Concentrations of Volatile Organic Compounds in Indoor Air – A Review

A review is presented of investigations of volatile organic compound (VOC) concentrations in indoor air of buildings of different classifications (dwellings, offices, schools, hospitals) and categories (established, new and complaint buildings). Measured concentrations obtained from the published literature and from research in progress overseas were pooled so that VOC concentration profiles could be derived for each building classification/category. Mean concentrations of individual compounds in established buildings were found to be generally below 50 μg/m³, with most below 5 μg/m³. Concentrations in new buildings were much greater, often by an order of magnitude or more, and appeared to arise from construction materials and building contents. The nature of these sources and approaches to reduce indoor air concentrations by limiting source VOC emissions is discussed. Total VOC (TVOC) concentrations were substantially higher than concentrations of any individual VOCs in all situations, reflecting the large number of compounds present, but interpretation of such measurements was limited by the lack of a common definition for TVOC relevant to occupant exposure.     

Characterizing sources and emissions of volatile organic compounds in a northern California residence using space‐ and time‐resolved measurements

We investigate source characteristics and emission dynamics of volatile organic compounds (VOCs) in a single‐family house in California utilizing time‐ and space‐resolved measurements. About 200 VOC signals, corresponding to more than 200 species, were measured during 8 weeks in summer and five in winter. Spatially resolved measurements, along with tracer data, reveal that VOCs in the living space were mainly emitted directly into that space, with minor contributions from the crawlspace, attic, or outdoors. Time‐resolved measurements in the living space exhibited baseline levels far above outdoor levels for most VOCs; many compounds also displayed patterns of intermittent short‐term enhancements (spikes) well above the indoor baseline. Compounds were categorized as “high‐baseline” or “spike‐dominated” based on indoor‐to‐outdoor concentration ratio and indoor mean‐to‐median ratio. Short‐term spikes were associated with occupants and their activities, especially cooking. High‐baseline compounds indicate continuous indoor emissions from building materials and furnishings. Indoor emission rates for high‐baseline species, quantified with 2‐hour resolution, exhibited strong temperature dependence and were affected by air‐change rates. Decomposition of wooden building materials is suggested as a major source for acetic acid, formic acid, and methanol, which together accounted for ~75% of the total continuous indoor emissions of high‐baseline species.     

The effects of paints and moisture content on the indoor air emissions from pinewood (Pinus sylvestris) boards

The emissions of volatile organic compounds (VOCs) from building materials may significantly contribute to indoor air pollution, and VOCs have been associated with odor annoyance and adverse health effects. Wood materials together with coatings are commonly used indoors for furniture and large surfaces such as walls, floors, and ceilings. This leads to high surface-to-volume ratios, and therefore, these materials may participate remarkably to the VOC levels of indoor environment. We studied emissions of VOCs and carbonyl compounds from pinewood (Pinus sylvestris) boards of 10% and 16% moisture contents (MC) with three paints using small-scale test chambers (27 L). The emissions from uncoated pinewood and paints (on a glass substrate) were tested as references. The 28-day experiment showed that the VOC emissions from uncoated pinewood were lower from sample with 16% MC. Painted pinewood samples showed lower emissions compared to paints on glass substrate. Additionally, paints on 16% MC pinewood exhibited lower emissions than on drier 10% MC wood. The emissions from painted pinewood samples were dominated by paint-based compounds, but the share of wood-based compounds increased over time. However, we noticed differences between the paints, and wood-based emissions were clearly higher with the most permeable paint.     

Monitoring of volatile organic compounds in non-residential indoor environments

A weekly monitoring campaign of volatile organic compounds (VOC), with single sampling of 24 h, was carried out in non-residential indoor environments such as libraries, pharmacies, offices, gymnasiums, etc., in order to evaluate the VOC concentrations to which people are exposed. Moreover, an outdoor sample was coupled to each indoor site to point out the influence of indoor sources. They were sampled with Radiello diffusive samplers for thermal desorption and analyzed by GC-MS. As already described in other papers, the VOC levels of most of the indoor sites were higher than that observed in the corresponding outdoor sites. For example, some sites showed a level of pollution that is ten times higher than their corresponding outdoor site. The monitored environments that had higher concentrations of the investigated VOC were the pharmacies, a newspaper stand, a copy center, and the coffee shops. Analysis of the weekly average concentrations of each pollutant and the use of literature allowed pointing out some site-specific characteristics that singled out possible sources of VOC. These results were verified analyzing the indoor-outdoor ratio (I/O) too. Newspaper stands were characterized by very high concentrations of toluene and pharmacies were characterized by high concentrations of aromatic compounds. PRACTICAL IMPLICATIONS: Indoor air pollution caused by volatile organic compounds (VOC) might affect human health at home as well as in public and commercial buildings. The main VOC sources in indoor environments are human activities, personal care products, smoking, house cleaning products, building products, and outside pollution. To preserve human health it is necessary to evaluate the average concentrations of VOC to which people are exposed and to identify the main sources of indoor pollution by means of suitable indoor monitoring campaigns in several environments. These investigations allow pointing out the characteristic critical situations of some indoor environments or some other types of environments.     

Secondary organic aerosol formation from a large number of reactive man-made organic compounds

A photochemical trajectory model has been used to examine the relative propensities of a wide variety of volatile organic compounds (VOCs) emitted by human activities to form secondary organic aerosol (SOA) under one set of highly idealised conditions representing northwest Europe. This study applied a detailed speciated VOC emission inventory and the Master Chemical Mechanism version 3.1 (MCM v3.1) gas phase chemistry, coupled with an optimised representation of gas-aerosol absorptive partitioning of 365 oxygenated chemical reaction product species. In all, SOA formation was estimated from the atmospheric oxidation of 113 emitted VOCs. A number of aromatic compounds, together with some alkanes and terpenes, showed significant propensities to form SOA. When these propensities were folded into a detailed speciated emission inventory, 15 organic compounds together accounted for 97% of the SOA formation potential of UK man made VOC emissions and 30 emission source categories accounted for 87% of this potential. After road transport and the chemical industry, SOA formation was dominated by the solvents sector which accounted for 28% of the SOA formation potential.     

Volatile organic compound emissions from latex paint--Part 2. Test house studies and indoor air quality (IAQ) modeling

Emission models developed using small chamber data were combined with an Indoor Air Quality (IAQ) model to analyze the impact of volatile organic compound (VOC) emissions from latex paint on indoor environments. Test house experiments were conducted to verify the IAQ model's predictions. The agreement between model predictions and experimental measurements met the American Society for Testing and Materials criteria for model verification in the room with the source and met most of the requirements in other rooms. The major cause of disagreement between the model predictions and the experimental data in the test house appears to be an inadequate sink model.     

Volatile organic pollutants in new and established buildings in Melbourne, Australia

Volatile organic compounds (VOCs) within new and established buildings have been determined and factors significant to their presence have been identified. In established dwellings, total volatile organic compound (TVOC) concentrations were low, but were approximately four times higher than in outdoor air, showing a dominant effect of indoor sources. The presence of attached garages, site contamination and 'faulty' wool carpet were associated with higher indoor pollution. In three dwellings, unidentified sources of benzene were indicated. Much higher VOC concentrations were observed in new or renovated buildings, persisting above "baseline" levels for several weeks, concentration decay rate correlating with VOC molecular volume, indicating emissions were limited by material diffusion processes. VOC and formaldehyde emission decays in a new dwelling occurred by a double-exponential source model. This shows that persistent low levels of volatile organic pollutants in established dwellings can occur due to long-term emissions from building materials.     

Factors controlling volatile organic compounds in dwellings in Melbourne,Australia

This study characterized indoor volatile organic compounds (VOCs) and investigated the effects of the dwelling characteristics, building materials, occupant activities, and environmental conditions on indoor VOC concentrations in 40 dwellings located in Melbourne, Australia, in 2008 and 2009. A total of 97 VOCs were identified. Nine VOCs, n‐butane, 2‐methylbutane, toluene, formaldehyde, acetaldehyde, d‐limonene, ethanol, 2‐propanol, and acetic acid, accounted for 68% of the sum of all VOCs. The median indoor concentrations of all VOCs were greater than those measured outdoors. The occupant density was positively associated with indoor VOC concentrations via occupant activities, including respiration and combustion. Terpenes were associated with the use of household cleaning and laundry products. A petroleum‐like indoor VOC signature of alkanes and aromatics was associated with the proximity of major roads. The indoor VOC concentrations were negatively correlated (P < 0.05) with ventilation. Levels of VOCs in these Australian dwellings were lower than those from previous studies in North America and Europe, probably due to a combination of an ongoing temporal decrease in indoor VOC concentrations and the leakier nature of Australian dwellings.     

确定建筑材料有害物散发量的三种传质模型

室内空气污染源散发量的确定是建立室内空气质量(IAQ)模型的重要步骤之一。目前研究建筑装饰材料和建筑涂料散发污染物的模型主要有经验模型和理论模型两类。经验模型简洁，但应用受到测试条件的限制，不具有普适性。基于传质理论而提出的理论模型目前研究较多，本文对研究建筑材料散发有害物的三个传质模型进行了评述。VB模型是一个简单的溶剂基室内涂料散发的总挥发性有机物(TVOC)的传质模型，低估了污染物的长期散发量。对流传质模型是基于界面平衡所导出的稳态模型，适用于固体和液体等材料的散发过程。Yang等提出的四层传质模型通常需与数值求解结合，计算较麻烦，但能较好地确定建筑材料散发挥发性有机物的散发量。     

挥发性有机化合物对室内空气品质影响研究进展

系统回顾了近年来一些国家对室内空气环境中挥发性有机化合物（VOC）研究的各个方面,包括VOC研究在室内空气品质研究中的地位,建筑物内VOC对人体健康的影响,VOC研究的实验方法、理论方法及主要研究结论,各国政府、学术团体采取的行动等。得出结论：与建筑科学、环境科学及人体健康相关的工作人员,如居住者、建筑业主、建筑科学家、环境科学家、心理学家和生理学家、建筑师与暖通空调设计人员、建筑和装饰材料生产商、供应商,都应重视VOC问题。     

Ozone reaction with clothing and its initiated VOC emissions in an environmental chamber

Human health is adversely affected by ozone and the volatile organic compounds (VOCs) produced from its reactions in the indoor environment. Hence, it is important to characterize the ozone‐initiated reactive chemistry under indoor conditions and study the influence of different factors on these reactions. This investigation studied the ozone reactions with clothing through a series of experiments conducted in an environmental chamber under various conditions. The study found that the ozone reactions with a soiled (human‐worn) T‐shirt consumed ozone and generated VOCs. The ozone removal rate and deposition velocity for the T‐shirt increased with the increasing soiling level and air change rate, decreased at high ozone concentrations, and were relatively unaffected by the humidity. The deposition velocity for the soiled T‐shirt ranged from 0.15 to 0.29 cm/s. The ozone‐initiated VOC emissions included C6–C10 straight‐chain saturated aldehydes, acetone, and 4‐OPA (4‐oxopentanal). The VOC emissions were generally higher at higher ozone, humidity, soiling of T‐shirt, and air change rate. The total molar yield was approximately 0.5 in most cases, which means that for every two moles of ozone removed by the T‐shirt surface, one mole of VOCs was produced.     

Volatile organic compound measurements in the California/Mexico border region during SCOS97

Measurements of volatile organic compounds (VOC) were carried out in the California/Mexico border region during the Southern California Ozone Study in the summer of 1997 (SCOS97). Integrated 3-h samples were collected in Rosarito (south of Tijuana, Mexico) and in Mexicali during intensive operational periods (IOP), twice per IOP day. VOC were collected using stainless-steel 6-1 canisters; carbonyl compounds were collected using 2,4-dinitrophenyl-hydrazine (DNPH) impregnated C18 SepPak cartridges. The canister samples were analyzed for speciated volatile hydrocarbons (C2-C12), CO, CO2, CH4, methyl t-butyl ether (MTBE), and halogenated hydrocarbons. DNPH-impregnated cartridges were analyzed for 14 C1-C7 carbonyl compounds. The concentrations of all species were higher at Mexicali than in Rosarito. A good correlation between total non-methane hydrocarbons (TNMHC), CO, and other pollutants associated with motor vehicle emissions observed for Mexicali indicates that the main source of TNMHC at this site is vehicular traffic.     

Occupational exposure and health risks of volatile organic compounds of hotel housekeepers: Field measurements of exposure and health risks

Hotel housekeepers represent a large, low-income, predominantly minority, and high-risk workforce. Little is known about their exposure to chemicals, including volatile organic compounds (VOCs). This study evaluates VOC exposures of housekeepers, sources and factors affecting VOC levels, and provides preliminary estimates of VOC-related health risks. We utilized indoor and personal sampling at two hotels, assessed ventilation, and characterized the VOC composition of cleaning agents. Personal sampling of hotel staff showed a total target VOC concentration of 57 ± 36 µg/m³ (mean ± SD), about twice that of indoor samples. VOCs of greatest health significance included chloroform and formaldehyde. Several workers had exposure to alkanes that could cause non-cancer effects. VOC levels were negatively correlated with estimated air change rates. The composition and concentrations of the tested products and air samples helped identify possible emission sources, which included building sources (for formaldehyde), disinfection by-products in the laundry room, and cleaning products. VOC levels and the derived health risks in this study were at the lower range found in the US buildings. The excess lifetime cancer risk (average of 4.1 × 10⁻⁵) still indicates a need to lower exposure by reducing or removing toxic constituents, especially formaldehyde, or by increasing ventilation rates.     

How to measure and evaluate volatile organic compound emissions from building products. A perspective

The primary emissions of VOCs (e.g. solvents) from building products influence the perceived indoor air quality during the initial decay period. However, secondary emissions will continue thereafter (chemical or physical degradation, e.g. oxidation, hydrolysis, mechanical wear, maintenance), in addition to sorption processes. Emission testing for primary VOC emissions is necessary, but insufficient to characterise the impact of building products in their entire life span on the perceived air quality. Methods to distinguish between the two types of emissions are required. Also, the influence of climate parameters on the emission rates is necessary to know for proper testing. Future product development and selection strategies of new building products should consider the secondary emissions, in addition to the contribution from the use of auxiliary agents for cleaning, maintenance, and other potential impacts either physical or chemical in nature. Some of the requirements for emission testing are discussed in terms of secondary vs. primary emissions in order to develop 'healthier/better' building products for the indoor environment. In addition, some of the assumptions about the possible impact of VOCs on health and comfort in the indoor environment are presented. Odour thresholds for VOCs are one or more orders of magnitude lower than the corresponding airway irritation estimates, and it also appears that chemically non-reactive VOCs are not sufficiently strong irritants to cause airway irritation at concentrations normally encountered indoors. Finally, future requirements for analytical laboratory performances is proposed to accommodate the increasing need to establish which VOCs may be responsible for the perception of odour intensity from building products.     

A review of the emission of VOCs from polymeric materials used in buildings

Building and furnishing materials and consumers products are important sources of formaldehyde and other volatile organic compounds (VOCs) in the indoor environment. The emission from materials is usually continuous and may last for many years in a building. The available evidence indicates that VOCs can cause adverse health effects to the building occupants and may contribute to symptoms of ‘Sick Building Syndrome’.

Control of VOC emission should increasingly become an important consideration for the design and manufacture of polymeric materials used in buildings. The EC Construction Products Directive ‘Essential Requirements’ set a framework for limiting the use of materials that could pose a health risk to building occupants. Furthermore, the on-going development of voluntary labelling schemes and data bases of material emissions that could be used by building designers, should further strengthen the demand for ‘low VOC emitting’ products.

This paper reviews available information about the emission of VOCs from polymeric building materials, the level of emissions in the indoor environment and the requirements for testing of the materials.     

Simulation of VOC emissions from building materials by using the state-space method

There are many mass-transfer models for predicting VOC emissions from building materials described in the literature. In these models, the volatile organic compound (VOC) emission rate and its concentration in a chamber or a room are usually obtained by analytical method or numerical method. Although these methods demonstrate some salient features, they also have some flaws, e.g., for analytical method the solutions of both room or chamber VOC concentration and building material VOC emission rate are constituted of the sum of an infinite series, in which additional computation for finding roots to a transcendental function is necessary, but sometimes quite complicated. Besides, when it is applied in complex cases such as multilayer emission with internal reaction, the solution is very difficult to get; for conventional numerical methods such as finite difference method, discrete treatment of both time and space may cause calculation errors. Considering that, the state-space method widely used in modern automation control field and the heat transfer field is applied to simulate VOC emissions from building materials. It assumes that a slab of building material is composed of a number of finite layers, in each of which the instantaneous VOC concentration is homogenous during the entire process of emission, while the time is kept continuous. Based on this assumption we can predict both the VOC emissions rate and the concentrations of VOCs in the air of a chamber or room. The method is generally applied to simulate VOC emissions from arbitrary layers of building materials, and the solution is explicit and simple. What's more, the method can be applied to the cases where a reaction producing/removing VOC in building materials exists. For some specific cases the method is validated using the experimental data and the analytical solutions in the literature. The method provides a simple but powerful tool for simulating VOC emissions from building materials, which is especially useful in developing indoor air quality (IAQ) simulation software.     

TVOC and formaldehyde emission behaviors from flooring materials bonded with environmental-friendly MF/PVAc hybrid resins

Polyvinyl acetate (PVAc) was added as a replacement for melamine-formaldehyde (MF) resin in the formaldehyde-based resin system to reduce formaldehyde and volatile organic compound (VOC) emissions from the adhesives used between plywoods and fancy veneers. A variety of techniques, including 20-l chamber, field and laboratory emission cell (FLEC), VOC analyzer and standard formaldehyde emission test (desiccator method), were used to determine the formaldehyde and VOC emissions from engineered flooring bonded with five different MF resin and PVAc blends at MF/PVAc ratios of 100:0, 70:30, 50:50, 30:70 and 0:100. Although urea-formaldehyde (UF) resin had the highest formaldehyde emission, the emission as determined by desiccator method was reduced by exchanging with MF resin. Furthermore, the formaldehyde emission level was decreased with increasing addition of PVAc as the replacement for MF resin. UF resin in the case of beech was over 5.0 mg/l, which exceeded E2 (1.5-5.0 mg/l) grade. However, MF30:PVAc70 was 相似文献   

Emissions of VOCs,SVOCs, and mold during the construction process: Contribution to indoor air quality and future occupants’ exposure

Building materials and human activities are important sources of contamination indoors, but little information is available regarding contamination during construction process which could persist during the whole life of buildings. In this study, six construction stages on two construction sites were investigated regarding the emissions of 43 volatile organic compounds (VOCs), 46 semi-volatile organic compounds (SVOCs), and the presence of 4 genera of mold. Results show that the future indoor air quality does not only depend on the emissions of each building product but that it is also closely related to the whole implementation process. Mold spore measurements can reach 1400 CFU/m³, which is particularly high compared with the concentrations usually measured in indoor environments. Relatively low concentrations of VOCs were observed, in relation to the use of low emissive materials. Among SVOCs analyzed, some phthalates, permethrin, and hydrocarbons were found in significant concentrations upon the delivery of building as well as triclosan, suspected to be endocrine disruptor, and yet prohibited in the treatment of materials and construction since 2014. As some regulations exist for VOC emissions, it is necessary to implement them for SVOCs due to their toxicity.     

Theoretical study of simultaneous water and VOCs adsorption and desorption in a silica gel rotor

One-dimensional partial differential equations were used to model the simultaneous water and VOC (Volatile Organic Compound) adsorption and desorption in a silica gel rotor which was recommended for indoor air cleaning. The interaction among VOCs and moisture in the adsorption and desorption process was neglected in the model as the concentrations of VOC pollutants in typical indoor environment were much lower than that of moisture and the adsorbed VOCs occupied only a minor portion of adsorption capacity of the rotor. Consequently VOC transfer was coupled with heat and moisture transfer only by the temperatures of the rotor and the air stream. The VOC transfer equations were solved by discretizing them into explicit up-wind finite differential equations. The model was validated with experimental data. The calculated results suggested that the regeneration time designed for dehumidification may be prolonged to allow complete removal of the VOC pollutants from the rotor. The regeneration temperature designed for dehumidification provides considerable efficiency for indoor air cleaning. The application of the model in estimating the cleaning capacity of the rotor for VOC pollutants was demonstrated. PRACTICAL IMPLICATIONS: Silica gel rotors, usually used to dehumidify air, were found to be effective to remove VOCs by experiments recently. But the removal characteristics of VOCs are different from that of moisture. Therefore, the rotor structure and operating parameters for dehumidification needs to be optimized for the use of removing moisture and VOCs. This paper gives a way for the optimization.     

Assessment of the Health and Comfort Effects of Chemical Emissions from Building Materials: the State of the Art in the European Union*

Abstract The promotion of healthier indoor air requires the use of building materials whose chemical emissions are free of toxicity and unfavourable sensory properties. Testing and assessment of chemical emissions are essential in order to identify “safe” materials, and to encourage manufacturers to produce, and the market to adopt, such materials. Various testing and assessment procedures for building materials have been developed in European countries such as Germany, Denmark, Sweden, and Finland. Recently the European Collaborative Action “Indoor Air Quality and its Impact on Man” proposed criteria and a testing procedure for the assessment of VOC emissions from solid flooring materials. The innovative aspects of this proposal are: a procedure for the performance of chemical emissions testing; sensory testing coupled with toxicological evaluation; and a procedure to handle compounds for which toxicological information is scarce or absent. This procedure, after validation and experience from practical use, will probably be extended to other building materials.