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循环用阀控电池失效模式的研究 总被引:5,自引:0,他引:5
采用孔率测试、X射线衍射、电镜扫描等手段,对循环失效后的活性物质(AM)的成分与结构进行了较深入的研究,分析认为循环使用条件下,电池的失效主要是由正极活性物质(PAM)的软化、脱落所致。 相似文献
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对不同批次2 V2、00 Ah(C10=200 Ah)的VRLA电池单只和3只串联分别进行100%DOD循环实验。导致整组串联电池循环寿命提前结束的原因,主要是电池容量的均一性问题,落后的电池影响了循环寿命。对循环失效的电池进行解剖研究,发现造成电池失效的主要原因是正极活性物质的软化和脱落。 相似文献
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铅酸蓄电池循环寿命性能衰退通常由正极板性能降低所造成的,正极板的失效与正极活性物质的软化、正极板栅腐蚀和膨胀,以及正极板栅与活性物质界面纯化有关。讨论了正极活性物质的失效模式。 相似文献
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Abstract We have investigated the fatigue of electromechanical and dielectric properties of sol-gel derived PZT(53/47) thin films deposited on metallic substrates by means of electric and mechanical cycling. For the mechanical cycling a two point bending method was used to apply transversal stress to the samples. During mechanical cycling the piezoelectric coefficient d31 remained constant up to about 105 cycles, for a higher number of cycles a strong decrease was observed. During electric cycling no significant changes in the ferroelectric and electromechanical hysteresis loops could be found up to about 3×105 cycles. Above this number the coercive field increases, the maximum strain and the remanent polarization decrease. Obviously each electric cycling of the investigated films is accompanied by a mechanical cycling. It is assumed, that microcracks induced by mechanical stress are the main reason for the deterioration of the physical properties films during electric and mechanical cycling both. 相似文献
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Yi-Shao Lai Tong Hong Wang Chang-Chi Lee 《Device and Materials Reliability, IEEE Transactions on》2008,8(1):122-128
In this paper, we apply the sequential thermal-mechanical coupling analysis that solves, in turn, the transient temperature field and subsequent thermomechanical deformations to investigate thermal characteristics along with fatigue reliability of board-level thin-profile fine-pitch ball-grid-array chip-scale packages under coupled power- and thermal-cycling test conditions. Pure thermal-cycling and pure power-cycling test conditions are also examined and compared. From the comparison of different test conditions, we note that the presence of power cycling leads to significant deviations of junction and mold-top temperatures from the thermal-cycling profile. Nevertheless, for components away from the die, the deviations are less significant. As the power specified to the test vehicle is low, temperature histories on the components induced by coupled power and thermal cycling can be approximated by superposition of the temperature histories induced by pure power cycling and the ones by pure thermal cycling. For the test conditions proposed in this paper, pure power cycling leads to the longest fatigue life among all. For coupled power and thermal cycling, the involvement of power cycling reduces the fatigue life of the test vehicle by about 50% as compared to pure thermal cycling. 相似文献
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Lin PY Lin SI Chen JJ 《IEEE transactions on neural systems and rehabilitation engineering》2012,20(1):78-84
Functional decline of lower-limb affects the ability of locomotion and the age-related brain differences have been elucidated among the elderly. Cycling exercise is a common training program for restoring motor function in the deconditioned elderly or stroke patients. The provision of speed feedback has been commonly suggested to clinical therapists for facilitating learning of controlled cycling performance and maintaining motivation in training programs with elderly participants. However, the cortical control of pedaling movements and the effect of external feedback remain poorly understanding. This study investigated the regional cortical activities detected by functional near infrared spectroscopy (fNIRS) in 12 healthy young and 13 healthy elderly subjects under conditions of cycling without-(free cycling) and with feedback (target cycling). The elderly exhibited predominant activation of the sensorimotor cortex during free cycling similar to young subjects but with poorer cycling performance. The cycling performance improved in both groups, and the elderly showed increased brain activities of the supplementary motor area and premotor cortex under target cycling condition. These findings demonstrated age-related changes in the cortical control in processing external feedback and pedaling movements. Use of fNIRS to evaluate brain activation patterns after training may facilitate brain-based design of tailored therapeutic rehabilitation strategies. 相似文献
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添加剂(RSO_3H)对铅酸蓄电池正极循环寿命的影响 总被引:3,自引:2,他引:1
测定了添加剂RSO3H对铅酸蓄电池正极充放电循环寿命的影响。结果表明,添加剂RSO3H可使正极的循环寿命缩短;若向正极铅膏中同时加入RSO3H和聚四氟乙烯(PTFE),则正极的循环寿命可以相对延长。 相似文献
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Nair D.R. Mohapatra N.R. Mahapatra S. Shukuri S. Bude J.D. 《Device and Materials Reliability, IEEE Transactions on》2004,4(1):32-37
Drain disturb is studied in NOR flash EEPROM cells under CHE and CHISEL programming operation, before and after repeated program/erase (P/E) cycling. Drain disturb is shown to originate from band-to-band tunneling under CHISEL operation, unlike under CHE operation where it originates from source-drain leakage. Under identical initial programming time, CHISEL operation always shows slightly lower program/disturb (P/D) margin before cycling but similar P/D margin after repetitive P/E cycling when compared to CHE operation. The degradation of gate coupling coefficient that affects source/drain leakage and the increase in trap-assisted band-to-band tunneling seems to explain well the behavior of CHE and CHISEL drain disturb after cycling. 相似文献
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Hunt K.J. Stone B. Negard N.-O. Schauer T. Fraser M.H. Cathcart A.J. Ferrario C. Ward S.A. Grant S. 《IEEE transactions on neural systems and rehabilitation engineering》2004,12(1):89-101
AIM: The aim of this study was to investigate feedback control strategies for integration of electric motor assist and functional electrical stimulation (FES) for paraplegic cycling, with particular focus on development of a testbed for exercise testing in FES cycling, in which both cycling cadence and workrate are simultaneously well controlled and contemporary physiological measures of exercise performance derived. A second aim was to investigate the possible benefits of the approach for mobile, recreational cycling. METHODS: A recumbent tricycle with an auxiliary electric motor is used, which is adapted for paraplegic users, and instrumented for stimulation control. We propose a novel integrated control strategy which simultaneously provides feedback control of leg power output (via automatic adjustment of stimulation intensity) and cycling cadence (via electric motor control). Both loops are designed using system identification and analytical (model-based) feedback design methods. Ventilatory and pulmonary gas exchange response profiles are derived using a portable system for real-time breath-by-breath acquisition. RESULTS: We provide indicative results from one paraplegic subject in which a series of feedback-control tests illustrate accurate control of cycling cadence, leg power control, and external disturbance rejection. We also provide physiological response profiles from a submaximal exercise step test and a maximal incremental exercise test, as facilitated by the control strategy. CONCLUSION: The integrated control strategy is effective in facilitating exercise testing under conditions of well-controlled cadence and power output. Our control approach significantly extends the achievable workrate range and enhances exercise-test sensitivity for FES cycling, thus allowing a more stringent characterization of physiological response profiles and estimation of key parameters of aerobic function. We further conclude that the control approach can significantly improve the overall performance of mobile recreational cycling. 相似文献
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为了考察LiMn2O4锂离子蓄电池正极材料在充放电过程中的化学变化,采用高温固相法制备了尖晶石型LiMn2O4,并对其电化学性能进行了表征,利用X射线衍射分析的结果,结合Li-Mn-O相图,对LiMn2O4在多次循环充放电所发生的相变进行了研究。实验结果表明,其首次放电比容量为123 mAh/g,循环200次后的放电比容量为107 mAh/g;LiMn2O4发生歧化反应,以及在LiMn2O4微粒表面形成的Li2Mn2O4进一步转化成无电化学活性的Li2MnO3,这两种相变都会导致电池的不可逆容量损失。 相似文献