Analysis and performance assessment of a combined geothermal power-based hydrogen production and liquefaction system

In this paper, the thermodynamic study of a combined geothermal power-based hydrogen generation and liquefaction system is investigated for performance assessment. Because hydrogen is the energy of future, the purpose of this study is to produce hydrogen in a clear way. The results of study can be helpful for decision makers in terms of the integrated system efficiency. The presented integrated hydrogen production and liquefaction system consists of a combined geothermal power system, a PEM electrolyzer, and a hydrogen liquefaction and storage system. The exergy destruction rates, exergy destruction ratios and exergetic performance values of presented integrated system and its subsystems are determined by using the balance equations for mass, energy, entropy, energy and exergy and evaluated their performances by means of energetic and exergetic efficiencies. In this regard, the impact of some design parameters and operating conditions on the hydrogen production and liquefaction and its exergy destruction rates and exergetic performances are investigated parametrically. According to these parametric analysis results, the most influential parameter affecting system exergy efficiency is found to be geothermal source temperature in such a way that as geothermal fluid temperature increases from 130 °C to 200 °C which results in an increase of exergy efficiency from 38% to 64%. Results also show that, PEM electrolyzer temperature is more effective than reference temperature. As PEM electrolyzer temperature increases from 60 °C to 85 °C, the hydrogen production efficiency increases from nearly 39% to 44%.     

Exergy modeling of a new solar driven trigeneration system

In this paper, exergy modeling is used to assess the exergetic performance of a novel trigeneration system using parabolic trough solar collectors (PTSC) and an organic Rankine cycle (ORC). Four cases are considered: electrical-power, cooling-cogeneration, heating-cogeneration, and trigeneration. In this trigeneration system a single-effect absorption chiller is utilized to provide the necessary cooling energy and a heat exchanger is utilized to provide the necessary heating energy. The trigeneration system considered is examined using three modes of operation. They are: solar mode during the low-solar radiation time of the day, solar and storage mode during the high-solar radiation time of the day, and storage mode during night time. The storage mode is operated through the heat collected in a thermal storage tank during the solar and storage mode. The exergy efficiencies and exergy destruction rates are examined under the variation of the ORC evaporator pinch point temperature, ORC pump inlet temperature, and turbine inlet pressure. This study reveals that the maximum electrical-exergy efficiency for the solar mode is 7%, for the solar and storage mode is 3.5%, and for the storage mode is 3%. Alternatively, when trigeneration is used, the exergy efficiency increases noticeably. The maximum trigeneration-exergy efficiency for the solar mode is 20%, for solar and storage mode is 8%, and for the storage mode is 7%. Moreover, this study shows that the main sources of exergy destruction rate are the solar collectors and ORC evaporators. Therefore, careful selection and design of these two components are essential to reduce the exergy destructed by them and, thus, increase the exergy efficiencies of the system.     

Exergetic analysis of a double stage LiBr–H2O thermal compressor cooled by air/water and driven by low grade heat

In the present paper, an exergetic analysis of a double stage thermal compressor using the lithium bromide–water solution is performed. The double stage system considered allows obtaining evaporation temperatures equal to 5 °C using solar heat coming from flat plate collectors and other low grade thermal sources. In this study, ambient air and water are alternatively used as cooling fluids without crystallization problems up to condensation–absorption temperatures equal to 50 °C. The results obtained give the entropy generated, the exergy destroyed and the exergetic efficiency of the double stage thermal compressor as a function of the absorption temperature. The conclusions obtained show that the irreversibilities generated by the double stage thermal compressor will tend to increase with the absorption temperature up to 45 °C. The maximum value corresponds to 1.35 kJ kg⁻¹ K⁻¹. The entropy generated and the exergy destroyed by the air cooled system are higher than those by the water cooled one. The difference between the values increases when the absorption temperature increases. For an absorption temperature equal to 50 °C, the air cooled mode generates 14% more entropy and destroys 14% more exergy than the water cooled one. Also, the results are compared with those of previous studies for single and double effect air cooled and water cooled thermal compressors. The conclusions show that the double stage system has about 22% less exergetic efficiency than the single effect one and 32% less exergetic efficiency than the double effect one.     

Thermodynamic performance assessment of ocean thermal energy conversion based hydrogen production and liquefaction process

In the proposed study, the thermodynamic performance assessment of ocean thermal energy conversion (OTEC) based hydrogen generation and liquefaction system are evaluated. In this context, the energetic and exergetic analyses of integrated system are conducted for multigeneration. This integrated process is consisted of the heat exchangers, turbine, condenser, pumps, solar collector system, hot storage tank, cold storage tank and proton exchange membrane (PEM) electrolyzer. In addition to that, the impacts of different design indicators and reference ambient parameters on the exergetic performance and exergy destruction rate of OTEC based hydrogen production system are analyzed. The energetic and exergetic efficiencies of integrated system are founded as 43.49% and 36.49%, respectively.     

Comparison of energy and exergy efficiencies of an underground solar thermal storage system

In this experimental study, solar energy was stored daily using the volcanic material with the sensible heat technique. The external heat collection unit consisted of 27 m² of south‐facing solar air collectors mounted at a 55° tilt angle. The dimensions of the packed‐bed heat storage unit were 6 × 2 × 0.6 m deep. The packed‐bed heat storage unit was built under the soil. The heat storage unit was filled with 6480 kg of volcanic material. Energy and exergy analyses were applied in order to evaluate the system efficiency. During the charging periods, the average daily rates of thermal energy and exergy stored in the heat storage unit were 1242 and 36.33 W, respectively. Since the rate of exergy depends on the temperature of the heat transfer fluid and surrounding, the rate of exergy increased as the difference between the inlet and outlet temperatures of the heat transfer fluid increased during the charging periods. It was found that the average daily net energy and exergy efficiencies in the charging periods were 39.7 and 2.03%, respectively. The average daily net energy efficiency of the heat storage system remained nearly constant during the charging periods. The maximum energy and exergy efficiencies of the heat storage system were 52.9 and 4.9%, respectively. Copyright © 2004 John Wiley & Sons, Ltd.     

Exergetic optimization for solar heat receiver with heat loss and viscous dissipation

The exergetic efficiency of heat receiver in solar thermal power system is optimized by considering the heat loss outside the receiver and fluid viscous dissipation inside the receiver. The physical models of heat loss and pumping power consumption for solar heat receiver are first proposed, and associated exergetic efficiency is further induced. As the flow velocity rises, the pumping power consumption and heat absorption efficiency significantly rises, and the maximum absorption efficiency and optimal incident energy flux also increase. Along the flow direction of solar receiver, the exergy flux increment and the flow exergy loss almost linearly increase, while the exergetic efficiency varies very slowly at high flow velocity. According to the exergetic efficiency loss from flow viscou’s dissipation, the exergetic efficiency of solar heat receiver will first increase and then decrease with the flow velocity. Because of the coupling effects of heat absorption efficiency and exergetic efficiency from fluid internal energy, the exergetic efficiency of solar heat receiver will approach to the maximum at proper inlet temperature. As a result, the exergetic efficiency of solar heat receiver will reach the maximum at optimal inlet temperature, incident energy flux and flow velocity.     

Energy and exergy analyses of a solar based hydrogen production and compression system

In this study, a solar thermal based integrated system with a supercritical-CO₂ (sCO₂) gas turbine (GT) cycle, a four-step Mg–Cl cycle and a five-stage hydrogen compression plant is developed, proposed for applications and analyzed thermodynamically. The solar data for the considered solar plant are taken for Greater Toronto Area (GTA) by considering both daily and yearly data. A molten salt storage is considered for the system in order to work without interruption when the sun is out. The power and heat from the solar and sCO₂-GT subsystems are introduced to the Mg–Cl cycle to produce hydrogen at four consecutive steps. After the internal heat recovery is accomplished, the heating process at required temperature level is supplied by the heat exchanger of the solar plant. The hydrogen produced from the Mg–Cl cycle is compressed up to 700 bar by using a five-stage compression with intercooling and required compression power is compensated by the sCO₂-GT cycle. The total energy and exergy inputs to the integrated system are found to be 1535 MW and 1454 MW, respectively, for a 1 kmol/s hydrogen producing plant. Both energy and exergy efficiencies of the overall system are calculated as 16.31% and 17.6%, respectively. When the energy and exergy loads of the receiver are taken into account as the main inputs, energy and exergy efficiencies become 25.1%, and 39.8%, respectively. The total exergy destruction within the system is found to be 1265 MW where the solar field contains almost 64% of the total irreversibility with a value of ～811 MW.     

Energy and exergy analyses of an ice-on-coil thermal energy storage system

In this study, energy and exergy analyses are carried out for the charging period of an ice-on-coil thermal energy storage system. The present model is developed using a thermal resistance network technique. First, the time-dependent variations of the predicted total stored energy, mass of ice, and outlet temperature of the heat transfer fluid from a storage tank are compared with the experimental data. Afterward, performance of an ice-on-coil type latent heat thermal energy storage system is investigated for several working and design parameters. The results of a comparative study are presented in terms of the variations of the heat transfer rate, total stored energy, dimensionless energetic/exergetic effectiveness and energy/exergy efficiency. The results indicate that working and design parameters of the ice-on-coil thermal storage tank should be determined by considering both energetic and exergetic behavior of the system. For the current parameters, storage capacity and energy efficiency of the system increases with decreasing the inlet temperature of the heat transfer fluid and increasing the length of the tube. Besides, the exergy efficiency increases with increasing the inlet temperature of the heat transfer fluid and increasing the length of the tube.     

盐梯度太阳池Kalina循环发电系统性能研究

Kalina循环发电系统是一种典型的低温热源发电系统,具有广阔的应用前景。盐梯度太阳池能够实现连续聚热和跨季节蓄热,可广泛应用于光热发电系统和光热供热系统。文章提出了一种以太阳池储热量为热源的盐梯度太阳池Kalina循环发电系统,并利用Aspen Hysys软件对该系统进行建模。而后根据模拟结果,研究了提热温度、运行压力和氨水浓度对该系统各项性能的影响。此外,还分析了典型工况下,该系统的热力性能。分析结果表明:随着提热温度逐渐升高,盐梯度太阳池Kalina循环发电系统的发电功率、热效率和效率均逐渐增加;随着运行压力逐渐升高,该系统的热效率和效率逐渐升高,并且存在最佳的运行压力1.75 MPa,使得该系统获得最大发电功率;随着氨水浓度逐渐增大,该系统的发电功率也会逐渐增大,但热效率和效率却逐渐降低;当氨水浓度为85%、运行压力为1.75 MPa、提热温度为90℃时,该系统的热效率和效率分别为7.93%,57.59%。     

Development and performance assessment of a novel solar-assisted multigenerational system using high temperature phase change material

Solar-assisted multi-generation systems are eco-friendly with exceptional thermal performance. In the present study, a novel solar-assisted multi-generational system is proposed and investigated for multiple outputs. The proposed system consists of solar tower with heliostat, combined cycle (topping is Brayton cycle, while bottoming is Rankine cycle with reheat and regeneration processes), single effect Lithium-Bromide/water absorption chiller, heat pump, water-based thermal energy storage system and an electrolyzer. The system is integrated with high temperature phase change material (PCM) based thermal storage system for the continuous system operation. The salt PCM KF-MgF₂ is selected from the literature having melting temperature of 1280 K with high density and latent heat of fusion. The storage system ensures the stable and continuous working of the system during off sun hours. The aim of the present study is to thermodynamically and exergo-environmentally investigate the performance of PCM based solar driven multi-generation system.The results of the study depict that energy efficiency of single and multi-generation system is approximately 20.93% and 51.62%, while exergy efficiency is almost 22.51% and 53.45%, respectively. Hydrogen production rate and exergetic sustainability index of the proposed system is approximately 0.00742 kg/s and 0.078, respectively. Energy efficiency of multigeneration system is approximately 15.9% and 61% higher than tri-generation and co-generation systems at concentration ratio of 1000. Exergo-environmental impact index decreases to almost 5% by increasing direct normal irradiation, while exergetic sustainability index and exergy stability factor are increased to 125% and 54.2%, accordingly. Finally, energy efficiency of the single generation and multi generation systems are optimized at 23.56% and 56.83%, respectively.     

Partitioning of MCHP‐TES system run time to incorporate transient system behaviour: a comprehensive exergy‐based analysis using simulation

By combining heat and power generation, mini‐combined and micro‐combined heat and power systems (MCHP) provide an efficient, decentralised means of power generation that can complement the composition of the electricity generation mix. Dynamic tools capable of handling transient system behaviour are required to assess MCHP efficiency beyond a mere static analysis based on steady‐state design parameters. Using a simulation of a cogeneration system, we combine exergetic definitions for different operational system states to quantify the overall system efficiency continuously over the whole period of operation. The concept of exergy allows direct comparison of different forms of energy. A sensitivity analysis was performed where we quantified the effect on MCHP overall performance under varying engine rotational speed, thermal energy storage size and fluid storage temperature in a range of MCHP simulations. We found that the exergetic quantity of natural gas used by the MCHP decreased slightly at higher engine speeds (?2% to ?4%). While the total amount of electricity generated is almost constant across the range of different engine output, more thermal exergy (up to +21%) can be recovered when the engine is operating at elevated speeds. Furthermore, selection of specific optimal thermal storage fluid temperatures can aid in improving system efficiency. Copyright © 2016 John Wiley & Sons, Ltd.     

Analysis of the exergetic performance of the reverse-side absorber-plate shallow solar pond

Results of exergetic performance analysis of three shallow solar pond (SSP) types – the CSSP, the RASSPgc, and RASSPins – are presented for the first time. The study shows that the highest irreversibilities are encountered in the components of the RASSPgc and that better exergetic performances in SSPs may be obtained by improving the surface properties: absorptivity, reflectivity, and transmissivity. Steady-state analysis also shows that exergy ‘losses’ in the SSPs due to irreversibilities in their water masses are significant and result from the direct absorption of solar radiation. Transient analysis reveals that the RASSPgc achieves the highest overall exergetic efficiency (4.37%), followed by the RASSPins (3.96%) and then the CSSP (2.87%). At the end of a 24 h operation, the exergy content of the water masses in the RASSPgc and the CSSP is negligible, whereas the water mass in the RASSPins retains 0.057 MJ of the exergy accumulated during daytime heating.     

SECOND LAW ANALYSIS OF A SOLAR THERMAL POWER SYSTEM

This communication presents second law analysis based on exergy concept for a solar thermal power system. Basic energy and exergy analysis for the system components (viz. parabolic trough collector/receiver and Rankine heat engine etc.) are carried out for evaluating the energy and exergy losses as well as exergetic efficiency for typical solar thermal power system under given operating conditions. Relevant energy flow and exergy flow diagrams are drawn to show the various thermodynamic and thermal losses. It is found that the main energy loss takes place at the condenser of the heat engine part whereas the exergy analysis shows that the collector-receiver assembly is the part where the losses are maximum. The analysis and results can be used for evaluating the component irreversibilities which can also explain the deviation between the actual efficiency and ideal efficiency of solar thermal power system.     

Application of a ground source heat pump system with PCM‐embedded radiant wall heating for buildings

This paper deals with the utilization of a renewable energy‐based integrated system with the latent heat storage option for building thermal management systems. Both energy and exergy‐based assessments of the current combined system are conducted. For this purpose, phase change material (PCM)‐embedded radiant wall heating system using solar heating and ground source heat pump (GSHP) is studied thermodynamically. Heat is essentially stored within the PCMs as used in the panels to increase the effectiveness. The stored heat is released when the solar energy is not available. In the thermal energy storage analyses, four different PCMs are considered. The present results show that the overall first ‐ law (energy) and second ‐ law (exergy) efficiencies of the PCM‐free radiant heating system are much lower than the case with the PCM‐embedded radiant heating system. Therefore, it is confirmed that the energy efficiency increases from 62% to 87% while the exergy efficiency rises from 14% to 56% with the option where SP26E PCM is employed accordingly.     

A new hybrid solar photovoltaic/ phosphoric acid fuel cell and energy storage system; Energy and Exergy performance

Present work investigates the performance of a combined solar photovoltaic (PV) and Pumped-Hydro and Compressed-Air energy storage system to overcome the challenges of using solar energy systems. This energy system, which is one of the newest hybrid systems, is able to generate electricity and store energy. To examine the solar PV performance the climatic conditions of Shiraz (in Iran) and Abu Dhabi (in UAE) are considered. The results revealed that, the required pump work, which must be supplied by PV system, is equal to 2.85 and 2.62 MJ/m³ for isothermal and isentropic processes, respectively. Furthermore, the total system efficiency is equal to 76.5%. In addition, the total exergy destruction of hybrid system for isentropic process is 8.91% less than that isothermal process. In addition, instead of the solar PV system, a phosphoric acid fuel cell is coupled to the storage system and the results are compared with the main system.     

Experimental evaluation of energy and exergy efficiency of a seasonal latent heat storage system for greenhouse heating

In the following work, a seasonal thermal energy storage using paraffin wax as a PCM with the latent heat storage technique was attempted to heat the greenhouse of 180 m² floor area. The system consists mainly of five units: (1) flat plate solar air collectors (as heat collection unit), (2) latent heat storage (LHS) unit, (3) experimental greenhouse, (4) heat transfer unit and (5) data acquisition unit. The external heat collection unit consisted of 27 m² of south facing solar air heaters mounted at a 55° tilt angle. The diameter and the total volume of the steel tank used as the latent heat storage unit were 1.7 m and 11.6 m³, respectively. The LHS unit was filled with 6000 kg of paraffin, equivalent to 33.33 kg of PCM per square meter of the greenhouse ground surface area. Energy and exergy analyses were applied in order to evaluate the system efficiency. The rate of heat transferred in the LHS unit ranged from 1.22 to 2.63 kW, whereas the rate of heat stored in the LHS unit was in the range of 0.65–2.1 kW. The average daily rate of thermal exergy transferred and stored in the LHS unit were 111.2 W and 79.9 W, respectively. During the experimental period, it was found that the average net energy and exergy efficiencies were 40.4% and 4.2%, respectively. The effect of the temperature difference of the heat transfer fluid at the inlet and outlet of the LHS unit on the computed values of the energy and exergy efficiency is evaluated during the charging period.     

Exergetic analysis of a solar thermal power system

This communication presents a second law analysis based on an exergy concept for a solar thermal power system. Basic energy and exergy analysis for the system components (viz. parabolic trough collector/receiver and Rankine heat engine, etc.) are carried out for evaluating the respective losses as well as exergetic efficiency for typical solar thermal power systems under given operating conditions. It is found that the main energy loss takes place at the condenser of the heat engine part, whereas the exergy analysis shows that the collector–receiver assembly is the part where the losses are maximum. The analysis and results can be used for evaluating the component irreversibilities which can also explain the deviation between the actual efficiency and ideal efficiency of a solar thermal power system.     

Exergy Analysis of Solar Still with Sand Heat Energy Storage

This paper studies the experimental and exergy analysis of solar still with the sand heat energy storage system. The cumulative yield from solar still with and without energy storage material is found to be 3.3 and 1.89 kg/m², respectively for 8-h operation. Results show that the exergy efficiency of the system is higher with the least water depth of 0.02 m (m_w = 20 kg). Competitive analysis of second law efficiency shows that the exergy efficiency improves the system by 30% than conventional single slope solar still without any heat storage. The maximum exergy efficiency with energy storage material is found as 13.2% and it is less than the conventional solar still without any material inside the basin.     

Exergetic analysis and economic evaluation of central tower receiver solar thermal power plant

This article presents the analytical evaluation of a central tower receiver solar thermal power plant with air‐cooled volumetric receiver using exergy analysis. The energetic and exergetic losses as well as the efficiencies of a typical central tower receiver‐based solar thermal power plant have been carried out under the specific operating conditions. The enhancement in efficiency of the plant from the variation in power input to constant power input achieved by thermal storage backup condition has been determined. It is found that the year round average energetic efficiency can be increased from 24.15% to 25.08% and year round average exergetic efficiency can be increased, from 26.10% to 27.10% for the selected location Jodhpur. The unit cost of electric energy generation (kWh_e) is found to be INR 10.09 considering 30‐year lifespan of the solar plant along with a 10% interest rate. The present study provides a base for the development of future solar thermal power plants in India. Copyright © 2013 John Wiley & Sons, Ltd.     

Exergetic sustainability indicators for a high pressure hydrogen production and storage system

This study examines the exergetic sustainability effect of PEM electrolyzer (PEME) integrated high pressure hydrogen gas storage system whose capacity is 3 kg/h. For this purpose, the indicators, previously used in the literature, are taken into account and their variations are parametrically studied as a function of the PEME operating pressure and storage pressure by considering i) PEME operating temperature at 70 °C, ii) PEME operating pressures at 10, 30, 50 and 100 bar, iii) hydrogen gas flow rate at 3 kg/h and iv) storage pressure between 200 and 900 bar. Consequently, the results from the parametric investigation indicate that, with the ascent of storage pressure from 200 to 900 bar at a constant PEME operating pressure (=50 bar), exergetic efficiency changes decreasingly between 0.612 and 0.607 while exergetic sustainability between 1.575 and 1.545. However, it is estimated that waste exergy ratio changes increasingly between 0.388 and 0.393 while environmental effect factor between 0.635 and 0.647. Additionally, it is said that the higher PEME outlet pressure causes the higher exergetic sustainability index, the lower environmental effect factor, the lower waste exergy output, the higher exergetic efficiency. However, the higher storage pressure causes the lower exergetic efficiency, the higher waste exergy output, the higher environmental effect factor and the lower exergetic sustainability index. Thus, it is recommended that this type of the system should be operated at higher PEME outlet pressure, and at an optimum hydrogen storage pressure.