Characterization of flooding and two-phase flow in polymer electrolyte membrane fuel cell stacks

A partially flooded gas diffusion layer (GDL) model is proposed and solved simultaneously with a stack flow network model to estimate the operating conditions under which water flooding could be initiated in a polymer electrolyte membrane (PEM) fuel cell stack. The models were applied to the cathode side of a stack, which is more sensitive to the inception of GDL flooding and/or flow channel two-phase flow. The model can predict the stack performance in terms of pressure, species concentrations, GDL flooding and quality distributions in the flow fields as well as the geometrical specifications of the PEM fuel cell stack. The simulation results have revealed that under certain operating conditions, the GDL is fully flooded and the quality is lower than one for parts of the stack flow fields. Effects of current density, operating pressure, and level of inlet humidity on flooding are investigated.     

Effects of gas diffusion layer deformation on the transport phenomena and performance of PEM fuel cells with interdigitated flow fields

In this study, a three-dimensional, non-isothermal, two-phase flow mathematical model is developed and applied to investigate the effect of the GDL deformation on transport phenomena and performance of proton exchange membrane (PEM) fuel cells with interdigitated flow fields. The thickness and porosity of the GDL is decreased after compression, and the corresponding transport parameters (permeability, mass diffusivity, thermal conductivity and electrical conductivity) are affected significantly. The alterations in geometry and transport parameters of the GDL are considered in the mathematical model. The oxygen concentration, temperature, liquid water saturation and volumetric current density distributions of PEM fuel cells without compression are investigated and then compared to the PEM fuel cells with various assembly forces. The numerical results show that the cell performance is considerably improved with increasing assembly forces. However, the pressure drops in the gas flow channels are also substantially increased. It is concluded that the assembly force should be as small as possible to decrease the parasitic losses with consideration of gas sealing concern.     

Efficient hydrogen production from aqueous methanol in a PEM electrolyzer with porous metal flow field: Influence of PTFE treatment of the anode gas diffusion layer

In a proton exchange membrane (PEM) methanol electrolyzer, the even supply of reactant to and the smooth removal of carbon dioxide from the anode are very important in order to achieve a high hydrogen production performance. An appropriate design of flow field and gas diffusion layer (GDL) is a key factor in satisfying the above requirements. Previous research has shown that hydrogen production performance of the PEM methanol electrolyzer cell was largely improved with a porous flow field made of sintered spherical metal powder compared with a conventional groove type flow field. Based on this improvement, the current study investigated the influence of polytetrafluoroethylene (PTFE) treatment of the anode GDL on hydrogen production performance of the PEM methanol electrolyzer with porous metal flow fields. Influences of operating conditions such as methanol concentration and cell temperature with the flow field were also investigated.     

Effect of gas diffusion layer compression on PEM fuel cell performance

The gas diffusion layer (GDL) plays a very important role in the performance of Proton Exchange Membrane (PEM) fuel cells. The amount of compression on the GDL affects the contact resistance, the GDL porosity, and the fraction of the pores occupied by liquid water, which, in turn, affect the performance of a PEM fuel cell. In order to study the effects of GDL compression on fuel cell performance a unique fuel cell test fixture was designed and created such that, without disassembling the fuel cell, varying the compression of the GDL can be achieved both precisely and uniformly. Besides, the compression can be precisely measured and easily read out. Using this special fuel cell fixture, the effects of GDL compression on PEM fuel cell performance under various anode and cathode flow rates were studied. Two different GDL materials, carbon cloth double-sided ELAT and TORAY™ carbon fiber paper were used in these studies. The experimental results show that generally the fuel cell performance decreases with the increase in compression and over-compression probably exists in most fuel cells. In the low current density region, generally there exists an optimal compression ratio.     

Analysis of transient response of a unit proton-exchange membrane fuel cell with a degraded gas diffusion layer

The transient response characteristics and durability problems of proton-exchange membrane fuel cells are important issues for the application of PEM fuel cells to automotive systems. The gas diffusion layer is the key component of the fuel cell because it directly influences the mass transport mechanism. In this study, the effects of GDL degradation on the transient response of the PEM fuel cell are systematically studied using transient response analysis under different stoichiometric ratios and humidity conditions. With GDLs aged by the accelerated stress test, the effects of hydrophobicity and structural changes due to carbon loss in the GDL on the transient response of PEM fuel cells are determined. The cell voltage is measured according to the sudden current density change. The degraded GDLs that had uneven hydrophobicity distributions cause local water flooding inside the GDL and induce lower and unstable voltage responses after load changes.     

A numerical study of flow crossover between adjacent flow channels in a proton exchange membrane fuel cell with serpentine flow field

The focus of this paper is to study the flow crossover between two adjacent flow channels in a proton exchange membrane (PEM) fuel cell with serpentine flow field design in bipolar plates. The effect of gas diffusion layer (GDL) deformation on the flow crossover due to the compression in a fuel cell assembly process is particularly investigated. A three-dimensional structural mechanics model is created to study the GDL deformation under the assembly compression. A three-dimensional PEM fuel cell numerical model is developed in the aforementioned deformed domain to study the flow crossover between the adjacent channels in the presence of the GDL intrusion. The models are solved in COMSOL Multiphysics—a finite element-based commercial software package. The pressure, velocity, oxygen mass fraction and local current density distribution are presented. A parametric study is conducted to quantitatively investigate the effect of the GDL’s transport related parameters such as porosity and permeability on the flow crossover between the adjacent flow channels. The polarization curves are also examined with and without the assembly compression considered. It is found that the compression effect is evident in the high current density region. Without considering the assembly compression, the fuel cell model tends to over-predict the fuel cell’s performance. The proposed method to simulate the crossover with the deformed computational domain is more accurate in predicting the overall performance.     

Measurement of the water transport rate in a proton exchange membrane fuel cell and the influence of the gas diffusion layer

Water management in a PEM fuel cell significantly affects the fuel cell performance and durability. The gas diffusion layer (GDL) of a PEM fuel cell plays a critical role in the water management process. In this short communication, we report a simple method to measure the water transport rate across the GDL. Water rejection rates across a GDL at different cathode air-flow rates were measured. Based on the measurement results, the fuel cell operating conditions, such as current density, temperature, air stoichiometry and relative humidity, corresponding to membrane drying and flooding conditions were identified for the particular GDL used. This method can help researchers develop GDLs for a particular fuel cell design with specific operating conditions and optimize the operation conditions for the given PEM fuel cell components.     

Three‐dimensional optimisation of a fuel gas channel of a proton exchange membrane fuel cell for maximum current density

Proton exchange membrane (PEM) fuel cells operated with hydrogen and air offer promising alternative to conventional fossil fuel sources for transport and stationary applications because of its high efficiency, low‐temperature operation, high power density, fast start‐up and potable power for mobile application. Power levels derivable from this class of fuel cell depend on the operating parameters. In this study, a three‐dimensional numerical optimisation of the effect of operating and design parameters of PEM fuel cell performance was developed. The model computational domain includes an anode flow channel, membrane electrode assembly and a cathode flow channel. The continuity, momentum, energy and species conservation equations describing the flow and species transport of the gas mixture in the coupled gas channels and the electrodes were numerically solved using a computational fluid dynamics code. The effects of several key parameters, including channel geometries (width and depth), flow orientation and gas diffusion layer (GDL) porosity on performance and species distribution in a typical fuel cell system have been studied. Numerical results of the effect of flow rate and GDL porosity on the flow channel optimal configurations for PEM fuel cell are reported. Simulations were carried out ranging from 0.6 to 1.6 mm for channel width, 0.5 to 3.0 mm for channel depth and 0.1 to 0.7 for the GDL porosity. Results were evaluated at 0.3 V operating cell voltage of the PEM fuel cell. The optimisation results show that the optimum dimension values for channel depth and channel width are 2.0 and 1.2 mm, respectively. In addition, the results indicate that effective design of fuel gas channel in combination with the reactant species flow rate and GDL porosity enhances the performance of the fuel cell. The numerical results computed agree well with experimental data in the literature. Consequently, the results obtained provide useful information for improving the design of fuel cells. Copyright © 2011 John Wiley & Sons, Ltd.     

Novel gas distributors and optimization for high power density in fuel cells

A novel gas distributor for fuel cells is proposed. It has three-dimensional current-collecting elements distributed in gas-delivery fields for effective current collection and heat/mass transfer enhancement. An analysis model has been developed in order to understand the performance of the output power density when the dimensions and distributive arrangement of the current collectors are different. Optimization analysis for a planar-type SOFC was conducted in order to outline the approach in optimizing a gas-delivery field when adopting three-dimensional current-collecting elements in a fuel cell. Experimental test of a proton exchange membrane (PEM) fuel cell adopting the novel gas distributor was conducted for verification of the new approach. Significant improvement of power output was obtained for the proposed new PEM fuel cells compared to the conventional ones under the same conditions except for the different gas distributors. Both the experimental results and modeling analysis are of great significance to the design of fuel cells of high power density.     

Numerical evaluation of a PEM fuel cell with conventional flow fields adapted to tubular plates

In this research a 3D numerical study on a PEM fuel cell model with tubular plates is presented. The study is focused on the performance evaluation of three flow fields with cylindrical geometry (serpentine, interdigitated and straight channels) in a fuel cell. These designs are proposed not only with the aim to reduce the pressure losses that conventional designs exhibit with rectangular flow fields but also to improve the mass transport processes that take place in the fuel cell cathode. A commercial computational fluid dynamics (CFD) code was used to solve the numerical model. From the numerical solution of the fluid mechanics equations and the electrochemical model of Butler-Volmer different analysis of pressure losses, species concentration, current density, temperature and ionic conductivity were carried out. The results were obtained at the flow channels and the catalyst layers as well as in the gas diffusion layers and the membrane interfaces. Numerical results showed that cylindrical channel configurations reduced the pressure losses in the cell due to the gradual reduction of the angle at the flow path and the twist of the channel, thus facilitating the expulsion of liquid water from the gas diffusion layers and in turn promoting a high oxygen concentration at the triple phase boundary of the catalyst layers. Moreover, numerical results were compared to polarization curves and the literature data reported for similar designs. These results demonstrated that conventional flow field designs applied to conventional tubular plates have some advantages over the rectangular designs, such as uniform pressure and current density distributions among others, therefore they could be considered for fuel cell designs in portable applications.     

Computational model of a PEM fuel cell with serpentine gas flow channels

A three-dimensional computational fluid dynamics model of a PEM fuel cell with serpentine flow field channels is presented in this paper. This comprehensive model accounts for the major transport phenomena in a PEM fuel cell: convective and diffusive heat and mass transfer, electrode kinetics, and potential fields. A unique feature of the model is the implementation of a voltage-to-current (VTC) algorithm that solves for the potential fields and allows for the computation of the local activation overpotential. The coupling of the local activation overpotential distribution and reactant concentration makes it possible to predict the local current density distribution more accurately. The simulation results reveal current distribution patterns that are significantly different from those obtained in studies assuming constant surface overpotential. Whereas the predicted distributions at high load show current density maxima under the gas channel area, low load simulations exhibit local current maxima under the collector plate land areas.     

A novel technique for measuring current distributions in PEM fuel cells

A novel and simple technique was developed to measure current distribution in PEM fuel cells with serpentine flow fields. In this technique, a specially designed measuring gasket was inserted between the flow field plate and the gas diffusion layer, and the current at each sub-area of the fuel cell was measured by each of the current collecting strips on the measuring gasket. The current distribution measurement gasket was independent of PEM fuel cells, and can be used in any fuel cell without the need of a special fuel cell or modification of any component of an existing fuel cell. More importantly, this technique can be easily used to measure current density distribution in any cell or every cell in a fuel cell stack. In addition, this technique is very inexpensive, with the only additional cost being that of the measuring gasket. In this work, this measurement gasket technique was used to study the influences of humidification temperatures, cell operating temperatures, reactant flow rates, and operating pressures on current distributions in a PEM fuel cell. Local membrane hydration, reactant depletion and possible cathode flooding can be deduced from the measurement results, and some potential improvements in fuel cell designs are suggested.     

Effects of electrode wettabilities on liquid water behaviours in PEM fuel cell cathode

Liquid water transport is one of the key challenges for water management in a proton exchange membrane (PEM) fuel cell. Investigation of the air–water flow patterns inside fuel cell gas flow channels with gas diffusion layer (GDL) would provide valuable information that could be used in fuel cell design and optimization. This paper presents numerical investigations of air–water flow across an innovative GDL with catalyst layer and serpentine channel on PEM fuel cell cathode by use of a commercial Computational Fluid Dynamics (CFD) software package FLUENT. Different static contact angles (hydrophilic or hydrophobic) were applied to the electrode (GDL and catalyst layer). The results showed that different wettabilities of cathode electrode could affect liquid water flow patterns significantly, thus influencing on the performance of PEM fuel cells. The detailed flow patterns of liquid water were shown, several gas flow problems were observed, and some useful suggestions were given through investigating the flow patterns.     

Humidity of reactant fuel on the cell performance of PEM fuel cell with baffle-blocked flow field designs

The objective of this work is to examine the effects of humidity of reactant fuel at the inlet on the detailed gas transport and cell performance of the PEM fuel cell with baffle-blocked flow field designs. It is expected that, due to the water management problem, the effects of inlet humidity of reactant fuel gases on both anode and cathode sides on the cell performance are considerable. In addition, the effects of baffle numbers on the detailed transport phenomena of the PEM fuel cell with baffle-blocked flow field are examined. Due to the blockage effects in the presence of the baffles, more fuel gas in the flow channel can be forced into the gas diffuser layer (GDL) and catalyst layer (CL) to enhance the chemical reactions and then augment the performance of the PEMFC systems. Effect of liquid water formation on the reactant gas transport is taken into account in the numerical modeling. Predictions show that the local transport of the reactant gas, the local current density generation and the cell performance can be enhanced by the presence of the baffles. Physical interpretation for the difference in the inlet relative humidity (RH) effects at high and low operating voltages is presented. Results reveal that, at low voltage conditions, the liquid water effect is especially significant and should be considered in the modeling. The cell performance can be enhanced at a higher inlet relative humidity, by which the occurrence of the mass transport loss can be delayed with the limiting current density raised considerably.     

Liquid water visualization in PEM fuel cells: A review

Over the past few years, the importance of water management to the successful operation of polymer electrolyte membrane (PEM) fuel cells has stimulated an extensive research focus on liquid water transport and its effect on performance and durability. Empirical methods employed to investigate water transport in the fuel cell have the potential to provide useful feedback for developing empirical correlations and validating numerical models for fuel cell research and development. In this paper, a literature review is provided for the experimental techniques that have been applied to visualize liquid water in operating hydrogen PEM fuel cells and flow fields. The main hypotheses that have been proposed to describe liquid water transport in the gas diffusion layer (GDL) and current challenges will also be discussed.     

Effects of assembling method and force on the performance of proton-exchange membrane fuel cells with metal foam flow field

Recently, highly porous metal foams have been used to replace the traditional open-flow channels to improve gas transport and distribution in the cells. Deformation of flow plate, gas diffusion layer (GDL), and metal foam may occur during assembling. When the cell size is small, the deformation may not be significant. For large area cells, the deformation may become significant to affect the cell performance. In this study, an assembling device that is capable of applying uniform clamping force is built to facilitate fuel cell assembling and alleviate the deformation. A compressing plate that is the same size of the active area is used to apply uniform clamping force before surrounding bolts are fastened. Therefore, bending of the flow plate and deformation of GDL and metal foam can be minimized. Effects of the clamping force on the microstructures of GDL and metal foam, various resistances, pressure drops, and cell performance are investigated. Distribution of the contact pressure between metal foam and GDL is measured by using pressure sensitive films. Field-emission scanning electron microscope is used to observe the microstructures. Electrochemical impedance spectroscopy analysis is used measure resistances. The fuel cell performance is measured by using a fuel cell test system. For the cell design used in this study, the optimum clamping force is found to be 200 kgf. Using this optimum clamping force, the cell performance can be enhanced by 50%, as compared with that of the cell assembled without using clamping plates. With appropriate clamping force, the compression force distribution across the entire cell area can approach uniform. This enables uniform flow distribution and reduces mass transfer resistance. Good contact between GDL and metal foam also lowers the interface resistance. All these factors contribute to the enhanced cell performance.     

Effect of the micro porous layer design on the dynamic performance of a proton exchange membrane fuel cell

The mass transport characteristics of a gas diffusion layer (GDL) predominantly affect the performance of a proton exchange membrane (PEM) fuel cell. However, studies examining the transient response related to the GDL are insufficient, although the dynamic behavior of a PEM fuel cell is an important issue. In this study, the effects of the design of a micro porous layer (MPL) on the transient response of a PEM fuel cell are investigated. The MPL slurry density and multiple functional layers are treated as the variable design parameter. The results show that the transient response is determined by the capillary pressure gradient through the GDL. The trade-off relation for the PEM fuel cell performance under low and high humidity conditions due to the hydrophobic GDL is mitigated by designing a reverse capillary pressure gradient in the MPL.     

The effects of porosity distribution variation on PEM fuel cell performance

Gas diffusion layers (GDL) are one of the important parts of the PEM fuel cell as they serve to transport the reactant gases to the catalyst layer. Porosity of this layer has a large effect on the PEM fuel cell performance. The spatial variation in porosity arises due to two effects: (1) compression of the electrode on the solid landing areas and (2) water produced at the cathode side of gas diffusion layers. Both of these factors change the porosity of gas diffusion layers and affect the fuel cell performance. To implement this performance analysis, a mathematical model which considers oxygen and hydrogen mass fraction in gas diffusion layer and the electrical current density in the catalyst layer, and the fuel cell potentials are investigated. The porosity variation in the GDL is calculated by considering the applied pressure and the amount of the water generated in the cell. The validity of the model is approved by comparing the computed results with experimental data. The obtained results show that the decrease in the average porosity causes the reduction in oxygen consumption, so that a lower electrical current density is generated. It is also shown that when the electrical current density is low, the porosity variation in gas diffusion layer has no significant influence on the level of polarization whereas at higher current density the influence is very significant. The porosity variation causes non-uniformity in the mass transport which in turn reduces the current density and a lower fuel cell performance is obtained.     

X-ray tomography and modelling study on the mechanical behaviour and performance of metal foam flow-fields for polymer electrolyte fuel cells

Porous metal foams have been used as alternative flow-fields in proton exchange membrane fuel cells (PEMFCs), exhibiting improved performance compared to conventional ‘land and channel’ designs. In the current work, the mechanical behaviour of PEMFCs using metal foam flow-fields is investigated across different length scales using a combination of electrochemical testing, X-ray computed tomography (CT), compression tests, and finite element analysis (FEA) numerical modelling.Fuel cell peak power was seen to improve by 42% when foam compression was increased from 20% to 70% due to a reduction in the interfacial contact resistance between the foam and GDL. X-ray CT scans at varying compression levels reveal high levels of interaction between the metal foam and gas diffusion layer (GDL), with foam ligaments penetrating over 50% of the GDL thickness under 25% cell compression. The interfacial contact area between the foam and GDL were seen to be 10 times higher than between the foam and a stainless-steel plate. Modelling results demonstrate highly uniform contact pressure distribution across the cell due to plastic deformation of the foam. The effect of stack over-tightening and operating conditions are investigated, demonstrating only small changes in load distribution when paired with a suitable sealing gasket material.