CdSe(ZnS) nanocomposite luminescent high temperature sensor

High temperature luminescence-based sensing is demonstrated by embedding colloidal CdSe(ZnS) quantum dots into a high temperature SiO(2) dielectric matrix. The nanocomposite was fabricated by a solution process method. As-prepared CdSe(ZnS) quantum dots in the nanocomposite sensor show an absorption band at a wavelength of 600 nm (2.06 eV). Photoluminescence (PL) measurements show a room temperature emission peak at 606 nm (2.04 eV). The temperature-dependent emission spectra study shows for the first time a CdSe(ZnS)-SiO(2) nanocomposite-based high temperature sensor. The temperature-dependent spectral and intensity modes of the nanocomposite thin film photoluminescence were investigated from 295-525 K. The sensor shows a variation of the emission wavelength as a function of temperature with a sensitivity of ～ 0.11 nm °C( - 1). The film morphology and roughness are characterized using AFM.     

ZrO2 thin-film-based sapphire fiber temperature sensor

A submicrometer-thick zirconium dioxide film was deposited on the tip of a polished C-plane sapphire fiber to fabricate a temperature sensor that can work to an extended temperature range. Zirconium dioxide was selected as the thin film material to fabricate the temperature sensor because it has relatively close thermal expansion to that of sapphire, but more importantly it does not react appreciably with sapphire up to 1800 °C. In order to study the properties of the deposited thin film, ZrO2 was also deposited on C-plane sapphire substrates and characterized by x-ray diffraction for phase analysis as well as by atomic force microscopy for analysis of surface morphology. Using low-coherence optical interferometry, the fabricated thin-film-based sapphire fiber sensor was tested in the lab up to 1200 °C and calibrated from 200° to 1000 °C. The temperature resolution is determined to be 5.8 °C when using an Ocean Optics USB4000 spectrometer to detect the reflection spectra from the ZrO2 thin-film temperature sensor.     

Discrimination between strain and temperature by cascading single-mode thin-core diameter fibers

A simple fiber-optic sensor capable of discrimination between temperature and strain is proposed and experimentally demonstrated. The sensor head is formed by cascading two sections of single-mode thin-core diameter fibers (TCFs) that act as two different inter-modal interferometers (IMIs). Due to the different sensitivity responses of the two IMIs to strain and temperature, it is possible to discriminate temperature and strain by monitoring the resonant wavelength shifts. The experimental results indicate that the measured strain and temperature resolutions are 37.41 με and 0.732 °C within a strain range of 0-1333.3 με and a temperature range from 26.9 °C to 61.7 °C. The sensing sensitivities of strain and temperature are -1.03 pm/με and 30.74 pm/°C, respectively. The proposed sensor features the advantages of easy fabrication, low cost and high sensitivity, and it exhibits great potential in dual-parameter measurement.     

Investigations on AlN/sapphire piezoelectric bilayer structure for high-temperature SAW applications

This paper explores the possibility of using AlN/sapphire piezoelectric bilayer structures for high-temperature SAW applications. To determine the temperature stability of AlN, homemade AlN/sapphire samples are annealed in air atmosphere for 2 to 20 h at temperatures from 700 to 1000°C. Ex situ X-ray diffraction measurements reveal that the microstructure of the thin film is not affected by temperatures below 1000°C. Ellipsometry and secondary ion mass spectroscopy investigations attest that AlN/sapphire is reliable up to 700°C. Beyond this temperature, both methods indicate ongoing surface oxidation of AlN. Additionally, Pt/Ta and Al interdigital transducers are patterned on the surface of the AlN film. The resulting SAW devices are characterized up to 500°C and 300°C, respectively, showing reliable frequency response and a large, quasi-constant temperature sensitivity, with a first-order temperature coefficient of frequency around -75 ppm/°C. Between room temperature and 300°C, both electromechanical coupling coefficient K(2) and propagation losses increase, so the evolution of delay lines' insertion losses with temperature strongly depends on the length of the propagation path.     

Silicon Carbide-Based Extreme Environment Hybrid Design Temperature Sensor Using Optical Pyrometry and Laser Interferometry

To the best of the authors' knowledge, proposed and demonstrated is the first extreme environment temperature sensor using Blackbody (BB) radiation of a high-temperature material optical chip for coarse temperature measurement and classical Fabry-Perot (FP) laser interferometry via the same chip for fine temperature measurement. Such a hybrid design sensor can be used to accurately measure temperatures in excess of 750°C such as needed for gas turbines in power plants and aircraft engines. The proposed sensor is designed and demonstrated using an all-Silicon Carbide (SiC) probe for temperatures from 795°C to 1077°C with an estimated average measurement resolution of 0.1°C.     

Influence of pyrolytic temperature on the properties of ZnO films optimized for H2 sensing application

In this work, we report the influence of pyrolytic temperature on the properties of ZnO films deposited by a novel spray pyrolysis deposition route. XRD results revealed an improvement in crystal quality of the films with increase in growth temperature. The optical measurements of the films show a maximum transmittance of ~85 % and the band gap of ~3.5 eV. Photoluminescence spectra revealed that the UV emission peaks at 385 nm is improved with increase in growth temperature upto 300 °C, which corresponds to the increase of optical quality and decrease of Zn interstitial defect in the films. Gold ohmic contacts were evaporated on the optimized ZnO film prepared at the substrate temperature of 300 °C, and response of the film to different concentrations of hydrogen (150–500 ppm) at room temperature was investigated. The ZnO sensor showed significant sensitivity to hydrogen for concentration as low as 150 ppm at room temperature, and the sensor response was observed to increase with increase in hydrogen concentration. The increased sensitivity of the film was attributed to the large roughness of the film revealed from AFM analysis. The results ensure the application of our novel sensor, to detect H₂ at low concentration and at room temperature.     

A Precision Silicon Transistor Thermometer

This article describes a mass-producible electronic thermometer employing an inexpensive transistor as a temperature sensor. The instrument features ±0.1°C accuracy from -50 to + 125°C; ±0.02°C stability throughout a 1000-day 125°C temperature cycle test; and probes that are freely interchangeable with no calibration by user. Probes need be factory-calibrated at only one temperature, and are based on a novel low-thermal-mass hermetic transistor package. Also described are the theoretical analysis and experiments carried during development. It is shown that sensor transistor Vbe will vary almost linearly with temperature if collector current is an appropriate quadratic function of absolute temperature. Effects of various current functions on Vbe linearity are theoretically analyzed and experimental results given for comparison. The technique used to find the optimum current function is explained, and the circuit which generates the function is described. It is shown that using a more expensive function generator and a 3-point sensor calibration will yield ±0.01°C accuracy. Also discussed is the degree to which different commercially available transistors conform to the theoretical predictions. Criteria are given for selecting an appropriate transistor type.     

High temperature circular position sensor based on a giant magnetoresistance nanogranular Ag/sub x/Co/sub 1-x/ alloy

A new circular position sensor based on giant magnetoresistances has been developed. The sensing film is an AgCo nanogranular thin film patterned in a circular Wheatstone bridge configuration. This alloy shows a high magnetoresistance (8%) at room temperature within the field generated by an NdFeB permanent magnet that provides a sensitivity of 440 /spl mu/V/V/(/spl deg/). The operational temperature range of this sensor is -40/spl deg/C/+120/spl deg/C, although the magnetic film tolerates higher temperatures up to 200/spl deg/C. These parameters and the contactless way of sensing make this device appropriate for automotive applications. The developed sensor presents excellent characteristics for life, since it is not sensitive to pollution; it is frictionless and does not present any type of electrical noise generated by contacts.     

Influence of temperature on the sensitivity and signal-to-noise ratio of a fiber-optic surface-plasmon resonance sensor

We have theoretically analyzed the influence of temperature on the performance of a fiber-optic sensor based on surface-plasmon resonance (SPR). The performance of the sensor has been evaluated in terms of its sensitivity and signal-to-noise ratio (SNR). The theoretical model for temperature dependence includes the thermo-optic effect in the fiber core and sensing layer, and phonon-electron scattering along with electron-electron scattering in the metal layer. The effect of temperature on the SNR and the sensitivity of the sensor with two different metals has been compared. The same comparison is carried out for the sensing layers with positive and negative thermo-optic coefficients. The theoretical model has been analyzed for both the nonremote and remote sensing cases. This detailed analysis of temperature-dependent SNR and sensitivity leads to achieving the best possible performance from a fiber-optic SPR sensor against the temperature variation.     

Al2O3/silicon nanoISFET with near ideal nernstian response

Nanoscale ISFET (ion sensitive field-effect transistor) pH sensors are presented that produce the well-known sub-nernstian pH-response for silicon dioxide (SiO(2)) surfaces and near ideal nernstian sensitivity for alumina (Al(2)O(3)) surfaces. Titration experiments of SiO(2) surfaces resulted in a varying pH sensitivity ～20 mV/pH for pH near 2 and >45 mV/pH for pH > 5. Measured pH responses from titrations of thin (15 nm) atomic layer deposited (ALD) alumina (Al(2)O(3)) surfaces on the nanoISFETs resulted in near ideal nernstian pH sensitivity of 57.8 ± 1.2 mV/pH (pH range: 2-10; T = 22 °C) and temperature sensitivity of 0.19 mV/pH °C (22 °C ≤ T ≤ 40 °C). A comprehensive analytical model of the nanoISFET sensor, which is based on the combined Gouy-Chapman-Stern and Site-Binding (GCS-SB) model, accompanies the experimental results and an extracted ΔpK ≈ 1.5 from the measured responses further supports the near ideal nernstian pH sensitivity.     

Simultaneous strain and temperature measurement using a compact photonic crystal fiber inter-modal interferometer and a fiber Bragg grating

An all-fiber sensor scheme for simultaneous strain and temperature measurement is presented. The sensing head is formed by serially connecting a polarization maintaining photonic-crystal-fiber-based inter-modal interferometer (IMI) with a fiber Bragg grating (FBG). The IMI, exhibiting an opposite strain response as compared to that of the FBG, is highly sensitive to strain, while it is insensitive to temperature. This has potential for improving the strain and temperature measurement resolutions. A sensor resolution of ±8.3 με in strain and ±2 °C in temperature are experimentally achieved within a strain range of 0-957.6 με and a temperature range of 24 °C-64 °C, respectively.     

Single-arm double-mode double-order planar waveguide interferometric sensor

A sensor is described for which interference measurements of the phase delay between two propagating modes of different orders in a slab thin-film waveguide are used as the sensing technique. The basic building block of the sensor is a polymer film doped with an indicator dye such as Bromocresol Purple. The modes of two orders such as TM(0) and TM(1) are simultaneously excited in the light-guiding film with a focusing optics and a prism coupler. The modes are decoupled from the film and recombined to produce an interference pattern in the face of an output optical fiber. The sensitivity of the sensor to the ambient temperature change is 1.5 degrees C, and the sensitivity to NH(3) is 200 parts in 10(6) for one full oscillation of the signal.     

Temperature sensor using an optical fiber coupler with a thin film

A temperature sensor was demonstrated and fabricated by coating thermosensitive film around a fiber coupler. Based on the multicladding equivalent method, the coated fiber coupler was simplified to a conventional one. With the high thermo-optical coefficient of organic-inorganic solgel material, a good sensing result was achieved. The range of temperature measured is from -50 to 100 degrees C. The resonant wavelength has a shift of about 25 nm. A sensitivity of 0.17 nm/degrees C is achieved. With the advantages of having a simple structure and being unaffected by the instability of the light source, the proposed fiber coupler temperature sensor will find wide applications.     

Development and evaluation of ZnO-Fe2O3 based nanocomposite sensors for butanol detection

Olfactory sensing of specific volatile organic compounds released by bacterial pathogens is one of the unique ways for determining microbial contamination in packaged food products. This study reports the development and evaluation of zinc oxide-iron oxide (ZnO-Fe2O3) nanocomposite sensors to detect low concentrations of butanol, one of the VOCs specific to Salmonella contamination in packaged beef, at low operating temperature (100 degrees C). The ZnO-Fe2O3 sensor was developed using modified Sol-gel method on an interdigitated alumina substrate. The sensor thin film characterization confirmed a uniform layer of ZnO-Fe2O3 thin film formation with ZnO nanorods of 100 nm height. Also, ZnO-Fe2O3 nanocomposite sensor demonstrated repeatable responses and good sensitivity to butanol with an estimated lower detection limit of about 26 ppm at 100 degrees C.     

General strategy for performing temperature programming in high performance liquid chromatography: prediction of linear temperature gradients

This paper describes how an empirical retention model is transferred from temperature-programmed gas chromatography (GC) to high temperature liquid chromatography (HT-HPLC). In order to evaluate the retention prediction, a temperature range from 50 to 180 °C was investigated using two test mixtures consisting of steroids and polycyclic aromatic hydrocarbons. In this temperature range, heating rates from 1.5 °C min(-1) up to 30 °C min(-1) were applied using four different high temperature stable HPLC columns with inner diameters of 1.0, 2.1, 3.0, and 4.6 mm. Temperature lag phenomena in the HPLC column as well as in the column oven are discussed, and it is shown that the linear elution strength (LES) model can be applied without any mathematical extension in order to take a temperature-dependent delay time into account. On the basis of this approximation, it is possible to perform a systematic method development using linear temperature gradients in liquid chromatography. Furthermore, it is shown that only two initial temperature gradient runs are necessary to predict the retention times of the analytes with a maximal relative error of less than 2%.     

Indium oxide thin film based ammonia gas and ethanol vapour sensor

A sensor for ammonia gas and ethanol vapour has been fabricated using indium oxide thin film as sensing layer and indium tin oxide thin film encapsulated in poly(methyl methacrylate) (PMMA) as a miniature heater. For the fabrication of miniature heater indium tin oxide thin film was grown on special high temperature corning glass substrate by flash evaporation method. Gold was deposited on the film using thermal evaporation technique under high vacuum. The film was then annealed at 700 K for an hour. The thermocouple attached on sensing surface measures the appropriate operating temperature. The thin film gas sensor for ammonia was operated at different concentrations in the temperature range 323–493 K. At 473 K the sensitivity of the sensor was found to be saturate. The detrimental effect of humidity on ammonia sensing is removed by intermittent periodic heating of the sensor at the two temperatures 323K and 448 K, respectively. The indium oxide ethanol vapour sensor operated at fixed concentration of 400 ppm in the temperature range 293–393 K. Above 373 K, the sensor conductance was found to be saturate. With various thicknesses from 150–300 nm of indium oxide sensor there was no variation in the sensitivity measurements of ethanol vapour. The block diagram of circuits for detecting the ammonia gas and ethanol vapour has been included in this paper.     

Design and test of a simple high-temperature laser microrefractometer

The design of a laser microrefractometer that is suitable for temperature-dependent measurements is described. The refractive index of methylene iodide is measured in the temperature range of 22-92 °C for laser wavelengths covering almost the entire visible range of the spectrum: 442, 488, 515, 543, 594, and 633 nm. A detailed analysis of the temperature-related experimental error is made.     

Influence of high temperatures on a fiber-optic probe for temperature measurement

The use of optical fiber in a temperature probe or sensor for optical pyrometry in the 100-1000 °C range is affected by the low thermal stability of classical fibers. We have studied the different sources of perturbations induced by exposure to high temperature. Two specific fibers especially suited for a high-temperature environment were tested and compared. Low (100 °C/min) and very fast (100 °C/s) fiber heating was performed to evaluate its influence on the guided flux and the induced error on temperature measurement. The metallic-coated fiber shows a reproducible temperature error that can be predicted. This important result permits the development of an uncooled fiber probe for temperature monitoring in high-temperature environments such as aerospace engines.     

Direct measurements of sample heating by a laser-induced air plasma in pre-ablation spark dual-pulse laser-induced breakdown spectroscopy (LIBS)

Direct measurements of temperature changes were made using small thermocouples (TC), placed near a laser-induced air plasma. Temperature changes up to ~500 °C were observed. From the measured temperature changes, estimates were made of the amount of heat absorbed per unit area. This allowed calculations to be made of the surface temperature, as a function of time, of a sample heated by the air plasma that is generated during orthogonal pre-ablation spark dual-pulse (DP) LIBS measurements. In separate experiments, single-pulse (SP) LIBS emission and sample ablation rate measurements were performed on nickel at sample temperatures ranging from room temperature to the maximum surface temperature that was calculated using the TC measurement results (500 °C). A small, but real sample temperature-dependent increase in both SP LIBS emission and the rate of sample ablation was found for nickel samples heated up to 500 °C. Comparison of DP LIBS emission enhancement values for bulk nickel samples at room temperature versus the enhanced SP LIBS emission and sample ablation rates observed as a function of increasing sample temperature suggests that sample heating by the laser-induced air plasma plays only a minor role in DP LIBS emission enhancement.     

Design principle for sensing coil of fiber-optic current sensor based on geometric rotation effect

The design principle exploiting the geometric rotation effect for the sensing coil of the fiber-optic current sensor (FOCS) on the basis of the polarization-rotated reflection interferometer is investigated. The sensing coil is formed by winding the low birefringence single-mode optical fiber in a toroidal spiral. The effects of the linear birefringence on the scale factor of the sensor can be suppressed with the reciprocal circular birefringence by appropriately designing the geometric parameters of the sensing coil. When the rated current is 1200 A(rms), the designed sensing coil can ensure the scale factor error of the sensor to satisfy the requirements of the 0.2 S class specified in IEC60044-8 over a temperature range from -40 °C to 60 °C.