Influence of soaking and polymerization conditions on the properties of polymer concrete

An experimental investigation was conducted to study the effect of soaking time and polymerization temperature on the mechanical and physical properties of polymer-impregnated concrete. Soaking time was controlled in 4, 8, 12, 16, 20 and 24 h, polymerization temperature was set at 70, 80 and 90 °C for 0.5, 1, 2, 4, 6, 12 and 24 h in impregnation process, respectively. Cylindrical concrete specimens with water/cement ratios of 0.45 and 0.65 were impregnated with methyl methacrylate (MMA) and benzoyl peroxide (BPO) mixtures. The polymer loading increases as immersion time increases until 12 h. Based on compressive strength and surface absorption, optimum polymerization temperature is 70 °C for Mix A (high cement content) and 80 °C for Mix B (low cement content). Polymer impregnation not only increases concrete strength and resistivity but also greatly decreases surface absorption comparing with normal concrete. SEM and MIP observations indicate that the micro-pores and meso-pores of PIC specimens are filled with PMMA and the total pore volume and maximum pore size are reduced significantly.     

Compressive strength loss and reinforcement degradations of reinforced concrete structure due to long-term exposure

Degradations due to long-term weathering actions on a reinforced concrete structure were investigated. Compressive strength and reinforcement corrosion developments of a prototype RC structure were monitored for 6 years using destructive and non-destructive tests which include periodic coring, compressive strength, rebound hammer, ultrasonic pulse velocity, carbonation, half-cell and tensile strength tests. Eventually, results have shown that more than a quarter of peak compressive strength can be lost within 5 years of continuous exposure. Corrosion of the exposed bars within the range of the testing period was also observed to be quite alarming. Thus, defects caused by prolonged actions of environmental factors may pose serious threats on the integrity of partially completed structures especially abandoned projects.     

Effect of concrete mixing parameters on propagation of ultrasonic waves

An experimental study was conducted to evaluate the effect of concrete aggregate gradation, water–cement ratio, and curing time on measured ultrasonic wave velocity (UPV). 30 × 30 × 10 cm Portland cement concrete slabs were cast for ultrasonic evaluation, while 10 cm diameter by 20 cm height cylinders were cast for compressive strength evaluation The slabs and cylinders were prepared using Portland cement and limestone aggregate. Two slabs were cast from each combination of coarse aggregate gradations and water cement ratio (0.40, 0.45, 0.50, and 0.55). Four ASTM gradations were considered, ASTM No: 8, 67, 56, and 4. These gradations have nominal maximum aggregate size 25, 4.75, 19.3, and 12.5 mm, respectively.The ultrasonic equipment used in this study was the portable ultrasonic non-destructive digital indicating tester (PUNDIT) with a generator having an amplitude of 500 V producing 54 kHz waves. The time needed to transfer the signal between the transducers was recorded and used to calculate the signal velocity, which was used as a parameter in the evaluation. Ultrasonic measurements were performed at 3, 7, 28, and 90 days after concrete casting.The results of the analysis indicated that water–cement ratio was found to have a significant effect on UPV. The UPV was found to decrease with the increase of water cement ratio. Aggregate gradation was also found to have significant effect on UPV. In general, the larger the aggregate size used in preparing Portland cement concrete, the higher the measured velocity of ultrasonic waves. Also, UPV was found to be increased as concrete curing time increased. Concrete compressive strength was found to be significantly affected by water–cement ratio and coarse aggregate gradation. Lower water–cement ratio produced higher concrete strength. Also, the concrete compressive strength increased as maximum aggregate size decreased.     

Use of natural and thermally activated porphyrite in cement production

The aim of the present study was to investigate the use of porphyrite in the production of Portland cement. Natural and thermally activated porphyrites were used as a clay raw material and an activator, respectively, at 0, 10, 20, 30, 40 and 50 wt% in order to assess their effects on the cement properties. According to the test results, the compressive strength of the specimens decreased with increasing natural porphyrite content in various curing periods. However, the compressive strength of cement produced with 10 wt% porphyrite (activator) activated at 650 °C for 30 min showed a higher value (56 MPa in TPC-6) than cement without activator (51 MPa in RPC-2). Due to thermal activation, porphyrite activator containing a glass phase possesses an enhanced reactivity during clinker hydration that intensifies the synthesis of hydrosilicates and improves compressive strength accordingly. The X-ray diffraction analysis confirmed an intensive formation of Portland cement minerals such as C₃S, β-C₂S, C₃A and C₄AF. The addition of thermally activated porphyrite has also led to an improvement of the rheological behavior, stability to expansion, increase in setting time and decrease in specific surface area of cement. As prepared cement composites and concretes with improved properties meet the requirements of State Standards 310-86 and 10181-81 for Portland cement and concrete, respectively. The findings in this report indicate that porphyrite can be utilized both as a raw material and an activator in the production of cement.     

The effect of sample size on Schmidt rebound hardness value of rocks

The Schmidt hammer has been commonly used device for hardness determination and for predicting the unconfined compressive strength and other mechanical properties of rocks, due to the fact that it is a quick, easy, inexpensive and non-destructive testing method. Testing is most commonly performed following the ISRM and ASTM standards. The effect of sample size for a consistent hardness value has not been well defined in previous works. ISRM [Rock characterization testing and monitoring ISRM suggested methods, suggested methods for determining hardness and abrasiveness of rocks, Part 3. Oxford: Pergamon; 1981. p. 101–3] suggested that block edge length should have at least 6 cm, while ASTM [Standard test method for determination of rock hardness by Rebound Hammer Method, D5873-05, 2005] indicated at least 15 cm. In this study, in order to analyze the effect of sample size on Schmidt rebound hardness (SRH) property of rocks, rock samples were collected from eight locations. Cubic samples having different edge dimensions of 6, 7, 8, 10, 12 and 15 cm were prepared. In the laboratory, Schmidt hammer tests were conducted according to the suggested procedure by ISRM (1981) together with different methods of recording SRH. By evaluating the measured data, it is showed that the size of the cubic samples significantly affects the SRH values. Edge dimension of the cubic block should be at least 11 cm for determining a consistent hardness value. An equation predicting the consistent hardness value from samples smaller than 11 cm was also suggested.     

Experimental study of shotcrete and concrete strength development in a hot spring environment

To determine the influence of hot spring water on mechanical characteristics of tunnel supports made from Portland cement, this study investigates strength development and associated temporal variations of shotcrete and concrete specimens cast in situ and cured in water from a hot spring. Experimental results reveal that weakly-base hot spring water with a curing temperature of 40 °C does not adversely affect strength development for shotcrete and concrete; however, the hot spring curing environment may benefit early stage strength development and subsequent integrity. Chloride and sulfate ions in hot spring water do not enhance the alkali–aggregate or alkali–carbonate reaction significantly. Concrete specimens with high uniaxial compressive strength have high surface hardness, high electrical resistance and low permeability, implying excellent short-term durability.     

Effect of rice husk ash on the strength and durability characteristics of concrete

This work investigates the effects of adding residual rice husk ash (RHA) from South Vietnam, generated when burning rice husk pellets in the boiler, to cement. To improve pozzolanic reactivity, RHA was ground for 1 h. The non-ground RHA and ground RHA were used to test strength activity index according to ASTM C311. The properties of the concrete were investigated, including compressive strength, concrete electrical resistivity, and ultrasonic pulse velocity. Results show that the non-ground RHA can be applied as a pozzolanic material. Decreasing the non-ground RHA average particle size provides a positive effect on the compressive strength of mortar. Compressive strength of cylindrical concrete in the 47–66 MPa range was obtained in this study. The results also indicate that up to 20% of ground RHA could be advantageously blended with cement without adversely affecting the strength and durability properties of concrete.     

Influence of fly ash on strength and sorption characteristics of cold-bonded fly ash aggregate concrete

Cold-bonded fly ash aggregate concrete with fly ash as part of binder or fine aggregate facilitates high volume utilization of fly ash in concrete with minimum energy consumption. This paper investigates the influence of fly ash on strength and sorption behaviour of cold-bonded fly ash aggregate concrete due to partial replacement of cement and also as replacement material for sand. While cement replacement must be restricted based on the compressive strength requirement at desired age, replacement of sand with fly ash appears to be advantageous from early days onwards with higher enhancement in strength and higher utilization of fly ash in mixes of lower cement content. Microstructure of concrete was examined under BSEI mode. Replacement of sand with fly ash is effective in reducing water absorption and sorptivity attributable to the densification of both matrix and matrix–aggregate interfacial bond. Cold-bonded fly ash aggregate concrete with a cement content of 250 kg/m³, results in compressive strength of about 45 MPa, with a total inclusion of around 0.6 m³ of fly ash in unit volume of concrete.     

Damage to cement concrete pavements due to exposure to organic compounds in a cold region

Pop-out and disaggregation of aggregate in a 1-year old cement concrete pavement originally mixed with air-entraining (AE) water-reducing agent was observed after the pavement had been exposed to ethylene glycol based snow-melting agent on the surface in the winter. The study used: gas chromatography–mass spectrometry (GC–MS) tests, ¹H Nuclear Magnetic Resonance (NMR) tests, X-ray fluorescence analysis, emission spectral analysis (ICP), elution tests in anion type surfactant solution conducted for mortar and aggregate taken from the cement concrete where pop-out had occurred, as well as samples made by cement paste in the laboratory. Tests of the tensile strength, thermal-stress, and three-dimensional crack analysis by micro-focus computerized tomography (CT) scanner were conducted for specimens (2.5 × 2.5 × 10 cm) taken from the cement concrete where pop-out had occurred and with cement concrete samples made in the laboratory. Microscope observations and Electron Probe Micro Analyzer (EPMA) analysis were conducted for thin samples (2.5 × 2.5 cm and 20 μm thick) taken from the cement concrete where pop-out had occurred. The tests results showed that organic compounds contained in the cement reacted with the cement during the hardening process, generating cracks and gel in the cement paste. It was established that these caused the pop-out of the aggregate, together with the effects of the ethylene glycol based snow-melting agent that the cement concrete had been exposed to. No pop-out or disaggregation of aggregate were found in cement concrete at a repaired section, at the same location, with aggregate of low absorbing water ratio in this cold region and in place for 2 years.     

Use of palm oil fuel ash as a supplementary cementitious material for producing high-strength concrete

The objective of this study is to investigate the use of ground palm oil fuel ash with high fineness (GPA) as a pozzolanic material to produce high-strength concrete. Samples were made by replacing Type I Portland cement with various proportions of GPA. Properties such as the compressive strength, drying shrinkage, water permeability, and sulfate resistance, were then investigated. After aging for 28 days, the compressive strengths of these concrete samples were found to be in the range of 59.5–64.3 MPa. At 90-day the compressive strength of concrete containing GPA 20% was as high as 70 MPa. The drying shrinkage and water permeability were lower than those of high-strength concrete made from Type I Portland cement. When the concrete samples were immersed in a 10% MgSO₄ solution for 180 days, the sulfate resistance in terms of the expansion and loss of compressive strength was improved. The results indicated that GPA is a reactive pozzolanic material and can be used as a supplementary cementitious material for producing high-strength concrete.     

Influence of class F fly ash on the abrasion–erosion resistance of high-strength concrete

This study investigates the abrasion–erosion resistance of high-strength concrete (HSC) mixtures in which cement was partially replaced by four kinds of replacements (15%, 20%, 25% and 30%) of class F fly ash. The mixtures containing ordinary Portland cement were designed to have 28 days compressive strength of approximately 40–80 MPa. Specimens were subjected to abrasion–erosion testing in accordance with ASTM C1138. Experimental results show that the abrasion–erosion resistances of fly ash concrete mixtures were improved by increasing compressive strength and decreasing the ratio of water-to-cementitious materials. The abrasion–erosion resistance of concrete with cement replacement up to 15% was comparable to that of control concrete without fly ash. Beyond 15% cement replacement, fly ash concrete showed lower resistance to abrasion–erosion compared to non-fly ash concrete. Equations were established based on effective compressive strengths and effective water-to-cementitious materials ratios, which were modified by cement replacement and developed to predict the 28- and 91-day abrasion–erosion resistance of concretes with compressive strengths ranging from approximately 30–100 MPa. The calculation results are compared favorably with the experimental results.     

Durability design and performance of self-consolidating lightweight concrete

In terms of the durability, the reduction in cement paste is crucial to both volume stability and long-term performance of concrete. The objective of this paper is to compare the performance of lightweight concrete under different w/cm ratio and different cement paste content. The slump and slump flow spread of fresh self-consolidating lightweight concrete (SCLWC) are designed to be within 230–270 and 550–650 mm, respectively. The test results indicate that the 91-day compressive strength of SCLWC is up to 56 MPa when cement content is 386 kg/m³ and water content is 150 kg/m³. If enough cement paste is used, then the less the paste amount and the denser the packing of aggregate, the higher the strength efficiency of cement and the electric resistance, and the lower the chloride ion penetrability capacity of SCLWC.     

Corrosion of steel reinforcement in concrete of different compressive strengths

Corrosion of steel bars embedded in concrete having compressive strengths of 20, 30 and 46 MPa was investigated. Reinforced concrete specimens were immersed in a 3% NaCl solution by weight for 1, 7 and 15 days. In order to accelerate the chemical reactions, an external current of 0.4 A was applied using portable power supply. Corrosion rate was measured by retrieving electrochemical information of polarization technique. Pull-out tests of reinforced concrete specimens were then conducted to assess the corroded steel/concrete bond characteristics.Experimental results showed that corrosion rate of steel bars and bond strength between corroded steel/concrete were dependent on concrete strength and accelerated corrosion period. As concrete strength increased from 20 to 46 MPa, corrosion rate of embedded steel decreased. First day of corrosion acceleration caused a slight increase in steel/concrete bond strength, whereas sever corrosion after 7 and 15 days of corrosion acceleration significantly reduced steel/concrete bond strength. Visual and metallographic observation of steel bars removed from concrete samples after testing revealed that the severity of corrosion reactions and reduction of steel bar diameter increased as the corrosion acceleration period increased. Presence of localized corrosion pits as well as severe corrosion grooves of steel bars was confirmed after 7 and 15 days of corrosion acceleration, respectively.     

Mix proportion of high-strength,roller-compacted,latex-modified rapid-set concrete for rapid road repair

In this study, we optimized a blend of high-strength, roller-compacted, latex-modified rapid-set concrete (RCLMC) that can be re-opened to traffic after 4 h. To this end, we tested several variables in laboratory experiments, including hardening acceleration agents, cement type, latex addition, and CSA admixture ratios. The target compressive strength was 21 MPa after 4 h. A mixture of Type III cement to CSA admixture at 235:165 kg/m³ (400 kg/m³ total binder) and 23.5 kg/m³ latex (10% of the cement weight) achieved the target compressive strength and was the most economically efficient.     

Study of the reactivity of cement/metakaolin binders at early age for specific use in steam cured precast concrete

The paper presents the results of a hydration study performed in order to explain the significant increase in compressive strength at one day of age observed on steam cured mortars when 25% by mass of cement was replaced with a metakaolin. Two CEM I 52.5R cements, differing in reactivity, and a metakaolin (MK) were used. By means of XRD and thermal analysis carried out on cement pastes, blended or not with MK, the main results showed that the improvement in strength at one day of age could be explained by the occurrence of a pozzolanic reaction due to MK, thermo-activated by the high curing temperature (55 °C). The pozzolanic reaction was observed through the consumption of calcium hydroxide and an increase in the amount of C–S–H and C–S–A–H hydrated phases. This change in the hydration product nature and amount was more pronounced when MK was combined with the less reactive cement, in agreement with the mechanical results on mortars. These results are of great importance for the concrete industry where the current trend is to decrease the clinker content in cements (1 ton of clinker = 1 ton of CO₂ released). In particular, the interesting mechanical performance at early ages can be helpful for precast concrete manufacturing.     

The effect of cement dosage on mechanical properties of concrete exposed to high temperatures

Although concrete is a non-combustible material, it is found that when exposed to high temperatures, such as fire, the physical, chemical and mechanical properties of concrete can drastically change. Thus, it becomes important to assess the relative properties of concrete under high temperatures in order to evaluate and predict the post-fire response of reinforced concrete (RC) buildings and structures. This paper assesses the effects of elevated temperatures and cement dosages on the mechanical properties of concrete. Two concrete mix designs were considered in this research in an attempt to study the effects of cement dosage (250 and 350 kg/m³) on the post-fire response of concrete. Once cast, the test samples were first exposed to elevated temperatures ranging from 100 to 800 °C, and then allowed to cool down slowly to ambient room temperature of 20 °C before being tested to failure. Several tests were then carried out to determine the mechanical properties of the cooled concrete specimens. The test results indicated that at temperature above 400 °C, concrete undergoes significant strength loss when compared to the strength of non-heated concrete. In addition this strength reduction was found to be unaffected by the cement dosages. The experimental results were also compared with current European standard (BS EN 1992-1-2:2004 standard) strength equations and American Concrete Institute standard (ACI 216.1).     

Evaluation of rubbercrete based on ultrasonic pulse velocity and rebound hammer tests

Several research works have been carried out to study the fresh and hardened properties of concrete containing crumb rubber (rubbercrete) as a replacement of fine aggregate. The outcomes of these studies have highlighted the advantages and disadvantages of rubbercrete compared with conventional concrete mixtures. In view of the fact that rubbercrete is being used in the construction industry for a variety of purposes, evaluations of the rubbercrete mixtures using non-destructive tests such as rebound hammer (RH) and ultrasonic pulse velocity (UPV) to establish valid relationships is worthwhile. Fifteen mixtures with different w/c ratios (ratios of weight of water to weight of cement) and crumb rubber content percentages were prepared, cast and tested using RH and UPV at different curing ages. Models were proposed and statistically validated to predict the relationship between compressive strength with UPV and rebound number (RN) for rubbercrete mixtures at 3, 7 and 28 days.     

Modified MSWI ash-mix slag for use in cement concrete

In this study, fly- and scrubber-ash from a municipal solid waste incinerator (MSWI) were mixed uniformly in their production weight proportions; then, the mixture was added to waste glass frit and melted to form a glassy slag. The toxicity characteristic leaching procedure test results for the glassy slag revealed that the amount of leached heavy metals was far below the regulatory threshold. The slag-blended cement concrete (SBCC) specimens were manufactured with 20 wt.% of the cement replaced by slag powder. Three water/cementitious ratios, 0.48, 0.58 and 0.68, were selected to mold the specimens for compressive strength testing. The strengths of the SBCC specimens were close to or higher than those of the ordinary Portland cement concrete (OPCC) specimens at an age of 28 days and were 5–10% higher than those of the OPCC specimens at ages of 56 and 90 days. The experimental results demonstrated the feasibility of recycling MSWI fly- and scrubber-ash with waste glass.     

Assessment of the effects of rice husk ash particle size on strength,water permeability and workability of binary blended concrete

This study develops the compressive strength, water permeability and workability of concrete by partial replacement of cement with agro-waste rice husk ash. Two types of rice husk ash with average particle size of 5 micron (ultra fine particles) and 95 micron and with four different contents of 5%, 10%, 15% and 20% by weight were used. Replacement of cement up to maximum of 15% and 20% respectively by 95 and 5 μm rice husk ash, produces concrete with improved strength. However, the ultimate strength of concrete was gained at 10% of cement replacement by ultra fine rice husk ash particles. Also the percentage, velocity and coefficient of water absorption significantly decreased with 10% cement replacement by ultra fine rice husk ash. Moreover, the workability of fresh concrete was remarkably improved by increasing the content of rice husk ash especially in the case of coarser size. It is concluded that partial replacement of cement with rice husk ash improves the compressive strength and workability of concrete and decreases its water permeability. In addition, decreasing rice husk ash average particle size provides a positive effect on the compressive strength and water permeability of hardened concrete but indicates adverse effect on the workability of fresh concrete.     

Comparison on efficiency factors of F and C types of fly ashes

Fly ashes are obtained from thermal power plants and they are pozzolanic materials, which can act as partial replacement material for both portland cement and fine aggregate. With their economical advantages and potential for improving fresh and hardened concrete performance, they have some benefits for using in concrete industry. In this study, the objective was to find the efficiency factors of Turkish C and F-type fly ashes and to compare their properties. Three different cement dosages were used (260, 320, 400 kg/m³), two different ratios (10% and 17%) of cement reduced from the control concretes and three different ratios (depending on cement reduction ratio) of fly ash were added into the mixtures. At the ages of 28 and 90 days, compressive strength, modulus of elasticity and ultrasound velocity tests were carried out. From the compressive strength results, the k efficiency factors of C and F-type fly ashes were obtained. As a result, it is seen that efficiency factors of the concrete produced by the replacement of F and C type fly ashes with cement increase with the increase in cement dosage and concrete age.