共查询到20条相似文献,搜索用时 15 毫秒
1.
The doping effect of the bubble formation oxide on the recrystallization of Mo wire was investigated. Five different wires
of 1 mm in diameter were prepared through sintering, swaging, and drawing processes. Each wire was doped with various amounts
of potassium (K) plus silicon (Si), i.e., 0, 0.028, 0.14, 0.28, and 0.49 by weight percent, and annealed for 30 minutes at
given temperatures. To understand the overall recrystallization phenomena, changes in hardness and in optical microstructures
were examined. Transmission electron micrographs were taken for the specimens in the as-drawn state and at the beginning of
the decrease in hardness. And also, the relative excess resistivity was measured as a function of heating temperature to confirm
the occurrence of the abnormal grain growth. During the grain growth, bubble dispersion was evaluated through fractography
by scanning electron microscopy (SEM). Primary re-crystallization started at 750 °C regardless of the amount of dopants. For
the specimens doped with 0.14 and 0.28 (K + Si), large elongated and interwoven grain structures indicating ab-normal grain
growth developed over 1400 °C and 1600 °C, respectively. For the specimens doped with 0.028 and 0.49 (K + Si), however, small
equiaxial grain structure developed similar to pure molybdenum wire. Such a difference was understood through the relationship
between grain structures and bubble dispersion parameters (the average bubble diameter, the bubble row density, the columnar
bubble spacing, and the bubble row distance). It was concluded that two of the most important parameters to develop a grain
structure of high aspect ratio were bubble row density and bubble row distance. At a high bubble row density, irregularity
in bubble row distance induced the higher aspect ratio (length/width (L/W)) of grain. 相似文献
2.
二次再结晶的发生会显著改变电工钢带材的组织和织构,进而影响其磁性能。以柱状晶组织高硅电工钢冷轧带材为研究对象,研究了不同退火方法对试样组织和织构的影响,明确了二次再结晶的发生条件、形成机理和控制方法。研究结果表明,柱状晶组织高硅电工钢冷轧试样发生二次再结晶的温度区间为850~1 000 ℃,在900 ℃退火可获得最大的晶粒尺寸。二次再结晶的形成是由于初次再结晶后试样的组织形成了织构抑制作用,小角度晶界抑制晶粒正常长大,大角度高能晶界迁移率高,具有大角度晶界的晶粒以取向长大方式发生二次再结晶。当退火温度高于1 000 ℃时,升温和冷却速率大于5 ℃/min可以有效抑制二次再结晶的发生。 相似文献
3.
通过对比中温含铜取向硅钢与普通取向硅钢和高磁感取向硅钢的组织和织构特征,分析中温含铜取向硅钢独特的织构演变规律及其对二次再结晶行为的影响.结果表明,为了获得有利于高斯晶粒长大的强γ取向线织构,中温含铜钢需经过回复退火处理和高温退火阶段慢速升温.回复过程中γ取向线晶粒储能降低,同时慢速升温有利于γ取向线晶粒的形核和再结晶.中温含铜钢的二次再结晶开始温度超过1000℃,由于初次再结晶晶粒组织以γ织构为主且非γ取向线晶粒较少,导致最终二次晶粒尺寸超大且晶界圆滑,二次再结晶机理以择优长大为主导,超大的二次晶粒尺寸导致最终成品的铁损升高,但通过激光刻痕处理后,整体铁损的降低效果比二次晶粒较小的高磁感取向硅钢更加显著. 相似文献
4.
《Acta Metallurgica》1986,34(7):1329-1334
The secondary recrystallization of drawn pure Mo wires has been studied; a particular attention has been paid on the effect of temperature gradients in the annealing process. The secondary recrystallized grains being very elongated along the wire axis have been obtained by annealing in a moderate temperature gradient furnace at about 2000°C. Orientations of the wire axis of the secondary recrystallized grains are mainly 〈023〉 or 〈135〉, while 〈011〉 oriented grains are less frequently observed. In contrast, the primary recrystallized texture consists of the 〈011〉 main component and 〈023〉-〈012〉 sub-component; many 〈011〉 oriented grains have large grain sizes. The observed discrepancy in orientation between the primary and secondary recrystallized grains is explained in terms of the difference in grain boundary mobilities which depend on the character of grain boundaries. 相似文献
5.
6.
低温加热渗氮型取向硅钢二次再结晶完全、磁性能却不高是一种常见的现场质量问题,其成因的判断及问题的解决对降低生产成本至关重要。本文对两组企业生产中存在上述现象的低温渗氮钢的一次再结晶板进行高温退火中断实验,确定其二次再结晶温度及基体晶粒和二次晶粒的取向分布特征,探索其成因。结果表明,磁性能下降的原因是二次晶粒取向度偏差大,主要向{110}<227>取向偏转;其本质是一次晶粒尺寸偏小,二次再结晶温度提前了约50 ℃;高斯晶粒以外的偏高斯取向晶粒优先形成。两组样品的差异不在于其二次再结晶温度不同,而是二次晶粒的偏差度不同。这种差异又反映出两组样品微小的一次退火组织织构和抑制剂的差异或成分波动性。 相似文献
7.
8.
David B. Snow 《Metallurgical and Materials Transactions A》1979,10(7):815-821
The recrystallization processes in both undoped and doped tungsten wire after drawing to a true strain of 7.7 were examined
by light microscopy and transmission electron microscopy. High angle grain boundary migration commenced at approximately the
same temperature in both materials, but proceeded much more rapidly in the undoped wire, where the absence of a potassium
bubble dispersion allowed a coarser, more equiaxed grain structure to form. No change from the (110) deformation texture was
observed in either case. Recrystallization in the undoped wire was dominated at lower temperatures (1100 to 1200°C) by the
growth of large grains into a much finer structure. As the annealing temperature was increased, this process was replaced
by a general grain coarsening which eventually produced a relatively equiaxed recrystallized grain structure. It appeared
probable that it was the second phase dispersion inhibition alone that prevented similar structural changes in the doped wire.
This paper is based on a presentation made at a symposium on “Recovery Recrystallization and Grain Growth in Materials” held
at the Chicago meeting of The Metallurgical Society of AIME, October 1977, under the sponsorship of the Physical Metallurgy
Committee. 相似文献
9.
The recrystallization behavior of W-l wt pct ThO2 wires of two sizes, 0.457 and 0.178 mm (18 and 7 mil), was studied using optical microscopy, transmission electron microscopy,
hardness, and resistivity ratio techniques. For the 0.178 mm wire the effects of heating rate were also analyzed. Recrystallization
of the 18 mil wire is characterized by rather gradual changes in hardness, resistivity ratio, and microstructure leading to
a small recrystallized grain size. The 0.178 mm wire, on the other hand, exhibits more abrupt changes in resistivity ratio
and hardness which coincide with the development of a recrystallized structure having a large grain-size range. Variation
of heating rates between about 150,000°C/min and 500°C/min did not significantly affect the grain structure or hardness achieved
for annealing temperatures of 2000°, 2500°, and 2700°C. However, very slow heating rates, less than 10°C/min, were shown to
prevent the formation of large grains in the 0.178 mm wire. These results are explained on the basis of differences in the
effectiveness of ThO2 particles in hindering grain boundary motion. 相似文献
10.
11.
12.
13.
The microstructures and longitudinal fracture resistances of 0.635 mm diam lamp-doped and undoped tungsten wire were examined
in the as-drawn condition and after anealing at temperatures between 600 and 1500°C. A variety of experimental techniques
were employed, including Auger Electron Spectroscopy, Scanning Electron Microscopy, Transmission Electron Microscopy and a
newly developed mechanical testing technique. The longitudinal fracture mode was intergranular for all wires and a second
phase was observed on the grain boundaries of all doped wires. High concentrations of the dopant element potassium were present
on the fracture surfaces of doped wires and experimental evidence was obtained which suggests they may be due to postfracture
surface diffusion. Doped wires demonstrated increasing amounts of structure coarsening up to 1500°C whereas large equiaxed
grains were formed in undoped wires annealed at 1300 and 1500°C. The longitudinal fracture resistance of undoped wire was
unaltered by annealing at 1050°C and below, but decreased dramatically after annealing at 1300 and 1500°C. In contrast the
fracture resistance of doped wire decreased after annealing at 1050 and 1300°C, but increased after annealing at 1500°C. Fracture
resistance is discussed in terms of microstructure and fracture surface chemistry.
A. W. FUNKENBUSCH, formerly Research Metallurgist with General Electric Refractory Metals Product Department 相似文献
14.
Hein Pcter Stüwe 《Metallurgical and Materials Transactions A》1986,17(8):1455-1459
During recrystallization, potassium-doped tungsten wire develops a favorable stable structure of elongated grains. This is
caused by a special bubble structure which is produced by the doping agent, potassium. The paper aims at a coherent semiquantitative
model describing the formation of sinter pores, of potassium bands during deformation, of the bubble structure, and of driving
and dragging forces during recrystallization. 相似文献
15.
In low carbon steels, dissolution and precipitation of the second phases such as carbides and nitrides during annealing cycles can affect the final structure and properties of the materials. The interaction of above processes depends on parameters such as reheating temperature, heating rate, annealing temperature, soaking time and finishing temperature in hot rolling stage before cold rolling. The effects of heating rate and annealing temperature on the microstructure and hardness were investigated. Two heating rates for annealing temperatures of 550, 610 and 720℃ were applied on cold-rolled specimens and St-14 low carbon steel, which were immediately quenched after isothermal annealing. The intercept method was used tO measure average grain sizes. However, resulted microstructures are dif- ferent for the two heating rates. While pancaked structures were observed in specimens annealed with low heating rate, in samples annealed with high heating rate, equiaxed microstructures were observed. Vickers micro-hardness values decreased at all temperatures, which were more significant at higher temperatures. At longer annealing time, signs of increase of hardness values were detected. All results and observations consistently suggest that a precipitati- on process has occurred concurrently with restoration processes during annealing. In addition, the energy dispersive spectroscopy analysis resulted from transmission electron microscopic micrographs have proved that the nano particles precipitated in grain boundaries are AlN. 相似文献
16.
利用电子背散射衍射技术(EBSD)、扫描电镜(SEM)分析了低温取向硅钢常化工艺、渗氮工艺对常化组织、再结晶组织与抑制剂的影响, 对比研究了常化冷却速率、渗氮温度和渗氮量对再结晶组织、织构和磁性能的影响规律.结果表明, 常化冷却速率越快, 一次再结晶晶粒尺寸越小.常化冷却速率较慢时, 高温渗氮的样品一次再结晶晶粒尺寸偏大, 使二次再结晶驱动力降低, 二次再结晶温度提高, 且渗氮量低, 追加抑制剂不足, 最终二次再结晶不完善.高温渗氮与低温渗氮导致脱碳板中抑制剂尺寸不同, 高温渗氮表层抑制剂与次表层抑制剂尺寸基本无差异, 低温渗氮表层抑制剂尺寸比次表层抑制剂尺寸大.低温渗氮且渗氮量低的样品虽然二次再结晶较完善, 但由于其常化温度低、常化冷却速率快, 一次再结晶晶粒尺寸小, 二次再结晶开始温度稍早, 黄铜取向晶粒出现, 最终磁性差.渗氮量较高的高温渗氮和低温渗氮样品虽都能基本完成二次再结晶, 但磁性存在差异, 磁性差的原因是高温渗氮样品的最终退火板中出现较多的偏{210} < 001>取向晶粒. 相似文献
17.
Dopant particle characterization and bubble evolution in aluminum-potassium-silicon-doped molybdenum wire 总被引:1,自引:0,他引:1
L. E. Iorio B. P. Bewlay M. Larsen 《Metallurgical and Materials Transactions A》2002,33(11):3349-3356
The present article describes the creation of dopant inclusions in aluminum-potassium-silicon (AKS)-doped molybdenum powder
and the generation of potassium bubbles in doped molybdenum wire. Molybdenum wire is used extensively in the incandescent
lamp industry for coiling mandrels, filament support wires, and foil seals. The AKS-doped molybdenum wire is an important
product, because it possesses greater high-temperature strength and a higher recrystallization temperature than undoped molybdenum;
both of these properties are important for structural applications in lamps. The AKS-doped molybdenum wire is produced in
a similar manner to AKS-doped tungsten wire, but lower processing temperatures are typically used for the production of molybdenum
wire. Previous studies on AKS-doped tungsten wire have shown that the dispersion which provides the interlocking grain structure
in recrystallized tungsten wire is bubbles of elemental potassium; these enhance incandescent lamp filament life. However,
there is little previous work on the potassium-containing dispersion in AKS-doped molybdenum wire. In AKS-doped molybdenum,
the dispersion can be either potassium bubbles, or solid oxide particles, depending on the processing method. This article
will describe a series of analyses of doped molybdenum wire and its precursors, namely, doped powder and sintered ingots.
The roles of high- and low-temperature sintering are also described. 相似文献
18.
Ronald P. Simpson George J. Dooley T. W. Haas 《Metallurgical and Materials Transactions B》1974,5(3):585-591
The combination of Auger electron spectroscopy and scanning electron microscopy has identified the source of the unique interlocked
elongated grains responsible for the high temperature sag resistance in doped tungsten and tungsten-rhenium alloys as due
to bubbles which are formed by the volatilization of potassium during sintering. By pinning grain boundaries these bubbles
raise the recrystallization temperature (from 1300†C to 2100†C) and their distribution within the material controls the recrystallized
grain morphology. There is a thin layer of potassium remaining on the bubble surfaces. The size and distribution of the bubbles
is related to the amount of material deformation during processing. Increasing rhenium content does not affect the concentration
or distribution of residual potassium. It has no noticeable effect on bubble size, distribution or density. The presence of
a thermal gradient during annealing does affect bubble density and recrystallization temperature.
Formerly with the Air Force Materials Laboratory, Wright-Patterson AFB, Ohio
Formerly with the Aerospace Research Laboratory, Wright-Patterson AFB, Ohio 相似文献
19.
对应用动态加热进行短时温度退火的取向电工钢进行了二次再结晶研究。所进行研究的实验用取向电工钢是经过终冷轧和后续罩式退火后的一条工业化生产线生产的。研究结果表明,运用短时热处理条件可引起研究钢完全的异常晶粒长大。在实验室处理的材料的织构和金相组织与工业化生产的经过终退火而获得的相同的取向电工钢类似。但是,在实验室处理的取向电工钢的二次再结晶的矩阵中可观测到"寄生"晶粒。从磁性观点看,这些"寄生"晶粒含有不理想的{111}取向织构。 相似文献
20.
Chester W. Dawson 《Metallurgical and Materials Transactions B》1972,3(12):3103-3107
Bubble distributions in doped tungsten wires have been examined following high temperature anneals (2500° to 3000°C) both
in the presence and absence of a thermal gradient. Electron and optical microscopy show that much more bubble growth occurs
during gradient anneals, and the results suggest that the gradient is a driving force for bubble growth. This process takes
place predominantly on the grain boundaries. Semiquantitative estimates of the bubble flux were made by measuring the change
in aggregate bubble surface areas found at various positions in the gradient. Stress induced bubble growth was shown not to
be a factor. 相似文献