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以纳米SiO2为核。以MMA为壳层单体,进行了无皂乳液聚合。研究了单体加入方式、引发剂用量、聚合反应温度等对无皂乳液聚合的影响。核壳产物对PVC材料的力学性能有明显的提高。 相似文献
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以交联的聚丙烯酸丁酯为核(橡胶相),以苯乙烯/丙烯腈共聚物为壳(塑料相),考察了核一壳乳液聚合动力学;并研究了一些聚合参数对接枝率的影响,利用傅里叶变换红外光谱仪和Perkin-Elmer240C元素分析仪对接枝物进行了定性定量表征。 相似文献
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纳米SiO_2/MMA无皂乳液聚合研究及其应用 总被引:4,自引:1,他引:4
以纳米 Si O2 为核 ,以 MMA为壳层单体 ,进行了无皂乳液聚合。研究了单体加入方式、引发剂用量、聚合反应温度等对无皂乳液聚合的影响。核壳产物对 PVC材料的力学性能有明显的提高。 相似文献
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从热力学、接枝工艺方面阐述了丙烯酸酯类复合乳液聚合机理,同时用实验验证了机理的合理性,提出了“涂层-接枝”核/壳结构机理。 相似文献
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G. Canch-Escamilla G. Rodríguez-Trujillo P. J. Herrera-Franco E. Mendizbal J. E. Puig 《应用聚合物科学杂志》1997,66(2):339-346
The grafting polymerization of methyl methacrylate (MMA) and cellulose from henequen (Agave fourcroydes) is investigated as a function of the initiator concentration (cerium-and-ammonium nitrate) and the monomer/cellulose ratio. The formation of cellulose-g-PMMA is confirmed by IR spectroscopy, DSC, and TGA. Both the initiator concentration and the MMA/cellulose ratio have a strong influence over the grafting parameters and over the molecular weight of the grafted PMMA. A higher initiator concentration and a lower monomer/cellulose ratio result in a lower molecular weight of the grafted polymer. Increasing the amount and the molecular weight of the grafted PMMA increases the compatibility of the fibers with SAN and PVC, as demonstrated by a mechanical test and scanning electron microscopy. SAN and PVC composites made with grafted cellulose exhibit higher flexural and tensile moduli, respectively, than those produced with the ungrafted fibers. Both moduli increase as the amount of reinforcement increases. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 66: 339–346, 1997 相似文献
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Howard L. Needles 《应用聚合物科学杂志》1971,15(10):2559-2566
Irradiation of wool by short-wavelength ultraviolet light in the presence of acrylate or methacrylate esters in dimethyl sulfoxide causes intermediate grafts (2%–10%) of polymer on the surface of the wool. The amount of grafting and homopolymerization and the evenness and regularity of photografted polymer are dependent upon the monomer used. With methyl acrylate, the reaction time, monomer concentration, and introduction of water as cosolvent affect the degree of fiber grafting and the amount and molecular weight of accompanying homopolymer. Polymers grafted onto wool by this technique change the tensile properties and the water desorption characteristics of the wool. 相似文献
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The seeded emulsion polymerization of styrene with emulsified monomer feeding was performed by polyethyl acrylate (PEA) latex as seed emulsion. It was shown that the grafting reactions occurred between two components on the composite latex particles. The loci of seeded polymerization were studied by the kinetics of grafting reaction. The highest grafting efficiency in the initial period of seeded emulsion polymerization supported the fact that the surfaces of PEA particles are the sites of polymerization of styrene. The grafting efficiency decreased with increasing monomer‐to‐polymer ratio and initiator concentration. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 72: 1495–1499, 1999 相似文献
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Grafting of the mixture of acrylamide and acrylic acid onto polyester and polypropylene fibers and mixture of acrylic acid and methacrylic acid onto polypropylene by the radiation method are reported. It is observed that when pure acrylamide was used for grafting, the grafting extent was small, whereas when the mixture was used, the amount of acrylamide content in the copolymer was found to be more than the feed ratios. The results are explained on the basis of chain transfer mechanism. With methacrylic acid and acrylic acid mixtures, the rate of grafting decreased with the increase in the concentration of acrylic acid in the feed ratio, and this has been explained on the basis of the formation of either a 3-dimensional network structure or a highly branched structure involving backbone polymer molecules with acrylic acid, which prevents the diffusion of the monomer from the solution phase to the swollen phase. 相似文献
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A study has been made of graft copolymerization of methyl methacrylate onto native potato starch in aqueous slurry at 30°C. As Mn3+ concentration was increased from 0.15 X 10-3M to 1.0 X 10-3M, conversion of monomer to polymer and add-on of polymer to starch increased and frequency of grafts (anhydroglucose units per grafted chain) decreased sharply. The average molecular weights of the PMMA grafts also decreased in this range. At Mn3+ concentrations from 1.0 X 10-3M to 3.0 X 10-3M, only minor changes in grafting parameters were observed. When the amount of starch charged per batch was increased threefold, the add-on decreased sharply, the molecular weight increased slightly, and the conversion of MMA monomer to polymer remained almost constant. The increase in frequency of grafts (AGU/chain) was almost directly proportional to the increase in the amount of starch charged. In all cases the average molecular weights of grafts were of the order of 106 and the grafting efficiencies high, normally greater than 85%. These results were compared with those previously obtained for grafting of acrylonitrile onto starch. They were interpreted in terms of initial (Mn3+)/(AGU) ratio, total number of radicals initiating grafting, and compatibility of methyl methacrylate monomer with poly(methyl methacrylate) chains. 相似文献
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The free‐radical graft polymerization of vinyl acetate onto nonporous silica particles was studied experimentally. The grafting procedure consisted of surface activation with vinyltrimethoxysilane, followed by free‐radical graft polymerization of vinyl acetate in ethyl acetate with 2,2′‐azobis(2,4‐dimethylpentanenitrile) initiator. Initial monomer concentration was varied from 10 to 40% by volume and the reaction was spanned from 50 to 70°C. The resulting grafted polymer, which was stable over a wide range of pH levels, consisted of polymer chains that are terminally and covalently bonded to the silica substrate. The experimental polymerization rate order, with respect to monomer concentration, ranged from 1.61 to 2.00, consistent with the kinetic order for the high polymerization regime. The corresponding rate order for polymer grafting varied from 1.24 to 1.43. The polymer graft yield increased with both initial monomer concentration and reaction temperature, and the polymer‐grafted surface became more hydrophobic with increasing polymer graft yield. The present study suggests that a denser grafted polymer phase of shorter chains was created upon increasing temperature. On the other hand, both polymer chain length and polymer graft density increased with initial monomer concentration. Atomic force microscopy–determined topology of the polymer‐grafted surface revealed a distribution of surface clusters and surface elevations consistent with the expected broad molecular‐weight distribution for free‐radical polymerization. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 300–310, 2003 相似文献
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以红薯淀粉(ST)为原料,丙烯酰胺(AM)为单体,N-羟甲基丙烯酰胺(NMA)为单体和交联剂,采用反向乳液聚合法制备了NMA-AM接枝ST(ST-g-NMA-AM)。考察了NMA用量、引发剂过硫酸铵用量及反应温度对接枝率的影响,利用傅里叶变换红外光谱对其结构进行表征。以亚甲基蓝为吸附质,考察了ST-g-NMA-AM对亚甲基蓝的吸附性能。结果表明:当NMA用量为0.75 g,引发剂用量为0.0500 g,反应温度为55℃时,单体转化率和接枝率最高,分别为90.41%,45.38%;当亚甲基蓝质量浓度为20 mg/L,吸附剂ST-g-NMA-AM质量浓度为1 g/L时,吸附量随着NMA用量的增加而先增大后减小,当引发剂用量为0.0500 g,NMA用量为0.75 g时,吸附量最大,为16.140 mg/g。 相似文献