Effect of mineral admixtures and curing periods on shrinkage and cracking age under restrained condition

This paper presents the test results on cracking behavior at medium age of uniaxially restrained specimens containing different types of mineral admixture, namely fly ash and limestone powder. In this study, the uniaxially restrained shrinkage, free shrinkage and strength tests were conducted to study the potential of cracking of concrete under restrained shrinkage condition. The influences of water to binder ratio, mineral admixtures and curing period of concrete on cracking behavior were investigated in this study. The investigation showed that cracking age and cracking strain of restrained specimens vary with mix proportion, mineral admixture and curing period. The potential of shrinkage cracking is not influenced only by cracking strain and amount of shrinkage but also on shrinkage rate and tensile creep. Mixture with lower water to binder ratio (w/b = 0.35) shows shorter cracking age than the mixture with higher water to binder ratio (w/b = 0.55). Fly ash and limestone powder significantly increase cracking age of concrete. The cracking age increases with the increase of the replacement ratio of fly ash. The higher shrinkage rate, when exposed to drying, of mixture with longer curing period leads to shorter cracking age.     

Metakaolin,a solution for the precast industry to limit the clinker content in concrete: Mechanical aspects

The current trend to decrease the clinker content in cements through the use of mineral additions in order to limit CO₂ emissions into the atmosphere is of major concern for the precast industry as the resulting binders are generally not very reactive at early ages. Here, composed cements (clinker + slag) or combinations between clinker and mineral admixtures are studied with a view to investigating the compressive strength of cement-based materials at both early (1 day) and later (28 days) ages under steam curing conditions. Limestone and siliceous fillers, silica fume and four metakaolins differing in their production process and impurity content were investigated. Considering performance, economic and environmental criteria, results in the laboratory showed that metakaolin (MK) is a very promising solution at a clinker replacement rate of 12.5–25% by mass. Compressive strength was significantly increased (1-day age) or practically the same as for reference mortars incorporating cement only (28-day age). Thus, in comparison with a reference concrete containing no MK and for an identical granular skeleton, the combination clinker/MK was validated in the precast factory in full-scale trials for slip-forming (25% replacement) and self-compacting (17.5% replacement) concrete applications: compressive strength and porosity were not affected.     

Use of palm oil fuel ash as a supplementary cementitious material for producing high-strength concrete

The objective of this study is to investigate the use of ground palm oil fuel ash with high fineness (GPA) as a pozzolanic material to produce high-strength concrete. Samples were made by replacing Type I Portland cement with various proportions of GPA. Properties such as the compressive strength, drying shrinkage, water permeability, and sulfate resistance, were then investigated. After aging for 28 days, the compressive strengths of these concrete samples were found to be in the range of 59.5–64.3 MPa. At 90-day the compressive strength of concrete containing GPA 20% was as high as 70 MPa. The drying shrinkage and water permeability were lower than those of high-strength concrete made from Type I Portland cement. When the concrete samples were immersed in a 10% MgSO₄ solution for 180 days, the sulfate resistance in terms of the expansion and loss of compressive strength was improved. The results indicated that GPA is a reactive pozzolanic material and can be used as a supplementary cementitious material for producing high-strength concrete.     

Effect of elevated temperature on the mechanical properties of concrete produced with finely ground pumice and silica fume

This study investigated the effect of elevated temperature on the mechanical and physical properties of concrete specimens obtained by substituting cement with finely ground pumice (FGP) at proportions of 5%, 10%, 15% and 20% by weight. To determine the effect of silica fume (SF) additive on the mechanical and physical properties of concrete containing FGP, SF has been added to all series except for the control specimen, which contained 10% cement by weight instead. The specimens were heated in an electric furnace up to 400, 600 and 800 °C and kept at these temperatures for one hour. After the specimens were cooled in the furnace, ultrasonic pulse velocity (UPV), compressive strength and weight loss values were determined. The results demonstrated that adding the mineral admixtures to concrete decreased both unit weight and compressive strength. Additionally, elevating the temperature above 600 °C affected the compressive strength such that the weight loss of concrete was more pronounced for concrete mixtures containing both FGP and SF. These results were also supported by scanning electron microscope (SEM) studies.     

Shrinkage characteristics of high-strength concrete for large underground space structures

This study forms part of a research project that was carried out on the development and application of high-strength concrete for large underground spaces. In order to develop 50 MPa high-strength concrete, eight optimal mixtures with different portions of fly ash and ground granulated blast furnace slag, which make the pozzolanic reaction, were selected. For assessments of shrinkage characteristics, free shrinkage tests with prismatic specimens and shrinkage crack tests were performed. The compressive strength was more than 30 MPa at 7 days, and stable design strength was acquired at 28 days. High-strength concrete containing blast furnace slag shows large autogenous shrinkage, while large shrinkage deformations and cracks will occur when mixtures are replaced with large volumes of cementitious materials. Hence, for these high-strength concrete mixtures, the curing conditions of initial ages that affect the reaction of hydration and drying effects need to be checked.     

Influence of class F fly ash on the abrasion–erosion resistance of high-strength concrete

This study investigates the abrasion–erosion resistance of high-strength concrete (HSC) mixtures in which cement was partially replaced by four kinds of replacements (15%, 20%, 25% and 30%) of class F fly ash. The mixtures containing ordinary Portland cement were designed to have 28 days compressive strength of approximately 40–80 MPa. Specimens were subjected to abrasion–erosion testing in accordance with ASTM C1138. Experimental results show that the abrasion–erosion resistances of fly ash concrete mixtures were improved by increasing compressive strength and decreasing the ratio of water-to-cementitious materials. The abrasion–erosion resistance of concrete with cement replacement up to 15% was comparable to that of control concrete without fly ash. Beyond 15% cement replacement, fly ash concrete showed lower resistance to abrasion–erosion compared to non-fly ash concrete. Equations were established based on effective compressive strengths and effective water-to-cementitious materials ratios, which were modified by cement replacement and developed to predict the 28- and 91-day abrasion–erosion resistance of concretes with compressive strengths ranging from approximately 30–100 MPa. The calculation results are compared favorably with the experimental results.     

Compressive strength and shrinkage of mortar containing various amounts of mineral additions

Three mineral additions largely used in cementitious materials were tested in order to follow the shrinkage behaviour for 1 year of observation when they substitute a part of cement. The tests were carried out on standardized mortars specimen where cement was replaced by 5%, 15% and 25% of limestone, 10%, 20%, 30% of natural pozzolan and 10%, 30% and 50% of slag. The substitution of cement by 10%, 20% and 30% of limestone powder, natural pozzolan and slag respectively involves an optimal improvement of compressive strength of mortar. The separate quantification of the autogeneous and drying shrinkage development shows the effective contribution of each addition on microstructure modification and of the additional hydrates production. The microstructure was improved in the presence of limestone and of a moderate rate of slag, whereas it remains normal with natural pozzolan. The replacement rate of an active addition lower than 10% led to an additional hydrates production. This overproduction which accompanies the autogeneous shrinkage is more pronounced when cement is largely replaced by limestone. The evolutions of strength and shrinkage of mortars follow the same tendency from where it is easier to find a linear relationship giving the shrinkage deformation according to the compressive strength.     

Influence of fly ash on strength and sorption characteristics of cold-bonded fly ash aggregate concrete

Cold-bonded fly ash aggregate concrete with fly ash as part of binder or fine aggregate facilitates high volume utilization of fly ash in concrete with minimum energy consumption. This paper investigates the influence of fly ash on strength and sorption behaviour of cold-bonded fly ash aggregate concrete due to partial replacement of cement and also as replacement material for sand. While cement replacement must be restricted based on the compressive strength requirement at desired age, replacement of sand with fly ash appears to be advantageous from early days onwards with higher enhancement in strength and higher utilization of fly ash in mixes of lower cement content. Microstructure of concrete was examined under BSEI mode. Replacement of sand with fly ash is effective in reducing water absorption and sorptivity attributable to the densification of both matrix and matrix–aggregate interfacial bond. Cold-bonded fly ash aggregate concrete with a cement content of 250 kg/m³, results in compressive strength of about 45 MPa, with a total inclusion of around 0.6 m³ of fly ash in unit volume of concrete.     

Utilization of separator bag filter dust for high early strength cement production

This paper presents the feasibility of incorporating ultra-fine particles collected in the separator bag filter during the process of manufacturing cement (SBFC) as an substitution material for cement. Approximately 2.5% of SBFC is produced during OPC manufacturing process. Also, the average size of SBFC particles is about 5 μm, the average size of OPC particles is about 14 μm. This method does not require additional processes needed in the existing processes to manufacture high early strength cement such as modifying mineral components and adjusting the firing temperature. Moreover, it can also solve the issue of efficiency decrease resulted from the increase of the grinding time applied in the existing process of manufacturing microcement. In order to investigate the characteristic properties of this cement mixture, cement blends have been produced by using different amounts of SBFC. While the blaine value of 100% SBFC was significantly higher (6953 cm²/g) than that of Ordinary Portland Cement (OPC), its chemical composition showed no significant difference. Cement paste, mortar mixtures have been prepared by using cement blends incorporating 0, 50 and 100% SBFC by weight. Flowability, setting time and compressive strength tests has been performed. Test results showed that substitution of SBFC negatively affect the flowability of cement paste and mortar mixtures. Moreover, setting times shortened, compressive and flexural strength values increased by the substitution of SBFC. Finally, microstructure analysis of cement paste samples showed that incorporation of SBFC reduced the internal porosity by 9% as determined by the proposed method. The internal porosity of paste was measured by mercury intrusion porosimetry (MIP). The compressive strength and bending strength of mortar were higher in the order of 100, 50 and 0% SBFC mixed.     

Study on early-age cracking of cement-based materials with superplasticizers

The addition of superplasticizers is an important approach to prepare high performance cement-based materials. The effect of polynaphthalene series superplasticizer (PNS) and polycarboxylate type superplasticizer (PC) on early-age cracking and volume stability of cement-based materials was investigated by means of multi-channel ellipse ring shrinkage cracking test, free shrinkage and strength test. The general effect of PNS and PC is to increase initial cracking time of mortars, and decrease cracking sensitivity of mortars. As for decreasing cracking sensitivity of mortars, PC > H-UNF (high-thickness-type PNS) > C-UNF (common-thickness-type PNS). To incorporate superplasticizers is apparently to increases free shrinkage of mortars when keeping the constant W/B ratio and the content of cement pastes. As for the effect of controlling volume stability of mortars, PC > C-UNF > H-UNF. Maximum crack width of mortars with PC is lower, but the development rate of maximum crack width of mortars with H-UNF is faster in comparison with control mortars. Flexural and compressive strength of mortars and concretes at 28 days increased with increasing superplasticizer dosages under drying conditions. C-UNF was approximate to H-UNF, but PC was superior to PNS in the aspect of increasing strength of cement-based materials.     

Performance of self-compacting concrete containing different mineral admixtures

This paper presents experimental study on the properties of self-compacting concrete (SCC). Portland cement (PC) was replaced with fly ash (FA), granulated blast furnace slag (GBFS), limestone powder (LP), basalt powder (BP) and marble powder (MP) in various proportioning rates. The influence of mineral admixtures on the workability, compressive strength, ultrasonic pulse velocity, density and sulphate resistance of SCC was investigated. Sulphate resistance tests involved immersion in 10% magnesium sulphate and 10% sodium sulphate solutions for a period of 400 days. The degree of sulphate attack was evaluated using visual examination and reduction in compressive strength. The test results showed that among the mineral admixtures used, FA and GBFS significantly increased the workability and compressive strength of SCC mixtures. Replacing 25% of PC with FA resulted in a strength of more than 105 MPa at 400 days. Moreover, the presence of mineral admixtures had a beneficial effect on the strength loss due to sodium and magnesium sulphate attack. On the other hand, the best resistance to sodium and magnesium sulphate attacks was obtained from a combination of 40% GBFS with 60% PC.     

The role of industrial by-products in self-compacting concrete

The development of self-compacting concrete is considered as a milestone achievement in concrete technology due to several advantages. In order to be self-compactable the fresh concrete must show high fluidity besides good cohesiveness. For the purpose of evaluating these properties, several concrete mixtures were prepared with a water to cement ratio of 0.45 in the presence of an acrylic-based superplasticizer at a dosage ranging from 1% to 2% by weight of very fine material fraction (maximum 150 μm). Either limestone powder or fly ash or recycled aggregate powder (that is a powder obtained from the rubble recycling process) were used as mineral addition, in order to assure adequate rheological properties, in terms of cohesiveness, in the self-compacting concretes. Preliminary rheological tests were carried out on cement pastes containing these mineral additions. In some cases, recycled instead of natural aggregate was used by substituting either the coarse or the fine aggregate fraction. The fresh concrete properties were evaluated through slump flow, L-box test and segregation resistance. Compressive strength of concrete was determined at 1, 3, 7 and 28 days of wet curing. Results obtained showed that an optimization of self-compacting concrete mixture seems to be achievable by the simultaneous use of rubble powder and coarse recycled aggregate with improved fresh concrete performance and unchanged concrete mechanical strength.     

Comparison on efficiency factors of F and C types of fly ashes

Fly ashes are obtained from thermal power plants and they are pozzolanic materials, which can act as partial replacement material for both portland cement and fine aggregate. With their economical advantages and potential for improving fresh and hardened concrete performance, they have some benefits for using in concrete industry. In this study, the objective was to find the efficiency factors of Turkish C and F-type fly ashes and to compare their properties. Three different cement dosages were used (260, 320, 400 kg/m³), two different ratios (10% and 17%) of cement reduced from the control concretes and three different ratios (depending on cement reduction ratio) of fly ash were added into the mixtures. At the ages of 28 and 90 days, compressive strength, modulus of elasticity and ultrasound velocity tests were carried out. From the compressive strength results, the k efficiency factors of C and F-type fly ashes were obtained. As a result, it is seen that efficiency factors of the concrete produced by the replacement of F and C type fly ashes with cement increase with the increase in cement dosage and concrete age.     

Effect of superplasticizer on plastic shrinkage of plain and silica fume cement concretes

Four types of superplasticizers were used in conjunction with three types of silica fume to prepare cement concrete slab specimens that were utilized to measure plastic shrinkage strain and time to attain maximum strain. The concrete slab specimens were cast and placed in an exposure chamber in which the relative humidity, temperature, and wind velocity were kept at 35 ± 5%, 45 ± 2 °C, and 15 ± 2 km/h, respectively. Results of this investigation indicate that the plastic shrinkage strain varied with the type of superplasticizer and the type of silica fume. Maximum plastic shrinkage strain was measured in the undensified silica fume cement concrete with all superplasticizers. Incompatibility was noted between polycarboxylic ether superplasticizer and plain and two types of silica fume cement concretes.     

Effect of elevated temperature on physico-mechanical properties of blended cement concrete

Pozzolanas are readily available for use in concrete in the local markets for strength and/or durability enhancement. Although safety and security against disasters are not new, they still presuming a challenge. For instance, the fire resistive properties of concrete are of prime interest.Through this work, the effect of different kinds of pozzolana on the fire resistive properties of concrete was studied. Four types of pozzolana were incorporated into the concrete mixtures, i.e. metakaolin (MK), silica fume (SF), fly ash (FA), and ground granulated blast furnace slag (GGBS). Each of the employed pozzolana was used in two ratios: 10% and 20%, either in the form of cement replacement or as an addition without affecting the cement content. A total of 17 mixes were cast.For all mixtures, compressive strength is evaluated after 28 days of water curing. The mixtures’ compressive strengths were also evaluated after exposure to elevated temperatures: 200 °C, 400 °C, 600 °C, and 800 °C. The residual compressive strengths after heat exposure are evaluated. The formed cementitious phases after incorporation of pozzolana and the heat-induced transformations are investigated via the X-ray diffraction technique (XRD).Test results demonstrate the impact of each type of the employed pozzolana on the heat resistive properties of concrete in addition to their influence on the strength development of the investigated mixes. Therefore, a decision could be made regarding optimizing the benefits specific to each type of pozzolana and their employment method.     

Influence of calcined kaolin on mortar properties

The use of calcined clay, in the form of metakaolin (MK), as a pozzolanic material for mortar and concrete has received considerable attention in recent years. The present paper describes the results of a research project initiated to study the calcination of local kaolin at various temperatures (650–950 °C) and durations (2, 3 and 4 h) to produce MK with a high pozzolanic activity. The pozzolanic activity was assessed by 28-days compressive strength and hydration heat methods. The maximum identified activity was obtained at 850 °C for 3 h duration. An increase of both hydration heat and compressive strength was obtained when ordinary Portland cement was replaced by 10% MK. The use of ternary blended cement improves the early age and the long-term compressive strength. The durability was also enhanced as better acidic resistance was observed.     

Influence of a combination of expansive and shrinkage-reducing admixture on autogenous deformation and self-stress of silica fume high-performance concrete

High-performance concrete (HPC) is characterized by its low water-to-cementitious materials (w/cm) and improved properties but also it exhibits high internal capillary tensile stress because the development of autogenous shrinkage which could result in early-age cracking risk and premature deterioration. Since the use of HPC in structural elements has gained wide acceptance in the last decades, the large magnitude of early-age autogenous strains and stresses has to be mitigated to enhance the durability of concrete structure. In this paper, internal stress development induced during the development of autogenous shrinkage strains, especially at early-age was investigated on three different types of HPC cured with a combination of two shrinkage-compensating admixtures. Binary HPC made with blended cement containing 10% of silica fume (SF) has been used with three different low (w/c + sf) of 0.15, 0.23, and 0.30. Shrinkage-reducing agent (SRA) and an expansive additive (EXA) were combined and added to the HPC mixtures to minimize autogenous shrinkage magnitude.The results indicate that the greater the autogenous shrinkage developed, the higher the induced internal tensile stress. It has been found that for the reference mixes, more than 90% of the ultimate magnitude of both autogenous shrinkage and self-tensile stress was developed during the first 24 h. However, the addition of a combination of SRA and EXA has resulted in a significant reduction and a gradual development of both autogenous shrinkage and self-tensile stress as compared to the rapid development and large magnitude in the reference concretes. Moreover, a high dimensional stability was obtained for the 0.30 and 0.23 HPC mixtures containing the combination of expansive and shrinkage-reducing admixtures. On the other hand, a slight decrease of the compressive, of the splitting tensile strengths and the modulus of elasticity was observed.     

Utilization of bagasse ash as a pozzolanic material in concrete

The physical properties of concrete containing ground bagasse ash (BA) including compressive strength, water permeability, and heat evolution, were investigated. Bagasse ash from a sugar factory was ground using a ball mill until the particles retained on a No. 325 sieve were less than 5wt%. They were then used as a replacement for Type I Portland cement at 10, 20, and 30wt% of binder. The water to binder (W/B) ratio and binder content of the concrete were held constant at 0.50 and 350 kg/m³, respectively.The results showed that, at the age of 28 days, the concrete samples containing 10–30% ground bagasse ash by weight of binder had greater compressive strengths than the control concrete (concrete without ground bagasse ash), while the water permeability was lower than the control concrete. Concrete containing 20% ground bagasse ash had the highest compressive strength at 113% of the control concrete. The water permeability of concrete decreased as the fractional replacement of ground bagasse ash was increased. For the heat evolution, the maximum temperature rise of concrete containing ground bagasse ash was lower than the control concrete. It was also found that the maximum temperature rise of the concrete was reduced 13, 23, and 33% as compared with the control concrete when the cement was replaced by ground bagasse ash at 10, 20, and 30wt% of binder, respectively. The results indicate that ground bagasse ash can be used as a pozzolanic material in concrete with an acceptable strength, lower heat evolution, and reduced water permeability with respect to the control concrete.     

Strength and drying shrinkage properties of concrete containing furnace bottom ash as fine aggregate

The strength and drying shrinkage of concretes with the natural sand replaced with furnace bottom ash (FBA) at 0%, 30%, 50%, 70% and 100% by mass, were studied at fixed water–cement ratios (W/C) and fixed slump ranges.The results showed that, at fixed water–cement ratios, the compressive strength and the drying shrinkage decreased with the increase of the FBA sand content. However, at fixed workability, the compressive strength was comparable with that of the control concrete, while the drying shrinkage increased with the increase of the FBA sand content beyond 30% replacement level. Nevertheless, 30% of the natural sand can be beneficially replaced with the FBA sand to produce concrete in the compressive strength range from 40 to 60 N/mm² without detrimentally affecting drying shrinkage properties of the concrete.     

The properties of concrete made with fine dune sand

This paper presents the results of a study that investigated the properties of concrete made with dune sand. Different control concrete mixtures using ordinary Portland cement (OPC) with a minimum design compressive strength of 40 N/mm² were prepared. The amount of fine aggregates constituted about 36% by weight of all the aggregates. The workability ranged from low of 16 mm to a high of 122 mm. For each control mix, other mixtures were prepared in which the fine aggregates were replaced by different percentages of dune sand ranging from 10% to 100%. The effect of dune sand on the workability, compressive strength, tensile strength, modulus of elasticity and initial surface absorption test (ISAT) was studied. Experimental results show an improvement in the workability of concrete when fine aggregates were partially replaced by dune sand. An increase in slump was measured with increase in dune sand content. However, at high dune sand contents (above 50%); the slump starts to decrease with an increase in dune sand. Generally, the strength values decrease with increase in dune sand replacement. The strength loss was not found considerable as the maximum reduction was less than 25% when fine aggregates were fully replaced by dune sand. The absorption characteristics of concrete made with OPC as measured by the (ISAT) generally increased with higher dune sand contents.