A comparative evaluation of HfN,Al2O3, TiC and TiN coatings on cemented carbide tools

Cemented carbide cutting tools coated with HfN, Al₂O₃, TiC and TiN were evaluated in continuous and interrupted turning of alloy steel and cast iron in the range from 600 to 1000 surface ft min^-1. The results showed that HfN was the most effective coating in prolonging tool life over the widest range of cutting conditions.     

Mathematical models to predict surface finish in fine turning of steel. Part II

This paper outlines further experimental development of mathematical models for predicting RMS surface finish in fine turning operation using TiC coated and cemented tungsten carbide throwaway cutting tools. The five independent variables included are: cutting speed, feed, depth of cut, time of cut of tool, nose radius. Using these five variables at different levels an experimental approach, predictive models for tungsten carbide and titanium coated tungsten carbide tools were developed. A sixth variable, 'the type of cutting tool,' was used to develop a single model for both the TiC coated and cemented carbide cutting tools. AIS1 4140 steel was used as workpiece specimen in the experimental work. Stepwise regression analysis was used in developing the models.     

Effect of cutting speed on the performance of Al2O3 based ceramic tools in turning nodular cast iron

This paper presents the results of an experimental investigation on the effect of cutting speed in turning nodular cast iron with alumina (Al₂O₃) based ceramic tools. Three different alumina based ceramic cutting tools were used, namely TiN coated Al₂O₃ + TiCN mixed ceramic, SiC whisker reinforced Al₂O₃ and uncoated Al₂O₃ + TiCN mixed ceramic tool. Turning experiments were carried out at four different cutting speeds, which were 300, 450, 600 and 750 m/min. Depth of cut and feed rate were kept constant at 1 mm and 0.1 mm/rev, respectively, throughout the experiments. Tool performance was evaluated with respect to tool wear, surface finish produced and cutting forces generated during turning. Uncoated Al₂O₃ + TiCN mixed ceramic was the worst performing tool with respect to tool wear and was the best with respect to surface finish. SiC whisker reinforced Al₂O₃ exhibited the worst performance with respect to cutting forces. If tool wear, surface finish and cutting force results are considered together, among the three tools studied, TiN coated Al₂O₃ + TiCN mixed ceramic tool is the most suitable one for turning nodular cast iron, especially at high cutting speeds (V_c > 600 m/min).     

Study of growth rate and failure mode of chemically vapour deposited TiN,TiCxNy and TiC on cemented tungsten carbide

The effects of deposition temperature and mole ratio of CH₄ to TiCl₄ on the growth rate of titanium compound coatings were investigated. Activation energies of TiN, TiC _x N _y and TiC deposition reactions of 4.8×10⁴, 1.9×10⁵ and 2.8×10⁵ J mol^–1, respectively, were obtained experimentally. The carbon content of TiC _x N _y deposit was increased as the CH₄ flow rate and deposition temperature increased. It was found that TiC _x N _y grain size was finer than TiC and TiN.The cutting temperatures of TiN-coated and TiC-coated tools were 10% (TiN) and 20% (TiC) lower than that of uncoated tools. Feed force and reaction force of coated tools were 30% and 18% less than those of uncoated tools, respectively. The dominant failure mode of coated tools was due to the microchipping of the cutting edge.     

Tool life model for Al2O3 particle reinforced MMCs using genetic expression programming

Abstract

In the present work, the wear of cutting tools in the machining of 7075Al alloy composites reinforced with 10 and 25 wt-% and 16 μm average size Al₂O₃ particles was investigated. Machining tests were performed on both as cast and heat treated composites by turning process using a physical vapour deposition coated carbide tool CP500 at different cutting conditions. A new model was developed to predict the tool life by genetic expression programming. The training and validation data sets were obtained from the well established machining test results. The weight fraction of particle P_w, cutting speed V, feedrate f and heat treatment Ht were used as independent input variables, while tool life T was used as a dependent output variable. Different models for tool life were predicted on the basis of the training data set using genetic programming, and the accuracy of the best model was proved with validation data set. The test results showed that the genetic expression programming model has produced correlation coefficient R values of ～0·958 for the training data and 0·952 for the validation data. The predicted tool life results were compared with experimental results and found to be in good agreement with the experimentally observed ones.     

On Applicability of Multilayer Coated Tool in Dry Machining of Aerospace Grade Stainless Steel

The present research work has been undertaken with a view to investigate the influence of CVD multilayer coated (TiN/TiCN/Al₂O₃/ZrCN) and cutting speed on various machining characteristics such as chip morphology, tool wear, cutting temperature, and machined surface roughness during dry turning of 17-4 PH stainless steel. In order to understand the effectiveness of CVD multilayer coated tool a comparison has been carried out with that of uncoated carbide insert. The surface roughness and cutting temperature obtained during machining with chemical vapor deposition (CVD) multilayer coated tool was higher than that of uncoated carbide insert at all cutting velocity. However, the results clearly indicated that CVD multilayer coated tool played a significant role in restricting various modes of tool failure and reducing chip deformation compared to its uncoated counterpart. Adhesion and abrasion were found to be dominating wear mechanism with flank wear, plastic deformation, and catastrophic failure being major tool wear modes.     

Impact of graphite particle on milling of Al/15Al2O3 and Al/15Al2O3/5Gr composites

ABSTRACT

Hybrid Metal Matrix Composites (MMCs) are a new class of composites, formed by a combination of the metal matrix and more than one type of reinforcement having different properties. Machining of MMCs is a difficult task because of its heterogeneity and abrasive nature of reinforcement, which results in excessive tool wear and inferior surface finish. This paper investigates experimentally the addition of graphite (Gr) on cutting force, surface roughness and tool wear while milling Al/15Al₂O₃ and Al/15Al₂O₃/5Gr composites at different cutting conditions using tungsten carbide (WC) and polycrystalline diamond (PCD) insert. The result reveals that feed has a major contribution on cutting force and tool wear, whereas the machined surface roughness was found to be more sensitive to speed for both composite materials. The incorporation of graphite reduces the coefficient of friction between the tool–workpiece interfaces, thereby reducing the cutting force and tool wear for hybrid composites. The surface morphology and worn tool are analyzed using scanning electron microscope (SEM). The surface damage due to machining extends up to 200 µm for Al/15Al₂O₃/5Gr composites, which is beyond 250 µm for Al/15Al₂O₃ composites.     

Development and characterisation of SiAlON composites with TiB2, TiN, TiC and TiCN

30 vol% of TiB₂, TiCN, TiN or TiC was added to a sialon matrix with an X-phase sialon (Si₁₂Al₁₈O₃₉N₈) and an Al₂O₃–Si₃N₄ (77/23 wt%) starting powder composition and hot pressed at 1650°C in vacuum. The microstructures of the obtained composites were characterised by means of X-ray diffraction and electron microscopy, and the mechanical properties; E-modulus, hardness, bending strength and fracture toughness were measured and evaluated.Fully dense composites with an X-phase sialon or a polyphase Al₂O₃–-sialon–X-sialon matrix with 30 vol% of TiB₂, TiN and TiCN were obtained. TiC, added as a dispersed phase, however reacts with the nitrogen from the Si₃N₄ during liquid phase sintering, with the formation of TiC_1–x N _x , SiC and a changed sialon matrix composition. In the case of the X-phase sialon starting composition, a mullite matrix is obtained after sintering. The microstructural observations with respect to the sialon-TiC composites are found to be in agreement with the thermodynamic calculations.     

Flux growth and characterization of TiC crystals

Single crystals of TiC were grown using nickel and cobalt metal as a flux at soaking temperatures of 1500 to 1800° C and at compositions of 12.5 to 30 mol% TiC. The use of cobalt flux produced crystal sizes less than 0.5 mm under all conditions. With a nickel flux, a maximum crystal size of 1.5 mm was obtained at 1700 and 1800°C and at 20 and 25 mol% TiC composition, using a cooling rate of 3° C min^–1. A slower cooling rate of 0.2° C min^–1 also gave crystals of 1.5 mm at 1600° C. The crystals were cubic and metallic-lustre silver grey in colour. The lattice parameter of the crystal was measured to bea ₀ = 0.432 75 ± 0.000 05 nm, with nearly stoichiometric composition. The grown faces were of the {1 0 0} family with a dislocation density around 10⁷ cm^-2. The Vickers' microhardness on these faces was in the range 2600 to 2800 kg mm^–2. The nickel impurity and free carbon contents in the crystals were 700 to 1000 p.p.m. and 0.8 to 4 wt%, respectively.     

Sintering properties of submicron TiC powders from carbon coated titania precursor

The sintering behavior of submicron titanium carbide (TiC) synthesized from carbon coated titania (TiO₂) precursor was investigated in TiC-Ni system. The densification was examined as functions of initial carbon content (30.95–34 wt.%) and Ni content (3–20 wt.%). The sintered density of TiC-Ni was markedly decreased with increased carbon content in the precursor. The amount of Ni had a relatively small influence on the densification of submicron TiC-Ni cermet compared with TiC (commercially available HCS)-Ni cermets. The results show that submicron TiC with only 3 wt.% Ni can be sintered to densities above 95% TD in flowing Ar+10H₂ at 1500°C and below. The improvements in densification result from the capillary force increase since it is inversely dependent on the particle size. With decreased Ni content, the Vickers hardness increased and the fracture toughness decreased, as expected. However, the sufficient densification cannot be achieved for commercial HCS TiC powder sintered with Ni (<10 wt.%) under the same conditions. Therefore, both the Vickers hardness and fracture toughness decreased as the Ni content decreased. This was due to the increase of porosity in the sintered samples containing commercial TiC powder.     

Analysis of coating interlayer between silicon nitride cutting tools and titanium carbide and titanium nitride coatings

Silicon nitride (Si₃N₄) cutting tools exhibit excellent thermal stability and wear resistance in the high-speed machining of cast irons, but show poor chemical wear resistance in the machining of steel. Conventional chemical vapour deposition (CVD) coating of Si₃N₄ tools has not been very successful because of thermal expansion mismatch between coatings and the substrate. This problem was overcome by developing a CVD process to tailor the interface for titanium carbide (TiC) and titanium nitride (TiN) coatings. Computer modelling of the CVD process was done to predict which phases would form at the interface, and the results compared with analyses of the interface. Three Si₃N₄ compositions were considered, including pure Si₃N₄, Si₃N₄ with a glass phase binder, and Si₃N₄ + TiC composite with a glass phase binder. Results of machining tests on coated tools show that the formation of an interlayer provides superior wear resistance and tool life in the machining of steel as compared to uncoated and conventionally coated Si₃N₄ tools.     

Preparation of single-crystal TiC (111) by radio frequency magnetron sputtering at low temperature

Single-crystal films of TiC (111) have been synthesized at room temperature on Al₂O₃ (0001) substrates by radio frequency magnetron sputtering using a compound Ti-C target. The substrate temperature and bias were varied to explore the influence of deposition parameters on the crystal structure. Both Al₂O₃ (0001) and Si (100) substrates were used for epitaxial growth of TiC films. A series of characterizations of TiC films were carried out, including Rutherford backscattering spectroscopy, X-ray diffraction, Raman and X-ray photoelectron spectroscopy. Single-crystal films of TiC (111) on the Al₂O₃ (0001) were demonstrated.     

Investigation on Some Machinability Aspects of Inconel 825 During Dry Turning

In the current study, attempt has been made to investigate the influence of cutting speed (Vc) (51, 84, and 124 m/min) on various machining characteristics like chip morphology, chip thickness ratio, tool wear, surface, and sub-surface integrity during dry turning of Inconel 825. Comparable study was carried out using uncoated and commercially available chemical vapor deposition multilayer coated (TiN/TiCN/Al₂O₃/ZrCN) cemented carbide (ISO P30 grade) insert. Chip morphology consists of chip forms obtained at different cutting conditions. Serrated chips were observed when machining Inconel 825 with both types of tool with more serration in case of uncoated insert. The chip thickness ratio increased as cutting speed was increased. Use of multilayer coated tool also resulted in increase in chip thickness ratio. Rake and flank surfaces were examined with scanning electron microscope and optical microscope. Abrasion, adhesion, and diffusion wears were found to be dominating tool wear mechanism during dry machining of Inconel 825. The beneficial effect of coated tool over its uncoated counterpart was most prominent during machining at high cutting speed (Vc = 124 m/min). The surface and sub-surface integrity obtained with coated tool were superior to that while machining Inconel 825 with uncoated tool.     

A novel fabrication method for TiC–Al2O3–Fe functional material under centrifugal acceleration

Compacted powders of titanium (Ti) and carbon (C) in form of pellets were exposed to a massive amount of heat generated from the thermite reaction of Fe₂O₃ and Al in a graphite–steel tube mounted in a developed centrifugal accelerator machine. The centrifugal force facilitated the formation of multi-component products during the process. Titanium carbide (TiC) product is joined to an Al₂O₃–Fe layer, which are the products of the thermite reaction. The existence of centrifugal acceleration had a significant effect on both metallurgical alloying and mechanical interlocking between different layers of the sample to form a functional material. A mathematical model developed for this experiment to describe the speed rate of iron infiltration inside the TiC product as well as viscosity rate variation was presented. The composition, microstructure and mechanical properties confirmed the model.     

In situ formation of TiC particulate composite layer on cast iron by laser alloying of thermal sprayed titanium coating

Commercial flake graphite cast iron substrate was coated with titanium powder by low pressure plasma spraying and was irradiated with a CO₂ laser to produce the wear resistant composite layer. The macro and microstructural changes of an alloyed layer with the traveling speeds of laser beam, the precipitate morphology of TiC particulate and the hardness profile of the alloyed layer was examined. From the results, it was possible to composite TiC particulate on the surface layer by direct reaction between carbon existed in the cast iron matrix and titanium with thermal sprayed coating by remelting and alloying them using laser irradiation. The cooling rate of the laser remelted cast iron substrate without a titanium coating was about 1 × 10⁴ K/s to 1 × 10⁵ K/s in the order under the condition of this study. The microstructure of the alloyed layer consisted of three zones; the TiC particulate precipitate zone (MHV 400–500), the mixed zone of TiC particulate + ledeburite (MHV 650–900) and the ledeburite zone (MHV 500–700). TiC particulates were precipitated as a typical dendritic morphology. The secondary TiC dendrite arms were grown to a polygonized shape and were necking. Then the separated arms became cubic crystal of TiC at the slowly solidified zone. In the rapidly solidified zone near the fusion boundary, however the fine granular TiC particulates were grouped like grapes.     

Deformability enhancement in ultra-fine grained, Ar-contained W compacts by TiC additions up to 1.1%

Nano-sized Ar bubbles give negative influence on the fracture resistance and occurrence of superplasticity in ultra-fine grained (UFG) W–TiC compacts. In order to enhance deformability in UFG, Ar-contained W–TiC compacts, effects of TiC addition on the high-temperature deformation behavior were examined. W–TiC compacts with TiC additions of 0, 0.25, 0.5, 0.8 and 1.1 wt% were fabricated by mechanical alloying in a purified Ar atmosphere and hot isostatic pressing. Tensile tests were conducted at 1673–1973 K (0.45–0.54 T_m, T_m: melting point of W) at initial strain rates from 5 × 10⁻⁵ to 5 × 10⁻³ s⁻¹. It is found that as TiC addition increases, the elongation to fracture significantly increases, e.g., from 3 to 7% for W–0 and 0.25TiC/Ar to above 160% for W–1.1TiC/Ar when tested at 1873 and 1973 K at 5 × 10⁻⁴ s⁻¹. The flow stress takes a peak at 0.25%TiC and decreases to a nearly constant level at 0.5–1.1%TiC. The ranges of the strain rate sensitivity of flow stress, m, and the activation energy for deformation, Q, with TiC additions are 0.17–0.30 and 310–600 kJ/mol, respectively. The observed effects of the TiC additions on the tensile properties are discussed.     

Development of ANFIS model and machinability study on dry turning of cryo-treated PH stainless steel with various inserts

This present investigation deals about the machinability comparison of cryogenically treated 15-5 PH stainless steel with various cutting tools such as uncoated tungsten carbide, cryogenic-treated tungsten carbide and wiper geometry inserts. Cryo-treated PH stainless steel is considered as the work material in this investigation and experimental trials were performed under dry turning condition. The machinability aspects considered for evaluation are cutting force (F_z), surface roughness (R_a) and tool wear. The outcomes of experimentation reveal that the tungsten carbide inserts which are cryogenically treated provide improved performance in machining while comparing with conventional and wiper geometry inserts at all machining conditions. The measured cutting force and the observed flank wear were less for the cryo-treated inserts. However, wiper tool produces a better surface finish during machining. An artificial intelligence decision-making tool named Adaptive Neuro Fuzzy Inference System has been evolved to determine the relation among the considered input machining variables and output measures, namely cutting force and surface roughness of the machined surface. An analysis has been performed to compare the results obtained from developed models and experimental results.     

Experimental studies on the cryogenic machining of biodegradable ZK60 Mg alloy using micro-textured tools

Reducing the contact area between the cutting tool rake surface and chip promotes the machining performance of the work material and increases the tool life. Magnesium alloys are ductile-lightweight materials that form continuous chips during machining. The present investigation discusses the orthogonal turning of ZK60 magnesium alloy with linearly textured cutting inserts under both dry and liquid nitrogen (LN₂) cooling conditions. Linear grooves that are parallel and perpendicular to chip flow direction were created using Nd-YAG laser on the tungsten carbide cutting inserts. The effect of texturing combined with the application of LN₂ cooling is studied by evaluating the machining temperature and forces, microhardness, surface roughness and tool wear. Textured tools considerably minimize the liaison area of the chip with the rake plane compared to non-textured tools, which resulted in favorable effects in machinability. In case of cryogenic machining, textured tools substantially minimize the friction by the coupled effect of micro-pool lubrication and the formation of thin-film lubrication between the tool–chip/tool–work interfaces. Parallel-textured tools aided with cryogenic cooling exhibit superior performance during machining among the different types of tools employed in the present investigation.     

Electrochemical behavior of p-Si/TiC in aqueous HF

The electrochemical behavior of p-Si in HF solution by modification of the silicon electrolyte interface is studied. For this purpose, the samples were coated with titanium carbide (TiC) deposited by RF pulverization of titanium under methane/argon atmosphere. The current-potential characteristics of TiC-coated electrodes in 5% HF are similar to the ones obtained with silicon. The scanning electron microscopy observation of the Si/CH_x surface structures shows that the coating is stable in HF environment but it can be destroyed upon flowing of an anodic current. The results presented suggest that a TiC film layer can be used as a potential tool for low-thickness masking and patterning. In addition, a promising class of optical filters is introduced, based on a p-Si/porous silicon/TiC.     

Preparation of micro-coiled SiC and TiC fibres by vapour phase metallizing of micro-coiled carbon fibres

Micro-coiled fibres of SiC and TiC were prepared by the vapour phase metallizing of micro-coiled carbon fibres with full preservation of the coiling morphology of the source coiled carbon fibres, and their preparation conditions and bulk electrical resistivity were examined. The SiC_1,0 coils were obtained at 1400 °C for 2 h, and TiC_1.0 coils were obtained at 1100–1200 °C for 1.5 h. The bulk resistivity of the coiled TiC fibres sharply decreased with the bulk density and was 10^–2 S^–1 cm at 1.4 g cm^–3.