergy, cost, energy and mass (EXCEM) analysis of a copper-chlorine thermochemical water splitting cycle driven by geothermal energy for hydrogen production. We also investigate and illustrate the relations between thermodynamic losses and capital costs. The results show that hydrogen cost is closely and directly related to the plant capacity and also exergy efficiency. Increasing economic viability and reducing the hydrogen production costs will help these cycles play a more critical role in switching to hydrogen economy.     

Methanol production using hydrogen from concentrated solar energy

Concentrated solar thermal technology is considered a very promising renewable energy technology due to its capability of producing heat and electricity and of its straightforward coupling to thermal storage devices. Conventionally, this approach is mostly used for power generation. When coupled with the right conversion process, it can be also used to produce methanol. Indeed methanol is a good alternative fuel for high compression ratio engines. Its high burning velocity and the large expansion occurring during combustion leads to higher efficiency compared to operation with conventional fuels. This study is focused on the system level modeling of methanol production using hydrogen and carbon monoxide produced with cerium oxide solar thermochemical cycle which is expected to be CO₂ free. A techno-economic assessment of the overall process is done for the first time. The thermochemical redox cycle is operated in a solar receiver-reactor with concentrated solar heat to produce hydrogen and carbon monoxide as the main constituents of synthesis gas. Afterwards, the synthesis gas is turned into methanol whereas the methanol production process is CO₂ free. The production pathway was modeled and simulations were carried out using process simulation software for MW-scale methanol production plant. The methanol production from synthesis gas utilizes plug-flow reactor. Optimum parameters of reactors are calculated. The solar methanol production plant is designed for the location Almeria, Spain. To assess the plant, economic analysis has been carried out. The results of the simulation show that it is possible to produce 27.81 million liter methanol with a 350 MW_th solar tower plant. It is found out that to operate this plant at base case scenario, 880685 m² of mirror's facets are needed with a solar tower height of 220 m. In this scenario a production cost of 1.14 €/l Methanol is predicted.     

Thermodynamic analysis of a novel solar and geothermal based combined energy system for hydrogen production

The present study develops a new solar and geothermal based integrated system, comprising absorption cooling system, organic Rankine cycle (ORC), a solar-driven system and hydrogen production units. The system is designed to generate six outputs namely, power, cooling, heating, drying air, hydrogen and domestic hot water. Geothermal power plants emit high amount of hydrogen sulfide (H₂S). The presence of H₂S in the air, water, soils and vegetation is one of the main environmental concerns for geothermal fields. In this paper, AMIS(AMIS® - acronym for “Abatement of Mercury and Hydrogen Sulphide” in Italian language) technology is used for abatement of mercury and producing of hydrogen from H₂S. The present system is assessed both energetically and exergetically. In addition, the energetic and exergetic efficiencies and exergy destruction rates for the whole system and its parts are defined. The highest overall energy and exergy efficiencies are calculated to be 78.37% and 58.40% in the storing period, respectively. Furthermore, the effects of changing various system parameters on the energy and exergy efficiencies of the overall system and its subsystems are examined accordingly.     

Mixed refrigerant as working fluid in Organic Rankine Cycle for hydrogen production driven by geothermal energy

The possibility of utilizing low temperature heat source systems for producing electricity has been significant due to increasing energy demand. In this study, the Organic Rankine Cycle (ORC) integrated with proton exchange membrane (PEM) electrolyzer is analyzed thermodynamically and economically. A mixture of butane, pentane and iso-pentane is selected as working fluid. The results show that utilizing the mixed refrigerant enhances the performance of the system and results in a higher hydrogen production rate because of a glide match of temperature profiles in the heat exchangers. Economic analysis results which are helpful in designing entire the system show that the highest cost component is electrolyzer, followed by the turbine and condenser.     

Research and development of geothermal energy production in Hungary

The basement of the Pannonian (Carpathian) basin is represented by Paleozoic metamorphic and Mesozoic dolomite and limestone formations. The Tertiary basin gradually subsided during the Alpine orogeny down to 6000 m and was filled by elastic sediments with several water horizons.A heat flow of 2.0 to 3.4 μcal/cm²s gives temperature gradients between 45 and 70 °C/km in the basin. At 2000 m depth the virgin rock temperature is between 110 and 150°C. 80 geothermal wells about 2000 m deep have shown the great geothermal potential of the basin.The main hot water reservoir is the Upper Pliocene (Pannonian) sandstone formation. Hot water is produced by wells from the blanket or sheet sand and sandstone, intercalated frequently by siltstone. Between a 100–300 m interval, 3 to 8 permeable layers are exploited resulting in 1–3 m³/min hot water at 80–99°C temperature.Wells at present are overflowing with shut-in pressures of 3–5 atm.The Pannonian basin is a conduction-dominated reservoir. Convection systems are negligible, hot igneous systems do not exist. The assessment of geothermal resources revealed that the content of the water-bearing rocks down to 3000 m amounts to 12,600 × 10¹⁸cal. In the Tertiary sediments 10,560 × 10¹⁸cal and in the Upper Pannonian, 1938 × 10¹⁸cal are stored. In the Upper Pannonian geothermal reservoir, below 1000 m, where the virgin rock temperature is between 70 and 140°C, the stored heat is 768 × 10⁸cal. A 10¹⁸ cal is equivalent to the combustion heat of 100 million tons of oil. The amount of recoverable geothermal energy from 768 × 10⁸cal is 7.42 × 10¹⁸cal, i.e. about 10,000 MW century, not considering reinjection.At present the Pannonian geothermal reservoir stores the greatest amount of identified heat which can be mobilized and used. Hungary has 496 geothermal wells with a nominal capacity of 428 m³/min, producing 1342 MW heat. 147 wells have an outflow temperature of more than 60°C producing 190 m³/min, that is, 845 MW. In 1974 290 MWyear of geothermal energy was utilized in agriculture, district heating and industry.     

Efficiency of hydrogen production systems using alternative nuclear energy technologies

Nuclear energy can be used as the primary energy source in centralized hydrogen production through high-temperature thermochemical processes, water electrolysis, or high-temperature steam electrolysis. Energy efficiency is important in providing hydrogen economically and in a climate friendly manner. High operating temperatures are needed for more efficient thermochemical and electrochemical hydrogen production using nuclear energy. Therefore, high-temperature reactors, such as the gas-cooled, molten-salt-cooled and liquid-metal-cooled reactor technologies, are the candidates for use in hydrogen production. Several candidate technologies that span the range from well developed to conceptual are compared in our analysis. Among these alternatives, high-temperature steam electrolysis (HTSE) coupled to an advanced gas reactor cooled by supercritical CO₂ (S-CO₂) and equipped with a supercritical CO₂ power conversion cycle has the potential to provide higher energy efficiency at a lower temperature range than the other alternatives.     

Techno economic feasibility study on hydrogen production using concentrating solar thermal technology in India

The techno-economic analysis of hydrogen (H₂) production using concentrating solar thermal (CST) technologies is performed in this study. Two distinct hydrogen production methods, namely: a) thermochemical water splitting [model 1] and b) solid oxide electrolysers [model 2], are modeled by considering the total heat requirement and supplied from a central tower system located in Jaisalmer, India. The hourly simulated thermal energy obtained from the 10 MW_th central tower system is fed as an input to both these hydrogen production systems for estimating the hourly hydrogen production rate. The results revealed that these models yield hydrogen at a rate of 31.46 kg/h and 25.2 kg/h respectively for model 1 and model 2. Further, the Levelized cost of hydrogen (LCoH) for model 1 and model 2 is estimated as ranging from $ 8.23 and $ 14.25/kg of H₂ and $ 9.04 and $ 19.24/kg, respectively, for different scenarios. Overall, the present work displays a different outlook on real-time hydrogen production possibilities and necessary inclusions to be followed for future hydrogen plants in India. The details of the improvisation and possibilities to improve the LCoH are also discussed in this study.     

Nanocatalyst fabrication and the production of hydrogen by using photon energy

An experimental and analytical study of nanocatalyst fabrication and the production of hydrogen utilizing photon energy was carried out. The porous structure of the nanocatalyst provides a high surface to volume ratio of the catalytic layer thereby increasing the activity of the catalyst. An experiment was carried out to obtain an effective nanocatalyst by using pulsed laser ablation (PLA) technology. The properties of the nanocatalyst are directly related to the performance of the catalytic reaction and are analyzed. Experiments and analyses were carried out to evaluate the activity enhancement of the nanocatalyst. Photonic energy provides the heat for the endothermic steam–methanol reforming reaction producing hydrogen. It is shown that photonic induced steam–methanol reforming in a nanocatalyst reformer is feasible and promising.     

Net energy production history of the Geysers geothermal project

Geothermal projects at the Geysers, California, have relatively high net energy ratios for electricity-production facilities. Comparison of the net cumulative electrical energy generated at the Geysers with the cumulative thermal energy invested for constrction and operation of the facility indicates a favorable energy return, even during periods of rapid systems expansion.