Analysis of Pulverized Coal by Laser-Induced Breakdown Spectroscopy

Laser-induced breakdown spectroscopy （LIBS） has been used to detect atomic species in various enviromnents. The quantitative analysis （C, H, O, N and S） of representative coal samples are being carried out with LIBS, and the effects of particle size are analyzed. A powerful pulse Nd：YAG laser is focused on the coal sample at atmosphere pressure, and the emission spectra from laser-induced plasmas are measured by time-resolved spectroscopy, and the intensity of analyzed spectral lines is obtained through observing the laser plasma with a delay time of 0.4 #s. The experimental results show that the slope of calibration curve is nearly 1 when the concentration of the analyzed element is relatively low, and the slope of curve is nearly 0.5 when the concentration of C is higher than other elements. In addition, using the calibration-free model without self-absorption effect, the results show that the decreasing of particle size leads to an increase of the plasma temperature.     

Modelling of carbon erosion and re-deposition for the EAST movable limiter

The movable limiter at the mid-plane of the Experimental Advanced Superconducting Tokamak(EAST)with carbon coatings on the surface was exposed to edge plasma to study the material erosion and re-deposition.After the experiments,the carbon erosion and re-deposition is modelled using the 3D Monte Carlo code ERO.The geometry of the movable limiter,3D configuration of the plasma parameters and electromagnetic fields under both limiter and divertor configurations have been implemented into the code.In the simulations,the main uncertain parameters such as carbon concentrationρ_c in the background plasma and cross-field transport coefficient D_⊥in the vicinity of surface according to the'funneling model',have been studied in comparison with experiments.The parameterρ_c mainly influences the net erosion and deposition profiles of the two sides of the movable limiter,while D_⊥mostly changes the profiles on the top surface.     

FDTD Analysis of Reflection of Electromagnetic Wave From a Conductive Plane Covered with Inhomogeneous Time-Varying Plasma

A finite-difference time-domain (FDTD) algorithm is applied to study the electromagnetic reflection of conduction plane covered with inhomogeneous time-varying plasma, homogeneous plasma and inhomogeneous plasma. The collision frequency of plasma is a function of electron density and plasma temperature. The number density profile follows a parabolic function. A discussion on the effect of various plasma parameters on the reflection coefficient is presented. Under the one-dimensional case, transient electromagnetic propagation through various plasmas has been obtained, and the reflection coefficients of EM wave through various plasmas are calculated under different conditions. The results illustrate that a plasma cloaking system can successfully absorb the incident EM wave.     

Development of miniaturized SAF-LIBS with high repetition rate acousto-optic gating for quantitative analysis

The self-absorption effect in laser-induced breakdown spectroscopy(LIBS) reduces the accuracy of quantitative measurement results.The self-absorption-free LIBS(SAF-LIBS) has been proved to directly capture the optically thin plasma spectra by setting an appropriate exposure time.In this work,a novel SAF-LIBS technique with high repetition rate acousto-optic gating is developed,in which an acousto-optic modulator is used as the shutter to diffract the optically thin fluorescence,and a high repeti...     

Plasma-assisted abatement of SF_6 in a packed bed plasma reactor: understanding the effect of gas composition

The potential impact of SF_6 as a potent greenhouse gas on the global climate is highly attractive.This paper studies the effect of H_2O concentration, SF_6 inlet concentration and pre-heating temperature on SF_6 abatement in a packed bed plasma reactor in terms of the removal efficiency and products selectivity. The results showed that the best performance in SF_6 abatement was obtained at 1% H_2O and 100 °C with 98.7% destruction and remove efficiency(DRE) at 2% SF_6.Higher energy yields was obtained under higher SF_6 inlet concentration. Moreover, the existence of water vapor weakened the micro-discharge and provided H and OH radicals for this system,which showed a close relationship to removal efficiency and products selectivity. Among four sulfur-containing products, SO2 F2 was more stable than SOF_2, SOF_4 and SO_2. Meanwhile, SOF_4 and SO_2 were very susceptible to the above parameters. This article provides a better understanding of SF_6 abatement in a view of both scientific and engineering.     

Enhanced Lower Hybrid Current Drive Experiments on HT-7 Tokamak

Effective Lower Hybrid Current Driving (LHCD) and improved confinement experiments in higher plasma parameters (Ip > 200 kA, ne > 2 ×1013 cm-3, Te≥ 1 keV) have been curried out in optimized LH wave spectrum and plasma parameters in HT - 7 superconducting tokamak. The dependence of current driving efficiency on LH power spectrum, plasma density ne and toroidal magnetic field BT has been obtained under optimal conditions. A good CD efficiency was obtained at higher plasma current and higher electron density. The improvement of the energy confinement time is accompanied with the increase in line averaged electron density, and in ion and electron temperatures. The highest current driving efficiency reached ηCD = IpneR/PRF≈1.05×1019 Am-2/W. Wave-plasma coupling was sustained in a good state and the reflective coefficient was less than 5%. The experiments have also demonstrated the ability of LH wave in the start-up and ramp-up of the plasma current. The measurement of the temporal distribution of plasma     

Experimental investigation of lift enhancement for flying wing aircraft using nanosecond DBD plasma actuators

The effects of the arrangement position and control parameters of nanosecond dielectric barrier discharge(NS-DBD)plasma actuators on lift enhancement for flying wing aircraft were investigated through wind tunnel experiments at a flow speed of 25 m s~(-1).The aerodynamic forces and moments were obtained by a six-component balance at angles of attack ranging from-4°to 28°.The lift,drag and pitching moment coefficients were compared for the cases with and without plasma control.The results revealed that the maximum control effect was achieved by placing the actuator at the leading edge of the inner and middle wing,for which the maximum lift coefficient increased by 37.8%and the stall angle of attack was postponed by 8°compared with the plasma-off case.The effects of modulation frequency and discharge voltage were also investigated.The results revealed that the lift enhancement effect of the NS-DBD plasma actuators was strongly influenced by the modulation frequency.Significant control effects were obtained at/=70 Hz,corresponding to F~+≈1.The result for the pitching moment coefficient demonstrated that the plasma actuator can induce the reattachment of the separation flows when it is actuated.However,the results indicated that the discharge voltage had a negligible influence on the lift enhancement effect.     

Radio Frequency Induction Plasma Spraying of Molybdenum

Radio frequency (RF) induction plasma was used to make free-standing deposition of molybdenum (Mo). The phenomena of particle melting, flattening, and stacking were investigated. The effect of process parameters such as plasma power, chamber pressure, and spray distance on the phenomena mentioned above was studied. Scanning electron microscopy (SEM) was used to analyze the plasma-processed powder, splats formed, and deposits obtained. Experimental results show that less Mo particles are spheroidized when compared to the number of spheroidized tungsten (W) particles at the same powder feed rate under the same plasma spray condition. Molten Mo particles can be suf[iciently flattened on substrate. The influence of the process parameters on the flattening behavior is not significant. Mo deposit is not as dense as W deposit, due to the splash and low impact of molten Mo particles. Oxidation of the Mo powder with a large particle size is not evident under the low pressure plasma spray.     

A Study of Energy Conversion Efficiency Versus Plasma Density by Lower Hybrid Current Drive in HT—7 Tokamak

Ramp-up experiments by means of lower hydrid wave on HT-7 superconducting tokamak have been performed and analyzed.A ramp-up rate of over 300kA/s is obtained and a conversion efficiency of over 10% has been achieved during the ramp-up phases.The study of the dependence of conversion efficiency on plasma density shows that the conversion efficiency is affected by the driven current,which is mainly dominated by the competition of impurity concentration with wave accessibility condition.In addition,the effect of current profile may play an important role in determining the conversion efficiency.     

Study on Mediated Electrochemical Oxidation for Destruction of Tributyl Phosphate

<正>The effect factors of electrochemical oxidation on TBP of waste organic solvent were studied by Ag/MEO technique in a homemade H-type electrolysis cell,and the parameters of electrochemical oxidation TBP were obtained.The effects of Ag~+concentration,current density andtemperature on electrochemical oxidation rate were studied and discussed.Under the condition of current density of 0.2 A/cm~2,the electrochemical oxidation rate of TBP increases with Ag~+concentration (Fig.1).When the Ag~+concentration increases from 0.1 mol/L to 0.5 mol/L,     

Preliminary Analysis of Volt-Second Consumption on HL-2M

Prediction of volt-second consumption has been done by the tokamak simulation code (TSC),which includes the whole plasma discharge of HL-2M conception design.It covers the volt-second consumptions at the entire current ramp-up phase and the plasma flattop phase.More important,the sensitivities of volt-second consumption with respect to the current ramp-up time and the impurity concentration have been studied,respectively.     

Evolution of plasma parameters in an Ar-N2/He inductive plasma source with magnetic pole enhancement

Magnetic pole enhanced inductively coupled plasmas(MaPE-ICPs) are a promising source for plasma-based etching and have a wide range of material processing appUcations.In the present study Langmuir probe and optical emission spectroscopy were used to monitor the evolution of plasma parameters in a MaPE-ICP Ar-N_2/He mixture plasma.Electron density(n_e) and temperature(T_e),excitation temperature(T_(exc)),plasma potential(V_p),skin depth(δ) and the evolution of the electron energy probability function(EEPF) are reported as a function of radiofrequency(RF) power,pressure and argon concentration in the mixture.It is observed that n_e increases while T_e decreases with increase in RF power and argon concentration in the mixture.The emission intensity of the argon line at 750.4 nm is also used to monitor the variation of the 'high-energy tail' of the EEPF with RF power and gas pressure.The EEPF has a'bi-Maxwellian' distribution at low RF powers and higher pressure in a pure N_2 discharge.However,it evolves into a 'Maxwellian' distribution at RF powers greater than 70 W for pure N_2,and at 50 W for higher argon concentrations in the mixture.The effect of argon concentration on the temperatures of two electron groups in the 'bi-Maxwellian' EEPF is examined.The temperature of the low-energy electron group T_L shows a decreasing trend with argon addition until the 'thermalization' of the two temperatures occurs,while the temperature of high-energy electrons T_H decreases continuously.     

Time-Resolved Optical Emission Spectroscopy Diagnosis of CO2 Laser-Produced SnO2 Plasma

The spectral emission and plasma parameters of SnO_2 plasmas have been investigated.A planar ceramic SnO_2 target was irradiated by a CO2 laser with a full width at half maximum of 80 ns.The temporal behavior of the specific emission lines from the SnO_2 plasma was characterized.The intensities of Sn I and Sn II lines first increased,and then decreased with the delay time.The results also showed a faster decay of Sn I atoms than that of Sn II ionic species.The temporal evolutions of the SnO_2 plasma parameters(electron temperature and density) were deduced.The measured temperature and density of SnO_2 plasma are 4.38 eV to0.5 eV and 11.38×10~(17) cm~(-3) to 1.1×10~(17) cm~(-3),for delay times between 0.1 μs and 2.2 μs.We also investigated the effect of the laser pulse energy on SnO_2 plasma.     

Temporal and spatial dynamics of optical emission from laser ablation of the first wall materials of fusion device

Laser-induced breakdown spectroscopy(LIBS) has been developed to in situ diagnose the chemical compositions of the first wall in the EAST tokamak. However, the dynamics of optical emission of the key plasma-facing materials, such as tungsten, molybdenum and graphite have not been investigated in a laser produced plasma(LPP) under vacuum. In this work, the temporal and spatial dynamics of optical emission were investigated using the spectrometer with ICCD.Plasma was produced by an Nd:YAG laser(1064 nm) with pulse duration of 6 ns. The results showed that the typical lifetime of LPP is less than 1.4 μs, and the lifetime of ions is shorter than atoms at ~10~(-6)mbar. Temporal features of optical emission showed that the optimized delay times for collecting spectra are from 100 to 400 ns which depended on the corresponding species. For spatial distribution, the maximum LIBS spectral intensity in plasma plume is obtained in the region from 1.5 to 3.0 mm above the sample surface. Moreover, the plasma expansion velocity involving the different species in a multicomponent system was measured for obtaining the proper timing(gate delay time and gate width) of the maximum emission intensity and for understanding the plasma expansion mechanism. The order of expansion velocities for various species is V_C~+ V_H V_(Si)~+ V_(Li) V_(Mo) V_W.These results could be attributed to the plasma sheath acceleration and mass effect. In addition, an optimum signal-to-background ratio was investigated by varying both delay time and detecting position.     

Diagnostics of First Wall Materials in Device by Polarization-Resolved a Magnetically Confined Fusion Laser-Induced Breakdown Spectroscopy

Laser-induced breakdown spectroscopy （LIBS） is a powerful analytical tool for real- time diagnostics and detection of multiple elements deposited at the first wall of magnetically confined plasma ft~sion devices. Recently, we have tested LIBS in our laboratory for application to in situ real-time diagnostics in the fusion device EAST. In this study, we applied polarization- resolved LIBS （PR-LIBS） to reduce the background continuum and enhance the resolution and sensitivity of LIBS. We used aluminium （A1） （as a substitute for Be） and the first wall materials tungsten （W） and molybdenum （Mo） to investigate polarized continuum emission and signal-to- background ratio （SBR）. A Nd：YAG laser with first, second and third harmonics was used to produce plasma. The effects of the laser polarization plane, environmental pressure and polarizer detection angle were investigated. The spectra obtained without using a polarizer （i.e. LIBS） were compared with those obtained with a polarizer （PR-LIBS）. Distribution of emission spectral intensity was observed to follow Malus＇ law with respect to variation in the angle of detection of the polarizer. The spectra obtained by PR-LIBS had a higher SBR and greater stability than those obtained by LIBS, thereby enhancing the reliability of LIBS for quantitative analyses. A comparison of A1, Mo and W showed that W exhibited a higher continuum with stronger polarization than the low-Z elements.     

Study on Modification of Nano-Sized Anatase Titanium Dioxide by Nitrogen-Plasma

The nano-sized particles of anatase titanium oxide （TiO2） were obtained by hydrolysis of titanium ester （TNB） in basic media and dehydrated in acid media. And then the anatase titanium oxide was treated with nitrogen plasma. The effect of nitrogen plasma treating time on the activity of photo-catalytic reduction of the Cr2O7^2- for sample obtained was investigated. The samples were characterized by X-ray diffraction （XRD）, X-ray photoelectron spectroscopy （XPS）, Transmission Electron Microscope （TEM） and Ultraviolet （UV）. A peak of 396 eV in the N 1 s XPS spectra of sample obtained with nitrogen plasma treated TiO2 showed that nitrogen-doped titanium oxide （TiO2-zNx） has been obtained. The spectra of UV showed that the light absorption of TiO2-xNz obtained by nitrogen plasma treated TiO2 for 10min. had moved to the visible region. The picture of TEM and spectra of XRD indicated that the crystallographic forms and particle dimension had no apparent change for both the modified and the unmodified TiO2. When the TiO2 sample was treated for 7 min with nitrogen plasma, it exhibited best photo-catalytic activity.     

Atmospheric Pressure Plasma Jet in Ar and O2/Ar Mixtures： Properties and High Performance for Surface Cleaning＊

An atmospheric pressure plasma jet generated in Ar and O2/Ar mixtures has been investigated by specially designed equipment with double power electrodes at 20~32 kHz, and their effects on the cleaning of surfaces have been studied. Properties of the jet discharge are studied by electrical diagnostics, including the waveform of discharge voltage, discharge current and the Q-V Lissajous figures. The optical emission spectroscopy is used to measure the plasma parameters, such as the excitation temperature and the gas temperature. It is found that the consumed power and the excitation temperature increase with increase of the discharge frequency. On the other hand, at the same discharge frequency, these parameters in O2/Ar mixture plasma are found to be much larger. The effect on surface cleaning is studied from the changes in the contact angle. For Ar plasma jet, the contact angle decreases with increase of the discharge frequency. For O2/Ar mixture plasma jet, the contact angle decreases with increase of discharge frequency up to 26 kHz, however, further increase of discharge frequency does not show further decrease in the contact angle. At the same discharge frequency, the contact angle after O2/Ar mixture plasma cleaning is found to be much lower compared to the case of pure Ar. From the results of quadrupole mass-spectrum analysis, we can identify more fragment molecules of CO and H2O in the emitted gases after O2/Ar plasma jet treatment compared with Ar plasma jet treatment, which are produced by the decomposition of surface organic contaminants during the cleaning process.     

The impact of dielectrics on the electrical capacity,concentration, efficiency ozone generation for the plasma reactor with mesh electrodes

This paper presents experimental results concerning the effect of dielectric type on ozone concentration and the efficiency of its generation in plasma reactor with two mesh electrodes.Three types of dielectric solid were used in the study; glass, micanite and Kapton insulating foil. The experiments were conducted for voltage ranges from 2.3 to 13 k V. A plasma reactor equipped with two 0.3?×?0.3 mm~2 mesh electrodes made of acid resistant AISI 304 mesh was used in the experiments. The influence of the dielectric type on the concentration and efficiency of ozone generation was described. The resulting maximum concentration of the ozone was about 2.70–9.30 g O_3 m~(-3), depending on the dielectrics used. The difference between the maximum and the minimum ozone concentration depends on the dielectric used,this accounts for 70% at the variance. The reactor capacity has also been described in the paper; total C_t and dielectric capacitance C_d depending on the dielectric used and its thickness.     

Spatial Resolution Measurements of C,Si and Mo Using LIBS for Diagnostics of Plasma Facing Materials in a Fusion Device

Recently,a laser-induced breakdown spectroscopic(LIBS) system has been developed for in situ measurements of the chemical compositions of plasma facing materials(PFMs)in the Experimental Advanced Superconducting Tokamak(EAST).In this study,a LIBS system,which was used in a similar optical configuration to the in situ LIBS system in EAST,has been developed to investigate the spatial distribution of PFM elements at 1CP4 Pa.The aim of this study was to understand the nature of the spatial distribution of atoms or ions of different elements in the plasma plume and optimize the signal to background ratio for the in situ LIBS diagnosis in EAST.The spatial profiles of the LIBS signals of C,Si,Mo and the continuous background were measured.Moreover,the influence of laser spot size and laser energy density on the LIBS signals of C,Si,Mo and H was also investigated.The results show that the distribution of the C,Si and Mo peaks' intensities first increased and then decreased from the center to the edge of the plasma plume.There was a maximum value at R≈1.5 mm from the center of the plasma plume.This work aims to improve the understanding of ablating plasma dynamics in very low pressure environments and give guidance to optimize the LIBS system in the EAST device.     

Performence Provement of the High Power KrF Laser and Its Application

A beam smoothing experiment of one beam of the 6-beams high power KrF laser system at CIAEhas been demonstrated using the technique of echelon-free induced spatial incoherence (EF-ISI). Thefocal profiles with 1.4% rms deviation from a flat top distribution through the laser system capable ofproducing 30～40 J per pulse in 50 ns at a target were obtained and the 50 ns pulse has been compressed to