Shrinkage characteristics of high-strength concrete for large underground space structures

This study forms part of a research project that was carried out on the development and application of high-strength concrete for large underground spaces. In order to develop 50 MPa high-strength concrete, eight optimal mixtures with different portions of fly ash and ground granulated blast furnace slag, which make the pozzolanic reaction, were selected. For assessments of shrinkage characteristics, free shrinkage tests with prismatic specimens and shrinkage crack tests were performed. The compressive strength was more than 30 MPa at 7 days, and stable design strength was acquired at 28 days. High-strength concrete containing blast furnace slag shows large autogenous shrinkage, while large shrinkage deformations and cracks will occur when mixtures are replaced with large volumes of cementitious materials. Hence, for these high-strength concrete mixtures, the curing conditions of initial ages that affect the reaction of hydration and drying effects need to be checked.     

Comparison on efficiency factors of F and C types of fly ashes

Fly ashes are obtained from thermal power plants and they are pozzolanic materials, which can act as partial replacement material for both portland cement and fine aggregate. With their economical advantages and potential for improving fresh and hardened concrete performance, they have some benefits for using in concrete industry. In this study, the objective was to find the efficiency factors of Turkish C and F-type fly ashes and to compare their properties. Three different cement dosages were used (260, 320, 400 kg/m³), two different ratios (10% and 17%) of cement reduced from the control concretes and three different ratios (depending on cement reduction ratio) of fly ash were added into the mixtures. At the ages of 28 and 90 days, compressive strength, modulus of elasticity and ultrasound velocity tests were carried out. From the compressive strength results, the k efficiency factors of C and F-type fly ashes were obtained. As a result, it is seen that efficiency factors of the concrete produced by the replacement of F and C type fly ashes with cement increase with the increase in cement dosage and concrete age.     

Influence of pozzolan from various by-product materials on mechanical properties of high-strength concrete

This paper presents experimentally investigated the effects of pozzolan made from various by-product materials on mechanical properties of high-strength concrete. Ground pulverized coal combustion fly ash (FA), ground fluidized bed combustion fly ash (FB), ground rice husk–bark ash (RHBA), and ground palm oil fuel ash (POFA) having median particle sizes less than 11 μm were used to partially replace Portland cement type I to cast high-strength concrete. The results suggest that concretes containing FA, FB, RHBA, and POFA can be used as pozzolanic materials in making high-strength concrete with 28-day compressive strengths higher than 80 MPa. After 7 days of curing, the concretes containing 10–40% FA or FB and 10–30% RHBA or POFA exhibited higher compressive strengths than that of the control concrete (CT). The use of FA, FB, RHBA, and POFA to partially replace Portland cement type I has no significant effect on the splitting tensile strength and modulus of elasticity as compared to control concrete or silica fume concretes. This results suggest that the by-products from industries can be used to substitute Portland cement to produce high-strength concrete without alteration the mechanical properties of concrete.     

Effects of post-mercury-control fly ash on fresh and hardened concrete properties

Activated carbon injection is the most mature technology for mercury capture from coal burning power plants; however, this technology increases the carbon content and mercury concentration in the fly ash. This, in turn, may reduce the suitability of fly ash for use in concrete and call into question the safety of using fly ash derived from this process. The focus of this paper is to investigate the reuse potential of post-mercury-control fly ash in concrete by examining the influence of three fly ashes derived from the activated carbon injection on the air content, compressive strength, permeability, and resistance to freezing and thawing of concrete mixtures. Laboratory testing confirmed the influence of the carbon on the air content of the concrete. However there was no difficulty in entraining air in activated carbon injection fly ash concretes within the recommended dosage range of the air-entraining admixture. All air-entrained fly ash concretes exhibited excellent characteristics in compressive strength (?32.0 MPa, 4641 psi at 28 days), resistance to chloride-ion penetration (moderate to low at 28 days of age) and freeze–thaw (?90 average durability factor after 300 cycles). The possible leaching of toxic elements including mercury from one fly ash sample used in this study was also evaluated using the US Environmental Protection Agency’s Toxicity Characteristic Leaching Procedure. The test results indicated that the leaching of toxic elements was much lower than the contamination level.     

The role of industrial by-products in self-compacting concrete

The development of self-compacting concrete is considered as a milestone achievement in concrete technology due to several advantages. In order to be self-compactable the fresh concrete must show high fluidity besides good cohesiveness. For the purpose of evaluating these properties, several concrete mixtures were prepared with a water to cement ratio of 0.45 in the presence of an acrylic-based superplasticizer at a dosage ranging from 1% to 2% by weight of very fine material fraction (maximum 150 μm). Either limestone powder or fly ash or recycled aggregate powder (that is a powder obtained from the rubble recycling process) were used as mineral addition, in order to assure adequate rheological properties, in terms of cohesiveness, in the self-compacting concretes. Preliminary rheological tests were carried out on cement pastes containing these mineral additions. In some cases, recycled instead of natural aggregate was used by substituting either the coarse or the fine aggregate fraction. The fresh concrete properties were evaluated through slump flow, L-box test and segregation resistance. Compressive strength of concrete was determined at 1, 3, 7 and 28 days of wet curing. Results obtained showed that an optimization of self-compacting concrete mixture seems to be achievable by the simultaneous use of rubble powder and coarse recycled aggregate with improved fresh concrete performance and unchanged concrete mechanical strength.     

The characteristics of air void and frost resistance of RCC with fly ash and expansive agent

In order to assure the outer concrete of Longtan dam in China possesses excellent of frost resistance, the losses of strength, mass and air void characteristics of roller compacted concrete (RCC) containing fly ash, superplasticizer and a novel MgO-bearing expansive agent (HNM) were studied using the freezing–thawing method ASTM C666. The results show that there is a linear correlation between strength and mass losses in RCC subjected to cycles of freezing and thawing.There is a relationship between the air void spacing factor and the frost resistance of RCC. However, for RCC containing fly ash and superplasticizer a spacing factor of 0.25 mm is not necessary. Using a water:binder ratio of 0.48 in RCC containing 50% fly ash and 8% HNM a durability factor of over D₃₀₀ can be achieved provided the spacing factor is less than 0.4 mm.     

Influence of class F fly ash on the abrasion–erosion resistance of high-strength concrete

This study investigates the abrasion–erosion resistance of high-strength concrete (HSC) mixtures in which cement was partially replaced by four kinds of replacements (15%, 20%, 25% and 30%) of class F fly ash. The mixtures containing ordinary Portland cement were designed to have 28 days compressive strength of approximately 40–80 MPa. Specimens were subjected to abrasion–erosion testing in accordance with ASTM C1138. Experimental results show that the abrasion–erosion resistances of fly ash concrete mixtures were improved by increasing compressive strength and decreasing the ratio of water-to-cementitious materials. The abrasion–erosion resistance of concrete with cement replacement up to 15% was comparable to that of control concrete without fly ash. Beyond 15% cement replacement, fly ash concrete showed lower resistance to abrasion–erosion compared to non-fly ash concrete. Equations were established based on effective compressive strengths and effective water-to-cementitious materials ratios, which were modified by cement replacement and developed to predict the 28- and 91-day abrasion–erosion resistance of concretes with compressive strengths ranging from approximately 30–100 MPa. The calculation results are compared favorably with the experimental results.     

Hybrid fiber reinforced self-compacting concrete with a high-volume coarse fly ash

This paper presents a study on the fresh and mechanical properties of a fiber reinforced self-compacting concrete incorporating high-volume fly ash that does not meet the fineness requirements of ASTM C 618. A polycarboxylic-based superplasticizer was used in combination with a viscosity modifying admixture. In mixtures containing fly ash, 50% of cement by weight was replaced with fly ash. Two different types of steel fibers were used in combination, keeping the total fiber content constant at 60 kg/m³. Slump flow time and diameter, V-funnel, and air content were performed to assess the fresh properties of the concrete. Compressive strength, splitting tensile strength, and ultrasonic pulse velocity of the concrete were determined for the hardened properties. The results indicated that high-volume coarse fly ash can be used to produce fiber reinforced self-compacting concrete, even though there is some reduction in the concrete strength because of the use of high-volume coarse fly ash.     

Influence of fly ash on strength and sorption characteristics of cold-bonded fly ash aggregate concrete

Cold-bonded fly ash aggregate concrete with fly ash as part of binder or fine aggregate facilitates high volume utilization of fly ash in concrete with minimum energy consumption. This paper investigates the influence of fly ash on strength and sorption behaviour of cold-bonded fly ash aggregate concrete due to partial replacement of cement and also as replacement material for sand. While cement replacement must be restricted based on the compressive strength requirement at desired age, replacement of sand with fly ash appears to be advantageous from early days onwards with higher enhancement in strength and higher utilization of fly ash in mixes of lower cement content. Microstructure of concrete was examined under BSEI mode. Replacement of sand with fly ash is effective in reducing water absorption and sorptivity attributable to the densification of both matrix and matrix–aggregate interfacial bond. Cold-bonded fly ash aggregate concrete with a cement content of 250 kg/m³, results in compressive strength of about 45 MPa, with a total inclusion of around 0.6 m³ of fly ash in unit volume of concrete.     

Permeability properties of self-compacting rubberized concretes

The paper presented herein was carried out to investigate the permeability characteristics of self-compacting rubberized concretes with and without fly ash. At a water–cementitious material (w/cm) ratio of 0.35, the self-compacting concretes (SCCs) were produced by replacing the fine aggregate with four designated crump rubber contents of 0%, 5%, 15%, and 25% by fine aggregate volume. Moreover, the SCCs with fly ash were produced by partial substitution of cement with fly ash at varying amounts of 20% to 60%. Totally, 16 concrete mixtures were cast and tested for permeability related properties such as chloride ion permeability, water sorptivity, and water absorption. The tests were conducted at 28 and 90 days after casting. Tests results revealed that using the crumb rubber aggravated all of the measured properties of self-compacting rubberized concretes (SCRCs) without fly ash. However, with the combined use of the crump rubber and fly ash, the concretes had better resistance to the chloride ion permeability, water sorptivity, and water absorption.     

Effect of mineral admixtures and curing periods on shrinkage and cracking age under restrained condition

This paper presents the test results on cracking behavior at medium age of uniaxially restrained specimens containing different types of mineral admixture, namely fly ash and limestone powder. In this study, the uniaxially restrained shrinkage, free shrinkage and strength tests were conducted to study the potential of cracking of concrete under restrained shrinkage condition. The influences of water to binder ratio, mineral admixtures and curing period of concrete on cracking behavior were investigated in this study. The investigation showed that cracking age and cracking strain of restrained specimens vary with mix proportion, mineral admixture and curing period. The potential of shrinkage cracking is not influenced only by cracking strain and amount of shrinkage but also on shrinkage rate and tensile creep. Mixture with lower water to binder ratio (w/b = 0.35) shows shorter cracking age than the mixture with higher water to binder ratio (w/b = 0.55). Fly ash and limestone powder significantly increase cracking age of concrete. The cracking age increases with the increase of the replacement ratio of fly ash. The higher shrinkage rate, when exposed to drying, of mixture with longer curing period leads to shorter cracking age.     

Influences of mixture composition on properties and freeze–thaw resistance of RCC

The paper reports a series of lab investigations carried out on roller compacted concrete (RCC) mixtures containing a wide range of cement contents (100 and 450 kg/m³). The key objectives were to appreciate the effects of variations in the cement content and air entrainment on basic physical, mechanical properties and freeze–thaw (F–T) resistances of RCC mixtures. The Vebe consistency, moisture–density relations, water absorption, permeable voids, compressive strength, and F–T resistances of comparable mixes were evaluated. Physical and mechanical properties indicated a significant deviation from the behavior shown by conventional concrete. Air entrainment was found to be affecting the strength and F/T durability of the mixes. Further analysis shows wide range applications of RCC in various pavement applications.     

Properties of self-compacting concrete mixtures containing metakaolin and blast furnace slag

Rheological, mechanical and durability properties of self-compacting concrete (SCC) mixes produced using blended binders containing metakaolin and blast furnace slag are studied. The rheological properties of SCC mix with metakaolin are characterized by significant yield stress and relatively low viscosity, while the mix with blast furnace slag shows zero yield stress and higher viscosity. The compressive strength of SCC with metakaolin grows very fast during the initial hardening period and remains significantly higher, as compared with the mix with blast furnace slag, up to 90 days. Durability properties of the mix containing metakaolin are excellent. Water absorption coefficient and water penetration depths are very low. The freeze resistance tests show zero mass loss after 56 cycles in deicing salt solution.     

Performance of self-compacting concrete containing different mineral admixtures

This paper presents experimental study on the properties of self-compacting concrete (SCC). Portland cement (PC) was replaced with fly ash (FA), granulated blast furnace slag (GBFS), limestone powder (LP), basalt powder (BP) and marble powder (MP) in various proportioning rates. The influence of mineral admixtures on the workability, compressive strength, ultrasonic pulse velocity, density and sulphate resistance of SCC was investigated. Sulphate resistance tests involved immersion in 10% magnesium sulphate and 10% sodium sulphate solutions for a period of 400 days. The degree of sulphate attack was evaluated using visual examination and reduction in compressive strength. The test results showed that among the mineral admixtures used, FA and GBFS significantly increased the workability and compressive strength of SCC mixtures. Replacing 25% of PC with FA resulted in a strength of more than 105 MPa at 400 days. Moreover, the presence of mineral admixtures had a beneficial effect on the strength loss due to sodium and magnesium sulphate attack. On the other hand, the best resistance to sodium and magnesium sulphate attacks was obtained from a combination of 40% GBFS with 60% PC.     

High-strength rice husk ash concrete incorporating quarry dust as a partial substitute for sand

Quarry dust is a by-product from the granite crushing process in quarrying activities. This paper presents the findings from experimental work undertaken to evaluate the suitability of quarry dust as a partial substitute for sand in high-strength concrete (HSC) containing rice husk ash (RHA). Two grades of HSC mixes, to achieve 60 MPa and 70 MPa at 28 days, were designed with and without the incorporation of RHA. Quarry dust was then used in the mixes containing RHA as a partial substitute for sand, in quantities ranging from 10% to 40%. The slump of the fresh concrete and the compressive strength development were monitored up to 28 days. Based on the results obtained, the mixes containing 20% quarry dust were chosen as the optimum mix design for both grades of concrete, which would then undergo further evaluation of their strength and mechanical properties up to one year. The results obtained in the next stage suggest that even though the use of quarry dust as a partial substitute for sand results in some minor negative effects in the compressive strength and other mechanical properties of concrete, these outcomes can easily be compensated by a good mix design and by the incorporation of RHA. The findings of the research assert that quarry dust can be used as a viable replacement material to sand to produce high-strength RHA concrete.     

Strength,durability, and micro-structural properties of concrete made with used-foundry sand (UFS)

This paper presents the design of concrete mixes made with used-foundry (UFS) sand as partial replacement of fine aggregates. Various mechanical properties are evaluated (compressive strength, and split-tensile strength). Durability of the concrete regarding resistance to chloride penetration, and carbonation is also evaluated. Test results indicate that industrial by-products can produce concrete with sufficient strength and durability to replace normal concrete. Compressive strength, and split-tensile strength, was determined at 28, 90 and 365 days along with carbonation and rapid chloride penetration resistance at 90 and 365 days. Comparative strength development of foundry sand mixes in relation to the control mix i.e. mix without foundry sand was observed. The maximum carbonation depth in natural environment, for mixes containing foundry sand never exceeded 2.5 mm at 90 days and 5 mm at 365 days. The RCPT values, as per ASTM C 1202-97, were less than 750 coulombs at 90 days and 500 coulombs at 365 days which comes under very low category. Thereby, indicating effective use of foundry sand as an alternate material, as partial replacement of fine aggregates in concrete. Micro-structural investigations of control mix and mixes with various percentages of foundry sand were also performed using XRD and SEM techniques. The micro-structural investigations shed some light on the nature of variation in strength at the different replacements of fine aggregates with foundry sand, in concrete.     

Properties of fly ash concrete modified with hydrated lime and silica fume

This paper presents the results of an experimental investigation on the properties of fly ash concrete incorporating either hydrated lime or silica fume to improve the early strength of concrete. Test results indicated that the addition of lime and silica fume improved the early age compressive strength of fly ash concrete. The inclusion of silica fume was also found to increase the 28 days strength significantly. The air permeability of concrete containing lime and silica fume either decreased or remained almost the same when compared to the concrete without these. The addition of lime and silica fume also improved the sorptivity of concrete.Through the use of differential scanning calorimetry and thermogravimetric analysis (DSC/TG), it was demonstrated that the addition of hydrated lime increased the Ca(OH)₂ content; whereas the addition of silica fume decreased the Ca(OH)₂ content in the cement paste. The mercury intrusion porosimetry (MIP) data confirmed the beneficial action of hydrated lime and silica fume, towards decreasing the total pore volume of fly ash cement paste.     

Properties of self-compacting concretes made with binary,ternary, and quaternary cementitious blends of fly ash,blast furnace slag,and silica fume

Self-compacting concretes (SCCs) have brought a promising insight into the concrete industry to provide environmental impact and cost reduction. However, the use of ternary and especially quaternary cementitious blends of mineral admixtures have not found sufficient applications in the production of SCCs. For this purpose, an experimental study was conducted to investigate properties of SCCs with mineral admixtures. Moreover, durability based multi-objective optimization of the mixtures were performed to achieve an optimal concrete mixture proportioning. A total of 22 concrete mixtures were designed having a constant water/binder ratio of 0.44 and a total binder content of 450 kg/m³. The control mixture included only a Portland cement (PC) as the binder while the remaining mixtures incorporated binary, ternary, and quaternary cementitious blends of PC, fly ash (FA), ground granulated blast furnace slag (S), and silica fume (SF). Fresh properties of the SCCs were tested for slump flow diameter, slump flow time, L-box height ratio, and V-funnel flow time. Furthermore, the hardened properties of the concretes were tested for sorptivity, water permeability, chloride permeability, electrical resistivity, drying shrinkage, compressive strength, and ultrasonic pulse velocity. The results indicated that when the durability properties of the concretes were taken into account, the ternary use of S and SF provided the best performance.     

Mechanical and durability properties of concrete made with dredged marine sand

The process of depletion of sources of natural aggregates challenges the production of technically and environmentally adequate concrete. Alternative material from marine sources, especially for concrete maritime structures, could represent an acceptable solution for this problem and it might also be of great interest for port management. This research work describes the study of the mechanical and durability properties of concretes fabricated with dredged marine sand (DMS) as a fine granular corrector in partial substitution of raw sand (from 15% to up to 50% by raw sand mass) designed for harbor pavements. Three DMS samples were extracted from the Port of Barcelona. The material was stockpiled in the open air and no washing, drying or decontamination process was carried out. Mineralogical, physical and chemical properties of DMS material were determined. Eight different mixtures were produced incorporating three types of DMS material as granular corrector in partial substitution of crushed limestone raw sand. The concretes were submitted to compressive strength tests after 7 and 28 days of moist curing, as well as density, absorption, accessible pores, elastic modulus, tensile and splitting tensile strength, abrasion, capillary suction, water penetration under pressure and ultrasonic pulse velocity (UPV) tests, all of them after 28 days of moist curing. This study shows that dredged marine sand can be successfully used as a fine aggregate for concrete production. This is justified by the similar physical and mechanical properties of concrete made with DMS comparing to reference concrete. It was verified that the use of DMS in substitution of raw sand maintained or reduced the accessible pores, the sorptivity and the water penetration depth under pressure.     

Long term performance of chloride binding capacity in fly ash concrete in a marine environment

The capacity of binding chloride ions in fly ash concrete under marine exposure was studied. The free and total chloride contents in concrete were determined by water and acid-soluble methods, respectively. In order to study the effects of W/B ratios, exposure time, and fly ash contents on chloride binding capacity of concrete in a marine site, a class F fly ash was used as a partial replacement of Portland cement type I at 0%, 15%, 25%, 35%, and 50% by weight of binder. Water to binder ratios (W/B) were varied at 0.45, 0.55, and 0.65. Concrete cube specimens of 200 mm were cast and placed into the tidal zone of a marine environment in the Gulf of Thailand. Consequently, acid-soluble and water-soluble chlorides in the concrete were measured after the concrete was exposed to the tidal zone for 3, 4, 5, and 7 years. It was found that the percentage of chloride binding capacity compared to total chloride content increased with the increase of fly ash in the concrete. The percentage of chloride binding capacity significantly decreased within 3–4 years after the concrete was exposed to the marine environment, and then its value was almost constant. The research also showed that the W/B ratio does not noticeably affect the chloride binding capacity of concrete.