Efficient utilization of waste heat from molten carbonate fuel cell in parabolic trough power plant for electricity and hydrogen coproduction

Direct steam generating parabolic trough power plant is an important technology to match future electric energy demand. One of the problems related to its emergence is energy storage. Solar-to-hydrogen is a promising technology for solar energy storage. Electrolysis is among the most processes of hydrogen production recently investigated. High temperature steam electrolysis is a clean process to efficiently produce hydrogen. In this paper, steam electrolysis process using solar energy is used to produce hydrogen. A heat recovery steam generator generates high temperature steam thanks to the molten carbonate fuel cell's waste heat. The analytical study investigates the energy efficiency of solar power plant, molten carbonate fuel cell and electrolyser. The impact of waste heat utilization on electricity and hydrogen generation is analysed. The results of calculations done with MATLAB software show that fuel cell produces 7.73 MWth of thermal energy at design conditions. 73.37 tonnes of hydrogen and 14.26 GWh of electricity are yearly produced. The annual energy efficiency of electrolyser is 70% while the annual mean electric efficiency of solar power plant is 18.30%.The proposed configuration based on the yearly electricity production and hydrogen generation has presented a good performance.     

Performance assessment of a solar hydrogen and electricity production plant using high temperature PEM electrolyzer and energy storage

This paper investigates the performance of a high temperature Polymer Electrolyte Membrane (PEM) electrolyzer integrated with concentrating solar power (CSP) plant and thermal energy storage (TES) to produce hydrogen and electricity, concurrently. A finite-time-thermodynamic analysis is conducted to evaluate the performance of a PEM system integrated with a Rankine cycle based on the concept of exergy. The effects of solar intensity, electrolyzer current density and working temperature on the performance of the overall system are identified. A TES subsystem is utilized to facilitate continuous generation of hydrogen and electricity. The hydrogen and electricity generation efficiency and the exergy efficiency of the integrated system are 20.1% and 41.25%, respectively. When TES system supplies the required energy, the overall energy and exergy efficiencies decrease to 23.1% and 45%, respectively. The integration of PEM electrolyzer enhances the exergy efficiency of the Rankine cycle, considerably. However, it causes almost 5% exergy destruction in the integrated system due to conversion of electrical energy to hydrogen energy. Also, it is concluded that increase of working pressure and membrane thickness leads to higher cell voltage and lower electrolyzer efficiency. The results indicate that the integrated system is a promising technology to enhance the performance of concentrating solar power plants.     

Modeling of a thermal energy storage system based on coupled metal hydrides (magnesium iron – sodium alanate) for concentrating solar power plants

Concentrating solar power plants represent low cost and efficient solutions for renewable electricity production only if adequate thermal energy storage systems are included. Metal hydride thermal energy storage systems have demonstrated the potential to achieve very high volumetric energy densities, high exergetic efficiencies, and low costs. The current work analyzes the technical feasibility and the performance of a storage system based on the high temperature Mg₂FeH₆ hydride coupled with the low temperature Na₃AlH₆ hydride. To accomplish this, a detailed transport model has been set up and the coupled metal hydride system has been simulated based on a laboratory scale experimental configuration. Proper kinetics expressions have been developed and included in the model to replicate the absorption and desorption process in the high temperature and low temperature hydride materials. The system showed adequate hydrogen transfer between the two metal hydrides, with almost complete charging and discharging, during both thermal energy storage and thermal energy release. The system operating temperatures varied from 450 °C to 500 °C, with hydrogen pressures between 30 bar and 70 bar. This makes the thermal energy storage system a suitable candidate for pairing with a solar driven steam power plant. The model results, obtained for the selected experimental configuration, showed an actual thermal energy storage system volumetric energy density of about 132 kWh/m³, which is more than 5 times the U.S. Department of Energy SunShot target (25 kWh/m³).     

Hydrogen production by coupling pressurized high temperature electrolyser with solar tower technology

Solar hydrogen production by coupling of pressurized high temperature electrolyser with concentrated solar tower technology is studied. As the high temperature electrolyser requires constant temperature conditions, the focus is made on a molten salt solar tower due to its high storage capacity. A flowsheet was developed and simulations were carried out with Aspen Plus 8.4 software for MW-scale hydrogen production plants. The solar part was laid out with HFLCAL software. Two different scenarios were considered: the first concerns the production of 400 kg/d hydrogen corresponding to mobility use (fuel station). The second scenario deals with the production of 4000 kg/d hydrogen for industrial use. The process was analyzed from a thermodynamic point of view by calculating the overall process efficiency and determining the annual production. It was assumed that a fixed hydrogen demand exists in the two cases and it was assessed to which extent this can be supplied by the solar high temperature electrolysis process including thermal storage as well as hydrogen storage. For time periods with a potential over supply of hydrogen, it was considered that the excess energy is sold as electricity to the grid. For time periods where the hydrogen demand cannot be fully supplied, electricity consumption from the grid was considered. It was assessed which solar multiple is appropriate to achieve low consumption of grid electricity and low excess energy. It is shown that the consumption of grid electricity is reduced for increasing solar multiple but the efficiency is also reduced. At a solar multiple of 3.0 an annual solar-to-H₂ efficiency greater than 14% is achieved at grid electricity production below 5% for the industrial case (4000 kg/d). In a sensitivity study the paramount importance of electrolyser performance, i.e. efficiency and conversion, is shown.     

Solar multi-mode heating system based on latent heat thermal energy storage and its application

为克服太阳能间断性和不稳定性的缺点进而实现太阳能集热与采暖的能量供需调节和全天候连续供热,提出了基于相变储热的太阳能多模式采暖方法（太阳能集热直接采暖、太阳能集热采暖+相变储热、太阳能相变储热采暖）,并在西藏林芝市某建筑搭建了太阳能与相变储热相结合的采暖系统,该系统可根据太阳能集热温度和外界供热需求实现太阳能多模式采暖的自动控制和自动运行。实验研究表明：在西藏地区采用真空管太阳能集热器可以和中低温相变储热器很好地结合,白天储热器在储热过程中平均储热功率为10.63 kW,储热量达到92.67 kW·h,相变平台明显;晚上储热器在放热过程中供热量达85.23 kW·h,放热功率和放热温度平稳,储放热效率达92%,其储热密度是传统水箱的3.6倍,可连续供热时间长达10 h,从而实现了基于相变储热的太阳能全天候连续供热,相关研究结果对我国西藏地区实施太阳能采暖具有一定的指导作用。     

Design and analysis of a solar tower power plant integrated with thermal energy storage system for cogeneration

In the current study, a solar tower–based energy system integrated with a thermal energy storage option is offered to supply both the electricity and freshwater through distillation and reverse osmosis technologies. A high‐temperature thermal energy storage subsystem using molten salt is considered for the effective and efficient operation of the integrated system. The molten salt is heated up to 565°C through passing the solar tower. The thermal energy storage tanks are designed to store heat up to 12 hours. The temperature variations in the storage tanks are studied and compared accordingly for evaluation. The effect of operating temperatures on the freshwater production and overall system efficiency is determined. About 24.46 MW electricity is generated in the steam turbine under sunny conditions. Furthermore, the storage subsystem stores heat during sunny hours to utilize later in cloudy hours and night time. The produced power decreases to 20.17 MW in discharging hours due to temperature decrease in the tank. The electricity generated by the system is then used to produce freshwater through the reverse osmosis units and also to supply electricity for the residential use. A total flowrate of 240.02 kg/s freshwater is obtained by distillation and reverse osmosis subsystems.     

Thermo-environ study of a concentrated photovoltaic thermal system integrated with Kalina cycle for multigeneration and hydrogen production

Unlike steam and gas cycles, the Kalina cycle system can utilize low-grade heat to produce electricity with water-ammonia solution and other mixed working fluids with similar thermal properties. Concentrated photovoltaic thermal systems have proven to be a technology that can be used to maximize solar energy conversion and utilization. In this study, the integration of Kalina cycle with a concentrated photovoltaic thermal system for multigeneration and hydrogen production is investigated. The purpose of this research is to develop a system that can generate more electricity from a solar photovoltaic thermal/Kalina system hybridization while multigeneration and producing hydrogen. With this aim, two different system configurations are modeled and presented in this study to compare the performance of a concentrated photovoltaic thermal integrated multigeneration system with and without a Kalina system. The modeled systems will generate hot water, hydrogen, hot air, electricity, and cooling effect with photovoltaic cells, a Kalina cycle, a hot water tank, a proton exchange membrane electrolyzer, a single effect absorption system, and a hot air tank. The environmental benefit of two multigeneration systems modeled in terms of carbon emission reduction and fossil fuel savings is also studied. The energy and exergy efficiencies of the heliostat used in concentrating solar radiation onto the photovoltaic thermal system are 90% and 89.5% respectively, while the hydrogen production from the two multigeneration system configurations is 10.6 L/s. The concentrated photovoltaic thermal system has a 74% energy efficiency and 45.75% exergy efficiency, while the hot air production chamber has an 85% and 62.3% energy and exergy efficiencies, respectively. Results from this study showed that the overall energy efficiency of the multigeneration system increases from 68.73% to 70.08% with the integration of the Kalina system. Also, an additional 417 kW of electricity is produced with the integration of the Kalina system and this justifies the importance of the configuration. The production of hot air at the condensing stage of the photovoltaic thermal/Kalina hybrid system is integral to the overall performance of the system.     

Analysis of low temperature solar thermal electric generation using regenerative Organic Rankine Cycle

The innovative configuration of low temperature solar thermal electric generation with regenerative Organic Rankine Cycle (ORC) is designed, mainly consisting of small concentration ratio compound parabolic concentrators (CPC) and the regenerative ORC. Advantages of the innovative configuration such as effectively reducing heat transfer irreversibility and permitting the use of thermal storage with phase change materials (PCMs) are outlined. The numerical simulation of the heat transfer and power conversion processes are carried out based on distributed parameters. The effects of regenerative cycle on the collector, ORC, and overall electricity efficiency are then analyzed. The results indicate that the regenerative cycle has positive effects on the ORC efficiency but negative ones on the collector efficiency due to increment of the average working temperature of the first-stage collectors. Thus, it is necessary to evaluate the overall electricity efficiency when regenerative cycle is adopted. Further investigation shows that there are maximum efficiencies for both the ORC and the system electric generation on conditions of constant irradiance, evaporation temperature, and environment temperature. And the regenerative temperature at which the system electricity efficiency reaches its maximum is smaller than that at which the ORC efficiency reaches its maximum by 12–21 °C. Thus, the regenerative cycle optimization of the solar thermal electric generation differs from that of a solo ORC. The system electricity efficiency with regenerative ORC is about 8.6% for irradiance 750 W/m² and is relatively higher than that without the regenerative cycle by 4.9%.     

Life-cycle energy efficiency estimation of large-scale ammonia fuel energy storage system

本文讨论了氨作为燃料使用会具备与传统化石燃料显著不同的环境效益,并进一步探讨了氨作为储能介质的特点,包括储能密度和规模大、受地理条件约束小、便于运输存储等。本文还针对目前的合成氨路线从理论分析和工业实际两个方面对合成效率进行了估算和评价。针对目前国内核能、风能、太阳能等清洁能源电力的低谷或弃电问题,建议采用以制氨的方式存储或外运,以便于在电力不足时将其用于发电。建议并评估了几条基于制氨并发电的路线,并基于现有氨燃料的发电效率计算了各路线在全生命周期内的总储能效率（25%～40%）和以电换电的效率[2.5～4.0(度/10度）]。     

Simulation of high temperature thermal energy storage system based on coupled metal hydrides for solar driven steam power plants

Concentrating solar power plants can achieve low cost and efficient renewable electricity production if equipped with adequate thermal energy storage systems. Metal hydride based thermal energy storage systems are appealing candidates due to their demonstrated potential for very high volumetric energy densities, high exergetic efficiencies, and low costs. The feasibility and performance of a thermal energy storage system based on NaMgH₂F hydride paired with TiCr_1.6Mn_0.2 is examined, discussing its integration with a solar-driven ultra-supercritical steam power plant. The simulated storage system is based on a laboratory-scale experimental apparatus. It is analyzed using a detailed transport model accounting for the thermochemical hydrogen absorption and desorption reactions, including kinetics expressions adequate for the current metal hydride system. The results show that the proposed metal hydride pair can suitably be integrated with a high temperature steam power plant. The thermal energy storage system achieves output energy densities of 226 kWh/m³, 9 times the DOE SunShot target, with moderate temperature and pressure swings. In addition, simulations indicate that there is significant scope for performance improvement via heat-transfer enhancement strategies.     

一种新型太阳能冷库系统的模拟及实验研究

针对太阳能光伏发电技术、需求侧管理（DSM）技术和储能技术提出一种新型太阳能冷库系统。探讨利用冷能储存和光伏发电来减少和转移峰值电力需求、降低电力消耗成本的潜力。建立系统的仿真模型并通过实验进一步修正,结果表明系统在5—8月份基本可节约60%以上的电费,能源节约率最高可达48.38%,相应的电费支付最高可节省65.40%。     

Design and thermodynamic analysis of compressed air energy storage system

压缩空气储能技术具有提升风能与太阳能等可再生资源电能质量的潜力,通过此项技术实现间歇性与不稳定性可再生电力的有效储存,进而在电网负荷高峰期以优质电力的形式稳定输出.结合热力学分析方法设计了储能功率56.58 MW,释能输出功率154.76 MW的压缩空气储能系统.在释能阶段透平机组配置上,参照GE 9171E燃机布置第二级透平入口参数,并以其812.41 K高温烟气余热提供第一级透平工质所需全部热量,无需为第一级透平配备专门燃烧器.在此思路下设计的压缩空气储能系统,热耗可降低至3783.96 kJ/(kW·h),储能系统的能量转换效率也高达56.11%.     

Distributed dynamic modeling and experimental study of PV evaporator in a PV/T solar-assisted heat pump

A novel photovoltaic/thermal solar-assisted heat pump (PV/T-SAHP) system is described in this paper. A specially designed direct-expansion evaporator (PV evaporator), which is laminated with PV cells on the front surface of the thermal absorber, has been adopted in our system to acquire simultaneously thermal energy and electricity from solar radiation. A dynamic model of the PV evaporator based on the distributed parameter approach is also presented. Given the instantaneous solar irradiance and ambient temperature, the numerical model is able to output the spatial distributions of refrigerant conditions, including pressure, temperature, vapor quality and enthalpy. A two-dimensional temperature distribution of the evaporator body is also computed. Comparisons between the simulation results and the experimental measurements show that the model is able to give satisfactory predictions. The results show that high electrical and thermal performance can be achieved. The PV efficiency and thermal efficiency are above 12% and 50% during the testing period.     

Development and performance assessment of a novel solar-assisted multigenerational system using high temperature phase change material

Solar-assisted multi-generation systems are eco-friendly with exceptional thermal performance. In the present study, a novel solar-assisted multi-generational system is proposed and investigated for multiple outputs. The proposed system consists of solar tower with heliostat, combined cycle (topping is Brayton cycle, while bottoming is Rankine cycle with reheat and regeneration processes), single effect Lithium-Bromide/water absorption chiller, heat pump, water-based thermal energy storage system and an electrolyzer. The system is integrated with high temperature phase change material (PCM) based thermal storage system for the continuous system operation. The salt PCM KF-MgF₂ is selected from the literature having melting temperature of 1280 K with high density and latent heat of fusion. The storage system ensures the stable and continuous working of the system during off sun hours. The aim of the present study is to thermodynamically and exergo-environmentally investigate the performance of PCM based solar driven multi-generation system.The results of the study depict that energy efficiency of single and multi-generation system is approximately 20.93% and 51.62%, while exergy efficiency is almost 22.51% and 53.45%, respectively. Hydrogen production rate and exergetic sustainability index of the proposed system is approximately 0.00742 kg/s and 0.078, respectively. Energy efficiency of multigeneration system is approximately 15.9% and 61% higher than tri-generation and co-generation systems at concentration ratio of 1000. Exergo-environmental impact index decreases to almost 5% by increasing direct normal irradiation, while exergetic sustainability index and exergy stability factor are increased to 125% and 54.2%, accordingly. Finally, energy efficiency of the single generation and multi generation systems are optimized at 23.56% and 56.83%, respectively.     

基于动态运行策略的太阳能分布式供能系统设计运行联合优化

提出将光伏剩余电量按照可变比例分配给储能电池及市政电网的动态运行策略,建立基于该策略的并网太阳能分布式供能系统设计运行联合优化模型,在不同分时电价下基于遗传算法对模型寻优,并将动态运行策略与对照运行策略（剩余电量优先并网或优先分配储能电池）下的系统运行结果进行比较分析。以陕西某乡村典型民居建筑为例进行分析,结果表明：1）分时电价的峰谷价差较大时,动态运行策略可有效降低太阳能分布式供能系统成本;2）分时电价的峰谷价差对于动态运行策略下储能电池的容量配置具有较大影响：峰谷价差越大,储能电池的配置容量越大;3）光伏度电补贴对3种运行策略下的系统成本影响程度为：动态运行策略>策略B（剩余电量优先分配储能电池）>策略A（剩余电量优先并网）。     

Thermoeconomic analysis of a standalone solar hydrogen system with hybrid energy storage

A comprehensive thermoeconomic analysis is presented for a novel integrated solar hydrogen energy system for standalone operation. The proposed system includes a solar PVT module (photovoltaic thermal), a FC (Fuel cell) and a battery to meet the electrical load demand and domestic hot water over a year. The PVT component works as a primary energy source converting solar energy into electricity and heat. The excess electrical energy and hot water produced by PVT are consumed for producing hydrogen, which can be stored. The generated hydrogen is fed to the fuel cell to produce electricity and water to satisfy the demand. The proposed system is convenient for different seasons of the year because in all time, produced power satisfy the demand. The first and second laws of thermodynamics are used to evaluate the performance of each component and the overall system. Economic assessment of this system is also conducted considering the net present cost, and the system performance is optimized based on this parameter. The overall electrical efficiency of the system is obtained as 9% and the levelized cost of electricity is determined as $ 0.286/kWh. For a steady operation of system, integrating a battery system is convenient when solar energy is not available for a short term. When there is a longer-term shortage of solar radiation, up to 8 days, the electricity can be supplied by utilizing the hydrogen storage system.     

Modeling and analysis of energetic and exergetic efficiencies of a LiBr/H<Subscript>2</Subscript>0 absorption heat storage system for solar space heating in buildings

The development of efficient long-term heat storage systems could significantly increase the use of solar thermal energy for building heating. Among the different heat storage technologies, the absorption heat storage system seems promising for this application. To analyze the potential of this technology, a numerical model based on mass, species, energy, and exergy balances has been developed. The evolution over time of the storage imposes a transient approach. Simulations were performed considering temperature conditions close to those of a storage system used for space heating coupled to solar thermal collectors (as the heat source), with ground source heat exchangers (as the cold source). The transient behavior of the system was analyzed in both the charging and discharging phases. This analysis highlights the lowering of energetic and exergetic performance during both phases, and these phenomena are discussed. The thermal efficiency and the energy storage density of the system were determined, equal to 48.4 % and 263 MJ/m³, respectively. The exergetic efficiency is equal to 15.0 %, and the exergy destruction rate is 85.8 %. The key elements in terms of exergy destruction are the solution storage tank, the generator, and the absorber. The impact of using a solution heat exchanger (SHX) was studied. The risk of the solution crystallizing in the SHX was taken into account. With a SHX, the thermal efficiency of the system can reach 75 %, its storage density was 331 MJ/m³, and its exergetic efficiency and exergy destruction rate was 23.2 and 77.3 %, respectively.     

Calcium looping in solar power generation plants

The use of a calcium looping based process as a thermal storage and transportation system for concentrated solar power plants is proposed in this work. This system exploits the reversible calcination–carbonation reaction of limestone and lime. Concentrated solar heat is used to calcine CaCO₃, which is then released as required by carbonating the resulting CaO. The CaO/CaCO₃ system has a high energy density and its high temperature operation allows the use of a gas turbine for power production. This paper presents a first order evaluation of the potential of this application of calcium looping, with particular consideration given to carbonation activity of the sorbent. A model including a solar calciner and a pressurised fluidised bed carbonator feeding a gas turbine in an open Brayton cycle has been developed. Results from the model indicate that electric efficiencies of 40–50% could be achieved with sorbent carbonation activities between 15% and 40%. Higher sorbent activity levels do not affect efficiency but would lead to lower capital costs. According to the model, CaO activity levels above 17% lead to significant reductions in the required storage volume over existing systems, such as molten salts. In principle, high efficiency and smaller footprint solar thermal power plants are possible with calcium looping. Such plants would have no process use of water and could be used as baseload, variable demand load or microgrid systems.     

Hybrid photovoltaic/thermal solar systems

We present test results on hybrid solar systems, consisting of photovoltaic modules and thermal collectors (hybrid PV/T systems). The solar radiation increases the temperature of PV modules, resulting in a drop of their electrical efficiency. By proper circulation of a fluid with low inlet temperature, heat is extracted from the PV modules keeping the electrical efficiency at satisfactory values. The extracted thermal energy can be used in several ways, increasing the total energy output of the system. Hybrid PV/T systems can be applied mainly in buildings for the production of electricity and heat and are suitable for PV applications under high values of solar radiation and ambient temperature. Hybrid PV/T experimental models based on commercial PV modules of typical size are described and outdoor test results of the systems are presented and discussed. The results showed that PV cooling can increase the electrical efficiency of PV modules, increasing the total efficiency of the systems. Improvement of the system performance can be achieved by the use of an additional glazing to increase thermal output, a booster diffuse reflector to increase electrical and thermal output, or both, giving flexibility in system design.     

Optimising energy use in an existing commercial building: a case study of Australia’s Reef HQ Aquarium

Reef HQ Aquarium is a major tourism attraction in tropical North Queensland, Australia. In 8 years, a 50% reduction in grid electricity was achieved through targeted infrastructure investment, whilst growing the business. Initially, grid energy consumption was 2438 MWh per annum, with 490-kW peak demand and energy intensity of 1625 MJ m^?2 year^?1 used on typical equipment such as HVAC (heating, ventilation and air conditioning), machinery, lighting and catering equipment. Savings of 13% were achieved in the first year by increasing indoor air temperature set-points by 1.5 °C with no significant costs or impacts on occupant thermal comfort or worker productivity. Peak demand was decreased by 46% by upgrading the computerised building management system (BMS), HVAC, machinery and lighting; and by installing a 206-kW photovoltaic (PV) solar power system. This case study illustrates that (a) significant energy use reductions are possible at low cost; (b) capital investment in energy-efficient infrastructure can have short payback times and high direct and indirect benefits, particularly where equipment is ending its life. This study is unique as it examines how a commercial building with integrated chilled water thermal energy storage (TES) and a 3.2-ML chilled seawater aquarium system can be controlled by a BMS to optimise solar power to manage peak energy demand and also increase the utilisation of generated PV power in the absence of electrical battery storage. An interesting building is used to demonstrate efficiency methods with elements such as HVAC and lighting which usually consume over half commercial buildings’ energy use.