Economic analysis of a combined heat and power molten carbonate fuel cell system

Fuel cells can be attractive for use as stationary combined heat and power (CHP) systems. Molten carbonate fuel cell (MCFC) power plants are prime candidates for the utilization of fossil based fuels to generate high efficiency ultra clean power. However, fuel cells are considerably more expensive than comparable conventional technologies and therefore a careful analysis of the economics must be taken. This work presents analysis on the feasibility of installing both a FuelCell Energy DFC^® 1500MA and 300MA system for use at Adams Thermal Systems, a manufacturing facility in the U.S. Midwest. The paper examined thoroughly the economics driving the appropriateness of this measure. In addition, a parametric study was conducted to determine scenarios including variation in electric and natural gas rates along with reduced installation costs.     

Dynamic modeling and evaluation of solid oxide fuel cell - combined heat and power system operating strategies

Operating strategies of solid oxide fuel cell (SOFC) combined heat and power (CHP) systems are developed and evaluated from a utility, and end-user perspective using a fully integrated SOFC-CHP system dynamic model that resolves the physical states, thermal integration and overall efficiency of the system. The model can be modified for any SOFC-CHP system, but the present analysis is applied to a hotel in southern California based on measured electric and heating loads. Analysis indicates that combined heat and power systems can be operated to benefit both the end-users and the utility, providing more efficient electric generation as well as grid ancillary services, namely dispatchable urban power.Design and operating strategies considered in the paper include optimal sizing of the fuel cell, thermal energy storage to dispatch heat, and operating the fuel cell to provide flexible grid power. Analysis results indicate that with a 13.1% average increase in price-of-electricity (POE), the system can provide the grid with a 50% operating range of dispatchable urban power at an overall thermal efficiency of 80%. This grid-support operating mode increases the operational flexibility of the SOFC-CHP system, which may make the technology an important utility asset for accommodating the increased penetration of intermittent renewable power.     

Estimating the power and number of microturbines in small-scale combined heat and power systems

Utilizing the combined heat and power (CHP) systems to produce both electricity and heat is growing rapidly due to their high efficiency and low emissions in domestic, commercial, and industrial applications. In the first two categories among available drivers, due to the compact size and low weight, microturbines are attractive choice. In this paper, by using an energy–economic analysis the type and number of the required microturbines for the specific electricity and heat load curves during a year were selected. For performing this task an objective function annual profit (AP) was introduced and maximized. The operation strategy and the payback period of the chosen system was also determined in this study.     

Impact of heat,power and hydrogen generation on optimal placement and operation of fuel cell power plants

In this paper, a stochastic model is proposed for planning the location and operation of Fuel Cell Power Plants (FCPPs) as Combined Heat, power, and Hydrogen (CHPH) units. Total cost, emissions of FCPPs and substation, and voltage deviation are the objective functions to be minimized. Location and operation of FCPPs as CHPH are considered in this paper while their investment cost is not taken into account. In the proposed model, indeterminacy refers to electrical and thermal loads forecasting, pressure of oxygen and hydrogen, and the nominal temperature of FCPPs. In this method, scenarios are produced using roulette wheel mechanism and probability distribution function of input random variables. Using this method, the probabilistic problem is considered to be distributed as some scenarios and consequently probabilistic problem is considered as combination of some deterministic problems. Considering the nature of objective functions, the problem of locating and operating FCPPs as CHPH is considered as a mixed integer nonlinear problem. A Self Adaptive Charged System Search (SACSS) algorithm is employed for determining the best Pareto optimal set. Furthermore, a set of non-dominated solutions is saved in repository during simulation procedure. A 69-bus distributed system is used for verifying the beneficiary proposed method.     

Design of a combined heat,hydrogen, and power plant from university campus waste streams

This paper presents analysis of a combined heat, hydrogen, and power (CHHP) plant for waste-to-energy conversion in response to the 2012 Hydrogen Student Design Contest. Our team designed the CHHP plant centered on a molten carbonate fuel cell (Fuel Cell Energy DFC-1500) fueled by syngas derived primarily from an oxygen-fed municipal waste gasifier. Catalytic methanation and supplemental utility natural gas increase the fuel methane content to meet the DFC-1500 fueling requirements for maintaining stack thermal energy balance. Internal reforming converts excess fuel from the fuel cell to an H₂-rich stream, which is purified downstream in a pressure-swing adsorption system. The separated H₂ (1000 kg per day) is compressed for storage to provide fuel for a campus fleet of PEM fuel cell buses. The system provides more than 1.1 MWe for the campus grid with approximately 20% of the fuel cell power used for H₂ compression and running the plant. Heat recovery steam generators provide steam for the methanation reactor and 0.4 MW of thermal energy for district heating or steam turbine-driven chillers. Cost analysis indicates that the system requires incentives for economic viability with current estimated operating costs, but advances to reduce capital expenses of comparable urban waste-driven CHHP systems can make them attractive for future implementation.     

Economic and environmental assessment of phosphoric acid fuel cell-based combined heat and power system for an apartment complex

Economic and environmental potential of medium-scale combined heat and power (CHP) systems in the residential sector was assessed by introducing a 400 kW_el-scale phosphoric acid fuel cell (PAFC)-based CHP system into an apartment building in New York City. Simulation-based analyses were carried out under two different CHP operation strategies; electrical-load-following (ELF) and thermal-load-following (TLF). Technical and economic analyses indicated that ELF would be the appropriate operation mode for this CHP application. Economic analysis indicated that the CHP/ELF system operation could economically benefit users within 10 years under the present grid prices in New York City. However, because the CO₂ emission factor of the NY grid is very low (300 g/kWh), the CHP/ELF system operation would increase CO₂ emission. Achieving carbon neutrality in this application thus requires improvement in the utilization ratio of recovered heat.     

Integration of direct carbon and hydrogen fuel cells for highly efficient power generation from hydrocarbon fuels

In view of impending depletion of hydrocarbon fuel resources and their negative environmental impact, it is imperative to significantly increase the energy conversion efficiency of hydrocarbon-based power generation systems. The combination of a hydrocarbon decomposition reactor with a direct carbon and hydrogen fuel cells (FC) as a means for a significant increase in chemical-to-electrical energy conversion efficiency is discussed in this paper. The data on development and operation of a thermocatalytic hydrocarbon decomposition reactor and its coupling with a proton exchange membrane FC are presented. The analysis of the integrated power generating system including a hydrocarbon decomposition reactor, direct carbon and hydrogen FC using natural gas and propane as fuels is conducted. It was estimated that overall chemical-to-electrical energy conversion efficiency of the integrated system varied in the range of 49.4–82.5%, depending on the type of fuel and FC used, and CO₂ emission per kW_elh produced is less than half of that from conventional power generation sources.     

Energy and cost analysis of a solar-hydrogen combined heat and power system for remote power supply using a computer simulation

A simulation program, based on Visual Pascal, for sizing and techno-economic analysis of the performance of solar-hydrogen combined heat and power systems for remote applications is described. The accuracy of the submodels is checked by comparing the real performances of the system’s components obtained from experimental measurements with model outputs. The use of the heat generated by the PEM fuel cell, and any unused excess hydrogen, is investigated for hot water production or space heating while the solar-hydrogen system is supplying electricity. A 5 kWh daily demand profile and the solar radiation profile of Melbourne have been used in a case study to investigate the typical techno-economic characteristics of the system to supply a remote household. The simulation shows that by harnessing both thermal load and excess hydrogen it is possible to increase the average yearly energy efficiency of the fuel cell in the solar-hydrogen system from just below 40% up to about 80% in both heat and power generation (based on the high heating value of hydrogen). The fuel cell in the system is conventionally sized to meet the peak of the demand profile. However, an economic optimisation analysis illustrates that installing a larger fuel cell could lead to up to a 15% reduction in the unit cost of the electricity to an average of just below 90 c/kWh over the assessment period of 30 years. Further, for an economically optimal size of the fuel cell, nearly a half the yearly energy demand for hot water of the remote household could be supplied by heat recovery from the fuel cell and utilising unused hydrogen in the exit stream. Such a system could then complement a conventional solar water heating system by providing the boosting energy (usually in the order of 40% of the total) normally obtained from gas or electricity.     

Optimum generation capacities of micro combined heat and power systems in apartment complexes with varying numbers of apartment units

A dynamic simulation of micro combined heat and power (micro-CHP) systems that includes the transient behavior of the system was developed by modeling the generation of electricity and recovery of heat separately. Residential load profiles were calculated based on statistical reports from a Korean government agency, and were used as input data to select the optimum capacities of micro-CHP systems based on the number of apartment units being served, focusing on both economic and energetic criteria. The capacity of internal combustion engine (ICE) based micro-CHP was assumed to be in the range 1–500 kW, and the dependence of the efficiency of the generator unit on the capacity was included. It was found that the configuration (i.e., the capacity and number of generator units) that maximized the annual savings also had favorable energetic performance. Additionally, the statistical mode calculated from the annual electrical load distribution was verified as a suitable indicator when deciding the optimum capacity of a micro-CHP system.     

Electrolyzer-fuel cell combination for grid peak load management in a geothermal power plant: Power to hydrogen and hydrogen to power conversion

This study provides comprehensive energy, exergy, and economic evaluations and optimizations of a novel integrated fuel cell/geothermal-based energy system simultaneously generating cooling and electricity. The system is empowered by geothermal energy and the electricity is mainly produced by a dual organic cycle. A proton exchange membrane electrolyzer is employed to generate the oxygen and hydrogen consumed by a proton exchange membrane fuel cell utilized to support the network during consumption peak periods. This fuel cell can be also used for supplying the electricity demanded by the network to satisfy the loads at different times. All the simulations are conducted using Engineering Equation Solver software. To optimize the system, a multi-objective optimization method based on genetic algorithm is applied in MATLAB software. The objective functions are minimized cost rate and maximized exergy efficiency. The optimum values of exergy efficiency and cost rate are found to be 62.19% and 18.55$/h, respectively. Additionally, the results reveal that combining a fuel cell and an electrolyzer can be an effective solution when it comes to electricity consumption management during peak load and low load periods.     

Combined heat and power in the Swedish district heating sector—impact of green certificates and CO2 trading on new investments

Combined heat and power (CHP) has been identified by the EU administration as an important means of reducing CO₂-emissions and increasing the energy efficiency. In Sweden, only about one third of the demand for district heat (DH) is supplied from CHP. This share could be significantly larger if the profitability of CHP generation increased. The objective of this study was to analyse the extent to which the profitability for investments in new CHP plants in the Swedish DH sector have changed thanks to the recently implemented trading schemes for green certificates (TGCs) and CO₂ emissions (TEPs). The analysis was carried out using a simulation model of the Swedish DH sector in which the profitability of CHP investments for all DH systems, with and without the two trading schemes applied, is compared. In addition, a comparison was made of the changes in CHP generation, CO₂ emissions, and operation costs if investments are made in the CHP plant shown to be most profitable in each system according to the model. The study shows that the profitability of investments in CHP plants increased significantly with the introductions of TGC and TEP schemes. If all DH utilities also undertook their most profitable CHP investments, the results indicate a major increase in power generation which, in turn, would reduce the CO₂ emissions from the European power sector by up to 13 Mton/year, assuming that coal condensing power is displaced.     

Performance assessment of concentrated solar power plants based on carbon and hydrogen fuel cells

In spite of the recent success on the implementation of Concentrating Solar Power (CSP), still this technology needs a substantial enhancement to achieve competitiveness. This paper provides thorough insight after previous analyses on an alternative concept for higher efficiency CSP systems based on the replacement of the power block by an electrochemical conversion system. Concentrating solar energy is herewith used to decompose methane into hydrogen and carbon, which are used in hydrogen and carbon fuel cells for electricity generation. This approach envisages modular, efficient and flexible generation plants. Dispatchability can be achieved by storing the solid carbon. Solar-to-electricity efficiency was calculated assuming thermodynamic equilibrium composition and experimental data available from literature, and compared with those of conventional power generation systems and commercial CSP plants. It is concluded that this new-generation CSP concept is potentially able to produce power more efficiently than the current state-of-the art solar thermal power plants.     

Role of UV irradiated Nafion in power enhancement of hydrogen fuel cells

The influence of optimum UV ray exposure of pristine Nafion polymer membranes on the improvement of proton conductivity and hydrogen fuel cell performance has been examined. Nafion membranes with thickness 183  μm (117), 90  μm (1035), 50  μm (212) and 25  μm (211) were irradiated with ultraviolet rays with doses in the range 0–250 mJ cm^?2 and their proton conductivities have been measured with standard method. The Nafion membranes have also been studied by measuring their water uptake, swelling-ratios and porosity using standard procedures. Hydrogen fuel cells with dual serpentine microchannels with active area 1.9 x 1.6 cm^-2 were assembled with anode gas diffusion layer, Nafion membrane, cathode gas diffusion layer and other components. An external humidifier was used to humidify hydrogen for the fuel cell. The experimental Results have shown an increase in the value of Nafion proton conductivity with an optimum UV irradiation which depends on the thickness of Nafion membrane: the optimum doses for peak proton conductivity were 196mJ/cm^?2 for Nafion 117, 190mJ/cm^?2for Nafion 1035, 180mJ/cm^?2 for Nafion 212 and 160mJ/cm^?2 for Nafion 211. This enhancement of proton conductivity is because of the optimal photo-crosslinking of –SO₃H groups in Nafion. This causes optimum pore-size in Nafion thereby facilitating increased proton-hopping between –SO₃H sites in Nafion. Hydrogen fuel cells were developed with pristine as well as with optimal UV irradiated Nafion with thicknesses of 90 and 50  μm. The polarization plots obtained for these devices showed an increase in power densities approximately by a factor of 1.8–2.0 for devices with optimally UV irradiated Nafion. These results indicate that optimal UV irradiation of Nafion is an excellent technique for enhancing power output of hydrogen fuel cells.     

Optimization of diesel engine design for combined heat and power

Prime movers and boilers have traditionally been optimized independently to convert fuel to power and heat, respectively. the design of devices to optimize the simultaneous production of heat and power has been neglected. This paper considers the optimization in this mode of diesel engines and concludes that simple modifications of design could increase the heat recoverable in the exhaust by the equivalent of 10 per cent of the fuel input. In monetary terms this is equivalent to about a 4 per cent increase in brake efficiency, recent improvements in brake efficiency of this magnitude have taken ten or fifteen years of continuous research and development. the changes now proposed would increase thermal loading and some development might be necessary.     

An experimental investigation of a PEM fuel cell to supply both heat and power in a solar-hydrogen RAPS system

The potential for both heat and power extraction from a PEM fuel cell is investigated experimentally and using computer simulation to improve the economics of a solar-hydrogen system supplying energy to a remote household. The overall average energy efficiency of the fuel cell was measured to be about 70% by utilizing the heat generated for domestic water heating, compared to only 35-50% for electricity generation alone. The corresponding round-trip energy efficiency of the hydrogen storage sub-system (electrolyzer, storage tank, and fuel cell) was raised from about 34% in a power-only application to about 50% in combined heat and power (CHP) mode. The economic benefit of using the fuel cell heat for boosting an LPG hot water system over a 30-year assessment period is estimated to be equivalent to about 15% of the total capital cost of the solar-hydrogen system. The stoichiometry of the input air, and the fuel cell operating temperature, were found to influence significantly the overall performance of the solar-hydrogen CHP system.     

The effect of temperature on corrosion behavior of SS316L in the cathode environment of proton exchange membrane fuel cells

The effect of temperature on the corrosion behavior of SS316L in simulated proton exchange membrane fuel cell (PEMFC) environments has been systematically studied. Electrochemical methods, both potentiodynamic and potentiostatic, are employed to characterize the corrosion behavior. Atomic force microscope (AFM) is used to examine the surface morphology and X-ray photoelectron spectroscopy (XPS) analysis is used to identify the composition and the depth profile of the passive film. Photo-electrochemical (PEC) measurements are also performed to determinate the band gap energy of the passive film semiconductor. Interfacial contact resistances (ICR) between polarized SS316L and carbon paper are also measured. The experimental results show that corrosion resistance decreases with temperatures even though the thickness of passive film increases with temperature, at a given cell potential, the corrosion behavior of SS316L can be significantly different at different temperatures in PEMFC cathode environments, and the band gap of passive films decrease with temperature. The results also show that within the temperature range studied (25-90 °C), after different passivation time, the corrosion current densities of SS316L are all lower than the US DOE 2015 target value of 1 μA cm⁻², but the ICR between the carbon paper and polarized SS316L does not satisfy the US DOE 2015 target.     

An emerging market in fuel cells? Residential combined heat and power in four countries

Global concerns about fossil fuel stocks and security of supply have stimulated governments and industry to explore the development of alternative sources of energy. This has led to the emergence of liberalised markets for energy and the growth of de-centralised generation and distribution systems. Within this context, the use of a sustainable technology, such as fuel cells, as a generator of heat and electricity for the residential market, is a significant market opportunity. Using a set of framework conditions to explain the diffusion of renewable energy technologies, this paper analyses recent developments in four leading industrial countries, and concludes that Japan and Germany are competing to be the lead country for the introduction of this technology. In the process, we highlight the impact of government and the extent to which the development of a fuel cell industry is being driven by incumbent large firms acting independently or in collaboration with a range of other companies across the value chain.     

How to analyse and maximise the forest fuel supply availability to power plants in Eastern Finland

The annual use of forest fuels has grown rapidly in Finland during the 21st century. In 2007 the annual use was 5.3 TWh (firewood use excluded), whereas the targeted growth by the year 2010 is 10.6 TWh, i.e. some 5 million m³. The purpose of this work was to evaluate the maximum availability of forest fuels to CHP plants in Eastern Finland. The total availability to the selected CHP plant population was 7 TWh at the maximum transport distance of 100 km. The main share came from logging residues, 3.3 TWh, and the rest from stumps, 1.8 TWh, and small diameter energy wood, 1.9 TWh. The highest plant-specific availability reached the level of 1.7-1.8 TWh, but the overlapping procurement areas reduced the availability for most plants to a level less than 1 TWh. In all plant sites peat fuel could be partially compensated with forest fuels according to availability, but not completely due to the boiler technology. Increasing the targeted national forest fuel use presupposes the use of new logistics supply solutions, such as other transport modes and regional buffer storage networks. This makes it possible to widen the traditional procurement area-based on truck transportation, which is less than 60 km because of a dense plant network.     

Water transport in polymer electrolyte membrane fuel cells

Polymer electrolyte membrane fuel cell (PEMFC) has been recognized as a promising zero-emission power source for portable, mobile and stationary applications. To simultaneously ensure high membrane proton conductivity and sufficient reactant delivery to reaction sites, water management has become one of the most important issues for PEMFC commercialization, and proper water management requires good understanding of water transport in different components of PEMFC. In this paper, previous researches related to water transport in PEMFC are comprehensively reviewed. The state and transport mechanism of water in different components are elaborated in detail. Based on the literature review, it is found that experimental techniques have been developed to predict distributions of water, gas species, temperature and other parameters in PEMFC. However, difficulties still remain for simultaneous measurements of multiple parameters, and the cell and system design modifications required by measurements need to be minimized. Previous modeling work on water transport in PEMFC involves developing rule-based and first-principle-based models, and first-principle-based models involve multi-scale methods from atomistic to full cell levels. Different models have been adopted for different purposes and they all together can provide a comprehensive view of water transport in PEMFC. With the development of computational power, application of lower length scale methods to higher length scales for more accurate and comprehensive results is feasible in the future. Researches related to cold start (startup from subzero temperatures) and high temperature PEMFC (HT-PEMFC) (operating at the temperatures higher than 100 °C) are also reviewed. Ice formation that hinders reactant delivery and damages cell materials is the major issue for PEMFC cold start, and enhancing water absorption by membrane electrolyte and external heating have been identified as the most effective ways to reduce ice formation and accelerate temperature increment. HT-PEMFC that can operate without liquid water formation and membrane hydration greatly simplifies water management strategy, and promising performance of HT-PEMFC has been demonstrated.     

Exergoeconomic analysis and optimization of combined heat and power production: A review

Exergoeconomics is also called thermoeconomics, and thermoeconomic analysis methodologies combine economic and thermodynamic analysis by applying the cost concept to exergy which accounts for the quality of energy. The main concept of thermoeconomics is the exergetic cost and it deals with cost accounting methods. This paper is a review on the exergoeconomic analysis and optimization of combined heat and power production (CHPP). A brief historical overview on the exergoeconomics analysis and optimization is given. The concept of exergetic cost and cost accounting methods are discussed. An application of relevant formulation is given using a diesel engine powered cogeneration system as an example. Main thermoeconomic methodologies available in literature are described and their advantages and disadvantages with respect to one another are compared and discussed through a well-known problem, namely CGAM. Important studies on thermoeconomic analysis and optimization of combined heat and power production are listed based on the methodology used and the type of system considered.