Study on early-age cracking of cement-based materials with superplasticizers

The addition of superplasticizers is an important approach to prepare high performance cement-based materials. The effect of polynaphthalene series superplasticizer (PNS) and polycarboxylate type superplasticizer (PC) on early-age cracking and volume stability of cement-based materials was investigated by means of multi-channel ellipse ring shrinkage cracking test, free shrinkage and strength test. The general effect of PNS and PC is to increase initial cracking time of mortars, and decrease cracking sensitivity of mortars. As for decreasing cracking sensitivity of mortars, PC > H-UNF (high-thickness-type PNS) > C-UNF (common-thickness-type PNS). To incorporate superplasticizers is apparently to increases free shrinkage of mortars when keeping the constant W/B ratio and the content of cement pastes. As for the effect of controlling volume stability of mortars, PC > C-UNF > H-UNF. Maximum crack width of mortars with PC is lower, but the development rate of maximum crack width of mortars with H-UNF is faster in comparison with control mortars. Flexural and compressive strength of mortars and concretes at 28 days increased with increasing superplasticizer dosages under drying conditions. C-UNF was approximate to H-UNF, but PC was superior to PNS in the aspect of increasing strength of cement-based materials.     

Performance of self-compacting concrete containing different mineral admixtures

This paper presents experimental study on the properties of self-compacting concrete (SCC). Portland cement (PC) was replaced with fly ash (FA), granulated blast furnace slag (GBFS), limestone powder (LP), basalt powder (BP) and marble powder (MP) in various proportioning rates. The influence of mineral admixtures on the workability, compressive strength, ultrasonic pulse velocity, density and sulphate resistance of SCC was investigated. Sulphate resistance tests involved immersion in 10% magnesium sulphate and 10% sodium sulphate solutions for a period of 400 days. The degree of sulphate attack was evaluated using visual examination and reduction in compressive strength. The test results showed that among the mineral admixtures used, FA and GBFS significantly increased the workability and compressive strength of SCC mixtures. Replacing 25% of PC with FA resulted in a strength of more than 105 MPa at 400 days. Moreover, the presence of mineral admixtures had a beneficial effect on the strength loss due to sodium and magnesium sulphate attack. On the other hand, the best resistance to sodium and magnesium sulphate attacks was obtained from a combination of 40% GBFS with 60% PC.     

Filler effect and pozzolanic reaction of ground palm oil fuel ash

This research examines the compressive strength of mortar and how the filler effect and pozzolanic reaction of ground palm oil fuel ash (POFA) contribute to this strength. POFA and river sand were ground to three different particle sizes and used to replace Type I Portland cement at 10–40% by weight of binder to cast the mortar. The compressive strengths of ground POFA and ground river sand mortars were determined at various ages between 7 and 90 days. The results showed that the compressive strength of mortar due to the filler effect of ground river sand was nearly constant during the 7–90 day period for a specified replacement rate of cement. However, the compressive strength of mortar due to the filler effect tended to increase slightly with increased cement replacement. The pozzolanic reaction of ground POFA increased with increasing particle fineness of ground POFA, replacement rate of cement, and age of the mortar. The compressive strength contribution from the pozzolanic reaction of ground POFA was much more pronounced than the contribution from the filler effect when the smallest sizes of both materials were considered.     

Compressive strength and shrinkage of mortar containing various amounts of mineral additions

Three mineral additions largely used in cementitious materials were tested in order to follow the shrinkage behaviour for 1 year of observation when they substitute a part of cement. The tests were carried out on standardized mortars specimen where cement was replaced by 5%, 15% and 25% of limestone, 10%, 20%, 30% of natural pozzolan and 10%, 30% and 50% of slag. The substitution of cement by 10%, 20% and 30% of limestone powder, natural pozzolan and slag respectively involves an optimal improvement of compressive strength of mortar. The separate quantification of the autogeneous and drying shrinkage development shows the effective contribution of each addition on microstructure modification and of the additional hydrates production. The microstructure was improved in the presence of limestone and of a moderate rate of slag, whereas it remains normal with natural pozzolan. The replacement rate of an active addition lower than 10% led to an additional hydrates production. This overproduction which accompanies the autogeneous shrinkage is more pronounced when cement is largely replaced by limestone. The evolutions of strength and shrinkage of mortars follow the same tendency from where it is easier to find a linear relationship giving the shrinkage deformation according to the compressive strength.     

Influence of activator on the strength and drying shrinkage of alkali-activated slag mortar

The development of new binders, as an alternative to traditional cement, by the alkaline activation of industrial by-products (i.e. ground granulated slag and fly ash) is an ongoing research topic in the scientific community [Puertas F, Amat T, Jimenez AF, Vazquez T. Mechanical and durable behaviour of alkaline cement mortars reinforced with polypropylene fibres. Cem Concr Res 2003;33(12): 2031–6]. The aim of this study was to investigate the feasibility of using and alkaline activated ground Turkish slag to produce a mortar without Portland cement (PC).Following the characterization of the slag, mortar specimens made with alkali-activated slag were prepared. Three different activators were used: liquid sodium silicate (LSS), sodium hydroxide (SH) and sodium carbonate (SC) at different sodium concentrations. Compressive and flexural tensile strength of alkali-activated slag mortar was measured at 7-days, 28-days and 3-months. Drying shrinkage of the mortar was measured up to 6-months. Setting times of the alkali-activated slag paste and PC paste were also measured.Setting times of LSS and SH activated slag pastes were found to be much slower than the setting time of PC paste. However, slag paste activated with SC showed similar setting properties to PC paste.LSS, SH and SC activated slag mortar developed 81, 29, and 36 MPa maximum compressive strengths, and 6.8, 3.8, and 5.3 MPa maximum flexural tensile strengths at 28-days. PC mortar developed 33 MPa compressive strength and 5.2 MPa flexural tensile strength. LSS and SH activated slag mortars were found to be more brittle than SC activated slag and PC mortars.Slag mortar made with LSS had a high drying shrinkage, up to six times that of PC mortar. Similarly, slag mortar made with SH had a shrinkage up to three times that of PC mortar. However, SC activated slag mortar had a lower or comparable shrinkage to PC mortar. Therefore, the use of SC as an activator for slag mortar is recommended, since it results in adequate strength, similar setting times to PC mortar and comparable or lower shrinkage.     

Influence of mineral additions on the performance of 100% recycled aggregate concrete

A judicious use of resources, by using by-products and waste materials, and a lower environmental impact, by reducing carbon dioxide emission and virgin aggregate extraction, allow to approach sustainable building development. Recycled aggregate concrete (RAC) containing supplementary cementitious materials (SCM), if satisfactory concrete properties are achieved, can be an example of such sustainable construction materials.In this work concrete specimens were manufactured by completely replacing fine and coarse aggregates with recycled aggregates from a rubble recycling plant. Also RAC with fly ash (RA + FA) or silica fume (RA + SF) were studied.Concrete properties were evaluated by means of compressive strength and modulus of elasticity in the first experimental part. In the second experimental part, compressive and tensile splitting strength, dynamic modulus of elasticity, drying shrinkage, reinforcing bond strength, carbonation, chloride penetration were studied. Satisfactory concrete properties can be developed with recycled fine and coarse aggregates with proper selection and proportioning of the concrete materials.     

Effect of fly ash addition on the mechanical properties of tile adhesive

Statistical relationship between various strengths of tile adhesives in which cement or sand was partially replaced with fly ash was studied. A low-lime fly ash was used in five different replacement levels from 5% to 30% by weight of either cement or sand. The tensile adhesion, flexural and compressive strengths of adhesives were determined at 2, 7 and 28 days. In small substitution levels, sand replacement increased the tensile adhesion strength. No strong relationship was found between tensile adhesion strength and flexural or compressive strength of the specimens in which the fly ash was used as sand replacement (r < 0.659). Strong relationship was observed between the same properties when fly ash was used as cement replacement (r > 0.896). Flexural and compressive strength values showed quite strong relationship (r > 0.949). This may be due to the fact that both of these strength values were obtained on the same specimens.     

Effects of curing regimes and cement fineness on the compressive strength of ordinary Portland cement mortars

Curing techniques and curing duration have crucial effects on the strength and other mechanical properties of mortars. Proper curing can protect against moisture loss from fresh mixes. The objective of this experimental work is to examine the compressive strength of ordinary Portland cement mortars (OMs) under various curing regimes and cement fineness. Six different curing methods including water, air, water heated, oven heated, air–water, and water–air were applied to the specimens and also six groups of mortars were used. The results showed that the highest and lowest compressive strengths are attributed to the specimens of OPC mortar water cured using grounded OPC for duration of 6 h (OM–G6–wc) and OPC mortar air cured under room temperature with oven heated after demoulding of the specimens at 60 °C for duration of 20 h (OM–OH–ac), respectively. The maximum levels obtained of compressive strengths at 7, 28, and 90 days are 57.5, 70.3, and 76.0 MPa, respectively.     

Influence of fine tailings on polyester mortar properties

The purpose of this study is to examine the basic properties of polyester mortars using a fine tailings (FT) from an abandoned mine as a filler. FT with sizes of 10–69 μm is obtained through the centrifugal separation of tailing (TA), and tested for such basic properties, as particle shape, fineness of size distribution, liquid resin absorption, and heavy metal leaching. Polyester mortars with FT and ground calcium carbonate (GC) are prepared with various filler-(filler + binder) ratios and replacements of GC with FT, and tested for working life, flexural and compressive strengths, and chemical corrosion resistance. As a result, FT has almost the same properties as GC in terms of particle shape, fineness of size and liquid resin absorption. The working life of polyester mortars is prolonged with an increased filler-(filler + binder) ratio and replacement of GC with FT. From the vantagepoint of the strength development of the polyester mortars with FT, it is recommended that the filler-(filler + binder) ratio and replacement of GC with FT should be controlled at 50% or less. Mass and strength changes are generally lower in mortars containing FT than in those containing GC in all chemical solutions.     

Characteristics of mortar and concrete containing fine aggregate manufactured from recycled waste polyethylene terephthalate bottles

This paper presents the development of lightweight aggregate concrete using fine aggregate that is manufactured from recycled waste polyethylene terephthalate (PET) bottles. Investigations on waste PET lightweight aggregate concrete included three phases: examination of the properties of waste PET lightweight aggregates (WPLA), analysis of the properties of mortar when WPLA was used as fine aggregate, and analysis of the properties of concrete when WPLA was used as fine aggregate. The results of the first phase showed that the WPLA had a density of 1390 kg/m³, a water absorption of 0% and a bulk density of 844 kg/m³. WPLA fineness modulus (F.M.), however, was 4.11, which is higher than the F.M. of river sand. This is because the WPLA was single graded. The results of the second phase showed that for the mortar, in which the WPLA was used as a fine aggregate, the flow value increased, while the compressive strength decreased proportionally to the addition of WPLA with elapsed time. In addition, the amount of water absorption by unit area was higher than for the control mortar (without WPLA) when the WPLA content was either 40% or 60%. For the third phase, the results showed that the slump of the WPLA concrete increased as the WPLA content increased regardless of the water-cement ratio (W/C). In comparison to the control concrete, the 28-day WPLA concrete compressive strength decreased by 5%, 15% and 30%, with an increase of WPLA content of 25%, 50% and 75%, respectively. In addition, for a W/C of 0.49, the structural efficiency (compressive strength/density ratio) of the concrete containing 25% of WPLA was higher than that for the control concrete.     

Properties of cement mortars containing clinoptilolite as a supplementary cementitious material

This paper presents a study of the properties and behavior of cement mortar with clinoptilolite which is one of the most common zeolite minerals found in nature. Six mortar mixtures were prepared by replacing the Portland cement with 0%, 5%, 10%, 15%, 20% and 30% clinoptilolite by weight. Test results showed that water demand, soundness and setting times of the cement pastes increased with the increase of clinoptilolite content. Compressive and flexural strength of the mortars containing clinoptilolite were higher than the control mixture. Dry unit weight of the mortars with clinoptilolite was lower than the control mortar. Clinoptilolite replacement decreased water absorption and porosity of the mortars. The control mortar showed less durability to carbonation compared to the mortars made with clinoptilolite at the end of carbonation tests. Freeze–thaw resistance of the mortars containing 5% clinoptilolite was higher than control mortar. The effect of clinoptilolite incorporation on high-temperature resistance seemed to be dependent on amount of clinoptilolite, temperature level, and the cooling method.     

Effect of mineral admixtures and curing periods on shrinkage and cracking age under restrained condition

This paper presents the test results on cracking behavior at medium age of uniaxially restrained specimens containing different types of mineral admixture, namely fly ash and limestone powder. In this study, the uniaxially restrained shrinkage, free shrinkage and strength tests were conducted to study the potential of cracking of concrete under restrained shrinkage condition. The influences of water to binder ratio, mineral admixtures and curing period of concrete on cracking behavior were investigated in this study. The investigation showed that cracking age and cracking strain of restrained specimens vary with mix proportion, mineral admixture and curing period. The potential of shrinkage cracking is not influenced only by cracking strain and amount of shrinkage but also on shrinkage rate and tensile creep. Mixture with lower water to binder ratio (w/b = 0.35) shows shorter cracking age than the mixture with higher water to binder ratio (w/b = 0.55). Fly ash and limestone powder significantly increase cracking age of concrete. The cracking age increases with the increase of the replacement ratio of fly ash. The higher shrinkage rate, when exposed to drying, of mixture with longer curing period leads to shorter cracking age.     

Strength and drying shrinkage properties of concrete containing furnace bottom ash as fine aggregate

The strength and drying shrinkage of concretes with the natural sand replaced with furnace bottom ash (FBA) at 0%, 30%, 50%, 70% and 100% by mass, were studied at fixed water–cement ratios (W/C) and fixed slump ranges.The results showed that, at fixed water–cement ratios, the compressive strength and the drying shrinkage decreased with the increase of the FBA sand content. However, at fixed workability, the compressive strength was comparable with that of the control concrete, while the drying shrinkage increased with the increase of the FBA sand content beyond 30% replacement level. Nevertheless, 30% of the natural sand can be beneficially replaced with the FBA sand to produce concrete in the compressive strength range from 40 to 60 N/mm² without detrimentally affecting drying shrinkage properties of the concrete.     

Mortars with nano-SiO2 and micro-SiO2 investigated by experimental design

This paper reports the effects of nanosilica (nS) and silica fume (SF) on rheology, spread on flow table, compressive strength, water absorption, apparent porosity, unrestrained shrinkage and weight loss of mortars up to 28 days. Samples with nS (0–7 wt.%), SF (0–20 wt.%) and water/binder ratio (0.35–0.59), were investigated through factorial design experiments. Nanosilica with 7 wt.% showed a faster formation of structures during the rheological measurements. The structure formation influences more yield stress than plastic viscosity and the yield stress relates well with the spread on table. Compressive strength, water absorption and apparent porosity showed a lack of fit of second order of the model for the range interval studied. In addition, the variation of the unrestrained shrinkage and weight loss of mortars do not follow a linear regression model. The maximum unrestrained shrinkage increased 80% for nS mortars (7 days) and 54% (28 days) when compared to SF mortars in the same periods.     

Freeze–thaw resistance of blended cements containing calcined paper sludge

This work deals with the frost resistance of blended cements containing calcined paper sludge (source for metakaolin) as partial Portland cement replacements. Freeze–thaw tests were performed on blended cement mortars containing 0%, 10% and 20% waste paper sludge calcined at 650 °C for 2 h. Cement mortar specimens were exposed to freezing and thawing cycles until the relative dynamic modulus of elasticity fell below 60%. The performance of the cement mortars was assessed from measurements of weight, ultrasonic pulse velocity, compressive strength, mercury intrusion porosimetry and SEM. Failure of the control cement mortar occurred before 40 freeze/thaw cycles, while cement mortar containing 20% calcined paper sludge failed after 100 cycles. After 28 and 62 freezing and thawing cycles, cement blended with 10% and 20% calcined paper sludge exhibited a smaller reduction in compressive strength than the control cement.     

The effect of high temperature curing on the strength and carbonation of pozzolanic structural lightweight concretes

An experimental study on the compressive strength and carbonation depth of lightweight concrete mixes that contain pulverized fuel ash (PFA) and silica fume (SF) as cement replacements is presented in this paper. Mixes that had a relatively high replacement level of PFA at 25, 40, and 55% and of SF at 5, 10, and 15% by weight were compared. The results indicated that accelerated curing at 60 °C for 3 days improved the 28-day compressive strength of the PFA- and SF-incorporated mixes but resulted in higher carbonation of the mixes compared with that under normal temperature curing. Mixes that had 25% PFA or 5–10% SF as partial cement replacements had slightly higher strength under accelerated curing and slightly lower strength under normal curing than the control mix. At higher replacement levels of PFA and SF, further lower strength and higher carbonation was observed.     

Metakaolin concrete at a low water to binder ratio

This paper investigates the performance of concrete containing metakaolin (MK) at a low water to binder ratio of 0.3. Portland cement (PC) was partially replaced with 0–20% MK. Testing included, compressive strength, ultrasonic pulse velocity (V), dynamic modulus of elasticity (E_d) and length change. Specimens were either cured in water or in air at 20 °C. The results indicate that the performance of MK concrete at low water to binder ratio is not different from that at higher water to binder ratios reported in a previous investigation. The maximum contribution of MK to strength occurs at 14 days of curing in that the relative strength of MK concrete shows a maximum value at that curing time as found in a previous investigation. The optimum replacement level of cement with MK is about 15%. Linear relationship exists between V and E_d for air cured and water cured specimens. A systematic increase in MK content of up to at least 20% leads to a decrease in shrinkage and an increase in expansion after 56 days of curing. Correlation between the various properties is also conducted.     

Use of palm oil fuel ash as a supplementary cementitious material for producing high-strength concrete

The objective of this study is to investigate the use of ground palm oil fuel ash with high fineness (GPA) as a pozzolanic material to produce high-strength concrete. Samples were made by replacing Type I Portland cement with various proportions of GPA. Properties such as the compressive strength, drying shrinkage, water permeability, and sulfate resistance, were then investigated. After aging for 28 days, the compressive strengths of these concrete samples were found to be in the range of 59.5–64.3 MPa. At 90-day the compressive strength of concrete containing GPA 20% was as high as 70 MPa. The drying shrinkage and water permeability were lower than those of high-strength concrete made from Type I Portland cement. When the concrete samples were immersed in a 10% MgSO₄ solution for 180 days, the sulfate resistance in terms of the expansion and loss of compressive strength was improved. The results indicated that GPA is a reactive pozzolanic material and can be used as a supplementary cementitious material for producing high-strength concrete.     

Influence of fly ash on strength and sorption characteristics of cold-bonded fly ash aggregate concrete

Cold-bonded fly ash aggregate concrete with fly ash as part of binder or fine aggregate facilitates high volume utilization of fly ash in concrete with minimum energy consumption. This paper investigates the influence of fly ash on strength and sorption behaviour of cold-bonded fly ash aggregate concrete due to partial replacement of cement and also as replacement material for sand. While cement replacement must be restricted based on the compressive strength requirement at desired age, replacement of sand with fly ash appears to be advantageous from early days onwards with higher enhancement in strength and higher utilization of fly ash in mixes of lower cement content. Microstructure of concrete was examined under BSEI mode. Replacement of sand with fly ash is effective in reducing water absorption and sorptivity attributable to the densification of both matrix and matrix–aggregate interfacial bond. Cold-bonded fly ash aggregate concrete with a cement content of 250 kg/m³, results in compressive strength of about 45 MPa, with a total inclusion of around 0.6 m³ of fly ash in unit volume of concrete.     

Effects of LOI of ground bagasse ash on the compressive strength and sulfate resistance of mortars

Raw bagasse ash collected from the Thai sugar industry has a high loss on ignition (LOI) of ～20%. When ground and ignited at 550 °C for 45 min, the LOI was reduced to ～5%. These high and low LOI of ground bagasse ashes were blended in the ratios of 1:2 and 2:1 by weight to give ground bagasse ashes with LOIs of 10% and 15%, respectively. Each of these ground bagasse ashes was used to replace Portland cement type I at 10%, 20%, 30%, and 40% by weight of binder to cast mortar.The results showed that the development of compressive strengths of mortars containing ground bagasse ash with high LOI was slower than that of mortar containing ground bagasse ash with low LOI. However, at the later age, both types of ground ash mortars displayed similar compressive strengths. Mortars containing high LOI (～20%) of ground bagasse ash at 20% and 30% by weight of binder could produce higher compressive strengths than a control mortar after 28 and 90 days, respectively. Mortar bars containing ground bagasse ash at 10% showed a greater potential sulfate resistance and displayed a reduce expansion compared to a control mortar. However, mortar bars containing high LOI (larger than 10%) of ground bagasse ashes showed greater deterioration from sulfate attack than the mortar bars containing low LOI (less than 10%) of ground bagasse ashes, especially at high replacement levels (30–40%).