Experimental characterisation of a thermal energy storage system using temperature and power controlled charging

The experimental set-up and technical aspects for charging a thermal energy storage (TES) of a proposed solar cooker at constant temperature and variable electrical power are presented. The TES is developed using a packed pebble bed. An electrical hot plate simulates the concentrator which heats up oil circulating through a copper coil absorber charging the TES system. A computer program to acquire data for monitoring the storage system and to maintain a nearly constant outlet charging temperature is developed using Visual Basic. The input power to the hot plate is also controlled to simulate the variation of the daily solar radiation by using another Visual Basic program. A combined internal model control (IMC) and proportional, integral and derivative (PID) temperature control structure is tested on the TES system under varying conditions and its performance is reasonable within a few degrees of the set temperature points. Results of the charging experiments are used to characterise the storage system. The different experiments indicate various degrees of stratification in the storage tank.     

A method to determine stratification efficiency of thermal energy storage processes independently from storage heat losses

A new method for the calculation of a stratification efficiency of thermal energy storages based on the second law of thermodynamics is presented. The biasing influence of heat losses is studied theoretically and experimentally. Theoretically, it does not make a difference if the stratification efficiency is calculated based on entropy balances or based on exergy balances. In practice, however, exergy balances are less affected by measurement uncertainties, whereas entropy balances can not be recommended if measurement uncertainties are not corrected in a way that the energy balance of the storage process is in agreement with the first law of thermodynamics. A comparison of the stratification efficiencies obtained from experimental results of charging, standby, and discharging processes gives meaningful insights into the different mixing behaviors of a storage tank that is charged and discharged directly, and a tank-in-tank system whose outer tank is charged and the inner tank is discharged thereafter. The new method has a great potential for the comparison of the stratification efficiencies of thermal energy storages and storage components such as stratifying devices.     

Thermal analysis of solar thermal energy storage in a molten-salt thermocline

A comprehensive, two-temperature model is developed to investigate energy storage in a molten-salt thermocline. The commercially available molten salt HITEC is considered for illustration with quartzite rocks as the filler. Heat transfer between the molten salt and quartzite rock is represented by an interstitial heat transfer coefficient. Volume-averaged mass and momentum equations are employed, with the Brinkman-Forchheimer extension to the Darcy law used to model the porous-medium resistance. The governing equations are solved using a finite-volume approach. The model is first validated against experiments from the literature and then used to systematically study the discharge behavior of thermocline thermal storage system. Thermal characteristics including temperature profiles and discharge efficiency are explored. Guidelines are developed for designing solar thermocline systems. The discharge efficiency is found to be improved at small Reynolds numbers and larger tank heights. The filler particle size strongly influences the interstitial heat transfer rate, and thus the discharge efficiency.     

Methods to determine stratification efficiency of thermal energy storage processes - Review and theoretical comparison

This paper reviews different methods that have been proposed to characterize thermal stratification in energy storages from a theoretical point of view. Specifically, this paper focuses on the methods that can be used to determine the ability of a storage to promote and maintain stratification during charging, storing and discharging, and represent this ability with a single numerical value in terms of a stratification efficiency for a given experiment or under given boundary conditions. Existing methods for calculating stratification efficiencies have been applied to hypothetical storage processes of charging, discharging and storing, and compared with the rate of entropy production caused by mixing calculated for the same experiments. The results depict that only one of the applied methods is in qualitative agreement with the rate of entropy production, however, none of the applied methods is in agreement with the rate of entropy production and also able to distinguish between the entropy production caused by mixing and the entropy changes due to heat losses.     

Thermal energy storage technologies and systems for concentrating solar power plants

This paper presents a review of thermal energy storage system design methodologies and the factors to be considered at different hierarchical levels for concentrating solar power (CSP) plants. Thermal energy storage forms a key component of a power plant for improvement of its dispatchability. Though there have been many reviews of storage media, there are not many that focus on storage system design along with its integration into the power plant. This paper discusses the thermal energy storage system designs presented in the literature along with thermal and exergy efficiency analyses of various thermal energy storage systems integrated into the power plant. Economic aspects of these systems and the relevant publications in literature are also summarized in this effort.     

The potential of metal hydrides paired with compressed hydrogen as thermal energy storage for concentrating solar power plants

Concentrating solar power (CSP) plants require thermal energy storage (TES) systems to produce electricity during the night and periods of cloud cover. The high energy density of high-temperature metal hydrides (HTMHs) compared to state-of-the-art two-tank molten salt systems has recently promoted their investigation as TES systems. A common challenge associated with high-temperature metal hydride thermal energy storage systems (HTMH TES systems) is storing the hydrogen gas until it is required by the HTMH to generate heat. Low-temperature metal hydrides can be used to store the hydrogen but can comprise a significant proportion of the overall system cost and they also require thermal management, which increases the engineering complexity. In this work, the potential of using a hydrogen compressor and large-scale underground hydrogen gas storage using either salt caverns or lined rock caverns has been assessed for a number of magnesium- and sodium-based hydrides: MgH₂, Mg₂FeH₆, NaMgH₃, NaMgH₂F and NaH. Previous work has assumed that the sensible heat of the hydrogen released from the HTMH would be stored in a small, inexpensive regenerative material system. However, we show that storing the sensible heat of the hydrogen released would add between US$3.6 and US$7.5/kWh_th to the total system cost for HTMHs operating at 565 °C. If the sensible heat of released hydrogen is instead exploited to perform work then there is a flow-on cost reduction for each component of the system. The HTMHs combined with underground hydrogen storage all have specific installed costs that range between US$13.7 and US$26.7/kWh_th which is less than that for current state-of-the-art molten salt heat storage. Systems based on the HTMHs Mg₂FeH₆ or NaH have the most near term and long term potential to meet SunShot cost targets for CSP thermal energy storage. Increasing the operating temperature and hydrogen equilibrium pressure of the HTMH is the most effective means to reduce costs further.     

Evaluation and selection of energy storage systems for solar thermal applications

Energy storage is one of the key technologies for energy conservation and therefore is of great practical importance. One of its main advantages is that it is best suited for solar thermal applications. This study deals with a comprehensive discussion of the evaluation and the selection of sensible and latent heat storage technologies, systems and applications in the field of solar energy. Several issues relating to energy storage are examined from the current perspective. In addition, some criteria, techniques, recommendations, checklists on the selection, implementation and operation of energy storage systems are provided for the use of energy engineers, scientists and policy makers. Copyright © 1999 John Wiley & Sons, Ltd.     

Sensitivity analysis for thermocline thermal storage tank design

Concentrated solar power coupled with thermal energy storage is a promising approach for providing the world with clean, renewable, sustainable and cost-competitive power on a large scale. Thermocline thermal energy storage has been proposed as an efficient and cost-competitive alternative to the traditional two-tank design. The thermocline thickness is directly linked to the efficiency of the storage tank. Sensitivity analysis is thus applied to a model of the thermocline thickness to identify the parameters that influence it the most. Results indicate that the tank height along with the thermophysical properties of the solid filler material influence the tank efficiency the most, with fluid properties and having a secondary effect.     

Simulated energy and exergy analyses of the charging of an oil-pebble bed thermal energy storage system for a solar cooker

Energy balance equations are used to model the solar energy capture (SEC) system and the thermal energy storage (TES) system of a proposed indirect solar cooker. An oil-pebble bed is used as the TES material. Energy and exergy analyses are carried out using two different charging methods to predict the performance of the TES system. The first method charges the TES system at a constant flowrate. In the second method, the flowrate is made variable to maintain a constant charging temperature. A Simulink block model is developed to solve the energy balance equations and to perform energy and exergy analyses. Simulation results using the two methods indicate a greater degree of thermal stratification and energy stored when using constant-temperature charging than when using constant-flowrate charging. There are greater initial energy and exergy rates for the constant-flowrate method when the solar radiation is low. Energy efficiencies using both methods are comparable whilst the constant-temperature method results in greater exergy efficiency at higher levels of the solar radiation. Parametric results showing the effect of each charging method on the energy and exergy efficiencies are also presented.     

Evaluation of distributed building thermal energy storage in conjunction with wind and solar electric power generation

Energy storage is often seen as necessary for the electric utility systems with large amounts of solar or wind power generation to compensate for the inability to schedule these facilities to match power demand. This study looks at the potential to use building thermal energy storage as a load shifting technology rather than traditional electric energy storage. Analyses are conducted using hourly electric load, temperature, wind speed, and solar radiation data for a 5-state central U.S. region in conjunction with simple computer simulations and economic models to evaluate the economic benefit of distributed building thermal energy storage (TES). The value of the TES is investigated as wind and solar power generation penetration increases. In addition, building side and smart grid enabled utility side storage management strategies are explored and compared. For a relative point of comparison, batteries are simulated and compared to TES. It is found that cooling TES value remains approximately constant as wind penetration increases, but generally decreases with increasing solar penetration. It is also clearly shown that the storage management strategy is vitally important to the economic value of TES; utility side operating methods perform with at least 75% greater value as compared to building side management strategies. In addition, TES compares fairly well against batteries, obtaining nearly 90% of the battery value in the base case; this result is significant considering TES can only impact building thermal loads, whereas batteries can impact any electrical load. Surprisingly, the value of energy storage does not increase substantially with increased wind and solar penetration and in some cases it decreases. This result is true for both TES and batteries and suggests that the tie between load shifting energy storage and renewable electric power generation may not be nearly as strong as typically thought.     

Economic evaluation of latent heat thermal energy storage using embedded thermosyphons for concentrating solar power applications

An economic evaluation of a latent heat thermal energy storage (LHTES) system for large scale concentrating solar power (CSP) applications is conducted. The concept of embedding gravity-assisted wickless heat pipes (thermosyphons) within a commercial-scale LHTES system is explored through use of a thermal network model. A new design is proposed for charging and discharging a large-scale LHTES system. The size and cost of the LHTES system is estimated and compared with a two-tank sensible heat energy storage (SHTES) system. The results suggest that LHTES with embedded thermosyphons is economically competitive with current SHTES technology, with the potential to reduce capital costs by at least 15%. Further investigation of different phase change materials (PCMs), thermosyphon working fluids, and system configurations has the potential to lead to designs that can further reduce capital costs beyond those reported in this study.     

A review on long-term sorption solar energy storage

In the past decade, long-term sorption and thermochemical heat storage has generated lot of interest. This paper presents the state of the art in this field of research, materials used in these systems and technological difficulties that researchers are set against. An emphasis is put on recent demonstrative projects including absorption and adsorption for long-term solar energy storage. It emerges that considerable breakthrough have been made. Even though there is no mature long-term sorption or thermochemical energy storage yet, primarily due to the high cost of materials, the suitability of this technology to long-term storage remains its main power of attracting.     

Dynamic simulation of thermal energy storage system of Badaling 1 MW solar power tower plant

In this paper, the thermal energy storage system of Badaling 1 MW solar power tower plant is modelled from mathematical models for whole of the working conditions using the modular modelling method. This model can accurately simulate the recharge and discharge processes of thermal energy storage system. The dynamic and static characteristics of the thermal energy storage system are analyzed based on the model response curves of the system state parameters that are obtained from different steam flow disturbances. Conclusions of this paper are good references for the design, operating, and control strategy of solar thermal power plant.     

Methodology for optimized operation strategies of solar thermal power plants with integrated heat storage

The entry into the Spanish market of solar thermal power plants with integrated heat storage offers operators the opportunity to increase their yearly revenues. If maximum revenues are to be obtained, the actual electricity price and weather forecast must be taken into account and the power plant must consequently be run with a price-driven strategy. To achieve this, it is necessary to solve a complex optimization problem for scheduling the power selling at the day-ahead market. The derivation of the optimization problem is presented and its adaption to dynamic programming will be shown in the present paper.     

Selection of metal hydrides for a thermal energy storage device to support low-temperature concentrating solar power plants

Metal hydrides have become more and more significant both as hydrogen storage devices and as basic elements in energy conversion systems. Besides the well-known rare earth hydrides, magnesium alloys are very promising in the field of thermal energy storage for concentrating solar power plants. There is interest in analysing the performances of such materials in this context; for this purpose, a numerical model to describe hydrogen absorption and desorption processes of a metal hydride has been connected to a model elaborated with the help of Cycle-Tempo software to simulate a CSP plant operation. The integration of this plant with four metal hydride systems, based on the combination of two low-temperature hydrides (LaNi₅, LaNi_4.8Al_0.2) and two high-temperature hydrides (Mg, Mg₂Ni) has been studied. The investigation has taken into account CSP overall performances, transfer surfaces and storage efficiencies, to determine the feasibility of designed plants. Results show that the selection of the optimal hydrides must take into account hydride operation temperatures, reaction enthalpies, storage capacities and kinetic compatibility. In the light of the calculated parameters, a solar ORC plant using R134a as the working fluid is a valuable choice if matched to a storage system composed of LaNi₅ and Mg₂Ni hydrides.     

Simulation of high temperature thermal energy storage system based on coupled metal hydrides for solar driven steam power plants

Concentrating solar power plants can achieve low cost and efficient renewable electricity production if equipped with adequate thermal energy storage systems. Metal hydride based thermal energy storage systems are appealing candidates due to their demonstrated potential for very high volumetric energy densities, high exergetic efficiencies, and low costs. The feasibility and performance of a thermal energy storage system based on NaMgH₂F hydride paired with TiCr_1.6Mn_0.2 is examined, discussing its integration with a solar-driven ultra-supercritical steam power plant. The simulated storage system is based on a laboratory-scale experimental apparatus. It is analyzed using a detailed transport model accounting for the thermochemical hydrogen absorption and desorption reactions, including kinetics expressions adequate for the current metal hydride system. The results show that the proposed metal hydride pair can suitably be integrated with a high temperature steam power plant. The thermal energy storage system achieves output energy densities of 226 kWh/m³, 9 times the DOE SunShot target, with moderate temperature and pressure swings. In addition, simulations indicate that there is significant scope for performance improvement via heat-transfer enhancement strategies.     

Operation strategies guideline for packed bed thermal energy storage systems

Packed bed thermal energy storage (TES) systems have been identified in the last years as one of the most promising TES alternatives in terms of thermal efficiency and economic viability. The relative simplicity of this storage concept opens an important opportunity to its implementation in many environments, from the renewable solar‐thermal frame to the industrial waste heat recovery. In addition, its implicit flexibility allows the use of a wide variety of solid materials and heat transfer fluids, which leads to its deployment in very different applications. Its potential to overcome current heat storage system limitations regarding suitable temperature ranges or storage capacities has also been pointed out. However, the full implementation of the packed bed storage concept is still incomplete since no industrial scale units are under operation. The main underlying reasons are associated to the lack of a complete extraction of the full potential of this storage technology, derived from a successful system optimization in terms of material selection, design, and thermal management. These points have been evidenced as critical in order to attain high thermal efficiency values, comparable to the state‐of‐the‐art storage technologies, with improved technoeconomic performance. In order to bring this storage technology to a more mature status, closer to a successful industrial deployment, this paper proposes a double approach. First, a low‐cost by‐product material with high thermal performance is used as heat storage material in the packed bed. Second, a complete energetic and efficiency analysis of the storage system is introduced as a function of the thermal operation. Overall, the impact of both the selected storage material and the different thermal operation strategies is discussed by means of a thermal model which permits a careful discussion about the implications of each TES deployment strategy and the underlying governing mechanisms. The results show the paramount importance of the selected operation method, able to increase the resulting cycle and material usage efficiency up to values comparable to standard currently used TES solutions.     

Latent heat storage for solar energy systems: Transient simulation of refrigerant storage

This paper presents a brief review of the available latent heat storage systems for solar energy utilization. A new concept of latent heat storage of solar energy via the refrigerant-absorbent mass storage in absorption cycle heat pump systems used for solar space heating/cooling has been proposed and assessed thermodynamically. A computer modelling and numerical simulation study shows that the concept of refrigerant storage is fundamentally sound, technically feasible and yields the following advantages over other storage methods: (i) the storage capacity per unit volume is high as the latent heat of vaporization of the refrigerant is high; (ii) the heat loss from the storage to the surroundings is minimum as the storage temperature is near the ambient; (iii) prolonged energy storage is possible with no degradation in system performance and hence suitable for combined solar heating and airconditioning. The effects of operating parameters on the energy storage concentration and storage efficiency have been studied in detail.     

A review on thermal energy storage systems in solar air heaters

The drying needs of agricultural, industrial process heat requirements and for space heating, solar energy is one of the prime sources which is renewable and pollution free. As the solar energy is inconsistent and nature dependent, more often there is a mismatch between the solar thermal energy availability and requirement. This drawback could be addressed to an extent with the help of thermal energy storage systems combined with solar air heaters. This review article focuses on solar air heaters with integrated and separate thermal energy storage systems as well as greenhouses with thermal storage units. A comprehensive study was carried out in solar thermal storage units consisting of sensible heat storage materials and latent heat storage materials. As the phase change heat storage materials offer many advantages over the sensible heat storage materials, the researchers are more interested in this system. The charging and discharging characteristics of thermal storage materials with various operational parameters have been reported. All the possible solar air heater applications with storage units have also been discussed.