A theoretical study on a novel combined power and ejector refrigeration cycle

A new combined power and refrigeration cycle is proposed for the cogeneration, which combines the Rankine cycle and the ejector refrigeration cycle by adding an extraction turbine between heat recovery vapor generator (HRVG) and ejector. This combined cycle could produce both power output and refrigeration output simultaneously, and could be driven by the flue gas from gas turbine or engine, solar energy, geothermal energy and industrial waste heats. Parametric analysis and exergy analysis are conducted to examine the effects of thermodynamic parameters on the performance and exergy destruction in each component for the combined cycle. The results show that the condenser temperature, the evaporator temperature, the turbine inlet pressure, the turbine extraction pressure and extraction ratio have significant effects on the turbine power output, refrigeration output, exergy efficiency and exergy destruction in each component in the combined cycle. It is also shown that the biggest exergy destruction occurs in the heat recovery vapor generator, followed by the ejector and turbine.     

Performance parameters for the design of a combined refrigeration and electrical power cogeneration system

This paper discusses the conservation of energy in a cogeneration system. A steam power cycle (Rankine) produces electrical power 2 MW and steam is bleeded off from the turbine at 7 bar to warm a factory or units of buildings during the winter or to supply a steam ejector refrigeration cycle to air-conditioning the same area during the summer. In the summer this system can be as alternative solution instead of absorption. Certainly the ejector refrigeration unit is more economical than absorption unit. The ratio of electrical power/heat is varied into the region (0.1–0.4) and the evaporator temperature of the ejector cycle is varied into the region (10–16 °C). A computer program has been developed for the study of performance parameters of the cogeneration system.     

Numerical design of ammonia bubble absorber applying binary nanofluids and surfactants

The objectives of this paper are to analyze the combined heat and mass transfer characteristics for the ammonia bubble absorption process and to study the effects of binary nanofluids and surfactants on the absorber size. The ammonia bubble absorbers applying binary nanofluids and surfactants are designed and parametric analyses are performed. In order to express the effects of binary nanofluids and/or surfactants on the absorption performance, the effective absorption ratios for each case are applied in the numerical model. The values of the effective absorption ratio are decided from the previous experimental correlations. The kinds and the concentrations of nano-particles and surfactants are considered as the key parameters. The considered surfactants are 2-ethyl-1-hexanol (2E1H), n-octanol, and 2-octanol and nano-particles are copper (Cu), copper oxide (CuO), and alumina (Al₂O₃). The results show that the application of binary nanofluids and surfactants can reduce the size of absorber significantly. In order to reach 16.5% ammonia solution under the considered conditions, for example, the addition of surfactants (2E1H, 700 ppm) can reduce the size of absorber up to 63.0%, while the application of binary nanofluids (Cu, 1000 ppm) can reduce it up to 54.4%. In addition, it is found that the effect of mass transfer resistance is more dominant than that of heat transfer resistance. That is, the enhancement of mass transfer performance is more effective than that of heat transfer performance.     

Mass transfer characteristics of a structured packing for ammonia rectification in ammonia–water absorption refrigeration systems

In ammonia–water absorption refrigeration systems a purification process of the vapours produced in the generator is required. One type of equipment to carry out the purification process is a packed column. However, detailed experimental studies at the normal operating conditions found in ammonia–water absorption refrigeration systems have not been found. An experimental facility has been designed and built to study the ammonia–water rectification in packed columns. Experimental tests have been performed at the normal operating conditions found in the high-pressure stage of a small power ammonia–water absorption refrigeration system. In this paper, the experimental set-up is described and experimental results of the height equivalent to a theoretical plate (HETP) and the volumetric mass transfer coefficient of a rectifying section with the Sulzer BX packing are presented. The HETP values and the experimental mass transfer coefficients are compared with different data and correlations proposed in the literature; it has been found that the differences are appreciable.     

Distillation column configurations in ammonia–water absorption refrigeration systems

In ammonia–water absorption refrigeration systems a purification process to reduce the water content in the vapour leaving the generator is required. During this process the water content in the vapour must be reduced to a minimum, otherwise it tends to accumulate in the evaporator and strongly deteriorates the efficiency of the system. The vapour purification can be carried out by partial condensation, by establishing a liquid–vapour counter flow or by combining both methods. In systems with partial condensation, the distillation column can be composed of one or more rectifiers using different cooling mediums, and the rectifying and stripping sections. In complete condensation systems only the rectifying and stripping sections can be used. Therefore different distillation column arrangements should be considered. This paper presents a study of several distillation column configurations for single stage ammonia–water absorption refrigeration systems with partial and complete condensation. In order to evaluate and compare the different configurations, a parameter that indicates the ratio of the ammonia vapour concentration increase in each part of the column to the total ammonia purification has been defined. The analysis has been based on the system COP. Finally the efficiency in each part of the column has been calculated to estimate its design requirements.     

Development of type 2 solution transportation absorption system for utilizing LNG cold energy

The objective of this paper is to develop a new energy transport system for district cooling application by using type 2 absorption cycle. Cold energy from the LNG storage system is utilized as the cooling source of the condenser and the rectifier. The pressures of the system, UAs of the evaporator and the desorber, the inlet temperatures of the refrigerant for each component, transportation distance and the pumping power per unit length are considered as the key parameters. The results show that UA of the evaporator has more dominant effect on COP than that of the desorber. The optimum system pressure for the demand side is also determined. For the present system, it is recommended that the refrigerant inlet temperature of the evaporator be lower than 4.3 °C for long distance transportation. It is concluded that the cold energy from the LNG storage system can be effectively applied to the long distance transportation system for district cooling application with the type 2 absorption cycle. The maximum transportation distance and the pumping power per unit length are calculated. The optimum operation conditions are also predicted from the parametric analysis.     

Thermoeconomic evaluation and optimization of a double-effect H2O/LiBr vapour-absorption refrigeration system

In this paper, the thermoeconomic concept is applied to the optimization of a double-effect H₂O/LiBr VAR system, aimed at minimizing its overall product cost. A simplified cost minimization methodology based on the thermoeconomic concept is applied to calculate the economic costs of all the internal flows and products of the system by formulating thermoeconomic cost balances. Once these costs are determined, the system is thermoeconomically evaluated to identify the effects of the design variables on cost of the flows and products. This enables to suggest changes of the design variables that would make the overall system cost-effective. Finally, an approximate optimum design configuration is obtained by means of an iterative procedure. The result shows significant improvement in the system performance. The sensitivity analysis shows that the changes in optimal values of the decision variables are negligible with changes in the fuel cost.     

Performance of diffusion absorption refrigeration cycle with organic working fluids

A diffusion absorption refrigeration (DAR) cycle is driven by heat and utilizes a binary solution of refrigerant and absorbent as working fluid, together with an auxiliary inert gas. Commercial DAR systems operate with ammonia–water solution and hydrogen or helium as the inert gas. In this work, the performance of a simplified DAR system working with an organic absorbent (DMAC – dimethylacetamide) and five different refrigerants and helium as inert gas was examined numerically, with the aim of lowering the generator temperature and system pressure along with a non-toxic refrigerant The refrigerants were: chlorodifluoromethane (R22), difluoromethane (R32), 2-chloro-1,1,1,2-tetrafluoroethane (R124), pentafluoroethane (R125) and 1,1,1,2-tetrafluoroethane (R134a). The results were compared with the performance of the same system working with ammonia–water and helium. Similar behavior was found for all systems, regarding the coefficient of performance (COP) and rich and poor solution concentrations as functions of generator temperature. It was found that typical generator temperature with the new substances was 150 °C, yet lower COPs, higher evaporator temperatures and lower condensation temperature of about 40 °C governed these systems.     

Experimental correlation of combined heat and mass transfer for NH3–H2O falling film absorptionCorrélation expérimentale entre le transfert de chaleur et de masse pour de l'absorption au NH3–H2O à film tombant

In this article, experimental analysis was performed for ammonia–water falling film absorption process in a plate heat exchanger with enhanced surfaces such as offset strip fin. This article examined the effects of liquid and vapor flow characteristics, inlet subcooling of the liquid flow and inlet concentration difference on heat and mass transfer performance. The inlet liquid concentration was selected as 5%, 10% and 15% of ammonia by mass while the inlet vapor concentration was varied from 64.7% to 79.7%. It was found that before absorption started, there was a rectification process at the top of the test section by the inlet subcooling effect. Water desorption phenomenon was found near the bottom of the test section. It was found that the lower inlet liquid temperature and the higher inlet vapor temperature, the higher Nusselt and Sherwood numbers are obtained. Nusselt and Sherwood number correlations were developed as functions of falling film Reynolds Re₁, vapor Reynolds number Re_v, inlet subcooling and inlet concentration difference with ±15% and ±20% error bands, respectively.     

Performance analysis of ammonia absorption GAX cycle for combined cooling and hot water supply modes

An ammonia Generator–Absorber heat eXchange (GAX) absorption cycle with combined cooling and hot water supply modes is developed in this study. This paper proposes new multi-modes GAX cycles which function in three different modes (case 1, case 2 and case 3) of cooling and hot water supply with one hardware (ammonia/water GAX absorption heat pump), and finds the best cycle for performance improvement by the parametric analysis. The key parameters are the outlet temperature of hot water and the split ratio of the solution. It is found that the COP_c values for case 1, case 2 and case 3 are 60%, 42% and 87% of COP_c for case 0, respectively, which is the standard cooling mode for the conventional GAX cycle. From the viewpoints of hot water supply, case 1 gives the best performance. However, during the summer season when the cooling mode is the primary purpose rather than the hot water supply, case 3 is the most desirable cycle. The split ratio of the solution should be carefully determined depending on the primary application of the modified GAX cycle; cooling or hot water supply applications. It is also recommended that the optimum design values of UA_SCA and UA_HCA for case 3 should be less than those for case 1.     

A theoretical study of a novel regenerative ejector refrigeration cycle

There has been a demand for developments of the ejector refrigeration systems using low grade thermal energy, such as solar energy and waste heat. In this paper, a novel regenerative ejector refrigeration cycle was described, which uses an auxiliary jet pump and a conventional regenerator to enhance the performance of the novel cycle. The theoretical analysis on the performance characteristics was carried out for the novel cycle with the refrigerant R141b. Compared with the conventional cycle, the simulation results show that the coefficient of performance (COP) of the novel cycle increases, respectively, by from 9.3 to 12.1% when generating temperature is in a range of 80–160 °C, the condensing temperature is in a range of 35–45 °C and the evaporating temperature is fixed at 10 °C. Especially due to the enhanced regeneration with increasing the pump outlet pressure, the improvement of COP of the novel cycle is approached to 17.8% compared with that in the conventional cycle under the operating condition that generating temperature is 100 °C, condensing temperature is 40 °C and evaporating temperature is 10 °C. Therefore, the characteristics of the novel cycle performance show its promise in using low grade thermal energy for the ejector refrigeration system.     

A novel hybrid absorption–compression refrigeration cycle

When used in traditional pool-boiling type refrigeration cycles, non-azeotropic mixed refrigerants tend to result in a reduced efficiency compared to pure refrigerants. This results from the composition shift effect, which distributes the mixture components: concentrating the more volatile component in the high pressure part of the cycle, and the less volatile component in the low pressure part. The obvious effect of this is to increase the compression ratio relative to a single component. This article investigates a way of manipulating the composition change of a refrigerant mixture, using two components of similar volatility, in order to reduce the compression ratio. Counter-current vapour–liquid contact is used in a “refrigeration column”, which is combined with a distillation column. The cycle is able to exploit heat sources below 100°C as input to the distillation column and the designer is able to optimise the consumption of compressor power and distillation heat input.     

Evaluation of the column components size on the vapour enrichment and system performance in small power NH3–H2O absorption refrigeration machines

This paper presents an analysis of the influence of the distillation column components size on the vapour enrichment and system performance in small power NH₃–H₂O absorption machines with partial condensation. It is known that ammonia enrichment is required in this type of systems; otherwise water accumulates in the evaporator and strongly deteriorates the system performance and efficiency. The distillation column analysed consists of a stripping adiabatic section below the column feed point and an adiabatic rectifying packed section over it. The partial condensation of the vapour is produced at the top of the column by means of a heat integrated rectifier with the strong solution as coolant and a water cooled rectifier. Differential mathematical models based on mass and energy balances and heat and mass transfer equations have been developed for each one of the column sections and rectifiers, which allow defining their real dimensions. Results are shown for a given practical application. Specific geometric dimensions of the column components are considered. Different distillation column configurations are analysed by selecting and discarding the use of the possible components of the column and by changing their dimensions. The analysis and comparison of the different column arrangements has been based on the system COP and on the column dimensions.     

Development and validation of “grey-box” models for refrigeration applications: A review of key concepts

“Grey-box” modelling combines the use of first-principle based “white-box” models and empirical “black-box” models, offering particular benefits when: (a) there is a lack of fundamental theory to describe the system or process modelled; (b) there is a scarcity of suitable experimental data for validation or (c) there is a need to decrease the complexity of the model. The grey-box approach has been used, for example, to create mathematical models to predict the shelf life of chilled products or the thermal behaviour of imperfectly mixed fluids, or to create models that combine artificial neural networks and dynamic differential equations for control-related applications. This paper discusses the main characteristics of white-box, black-box and their integration into grey-box models, the requirements and sourcing of accurate data for model development and important validation concepts and measures.     

Numerical simulation of an advanced energy storage system using H2O–LiBr as working fluid, Part 1: System design and modeling

The advanced energy storage technology proposed and patented by authors can be applied for cooling, heating, dehumidifying, combined cooling and heating, and so on. It is also called the variable mass energy transformation and storage (VMETS) technology in which the masses in one or two storage tanks change continuously during the energy charging and discharging processes. This paper presents an advanced energy storage system using aqueous lithium bromide (H₂O–LiBr) as working fluid. As one of VMETS systems, this system is a closed system using two storage tanks. It is used to shift electrical load and store energy for cooling, heating or combined cooling and heating. It is environmental friendly because the water is used as refrigerant in the system. Its working principle and process of energy transformation and storage are totally different from those of the traditional thermal energy storage (TES) systems. The electric energy in off-peak time is mostly transformed into the chemical potential of the working fluid and stored in the system firstly. And then the potential is transformed into cold or heat energy by absorption refrigeration or heat pump mode when the consumers need the cold or heat energy. The key to the system is to regulate the chemical potential by controlling the absorbent (LiBr) mass fraction or concentration in the working fluid with respect to time. As a result, by using a solution storage tank and a water storage tank, the energy transformation and storage can be carried out at the desirable time to shift electric load efficiently. Since the concentration of the working solution in the VMETS cycle varies continuously, the working process of the VMETS system is dynamic. As the first part of our study, the working principle and flow of the VMETS system were introduced first, and then the system dynamic models were developed. To investigate the system characteristics and performances under full-storage and partial-storage strategies, the numerical simulation will be performed in the subsequent paper. The simulation results will be very helpful for guiding the actual system and device design.     

Energy and exergy analysis of single effect and series flow double effect water–lithium bromide absorption refrigeration systems

In this paper, the energy and exergy analysis of single effect and series flow double effect water–lithium bromide absorption systems is presented. A computational model has been developed for the parametric investigation of these systems. Newly developed computationally efficient property equations of water–lithium bromide solution have been used in the computer code. The analysis involves the determination of effects of generator, absorber and evaporator temperatures on the energetic and exergetic performance of these systems. The effects of pressure drop between evaporator and absorber, and effectiveness of heat exchangers are also investigated. The performance parameters computed are coefficient of performance, exergy destruction, efficiency defects and exergetic efficiency. The results indicate that coefficient of performance of the single effect system lies in range of 0.6–0.75 and the corresponding value of coefficient of performance for the series flow double effect system lies in the range of 1–1.28. The effect of parameters such as temperature difference between heat source and generator and evaporator and cold room have also been investigated. Irreversibility is highest in the absorber in both systems when compared to other system components.     

Recent developments in simulation techniques for vapour-compression refrigeration systems

Simulation has been widely used for performance prediction and optimum design of refrigeration systems. A brief review on history of simulation for vapour-compression refrigeration systems is done. The models for evaporator, condenser, compressor, capillary tube and envelop structure are summarized. Some developing simulation techniques, including implicit regression and explicit calculation method for refrigerant thermodynamic properties, model-based intelligent simulation methodology and graph-theory based simulation method, are presented. Prospective methods for future simulation of refrigeration systems, such as noise-field simulation, simulation with knowledge engineering methodology and calculation methods for nanofluid properties, are introduced briefly.     

Experimental results for a hydraulic refrigeration system using n-butane

The hydraulic refrigeration system (HRS) is a vapor-compression system that accomplishes the compression and condensation of the refrigerant in a unique manner, by entraining refrigerant vapor in a down-flowing stream of water and utilizing the pressure head of the water to compress and condense the refrigerant. A multi-stage HRS was designed, fabricated, and tested using n-butane as the refrigerant. In general, both the refrigeration rate and the coefficient of performance (COP) increased with a corresponding decrease in the compression fluid temperature of the third and final stage. The refrigeration rate and COP were also found to increase with a corresponding increase in evaporator temperature. The predictions of an enhanced model incorporating two-phase hydraulic losses show excellent agreement with the experimental data with a maximum error of ±20%. The results of the experimental investigation indicate that the HRS offers an attractive and feasible alternative to conventional vapor-compression systems, especially in applications where direct-contact heat exchange in the evaporator is desirable.     

Experimental investigation of a micro-combined cooling, heating and power system driven by a gas engine

An experimental investigation of the performance of a micro-combined cooling, heating and power (CCHP) system is described. The natural gas and LPG-fired micro-CCHP system uses a small-scale generator set driven by a gas engine and a new small-scale adsorption chiller, which has a rated electricity power of 12 kW, a rated cooling of 9 kW and a rated heating capacity of 28 kW. Silica gel–water is used as working pair in the adsorption cooling system. The refrigeration COP of the adsorption chiller is over 0.3 for 13 °C evaporation temperature. The test facility designed and built is described, which supplies better test-rig platform for cooling, heating and power cogeneration. Experimental methodology of this system is presented and the results are discussed. An energetic analysis of micro-CCHP system is performed as well. The overall thermal and electrical efficiency is over 70%.     

Thermodynamic analysis of optimal condensing temperature of cascade-condenser in CO2/NH3 cascade refrigeration systems

This study thermodynamically analyzed a cascade refrigeration system that uses carbon dioxide and ammonia as refrigerants, to determine the optimal condensing temperature of the cascade-condenser given various design parameters, to maximize the COP and minimize the exergy destruction of the system. The design parameters include: the evaporating temperature, the condensing temperature and the temperature difference in the cascade-condenser. The results agreed closely with the reported experimental data. The optimal condensing temperature of the cascade-condenser increases with T_C, T_E and ΔT. The maximum COP increases with T_E, but decreases as T_C or ΔT increases. Two useful correlations that yield the optimal condensing temperature of the cascade-condenser and the corresponding maximum COP are presented.