Hydrogen storage system based on hydride materials incorporating a helical-coil heat exchanger

Metal hydrides offer the potential to store hydrogen at modest pressures and temperatures with high volumetric efficiencies. The process of charging hydrogen into a metal powder to form the hydride is exothermic. The heat released by the reaction must be removed quickly in order to maintain a rapid charging rate. An effective method for heat removal is to embed a heat exchanger within the metal hydride bed. Here, we investigate the effectiveness of a helical coil heat exchanger tube to remove the heat generated during the absorption process. This paper presents a three-dimensional mathematical model formulated in Ansys Fluent 12.1 to evaluate the transient heat and mass transfer in a cylindrical metal hydride tank embedded with a helical-coil cooling tube. We present results from a parametric study of hydrogen storage efficiency as a function of helical coil pitch and convective heat transfer coefficient (h) within the cooling tube. We also explore the effect of adding aluminum foam to enhance the thermal conductivity of the metal hydride. The parametric study reveals that the mass of stored hydrogen is less sensitive to the coil pitch when aluminum foam is added. It is also found that the absorption rate increases with h as expected, although the rate of improvement diminishes at high values of h. Results were examined at filling times of 3 and 6 min to draw conclusions about the overall effectiveness of this hydrogen storage system. At 3 min, it is found that the addition of 5% Al foam is optimal, and h = 1000 W/m²-K is sufficient to bring the metal hydride to saturation; under these conditions a non-dimensional pitch of 0.5 maximizes the hydrogen absorption. Adding Al foam beyond 5% does not improve volumetric efficiency as the Al foam begins to displace the active hydrogen-absorbing material.     

Hydrogen absorption performance of a novel cylindrical MH reactor with combined loop-type finned tube and cooling jacket heat exchanger

A novel cylindrical metal hydride (MH) reactor with loop-type finned tube and jacket heat exchanger was proposed in this work. This MH reactor is expected to possess high performance due to the enhanced heat transfer, compact structure and good gas tightness. A three-dimensional multi-physical model for hydrogen absorption was presented to investigate the evolutions of temperature and concentration in the MH bed, as well as the mean reaction rate of hydrogen absorption process. The effects of different fin configurations on the performance of the proposed MH reactor were also examined. It was indicated that the evolution curve of the mean reaction rate for the whole hydrogen absorption process can be divided into two stages. The reaction rate in the first stage is mainly dependent on the initial conditions (i.e., temperature and gas pressure) of MH bed, whereas the second stage is mainly influenced by the heat dissipation from MH bed to cooling fluid. For the proposed MH reactor, the total charging time for reaching 90% hydrogen saturation can be decreased by 56.8% and 81.9% as compared with that for cylindrical MH reactor with finned double U-shape tube heat exchanger and cylindrical MH reactor with finned single-tube heat exchanger, respectively. Also, it was found that the interlaced layout design of inner and outer fins can improve the uniformity of the temperature distribution inside the MH bed as compared with the parallel layout configuration. Besides, it was showed that increasing the number of fins with keeping the total fin volume constant, the absorption performance of the reactor can be improved.     

Numerical evaluation and the effects of geometrical and operational parameters on thermal performance of the shell and double coil tube heat exchanger

Heat exchangers are extensively used in various industries. In this study, the impact of geometric and flow parameters on the performance of a shell and double helical coil heat exchanger is studied numerically. The investigated geometric parameters include external coil pitch, internal coil pitch, internal coil diameter, and coil diameter. The influences of considered geometrical parameters are analyzed on the output temperature of the hot and cold fluid, convective heat transfer coefficient, pressure drop, and average Nusselt number. Water is considered as working fluid in both shell and tube. As an innovation, double helical coils are used instead of one in the heat exchanger. To compare the obtained results accurately, in each section, the heat transfer area (coil outer surface) is kept constant in all models. The results show that the geometrical parameters of double helical coils significantly affect the heat transfer rate.     

Design and investigation of hydriding alloy based hydrogen storage reactor integrated with a pin fin tube heat exchanger

The reaction between metal hydride (MH) and hydrogen gas generates substantial amount of heat. It must be removed rapidly to sustain the reaction in the metal hydride hydrogen storage reactor. Previous studies indicate that the performance of the reactor can be improved by inserting an efficient heat exchanger design inside the metal hydride bed. In the present study, a cylindrical shaped metal hydride system containing LaNi₅, integrated with a finned tube heat exchanger assembly made of copper pin fins and tubes, is presented. A 3-D numerical model is formulated in COMSOL Multiphysics 4.4 to study the transient behavior of sorption process inside the reactor. Experimental data obtained from the literature is used to approve the legitimacy of the proposed model. Influence of various operating and geometric parameters on the total absorption time of the reactor has been investigated. It is found that hydrogen supply pressure is the most influencing factor to increase the absorption rate of hydrogen. Total absorption time of the reactor is found to be 636 s with maximum storage capacity of 1.4 wt% at the operating conditions of 15 bar H₂ gas supply pressure, heat transfer fluid temperature of 298 K and flow rate of 6.75 l/min.     

Enhancement of hydrogen charging in metal hydride-based storage systems using heat pipe

Heat transfer in metal hydride bed significantly affects the performance of metal hydride reactors (MHRs). Enhancing heat transfer within the reaction bed improves the hydriding rate. This study presents performance analysis in terms of storage capacity and time of three different cylindrical MHR configurations using storage media LaNi₅: a) reactor cooled with natural convection, b) reactor with a heat pipe on the central axis, c) reactor with finned heat pipe. This study shows the impact of using heat pipes and fins for enhancing heat transfer in MHRs at varying hydrogen supply pressures (2–15 bar). At any absorption temperature, hydrogen absorption rate and hydrogen storage capacity increase with the supply pressure. Results show that using a heat pipe improves hydrogen absorption rate. It was found that finned heat pipe has a significant effect on the hydrogen charge time, which reduced by approximately 75% at 10 bar hydrogen supply pressure.     

Condensation heat transfer and pressure drop of HFC-134a in a helically coiled concentric tube-in-tube heat exchanger

The two-phase heat transfer coefficient and pressure drop of pure HFC-134a condensing inside a smooth helically coiled concentric tube-in-tube heat exchanger are experimentally investigated. The test section is a 5.786 m long helically coiled double tube with refrigerant flowing in the inner tube and cooling water flowing in the annulus. The inner tube is made from smooth copper tubing of 9.52 mm outer diameter and 8.3 mm inner diameter. The outer tube is made from smooth copper tubing of 23.2 mm outer diameter and 21.2 mm inner diameter. The heat exchanger is fabricated by bending a straight copper double-concentric tube into a helical coil of six turns. The diameter of coil is 305 mm. The pitch of coil is 35 mm. The test runs are done at average saturation condensing temperatures ranging between 40 and 50 °C. The mass fluxes are between 400 and 800 kg m⁻² s⁻¹ and the heat fluxes are between 5 and 10 kW m⁻². The pressure drop across the test section is directly measured by a differential pressure transducer. The quality of the refrigerant in the test section is calculated using the temperature and pressure obtained from the experiment. The average heat transfer coefficient of the refrigerant is determined by applying an energy balance based on the energy rejected from the test section. The effects of heat flux, mass flux and, condensation temperature on the heat transfer coefficients and pressure drop are also discussed. It is found that the percentage increase of the average heat transfer coefficient and the pressure drop of the helically coiled concentric tube-in-tube heat exchanger, compared with that of the straight tube-in-tube heat exchanger, are in the range of 33–53% and 29–46%, respectively. New correlations for the condensation heat transfer coefficient and pressure drop are proposed for practical applications.     

Optimization of heat exchanger designs in metal hydride based hydrogen storage systems

Design of the heat exchanger in a metal hydride based hydrogen storage system influences the storage capacity, gravimetric hydrogen storage density, and refueling time for automotive on-board hydrogen storage systems. The choice of a storage bed design incorporating the heat exchanger and the corresponding geometrical design parameters is not obvious. A systematic study is presented to optimize the heat exchanger design using computational fluid dynamics (CFD) modeling. Three different shell and tube heat exchanger designs are chosen. In the first design, metal hydride is present in the shell and heat transfer fluid flows through straight parallel cooling tubes placed inside the bed. The cooling tubes are interconnected by conducting fins. In the second design, heat transfer fluid flows through helical tubes in the bed. The helical tube design permits use of a specific maximum distance between the metal hydride and the coolant for removing heat during refueling. In the third design, the metal hydride is present in the tubes and the fluid flows through the shell. An automated tool is generated using COMSOL-MATLAB integration to arrive at the optimal geometric parameters for each design type. Using sodium alanate as the reference storage material, the relative merits of each design are analyzed and a comparison of the gravimetric and volumetric hydrogen storage densities for the three designs is presented.     

Numerical Study of Solid State Hydrogen Storage System with Finned Tube Heat Exchanger

Abstract

Absorption of hydrogen gas inside the metal hydride (MH)-based hydrogen storage system generates significant amount of heat. This heat must be removed rapidly to improve the performance of the system which can be accomplished by embedding a heat exchanger inside the MH bed. In this article, a tubular shape MH system, equipped with a heat exchanger consisting of copper tube and pin fin is presented. A detailed 3D mathematical model is developed using COMSOL Multiphysics 4.3b for the numerical study of absorption and desorption processes inside the storage system. Impact of various operating and geometric parameters on the charging time of the storage system has been examined. It is observed that these geometric and operating parameters influence the charging time of the storage system. In the last, the impact of heat exchanger material on the performance of the storage system is explored. It is found that aluminum made heat exchanger is the best for the storage systems. The absorption process is accomplished in 1152?s at the operating parameters of 15?bar, 298 K, and 6.75 lit/min. This numerical work suggests that the efficient design of storage system is very important for rapid absorption and desorption of hydrogen.     

Thermal performance and pressure drop of the helical-coil heat exchangers with and without helically crimped fins

In the present study, the thermal performance and pressure drop of the helical-coil heat exchanger with and without helical crimped fins are studied. The heat exchanger consists of a shell and helically coiled tube unit with two different coil diameters. Each coil is fabricated by bending a 9.50 mm diameter straight copper tube into a helical-coil tube of thirteen turns. Cold and hot water are used as working fluids in shell side and tube side, respectively. The experiments are done at the cold and hot water mass flow rates ranging between 0.10 and 0.22 kg/s, and between 0.02 and 0.12 kg/s, respectively. The inlet temperatures of cold and hot water are between 15 and 25 °C, and between 35 and 45 °C, respectively. The cold water entering the heat exchanger at the outer channel flows across the helical tube and flows out at the inner channel. The hot water enters the heat exchanger at the inner helical-coil tube and flows along the helical tube. The effects of the inlet conditions of both working fluids flowing through the test section on the heat transfer characteristics are discussed.     

An experimental study of thermal performance of shell-and-coil heat exchangers

In the present study an experimental investigation of the mixed convection heat transfer in a coil-in-shell heat exchanger is reported for various Reynolds and Rayleigh numbers, various tube-to-coil diameter ratios and dimensionless coil pitch. The purpose of this article is to assess the influence of the tube diameter, coil pitch, shell-side and tube-side mass flow rate over the performance coefficient and modified effectiveness of vertical helical coiled tube heat exchangers. The calculations have been performed for the steady-state and the experiments were conducted for both laminar and turbulent flow inside coil. It was found that the mass flow rate of tube-side to shell-side ratio was effective on the axial temperature profiles of heat exchanger. The results also indicate that the ? − NTU relation of the mixed convection heat exchangers was the same as that of a pure counter-flow heat exchanger.     

Numerical investigation of hydrogen absorption in a stackable metal hydride reactor utilizing compartmentalization

In this paper, a three-dimensional model for hydrogen absorption in a metal alloy has been developed, validated against the experimental data in the literature, and then applied to a novel design for a hydrogen storage unit. The proposed design is similar to the fuel cell stack, but here the Membrane Electrode Assembly (MEA) has been replaced by a metal hydride (MH) reactor placed between the flow-field plates. These are stacked together to achieve the required amount of hydrogen storage. The flow-field plates have channels engraved on one side for hydrogen supply and on the other, for coolant/heating medium. It is known that the effectiveness of a hydrogen storage unit is directly related to its heat transfer area, and therefore, the choice of its geometry is very important. The larger the size, the more the resistance to heat transfer. Although, the internal tubular heat exchangers have proven to be effective in heat transfer, they pose severe challenges such as cooling/heating medium leakage due to tube erosion, stresses generated, etc. and they displace the active metal hydride from the tank. The present stacked MH reactor configuration helps to overcome these challenges by stacking small MH reactors together and there is no chance of the cooling/heating medium leaking into the metal hydride. Numerical simulations were performed to investigate the effect of coolant flow rate and percentage of flow-field plate rib area exposed to the MH reactor on temperature evolution and the amount of hydrogen stored. Further, a detailed study was carried out to understand the effect of compartmentalization of the MH reactor on temperature distribution. The results revealed that compartmentalization substantially helps to uniformly distribute the temperature in the metal bed, which is very important to maintain uniform utilization of the metal powder. Consequently, the uniform metal powder density for repeated absorption-desorption cycles without significant loss of its hydrogen storage capabilities.     

Bio-inspired leaf-vein type fins for performance enhancement of metal hydride reactors

Hydrogenation of metals is an exothermic and reversible process. Thus, metal hydride reactors/devices become essentially heat-driven. Excellent heat control in the MH reactor is required to develop metal hydride devices such as H2 storage systems successfully. Few attempts at nature-inspired designs have proven to have good heat transfer capabilities. Based on this idea, the present study investigates novel bio-inspired leaf-vein type fins for the metal hydride reactor. Two reactor designs are proposed for heat transfer fluid flow, namely (i) central straight tube and (ii) narrow trapezoidal channels with 10 kg of LaNi₅ as a sample alloy. Compared to longitudinal finned single tube reactors (LFSTR), these designs provided better heat transmission and temperature uniformity. For LFSTR, Case-1, and Case-2, 90% storage capacity was reached in 210, 145, and 80 s. Different fin configurations, such as parallel, inclined fins, and fins of different thicknesses, are investigated further in the design with narrow trapezoidal channels. The inclined fin configuration shows better performance, and it is further optimized by varying the inclination angle from 3 to 9° and the fin number from 2 to 4. The optimized design with a 7° inclination angle and four fins required 57 s to attain 90% storage capacity and reduced absorption time by 73% compared to LFSTR. The influence of operating parameters such as hydrogen supply pressure, inlet temperature, and velocity of the heat transfer fluid on the performance is evaluated for the optimized design.     

Heat transfer improvement in a tube by inserting perforated conical ring and wire coil as turbulators

In the present study, two various passive methods for heat transfer enhancement, including conical ring and wire coil are placed in a tube as turbulators. Four conical rings with four side holes are utilized with the same distance. The wire coil is employed at the center of the tube. The considered Reynolds numbers are between 4000 and 10,000. The studied geometrical parameters contain the pitch and diameter of a wire coil. Four different pitches of wire coil, including 10, 12, 14, and 16 mm, are evaluated. Furthermore, four values of wire coil diameter such as 2, 4, 6, and 8 mm are certain. The obtained numerical results displayed that by declining the pitch of a wire coil (37.5%), the average Nusselt number increases by about 143%. Also, augmentation in wire coil diameter by 300% leads to a growth in average Nusselt number by about 131%. Moreover, owing to utilizing two various turbulators, the pressure drop is significantly high in comparison with the bare tube. At Re = 10,000, growth in the inner diameter of the wire coil by 300% leads to an increase in thermal performance by about 36.12%. Moreover, as the pitch of the wire coil rises by 60%, the thermal performance declines by about 35.71%.     

Two-phase pressure drops in a helically coiled steam generator

An experimental investigation regarding two-phase diabatic pressure drops inside a helically coiled heat exchanger have been carried out at SIET thermo-hydraulics labs in Piacenza (Italy). The experimental campaign is part of a wide program of study of the IRIS innovative reactor steam generator. The test section consists of an AISI 316 stainless steel tube, 32 m length, 12.53 mm inner diameter, curved in helical shape with a bend radius of 0.5 m and a helix pitch of 0.8 m, resulting in a total height of the steam generator tube of 8 m. The explored operating conditions for two-phase flow experiences range from 192 to 824 kg/m² s for the mass flux, from 0 to 1 for the quality, from 1.1 to 6.3 MPa for the pressure, from 50 to 200 kW/m² for the heat fluxes. A frictional two-phase pressure drops correlation, based on an energy balance of the two-phase mixture and including the 940 experimental points, is proposed. Comparison with existing correlations shows the difficulty in predicting two-phase pressure drops in helical coil steam generators.     

Convective heat transfer in helical coils for constant-property and variable-property flows with high Reynolds numbers

Forced convection heat transfer of single-phase water in helical coils was experimentally studied. The testing section was constructed from a stainless steel round tube with an inner diameter of 10 mm, coil diameter of 300 mm, and pitch of 50 mm. The experiments were conducted over a wide Reynolds number range of 40000 to 500000. Both constant-property flows at normal pressure and variable-property flows at supercritical pressure were investigated. The contribution of secondary flow in the helical coil to heat transfer was gradually suppressed with increasing Reynolds number. Hence, heat transfer coefficients of the helical tube were close to those of the straight tube under the same flow conditions when the Reynolds number is large enough. Based on the experimental data, heat transfer correlations for both incompressible flows and supercritical fluid flows through helical coils were proposed.     

Performance analysis of a high-temperature magnesium hydride reactor tank with a helical coil heat exchanger for thermal storage

Metal hydrides are regarded as one of the most attractive options for thermal energy storage (TES) materials for concentrated solar thermal applications. Improved thermal performance of such systems is vitally determined by the effectiveness of heat exchange between the metal hydride and the heat transfer fluid (HTF). This paper presents a numerical study supported by experimental validation on a magnesium hydride reactor fitted with a helical coil heat exchanger for enhanced thermal performance. The model incorporates hydrogen absorption kinetics of ball-milled magnesium hydride, with titanium boride and expanded natural graphite additives obtained by Sievert's apparatus measurements and considers thermal diffusion within the reactor to the heat transfer fluid for a realistic representation of its operation. A detailed parametric analysis is carried out, and the outcomes are discussed, examining the ramifications of hydrogen supply pressure and its flow rate. The study identifies that the enhancement of thermal conductivity in magnesium hydride has an insignificant impact on current reactor performance.     

On the performance of a vertical helical coil heat exchanger. Numerical model and experimental validation

A numerical model was developed in order to predict the heat transfer process and pressure drop in a vertical helical coil heat exchanger (HCHE) located inside a fluid storage tank in which water is used as inner and outer fluid. Natural convection was considered as boundary condition for the HCHE outer surface. The model was validated with experimental data obtained from an own facility with two HCHEs tested under several operating conditions. The model developed was used to evaluate the main HCHE representative geometrical parameter's influence on the overall heat transfer coefficient and pressure drop. The results show that by increasing the tube diameter causes an increase of the Nusselt number and a larger heat transfer rate to pressure drop ratio is obtained.     

Hydrogen release from a metal hydride tank with phase change material jacket and coiled-tube heat exchanger

Hydrogen fuel cells are received increasingly wide attention in order to develop green ships and reduce greenhouse gas emissions in the field of waterway transportation. Metal hydrides (MHs) can be used to store hydrogen for green ships due to their high volumetric storage capacity and safety. Various measures should be considered in the design and manufacture process of the MH reactor to strengthen its performance of heat and mass transfer and obtain an acceptable hydrogen storage capacity. In this work, LaNi₅ hydride is used as the hydrogen storage material and packed in the reactor. A basic axisymmetric numerical model for the hydrogen storage system without a heat exchanger has been developed and proved to be effective through the comparison between its simulation results and the published data during dehydriding. A hybrid heat exchanger, which is consisted of a phase change material (PCM) jacket and a coiled-tube, has been applied into the hydrogen storage system to relieve the thermal effect of MH in the dehydriding process on system performance. Effects of the heat transfer coefficient between the circulating heating water in the coil-tube and the MH bed, the temperature of circulating heating water and the pressure at the outlet on the dehydriding performance have been investigated. Based on parametric study, the relationships among the average dehydriding rate, the heat transfer coefficient, the heating water temperature and the outlet pressure have been found and fitted as simple equations. These fitted equations can be considered as a reference, which provides an important method to effectively control the dehydriding rate in order to satisfy the fuel requirement of the power unit and ensure the safe navigation of green ships in the future.     

Heat transfer characteristics in a tube fitted with helical screw-tape with/without core-rod inserts

Effects of insertion of a helical screw-tape with or without core-rod in a concentric double tube heat exchanger on heat transfer and flow friction characteristics are experimentally investigated. The heat exchanger has the outer and the inner tube diameters of 50 mm (D_o) and 25 mm (D) where the cold and the hot waters used as the test fluids are in shell and tube sides, respectively. The stainless steel helical screw-tape has the geometrical dimensions of width (W) 17 mm with the clearance to the tube wall (D − W) / 2 = 4 mm. Thus, the insertion of the screw-tape in the tube is considered as a loose-fit. In the experiment, the loose-fit helical tape with or without core-rod, is inserted in the inner tube of the heat exchanger and the hot water enters the tube based on its Reynolds number in a range of 2000 to 12,000. The experimental results show that the increases in average Nusselt number of using the loose-fit, helical tape with and without core-rod are found to be 230% and 340%, respectively, over the corresponding plain tube. It is worth noting that for the loose-fit, helical tape without core-rod, the friction factor is around 50% less than that for the one with core-rod while the Nusselt number is about 50% higher. Furthermore, the enhancement efficiency of the helical screw-tapes varies between 1.00 and 1.17, 1.98 and 2.14, for the tapes with and without core-rod, respectively.     

Experimental analysis of hydrogen storage performance of a LaNi5–H2 reactor with phase change materials

Energy storage, especially thermal energy storage, has an important place in terms of efficient use of energy. Systems in which phase change materials (PCMs) are used are among the thermal energy storage (TES) options, thanks to their advantages such as energy storage at almost constant temperature. The use of PCM as a TES material in the metal hydride (MH) reactor is an influential method to store the heat released by the exothermic reaction occurring in the hydrogen charging process and to recover this heat with the endothermic reaction occurring in the hydrogen discharge process. In the present study, hydrogen charge and discharge processes in a LaNi₅–H₂ reactor were experimentally investigated and compared with and without PCM. Therefore, a hybrid system was designed by integrating PCM around the cylindrical MH reactor filled with LaNi₅ alloy. The hydration process was carried out at both constant pressure and variable pressure. The temperature changes on the reactor surface and inside the PCM were measured over time. In experiments to determine the change in the amount of hydrogen stored in MH reactors over time, it was determined that the hydrogen storage pressure and reactor design significantly affect the hydrogen charge-discharge rate. Considering the use of MH reactors in transportation vehicles such as automobiles and submarines, designing a hybrid MH-PCM storage system is promising for the development of hydrogen storage technologies and transportation technologies.