Evaluation of the performance of CBN tools when turning Ti–6Al–4V alloy with high pressure coolant supplies

Cubic Nitride Boron (CBN) tools are generally used for machining harder alloys such as hardened high Cr steels, titanium and nickel alloys. The tools are expected to withstand the heat and pressure developed when machining at higher cutting conditions because of their high hardness and melting point. This paper evaluates the performance of different CBN tool grades in finish turning Ti–6Al–4V (IMI 318) alloy at high cutting conditions, up to 250 m min⁻¹, with various coolant supplies. Tool wear, failure modes, cutting and feed forces and surface roughness of machined surfaces were monitored and used to access the performance of the cutting tools. Comparative trials were carried out with uncoated carbide tools when machining at a speed of 150 m min⁻¹. Test results show that the performance of CBN tools, in terms of tool life, at the cutting conditions investigated is poor relative to uncoated carbide tools, as expected and often, reported due probably to rapid notching and excessive chipping of the cutting edge associated with a relatively high diffusion wear rate that tends to weaken the bond strength of the tool substrate. An increase in the CBN content of the cutting tool also led to a reduction in tool life when machining at the cutting conditions investigated.     

Thermodynamic analysis of alloys Ti–Al, Ti–V, Al–V and Ti–Al–V

Thermodynamic analysis of three binary Ti-based alloys: Ti–Al, Ti–V, and Al–V, as well as ternary alloy Ti–Al–V, is shown in this paper. Thermodynamic analysis involved thermodynamic determination of activities, coefficient of activities, partial and integral values for enthalpies and Gibbs energies of mixing and excess energies at four different temperatures: 2000, 2073, 2200 and 2273 K, as well as calculated phase diagrams for the investigated binary and ternary systems. The FactSage is used for all thermodynamic calculations.     

In situ impedance spectroscopy study of the electrochemical corrosion of Ti and Ti–6Al–4V in simulated body fluid at 25 °C and 37 °C

The corrosion resistance of Ti and Ti–6Al–4V was investigated through electrochemical impedance spectroscopy, EIS, potentiodynamic polarisation curves and UV–Vis spectrophotometry. The tests were done in Hank solution at 25 °C and 37 °C. The EIS measurements were done at the open circuit potential at specific immersion times. An increase of the resistance as a function of the immersion time was observed, for Ti (at 25 °C and 37 °C), and for Ti–6Al–4V (at 25 °C), which was interpreted as the formation and growth of a passive film on the metallic surfaces.     

High-speed milling of titanium alloys using binderless CBN tools

The performance of conventional tools is poor when used to machine titanium alloys. In this paper, a new tool material, which is binderless cubic boron nitride (BCBN), is used for high-speed milling of a widely used titanium alloy Ti–6Al–4V. The performance and the wear mechanism of the BCBN tool have been investigated when slot milling the titanium alloy in terms of cutting forces, tool life and wear mechanism. This type of tool manifests longer tool life at high cutting speeds. Observations based on the SEM and EDX suggest that adhesion of workpiece and attrition are the main wear mechanisms of the BCBN tool when used in high-speed milling of Ti–6Al–4V.     

Observations on chip formation and acoustic emission in machining Ti–6Al–4V alloy

Orthogonal cutting tests were undertaken to investigate the mechanisms of chip formation for a Ti–6Al–4V alloy and to assess the influences of such on acoustic emission (AE). Within the range of conditions employed (cutting speed, v_c=0.25–3.0 m/s, feed, f=20–100 μm), saw-tooth chips were produced. A transition from aperiodic to periodic saw-tooth chip formation occurring with increases in cutting speed and/or feed. Examination of chips formed shortly after the instant of tool engagement, where the undeformed chip thickness is slightly greater than the minimum undeformed chip thickness, revealed a continuous chip characterised by the presence of fine lamellae on its free surface. In agreement with the consensus that shear localisation in machining Ti and its alloys is due to the occurrence of a thermo-plastic instability, the underside of saw-tooth segments formed at relatively high cutting speeds, exhibiting evidence of ductile fracture. Chips formed at lower cutting speeds suggest that cleavage is the mechanism of catastrophic failure, at least within the upper region of the primary shear zone. An additional characteristic of machining Ti–6Al–4V alloy at high cutting speeds is the occurrence of welding between the chip and the tool. Fracture of such welds appears to be the dominant source of AE. The results are discussed with reference to the machining of hardened steels, another class of materials from which saw-tooth chips are produced.     

Dry drilling of alloy Ti–6Al–4V

This work is focused on the combined study of the evolution of tool wear, quality of machined holes and surface integrity of work-piece, in the dry drilling of alloy Ti–6Al–4V. Tool wear was studied with optical microscope and SEM–EDS techniques. The quality of machined holes was estimated in terms of geometrical accuracy and burr formation. Surface integrity involves the study of surface roughness, metallurgical alterations and microhardness tests. The end of tool life was reached because of catastrophic failure of the drill, but no significant progressive wear in cutting zone was observed previously. High hole quality was observed even near tool catastrophic failure, evaluated from the point of view of dimensions, surface roughness and burr height. However, microhardness measurements and SEM–EDS analysis of work-piece showed important microstructural changes related with a loss of mechanical properties. Depending on the application of the machined component, the state of the work-piece could be more restrictive than the tool wear, and the end of tool life should be established from the point of view of controlled damage in a work-piece.     

A novel Al–Ti–B alloy for grain refining Al–Si foundry alloys

Al–Ti–B refiners with excess-Ti (Ti:B > 2.2) perform adequately for wrought aluminium alloys but they are not as efficient in the case of foundry alloys. Silicon, which is abundant in the latter, forms silicides with Ti and severely impairs the potency of TiB₂ and Al₃Ti particles. Hence, Al–Ti–B alloys with excess-B (Ti:B < 2.2) and binary Al–B alloys are favored to grain refine hypoeutectic Al–Si alloys. These grain refiners rely on the insoluble (Al,Ti)B₂ or AlB₂ particles for grain refinement, and thus do not enjoy the growth restriction provided by solute Ti. It would be very attractive to produce excess-B Al–Ti–B alloys which additionally contain Al₃Ti particles to maximize their grain refining efficiency for aluminium foundry alloys. A powder metallurgy process was employed to produce an experimental Al–3Ti–3B grain refiner which contains both the insoluble AlB₂ and the soluble Al₃Ti particles. Inoculation of a hypoeutectic Al–Si foundry alloy with this grain refiner has produced a fine equiaxed grain structure across the entire section of the test sample which was more or less retained for holding times up to 15 min.     

Strong bonding of infrared brazed α2-Ti3Al and Ti–6Al–4V using Ti–Cu–Ni fillers

Infrared dissimilar brazing of α₂-Ti₃Al and Ti–6Al–4V using Ti–15Cu–25Ni and Ti–15Cu–15Ni filler metals has been performed in this study. The brazed joint consists primarily of Ti-rich and Ti₂Ni phases, and there is no interfacial phase among the braze alloy, α₂-Ti₃Al and Ti–6Al–4V substrates. The existence of the Ti₂Ni intermetallic compound is detrimental to the bonding strength of the joint. The amount of Ti₂Ni decreases with increasing brazing temperature and/or time due to the depletion of Ni content from the braze alloy into the Ti–6Al–4V substrate during brazing. The shear strength of the brazed joint free of the blocky Ti₂Ni phase is comparable with that of the α₂-Ti₃Al substrate, and strong bonding can thus be obtained.     

The effects of lanthanum on microstructure and electrochemical properties of Al–Zn–In based sacrificial anode alloys

In order to improve the non-uniform corrosion of Al–0.5Zn–0.03In–1Mg–0.05Ti alloys, Al–5Zn–0.03In–1Mg–0.05Ti–xLa (x = 0.3, 0.5 and 0.7 wt.%) alloys were developed. Microstructures and electrochemical properties of the alloys were investigated. The results show that the optimal microstructures and electrochemical properties are obtained in Al–5Zn–0.03In–1Mg–0.05Ti–0.5La alloy. The main precipitate phase is Al₂LaZn₂ particles. The excellent electrochemical properties of Al–5Zn–0.03In–1Mg–0.05Ti–0.5La alloy is mainly attributed to fine grains and grain boundaries containing fine Al₂LaZn₂ precipitates. At the same time the fine grains can improve the non-uniform corrosion of Al–0.5Zn–0.03In–1Mg–0.05Ti alloy.     

High-speed machining of titanium alloys using the driven rotary tool

Machining of titanium at high cutting speeds such as from 4 m/s to 8 m/s is very challenging. In this paper, a new generation of driven rotary lathe tool was developed for high-speed machining of a titanium alloy, Ti–6Al–4V. The rotary tool was designed and fabricated based on the requirements of compact structure, sufficient stiffness and minimal edge runout. Cylindrical turning experiments were conducted using the driven rotary tool (DRT) and a stationary cutting tool with the same insert, for comparison in the high-speed machining of Ti–6Al–4V. The results showed that the DRT can significantly increase tool life. Increase in tool life of more than 60 times was achieved under certain conditions. The effects of the rotational speed of the insert were also investigated experimentally. Cutting forces were found to decline slightly with increase of the rotational speed. Tool wear appears to increase with the rotational speed in a certain speed range.     

Microstructure and grain refining performance of a new Al–Ti–C–B master alloy

A kind of Al–Ti–C–B master alloy with a uniform microstructure is prepared using a melt reaction method. It is found that the average grain size of α-Al can be reduced from 3500 to 170 μm by the addition of 0.2 wt.% of the prepared Al–5Ti–0.3C–0.2B and the refining efficiency does not fade obviously within 60 min. It is considered that the TiC_xB_y and TiB_2−mC_n particles found at the grain center are the effective and stable nucleating substrates for α-Al during solidification, which accounts for the good grain refining performance.     

Tool life and wear mechanisms in high speed machining of Ti–6Al–4V alloy with PCD tools under various coolant pressures

Usage of titanium alloys has increased since the past 50 years despite difficulties encountered during machining. Many studies involving different tool materials, cutting parameters, tool geometry and cutting fluids when machining this important aerospace material have been published. However, there are relatively few literatures available on the application of ultra hard tools in the machining of titanium-alloys. The primary objective of this study is to investigate the behaviour of Polycrystalline Diamond (PCD) tools when machining Ti–6Al–4V alloy at high speed conditions using high pressure coolant supplies. Tool performance under different tribological conditions and the dominant wear mechanisms were investigated. Increase in coolant pressure tends to improve tool life and reduce the adhesion tendency, accelerated by the susceptibility of titanium alloy to gall during machining. Adhesion and attrition are the dominant wear mechanisms when machining at the cutting conditions investigated.     

Deformation history and the resultant microstructure and texture in backward tube spinning of Ti–6Al–2Zr–1Mo–1V

The correlations of microstructure and texture with deformation history in backward tube spinning were studied. Deformation history was calculated with initial and some intermediate configurations as reference configuration from FEM analysis. Microstructure and texture were investigated in the experimental workpiece of Ti–6Al–2Zr–1Mo–1V. The results show an obvious through-thickness inhomogeneity in deformation, microstructure and texture. Large material rotation occurs and plenty of grains are kinked and distorted in the outer layer, especially when thick-wall billet is spun. Deformation difference diminishes with wall thickness decreasing. The inhomogeneity of as-spun microstructure is reduced obviously in multi-pass and large deformation (for example, 85% total reduction) tube spinning. {0 0 0 2} texture develops generally without orthotropic symmetry. Textures in the outer and inner layers evolve differently because of inhomogeneous deformation histories.     

Microstructural changes and estimated strengthening contributions in a gamma alloy Ti–45Al–5Nb pack-rolled sheet

Thin sheets made of a gamma-titanium aluminide alloy, Ti–45Al–5Nb, produced by a pack-rolling process, were evaluated for microstructure variation and evolution taking place during aging and annealing treatments. The as-received sheet material was characterized by remarkably high yield strength, 810 MPa, and a complex bimodal microstructure. The microstructure consisted of a matrix of twinned gamma-phase grains and fine-lath lamellar grain microconstituent, together with a dispersed ultra-fine-grained gamma + alpha-2 mixture microconstituent. High-temperature isothermal aging treatments changed the microstructure to a stable mixture of gamma-phase grains (matrix) and coarse alpha-2-phase particles, having size distributions and volume fractions that were specific to the aging temperature. A concurrent strength loss reflects this trend and results in a stable strength level of 550 MPa upon aging at 1000 °C for 144 h. Using composition estimates from the phase-boundary shifts that occur from the Nb addition to a Ti–45Al base alloy and, the rule of mixtures, an analysis was made to show that the gamma-phase matrix has an intrinsic strength of 178 MPa. This is a significant intrinsic strength level, well over that of 70 MPa for the Ti–45Al binary alloy. This is rationalized as the solid-solution strengthening effect from shifts of the Ti and Nb levels in the gamma phase and, by an added effect due to increased oxygen solubility in the gamma phase. The overall strength of Ti–45Al–5Nb, however, is roughly the same as that of Ti–45Al, and this is explained by a drastic reduction in the volume fraction of alpha-2-phase in Ti–45Al–5Nb alloy, which is a result of the Nb-induced phase-boundary shifts.     

Thermo-optical modulation for improved ultrasonic fatigue crack detection in Ti–6Al–4V

Pulsed infrared laser irradiation was used to positively identify small fatigue cracks on the surface of fatigue damaged Ti–6Al–4V specimens. The resulting transient thermoelastic deformation perceptibly changes the opening of partially closed surface cracks without affecting other scatterers, such as surface grooves, corrosion pits, coarse grains, etc. that might hide the fatigue crack from ultrasonic detection. We found that this method, which was previously shown to be very effective in 2024 aluminum alloy, must be modified in order to successfully adapt it to Ti–6Al–4V titanium alloy, where significant thermo-optical modulation was found even from straight corners or open notches. This spurious modulation is caused by direct thermal modulation of the sound velocity in the intact material rather than thermal stresses via crack closure. Different methods have been developed to distinguish direct thermal modulation from crack-closure modulation due to thermoelastic stresses. It was found that the modified thermo-optical modulation method can increase the detectability of hidden fatigue cracks in Ti–6Al–4V specimens by approximately one order of magnitude.     

Grain refinement of cast titanium alloys via trace boron addition

The grain size of as-cast Ti–6Al–4V is reduced by about an order of magnitude from 1700 to 200 μm with an addition of 0.1 wt.% boron. A much weaker dependence of reduction in grain size is obtained for boron additions from >0.1% to 1.0%. Similar trends were observed in boron-modified as-cast Ti–6Al–2Sn–4Zr–2Mo–0.1Si.     

Al–Ti–B grain refiners via powder metallurgy processing of Al/K2TiF6/KBF4 powder blends

The response to thermal exposure of ball-milled Al/K₂TiF₆/KBF₄ powder blends was investigated to explore the potential of PM processing for the manufacture of Al–Ti–B alloys. K₂TiF₆ starts to be reduced by aluminium as early as 220 °C when ball-milled Al/K₂TiF₆/KBF₄ powder blends are heated. The reaction of KBF₄ with aluminium follows soon after. The Ti and B thus produced are both solutionized in aluminium before precipitating out as Al₃Ti and TiB₂. All these reactions take place below the melting point of aluminium. The ball-milled Al/K₂TiF₆/KBF₄ powder blends heat treated at approximately 525 °C can be compacted to produce Al–Ti–B pellets with in situ formed Al₃Ti and TiB₂ particles. These pellets are shown to be adequate grain refiners for aluminium alloys.     

Al–Ti–C–Sr master alloy—A melt inoculant for simultaneous grain refinement and modification of hypoeutectic Al–Si alloys

Present article is focused on the microstructural features of Al–Ti–C–Sr master alloy, an inoculant for simultaneous grain refinement and modification of hypoeutectic Al–Si alloys. This master alloy is basically a metal matrix composite consisting of TiC and Al₄Sr phases formed in situ in the Al-matrix. TiC particles initiate the refinement of primary α-Al through heterogeneous nucleation in molten hypoeutectic Al–Si alloy, while Al₄Sr phase dissolves in molten Al–7Si alloy enriching the melt with Sr, which eventually leads to modification of eutectic silicon during solidification of the Al–7Si alloy casting. Thus present master alloy serves in both ways, as a grain refiner and a modifier for hypoeutectic Al–Si alloys.     

Hydrolysis of ball milling Al–Bi–hydride and Al–Bi–salt mixture for hydrogen generation

In this paper, an effective method to produce hydrogen via the hydrolysis of the milled Al–Bi–hydride (or salts) in pure water at room temperature has been found. The result shows that the Al–Bi–hydrides (or salts) prepared by 5 h milling appear very effective to improve their hydrolysis reactivity. And the milled Al–Bi–hydrides (or salts) have high hydrogen yield in pure water, especially the Al–10 wt.% Bi–10 wt.% MgH₂ mixture or Al–10 wt.% Bi–10 wt.% MgCl₂ mixture all can produce 1050 ml/g within 5 min. The improvement mainly comes from three factors: (1) the additives (MgH_2, CaH₂, LiCl, MgCl₂, KCl, etc.) play an important role to decrease the mean size of the mixture particles; (2) the exothermic dissolution of the salt additive such as MgCl₂ can increase the temperature of aqueous solution, favoring the reaction between Al–Bi composite and water; (3) the hydrolysis of the additives can also offer conductive ions on the work of the micro-galvanic cell of Al–Bi composite. Furthermore, the high conductive ions around the Al–Bi composite are the uppermost effect for increasing the hydrogen yield and hydrogen generation rate.     

Micromilling characteristics and electrochemically assisted reconditioning of polycrystalline diamond tool surfaces for ultra-precision machining of high-purity SiC

The production of extremely thick silicon carbide (SiC) has recently become possible with the advent of a specific chemical vapor deposition process. Ultra-precision machining of high-purity SiC has been performed by using a polycrystalline diamond (PCD) micromilling tool to investigate the machining characteristics. Results indicate that a high-quality surface (R_a = 1.7 nm) can be obtained when the removed chips are thin enough to achieve ductile mode machining. Micron-sized wells and groove structures with nanometer-scale surface roughness were successfully machined by using the PCD tool. In addition, a new electrochemically assisted surface reconditioning process has been proposed to remove the contaminant material adhered onto the PCD tool surfaces after prolonged machining.