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丙烯酸类单体改性水性聚氨酯的研究进展 总被引:7,自引:1,他引:7
对丙烯酸类单体改性水性聚氨酯的各种方法进行了归纳分类,主要介绍了对水性聚氨酯膜改性的接枝改性法及对水性聚氨酯乳液改性的物理共混法、嵌段共聚法、核-壳乳液共聚法和互穿聚合物网络聚合法. 相似文献
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H. Y. Mostafa Ahmed I. Hussain Ahmed M. EL-Masry 《Polymer-Plastics Technology and Engineering》2017,56(4):411-420
A new core–shell structure of polymethyl methacrylate/butyl acrylate copolymer/vinyl silica nanocomposite was successfully prepared in aqueous solution through seed emulsion polymerization. Vinyl-functionalized silica nanoparticles were synthesized using sol–gel technique of triethoxyvinylsilane in aqueous solution. New established covalent bond between the vinyl groups located on the surface of vinyl-functionalized silica nanoparticles and vinyl group of monomers and the encapsulation into methyl methacrylate/butyl acrylate copolymer through seed emulsion polymerization process. The prepared core–shell latex polymers were characterized by Fourier transform infrared, UV–vis, thermal analyses, tensile strength, elongation at break, field emission scanning electron microscope, transmission electron microscope, and zeta potential. The tensile strength improved by introducing vinyl silica into the matrix up to 5%, which proved the reinforcing role of vinyl silica in the matrix of polymer. 相似文献
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采用种子乳液法制备了核壳型聚丙烯酸酯(ACR),并分别采用十二烷基硫醇和正辛基硫醇作为链转移剂对 ACR壳层的聚甲基丙烯酸甲酯(PMMA)进行相对分子质量调节,并用于PVC共混改性。黏度法对PMMA的相对分子质量测定表明,正辛基硫醇的相对分子质量调节能力较强。采用差示扫描量热分析测定PMMA的玻璃化转变温度(Tg),并对共混树脂进行动态力学性能测试。当ACR壳层PMMA平均相对分子质量低于12×104时,PVC/ACR 共混树脂的缺口冲击强度大大提高。与纯PVC相比,共混树脂的Tg均略有提高,其增量随ACR壳层PMMA平均相对分子质量的降低而减小。动态力学性能测试结果表明,ACR壳层聚合物平均相对分子质量越低,共混物分子链段运动活化能提高越少。 相似文献
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氯乙烯/丙烯酸酯二元及多元共聚物的研究进展 总被引:1,自引:0,他引:1
介绍了氯乙烯/丙烯酸酯多元共聚物、聚氯乙烯树脂/丙烯酸酯/顺丁烯二酰亚胺接枝共聚物、聚氯乙烯树脂/N-取代马来酸胺/丙烯酸酯接枝共聚树脂、氯乙烯/乙酸乙烯/丙烯酸羟丙酯共聚物、氯乙烯/乙酸乙烯/丙烯酸丁酯共聚乳液、聚丙烯酸酯-氯乙烯接枝共聚物、氯乙烯/乙烯/丙烯酸羟乙酯共聚涂料树脂、氯乙烯/丙烯酸甲酯共聚乳液的特点、生产工艺及其性能和用途. 相似文献
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Polystyrene/poly(vinyl acetate) latex nanoparticles with a core–shell morphology in an emulsifier‐free emulsion polymerization system were prepared with purified styrene and vinyl acetate (VAc) as monomers and 2,2′‐azo bis(2‐amino propane) dihydrochloride (ABA,2HCl) as the initiator and emulsifier. The optimized conditions of polymerization of VAc, on top of the already‐formed polystyrene as a core polymer, with a core–shell morphology were obtained using various parameters such as volume ratio of the first and second stages, type of process, and reaction time. The morphologic structure of the nanoparticles was studied by scanning electron microscopy and transmission electron microscopy. The latex nanoparticles and polymers were characterized by differential scanning calorimetry. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2409–2414, 2006 相似文献
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The toughness and morphology of (chlorinated poly[vinyl chloride])/(methyl methacrylate‐butadiene‐styrene) blends
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A series of methyl methacrylate‐butadiene‐styrene (MBS) graft copolymers were synthesized via seeded emulsion polymerization techniques by grafting styrene and methyl methacrylate on poly(butadiene‐co‐styrene) (SBR) particles. The chlorinated poly(vinyl chloride) (CPVC)/MBS blends were obtained by melting MBS graft copolymers with CPVC resin, and the effect of the core/shell ratio of MBS graft copolymer and SBR content of CPVC/MBS blends on the mechanical properties and morphology of CPVC/MBS blends was studied. The results showed that, with the increase in the core/shell ratio, the impact strength of the blend increased and then decreased. It was found that, when the core/shell ratio was 50/50, the impact strength was about 155 J/m, and the tensile strength evidently increased. The toughness of the CPVC/MBS blend was closely related to the SBR content of the blend, and with the increasing of SBR content of blend, the impact strength of the blend increased. The morphology of CPVC/MBS blends was observed via scanning electron microscopy. Scanning electron microscopy indicated that the toughness of CPVC/MBS blend was consistence with the dispersion of MBS graft copolymers in the CPVC matrix. J. VINYL ADDIT. TECHNOL., 22:501–505, 2016. © 2015 Society of Plastics Engineers 相似文献
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用种子乳液聚合法研究了硅氧烷改性丙烯酸酯的乳液聚合,对影响种子乳液聚合动力学的因素进行讨论,并分析了乳液聚合的成核机理.实验结果表明:反应温度、引发剂浓度、乳化剂浓度和有机硅氧烷用量对有机硅改性丙烯酸酯乳液聚合动力学有较大的影响.反应温度越高,引发剂浓度越高、乳化剂浓度越高、有机硅氧烷用量相对较小,乳液聚合反应的转化率越高;此外,体系的pH值在6~8之间时也有利于反应的进行.种子乳液聚合中RP∝[E]0.72,RP∝[I]0.56,表观活化能Ea为143.92 kJ8226;mol-1.种子乳液聚合初期,反应主要是单体液滴成核;进入壳层反应时,反应成核主要是以胶束成核为主. 相似文献
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Crosslinked poly(butyl acrylate-co-2-ethylhexyl acrylate)/poly(methyl methacrylate-co-styrene) (ACR I) latex was synthesized by multi-stage emulsion polymerization. A series of grafting vinyl chloride (VC) composite latices were prepared by emulsion copolymerization in the presence of core-shell ACR I latex. The effects of ACR I amount and its core/shell ratio on particle diameters of the composite latices and mechanical properties of the prepared materials were investigated. The grafting efficiency (GE) of VC grafted onto ACR I increases with an increasing ACR I content. Transmission electron microscope (TEM) study indicates that ACR I latex particles have a regular core-shell structure obviously. However, when styrene content in the shell of ACR I is more than 70 percent of the shell by weight, ACR I latex particles have an irregular core-shell morphology like sandwich. The composite latex particles synthesized by core-shell ACR I latex grafting VC have a clear three-layered core-shell structure. Dynamic mechanical analysis (DMA) study reveals that the compatibility between ACR I and PVC is well improved. With increasing ACR I content, the loss peak in low temperature range for every composite sample becomes stronger and stronger and gradually shifts to a higher temperature. Scanning electron microscope (SEM) graphs showed that the fractured surface of the composite sample exhibited better toughness of the material. TEM graphs showed that ACR I was uniformly dispersed in the PVC matrix. 相似文献
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Effect of ethyleneglycol dimethacrylate crosslinker on the performance of core‐double shell structure poly(vinyl acetate‐butyl acrylate) emulsion
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Core‐double shell structure poly(vinyl acetate‐butyl acrylate) emulsion was prepared by semicontinuous emulsion polymerization, and the effects of ethyleneglycol dimethacrylate crosslinker (EGDMA) on the emulsion particle structure and film performance were studied systematically. The emulsion particles' structure was characterized by transmission electron microscopy and Fourier transform infrared spectroscopy, and the particle size and distribution were characterized by Zeta potential—particle analyzer, as well as analysis of the film mechanical properties, water resistance, thermal properties, and so on. The results show that, when 0.1 and 0.5% EGDMA were added to the inner‐shell and outer‐shell reaction stage under the core‐double shell P(VAc‐BA) emulsion preparation process, respectively, it led to a more clear core‐double shell structure and a larger particle size (about 500–800 nm) of emulsion particles, and the comprehensive performance of the P(VAc‐BA) emulsion showed better. This work provided some insight into modifying the surface properties of the emulsion particles, which may expand the application field of the emulsion. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41899. 相似文献