Time-of-flight photoelectron spectroscopy of gases using synchrotron radiation

A gas-phase time-of-flight (TOF) photoelectron spectrometer has been developed for use with synchrotron radiation. The excellent time structure of the synchrotron radiation at the Stanford Positron Electron Accelerator Ring (SPEAR) has been used as the time base for the TOF measurements. The TOF analyzer employs two multichannel plates (MCPs) in tandem as a fast electron multiplier with a matched 50-Omega anode to form an electron detector with a timing resolution of 相似文献   

Time-resolved soft x-ray absorption setup using multi-bunch operation modes at synchrotrons

Here, we report on a novel experimental apparatus for performing time-resolved soft x-ray absorption spectroscopy in the sub-ns time scale using non-hybrid multi-bunch mode synchrotron radiation. The present setup is based on a variable repetition rate Ti:sapphire laser (pump pulse) synchronized with the ~500 MHz x-ray synchrotron radiation bunches and on a detection system that discriminates and singles out the significant x-ray photon pulses by means of a custom made photon counting unit. The whole setup has been validated by measuring the time evolution of the L(3) absorption edge during the melting and the solidification of a Ge single crystal irradiated by an intense ultrafast laser pulse. These results pave the way for performing synchrotron time-resolved experiments in the sub-ns time domain with variable repetition rate exploiting the full flux of the synchrotron radiation.     

A multi-crystal wavelength dispersive x-ray spectrometer

A multi-crystal wavelength dispersive hard x-ray spectrometer with high-energy resolution and large solid angle collection is described. The instrument is specifically designed for time-resolved applications of x-ray emission spectroscopy (XES) and x-ray Raman scattering (XRS) at X-ray Free Electron Lasers (XFEL) and synchrotron radiation facilities. It also simplifies resonant inelastic x-ray scattering (RIXS) studies of the whole 2d RIXS plane. The spectrometer is based on the Von Hamos geometry. This dispersive setup enables an XES or XRS spectrum to be measured in a single-shot mode, overcoming the scanning needs of the Rowland circle spectrometers. In conjunction with the XFEL temporal profile and high-flux, it is a powerful tool for studying the dynamics of time-dependent systems. Photo-induced processes and fast catalytic reaction kinetics, ranging from femtoseconds to milliseconds, will be resolvable in a wide array of systems circumventing radiation damage.     

Improving the timing resolution of an electromagnetic calorimeter based on lead tungstate crystals

Results of the beam tests of the prototype photon spectrometer PHOS for the ALICE experiment at the Large Hadron Collider (CERN) are presented. The spectrometer is based on detector elements composed of lead tungstate (PbWO₄) crystals with dimensions of 22 × 22 × 180 mm and Hamamatsu S8664-55 (S8148) avalanche photodiodes. The beam tests have been performed on the secondary T10 beamline of the PS proton synchrotron. The main emphasis has been placed on the possibility of improving the PHOS timing resolution. Introduction of an additional timing channel with a silicon photomultiplier (SiPM) used as a photodetector is shown to improve the timing resolution for 1-GeV deposited energy from current value σ _t = 3 to 0.3 ns. Silicon photomultipliers of the Hamamatsu MPPC S10362-33 family with an active area of 3 × 3 mm² are used in these measurements. Using fast photomultiplier tubes with an 8-mm-diameter photocathode, the timing resolution attainable in electromagnetic shower development in a lead tungstate crystal has been measured for a large-area photodetector. The timing resolution for a deposited energy of 1 GeV is 150 ps. The effect of the detector channel temperature on the timing resolution is investigated. Cooling the crystal results in an increase both in the scintillation intensity and in the decay time of the scintillator and fails to substantially improve the timing resolution.     

红外分光油分析仪的设计与研究

描述了红外分光油分析仪的基础原理、结构和数学模型 ,着重介绍了红外测油的原理、关键技术及应用     

中/长波红外双衍射级次共路Offner成像光谱仪

为提高成像光谱仪的工作波长范围,提出了基于双波段焦平面探测器(FPAs)的双衍射级次全共路Offner成像光谱仪结构。该结构中凸面光栅的一级衍射光和二级衍射光完全重叠共路传输,并可由焦平面处的双波段红外焦平面探测器IR FPAs实现级次的自然分离和同时探测。分析了该结构的工作原理和设计方法,基于几何光线追迹法仿真了谱线弯曲和色畸变特性,基于Huygens点扩散函数(PSF)仿真了光谱响应函数(SRF)并导出了光谱带宽。实验显示:双衍射级次共路Offner成像光谱仪的工作波段为3~6μm(二级衍射)和6~12μm(一级衍射),谱线弯曲和色畸变均小于0.5个像元宽度,光谱带宽分别为13.2~14.3nm(二级衍射)和28.3~33.3nm(一级衍射),两个工作波段内的衍射效率均大于或等于20%。整个系统结构简单紧凑、光谱范围宽,满足对地物或深空目标的中等分辨率的中远红外光谱探测需求。     

用热解石墨晶体作色散和聚焦光学元件的激光等离子体源的超快X射线光谱仪

由于激光等离子X射线源的光子通量显著低于同步辐射源的光子通量且射线为所有方向的各向同性辐射,所以,很需要具有大的集光立体角和高的积分反射率的光学元件,用热解石墨(PG)晶体作色散和聚焦元件可满足上述要求。由于PG晶体为嵌镶结构,所以可给出很高的积分反射率,而PG薄膜还可安装在任意形状的模具上构成任意形状的光学元件。此外,特殊形状的嵌镶聚焦使这些晶体甚至在弯曲的情况下,也可作为高分辨率X射线光学元件。基于上述元件特性,可以设计出有高集光效率的色散光学元件,用于激光等离子体源超快X射线光谱检测。文中描述了PG弯晶在一台改型的von HAMOS光谱仪中的应用,使用这台光谱仪,测量了飞秒激光器产生等离子体发射的X射线的光谱分布。讨论了产生的X射线在时间分辨扩展X射线吸收精细结构(EXAFS)分析中的应用。实验表明,通过优化晶体特性和光谱仪几何设置,可以实现对过渡金属K边的高分辨率EXAFS测量。     

Transient two-dimensional IR spectrometer for probing nanosecond temperature-jump kinetics

We have developed a Fourier transform two-dimensional infrared (2D IR) spectrometer to probe chemical reactions and biophysical processes triggered by a nanosecond temperature jump (T jump). The technical challenges for such a spectrometer involve (1) synchronization of a nanosecond T-jump laser and femtosecond laser system, (2) overcoming the decreased signal-to-noise ratio from low repetition rate data acquisition, and (3) performing an interferometric measurement through a sample with a density and index of refraction that varies with time delay after the T jump. The first challenge was overcome by synchronizing the two lasers to a clock derived from the Ti:sapphire oscillator, leading to timing accuracy of 2 ns for delays up to 50 ms. The data collection time is reduced by using undersampling with the improved signal-to-noise ratio obtained from a balanced detection scheme with a dual stripe array detector. Transient dispersed vibrational echo and 2D IR spectroscopy are applied to N-methylacetamide and ubiquitin, as examples, and the spectral responses by a temperature elevation and by structural changes of the protein are compared. The synchronization of 2D IR spectroscopy with a nanosecond temperature jump without losing its sensitivity at a low repetition rate opens a new applicability of the nonlinear spectroscopy to probe a variety of molecular structure changes induced by a nanosecond perturbation.     

Time-resolved photoelectron spectroscopy of liquids

We present a novel setup for the investigation of ultrafast dynamic processes in a liquid jet using time-resolved photoelectron spectroscopy. A magnetic-bottle type spectrometer with a high collection efficiency allows the very sensitive detection of photoelectrons emitted from a 10 μm thick liquid jet. This translates into good signal/noise ratio and rapid data acquisition making femtosecond time-resolved experiments feasible. We describe the experimental setup, a detailed spectrometer characterization based on the spectroscopy of nitric oxide in the gas phase, and results from femtosecond time-resolved experiments on sodium iodide solutions. The latter experiments reveal the formation and evolution of the solvated electron and we characterize two distinct spectral components corresponding to initially thermalized and unthermalized solvated electrons. The absence of dark states in photoionization, the direct measurement of electron binding energies, and the ability to resolve dynamic processes on the femtosecond time scale make time-resolved photoelectron spectroscopy from the liquid jet a very promising method for the characterization of photochemical processes in liquids.     

Photoacoustic infrared spectroscopy at the Canadian Light Source: commissioning experiments

The commissioning of synchrotron radiation (SR) photoacoustic (PA) infrared spectroscopy at the Canadian Light Source is described in this article. Aperture tests demonstrated an exponential relationship between the wavenumber where SR and thermal-source PA intensities are equal and beam diameter. Total PA intensity increased linearly with aperture size up to 1.5 mm (SR) or 3 mm (thermal source). At larger apertures, this intensity approached a limiting value. The SR beam diameter in the spectrometer was estimated to be about 0.8 mm in these tests. The low-frequency noise and dc offset that characterize SR PA spectra are suppressed through the calculation of average interferograms prior to Fourier transformation.     

Five-element Johann-type x-ray emission spectrometer with a single-photon-counting pixel detector

A Johann-type spectrometer with five spherically bent crystals and a pixel detector was constructed for a range of hard x-ray photon-in photon-out synchrotron techniques, covering a Bragg-angle range of 60°-88°. The spectrometer provides a sub emission line width energy resolution from sub-eV to a few eV and precise energy calibration, better than 1.5 eV for the full range of Bragg angles. The use of a pixel detector allows fast and easy optimization of the signal-to-background ratio. A concentration detection limit below 0.4 wt% was reached at the Cu Kα(1) line. The spectrometer is designed as a modular mobile device for easy integration in a multi-purpose hard x-ray synchrotron beamline, such as the SuperXAS beamline at the Swiss Light Source.     

便携式光谱仪的CCD智能检测器设计

光谱仪是一种重要的检测仪器,CCD光谱仪正朝着小型化甚至微型化的方向发展。针对便携式光谱仪的特点及要求提出一种光谱仪CCD智能检测器设计方案,它结合了单片机智能化控制的特点和CPLD时序准确、可编程的优点。并且该检测器集成了USB数据接口,可通过计算机软件进行光谱采集,并能实时控制积分时间,实现了光谱仪CCD检测器的小型化、智能化和集成化。     

Synchronizing fast electrically driven phenomena with synchrotron x-ray probes

Time scales of long-range physical processes in solids are typically in the range of picoseconds to nanoseconds. These times are commensurate with the time resolution of structural probes based on modern synchrotron x-ray sources. Several processes of technological and scientific interest can be driven by applied electric fields, but synchronizing electrically driven phenomena with an x-ray probe poses a technical challenge. We describe the synchronization of a well-defined number of fast electrical pulses with the time structure of synchrotron x rays to probe the dynamics of thin films and nanostructures. This synchronization technique yields x-ray transient signals with 600 ps transitions in ferroelectric thin films, with a contribution of approximately 320 ps due to timing jitter in the synchronization.     

高精度数据采集系统在近红外光谱测量仪中的应用

为了满足近红外测量对近红外光谱仪高精度的要求,采用AD公司的低噪声放大器ADA4841—1以及24位A／D芯片AD7767,设计了包括运算放大电路,A／D转换电路在内的数据采集系统。实现了对微弱信号的放大和A／D转换。用软件对采集的数字信号进行中值滤波后,将数据送到PC机进行算法分析。多次测试的结果表明,在采样速率为1kHz／s时,数据精度可达到13bit,满足了滤光片透射式近红外光谱仪的要求。     

Press molding of a Si–HDPE hybrid lens substrate and evaluation of its infrared optical properties

A hybrid structure of single-crystal silicon (Si) and high-density polyethylene (HDPE) was developed as a new substrate for infrared lenses by using precision press molding. A thin HDPE film was used to laminate a silicon wafer and their interface was directly bonded by the silane cross-link. The HDPE film is easy to be hot-embossed to form three-dimensional surface microstructures and the silicon wafer provides a high stiffness for the hybrid substrate. The infrared (IR) optical properties of the hybrid substrate were examined by two kinds of measurements, transmittance and image sharpness. Interestingly, the transmittance measurement result shows that the IR transmittance of the hybrid substrate is higher than that of Si itself in some region of wavelength. The imaging test result shows that the hybrid substrate is capable to produce similar image quality as Si itself. These results strongly demonstrate that the developed Si–HDPE hybrid substrate is a promising alternative substrate material for IR lens.     

基于LabVIEW焊接数据采集分析系统的开发

介绍了虚拟仪器领域中最具有代表性的图形化编程开发平台LabVlEW,并对Labview驱动普通数据采集卡进行了研究.利用实验室已有的焊接信号采集系统及光谱仪,基于LabVIEW软件进行编程,开发出了一套数据采集系统,将采集到的GMAW的电流、电压波形信号及光谱信息进行综合分析,实现了在每个时刻都在LabVlEW的界面上进行同步显示,并且同步显示此刻电压和电流的具体数值,使得对光谱和电信号的研究观察更加直观.     

Development of soft x-ray time-resolved photoemission spectroscopy system with a two-dimensional angle-resolved time-of-flight analyzer at SPring-8 BL07LSU

We have developed a soft x-ray time-resolved photoemission spectroscopy system using synchrotron radiation (SR) at SPring-8 BL07LSU and an ultrashort pulse laser system. Two-dimensional angle-resolved measurements were performed with a time-of-flight-type analyzer. The photoemission spectroscopy system is synchronized to light pulses of SR and laser using a time control unit. The performance of the instrument is demonstrated by mapping the band structure of a Si(111) crystal over the surface Brillouin zones and observing relaxation of the surface photo-voltage effect using the pump (laser) and probe (SR) method.     

Airfoil sampling of a pulsed Laval beam with tunable vacuum ultraviolet synchrotron ionization quadrupole mass spectrometry: application to low-temperature kinetics and product detection

A new pulsed Laval nozzle apparatus with vacuum ultraviolet (VUV) synchrotron photoionization quadrupole mass spectrometry is constructed to study low-temperature radical-neutral chemical reactions of importance for modeling the atmosphere of Titan and the outer planets. A design for the sampling geometry of a pulsed Laval nozzle expansion has been developed that operates successfully for the determination of rate coefficients by time-resolved mass spectrometry. The new concept employs airfoil sampling of the collimated expansion with excellent sampling throughput. Time-resolved profiles of the high Mach number gas flow obtained by photoionization signals show that perturbation of the collimated expansion by the airfoil is negligible. The reaction of C(2)H with C(2)H(2) is studied at 70 K as a proof-of-principle result for both low-temperature rate coefficient measurements and product identification based on the photoionization spectrum of the reaction product versus VUV photon energy. This approach can be used to provide new insights into reaction mechanisms occurring at kinetic rates close to the collision-determined limit.     

Development of analog-digital readout integrated circuits for infrared focal plane arrays

This paper describes the design of readout integrated circuits (ROICs) for hybrid infrared focal plane arrays (IR FPAs). This work contains the estimation of the noise equivalent temperature difference (NETD) of IR FPAs based on frame and row integration of pixel signals in the spectral ranges of 8 to 14 and 3 to 5 μm. This paper also describes the development of ROICs for IR FPAs created with the use of mercury—cadmium—telluride (MCT) photodiodes and quantum well infrared photodetectors (QWIPs). The designed ROICs ensure the use of matrix and linear photodetector chips, including those with increased dark currents, in order to produce IR FPAs with temperature resolution corresponding to the world level of array analogs.