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综述了合成阳离子丙烯酸系聚合物乳液的乳化剂、引发剂及单体体系和聚合方法,介绍了阳离子乳液的性质和应用。 相似文献
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以淀粉为主链、甲基丙烯酰氧乙基三甲基氯化铵(DMC)为功能单体、苯乙烯(St)和丙烯酸丁酯(BA)为改性单体,采用种子乳液共聚法制备了无皂淀粉基阳离子苯丙乳液。讨论了反应条件对该乳液稳定性及乳胶膜性能等影响,并采用红外光谱(FT-IR)法对乳液聚合物结构进行了表征。结果表明:当m(DMC)∶m(淀粉+St+BA)=0.8∶1、m(淀粉)∶m(St+BA)=1.00∶3、m(St)∶m(BA)=1.50∶1、反应温度为80℃、w(引发剂)=2%且m(过硫酸钾KPS)∶m(NaHSO3)=2∶1时,改性乳液的综合性能最佳。 相似文献
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前言 江西抚州造纸厂是“八五”期间国家批准兴建的大型企业,以木竹浆混合生产高强度牛皮箱板纸。为增加纸张强度、提高产品质量、降低生产成本,1993年2月用江西省科学院生产的阳离子淀粉进行湿部添加应用试验,证明该助剂使用性能较好,是较为理想的造纸助剂。 相似文献
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阳离子聚合物乳液的合成及其在涂料染色中的应用 总被引:1,自引:0,他引:1
采用无皂乳液聚合的方法,选择合适的阳离子单体和引发剂,合成了稳定的阳离子型聚合物乳液.分析了软单体BA、硬单体St、阳离子单体DMC、引发荆APS用量和搅拌速度等因素对乳液粒径及稳定性的影响.结果表明,当阳离子单体、软、硬单体用量分别为13.14%、6.18%和2.32%,引发剂用量为0.5%,搅拌速度为250 r/min时,合成的乳液粒径为383.3 nm,具有较好的稳定性.应用于涂料染色织物,阳离子聚合物乳液具有比商品粘合剂高的干湿摩擦牢度.电子显微镜的观察结果说明,阳离子乳液能够在织物表面形成更完整均匀的聚合物薄膜. 相似文献
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采用双酚A(BPA)和十二烷基酚(DDP)对双酚A型小分子量液体环氧树脂E-51进行扩链,然后用二乙醇胺(DEA)、N,N二甲基氨基丙胺(DMAPA)对其进行化学改性,再用乳酸中和并乳化在水中,制备了自乳化型阳离子环氧乳液。讨论了扩链反应时间,DDP、DEA和DMAPA用量以及中和度对自乳化环氧乳液外观及稳定性的影响,获得了较佳的反应条件:m(E-51)∶m(BPA)∶m(DDP)=50∶13.9∶10,n(DDP)∶n(DEA)∶n(DMAPA)=30∶40∶15,中和度40%,反应时间60min,反应温度150℃。以此条件下制备的自乳化型阳离子环氧乳液制备阴极电泳涂料,当电泳电压为125V、电泳温度30℃、电泳时间2min时,可制备出综合性能优良的阴极电泳涂料漆膜。 相似文献
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阳离子型聚丙烯酰胺乳液的工业开发研究 总被引:1,自引:0,他引:1
国外阳离子型聚丙烯酰胺的产量占聚丙烯酰胺产品的50%以上,该产品是水处理及造纸行业中用途最广泛的高分子聚合物之一。反相乳液聚合法合成阳离子型聚丙烯酰胺是国外80年代末期的先进技术,而国内一直没有相关报道。1996年(原)化工部广州聚丙烯酰胺工种技术中心承担了国家石油和化学工业局的“九五”国家重点科技攻关项目“微生物法丙烯酰胺聚合新品种的开发研究”,并已经于2000年通过鉴定验收。该项目已经建立300t/a的中试装置,生产工艺路线合理、能耗较低、产品性能稳定,具有速溶特性,在国内外市场有一定的竞争力。 相似文献
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《Chemical Engineering Communications》2002,189(12):1671-1683
In this study, we investigated the influence of the number of ethanol (EO) groups of cationic surfactants having one oleyl group on the drag-reducing effect (DR effect). Also the effect of mechanical pumping power on DR effect was experimentally investigated using two experimental setups, a circulation system (with pump) and a pressurized once-through system (without pump). The concluding remarks obtained in this study are: 1. The DR effect strongly depends on the re-formation rate of micelles disrupted mechanically. 2. When increasing the number of EO groups of the DR surfactants from 0 to 2, the available temperature range of large DR effect was shifted lower. But the DR surfactant having three EO groups (EO-3) barely exhibited the DR effect even at the low temperature. This is because the big hydrophilic head of EO groups probably delays the re-formation of micelles disrupted by pumping power. 3. The DR effect was more liable to be influenced by pumping power with a decrease in temperature. This is because it takes a long time to re-form micelles disrupted by pumping power at low temperature. 相似文献
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In this study, we investigated the influence of the number of ethanol (EO) groups of cationic surfactants having one oleyl group on the drag-reducing effect (DR effect). Also the effect of mechanical pumping power on DR effect was experimentally investigated using two experimental setups, a circulation system (with pump) and a pressurized once-through system (without pump). The concluding remarks obtained in this study are: 1. The DR effect strongly depends on the re-formation rate of micelles disrupted mechanically. 2. When increasing the number of EO groups of the DR surfactants from 0 to 2, the available temperature range of large DR effect was shifted lower. But the DR surfactant having three EO groups (EO-3) barely exhibited the DR effect even at the low temperature. This is because the big hydrophilic head of EO groups probably delays the re-formation of micelles disrupted by pumping power. 3. The DR effect was more liable to be influenced by pumping power with a decrease in temperature. This is because it takes a long time to re-form micelles disrupted by pumping power at low temperature. 相似文献
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Marco Sangermano Giulio Malucelli Roberta Bongiovanni Lorenzo Vescovo Aldo Priola Richard R. Thomas Yongsin Kim Charles M. Kausch 《大分子材料与工程》2004,289(8):722-727
Summary: Different fluorinated hyperbranched polymers (HBP) were synthesized starting from fluorinated oxetanes and employed as additives in cationic photopolymerization of epoxy monomers. As previously observed for other hydroxyl containing HBP, they interact with the polymeric carbocation through a chain transfer mechanism inducing an increase in the final epoxy conversion. High gel content values (>96%) for the photocured films confirm that the HBP additive is tightly crosslinked to the polymeric network. In the presence of this fluorine‐containing HBP it is possible to influence the bulk properties, as well as, the surface properties. The fluorinated HBP tends to migrate to the surface inducing an increase of hydrophobicity.
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阳离子蛋白是目前比较浒的护发添加剂之一,它对头发有较强的亲和性,能起到很好的修复受损头发及柔软、改善梳理性等作用,本文应用Lowry’s蛋白测定法对不同条件时阳离子蛋白在头发上的吸附作用进行了初步研究,得出了作用时间、阳离子蛋白浓度、非阳离子化及不同类型阳离子化蛋白反及基质对阳离子蛋白吸附性的影响等结果。 相似文献
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用聚醚二元醇、甲苯二异氰酸酯(TDI)、N–甲基二乙醇胺(N–MDEA)、乙酸为原料制备了阳离子水性聚氨酯乳液,然后向聚氨酯乳液中加入丙烯酸丁酯(BA)和引发剂进行自由基聚合制成阳离子水性聚氨酯/聚丙烯酸酯乳液。用旋转黏度计、FT–IR、电子万能(拉力)试验机对所制备的乳液黏度、膜的形态结构及力学性能进行了表征。结果表明,改性后的阳离子聚氨酯乳液综合性能明显提高。 相似文献