The effects of nickel and carbon concentrations on the wear resistance of Fe–Ni–C austenitic alloys

The effects of nickel and carbon concentrations on the wear resistance of Fe–xNi–yC (x = 14–20 wt.%, y = 0.6–1.0 wt.%) were investigated with respect to strain energy initiation of the martensitic transformation and hardness. The strain energy needed to initiate the martensitic transformation increased with increasing carbon and nickel concentrations, except in 1.0 wt.% C alloys. The wear resistance of the material decreased with increasing carbon concentration up to 0.9 wt.% C. This effect is most likely due to decrement of the martensite volume fraction with increasing carbon concentration induced by the incremental strain energy required to begin the martensitic transformation. In the case of 1.0 wt.% C, the improved wear resistance may be due to carbide precipitation.     

Effects of Ni and Mn on the Cavitation Erosion Resistance of Fe–Cr–C–Ni/Mn Austenitic Alloys

The effects of Ni and Mn concentrations on the cavitation erosion behavior of Fe–12Cr–0.4C–xNi/Mn (x = 5, 7, and 10) alloys were investigated with respect to strain-induced γ → α′ and γ → ε phase transformation. The cavitation erosion resistance of the Ni-added alloys decreased with increasing Ni concentration, whereas that of the Mn-added alloys improved with increasing Mn concentration. Also, the 7Mn-added alloy and 10Mn-added alloy, which additionally underwent the γ → ε phase transformation, had better resistance to cavitation erosion than the 5Mn-added alloy in which the γ → α′ phase transformation occurs most actively. These behaviors were considered to be due to the fact that the strain-induced ε martensite absorbs the cavity collapse energy and prevents the damage by cavitation erosion more effectively than the strain-induced α′ martensite.     

Cavitation erosion of Fe–Mn–Si–Cr shape memory alloys

Cavitation erosion tests of three Fe–Mn–Si–Cr shape memory alloys were carried out at speed 34 and 45 m/s using a rotating disc rig, and their cavitation damage has been investigated by comparison with a referring 13Cr–5Ni–Mo stainless steel used for hydraulic turbine vanes. The research results proved that the cavitation erosion of the Fe–Mn–Si–Cr shape memory alloys is a failure of low cycle fatigue and fracture propagates along grain boundaries. After 48 h cavitation erosion the cumulative mass losses of the studied alloys at speed 45 m/s are more than theirs at speed 34 m/s; however, the effect of velocity on cavitation damage of the Fe–Mn–Si–Cr alloys is much lower than that of 13Cr–5Ni–Mo stainless steel. The cumulative mass loss of the 13Cr–5Ni–Mo stainless steel are 26.3 mg at speed 45 m/s and 3.2 mg at speed 34 m/s, and the mass losses of the Fe–Mn–Si–Cr alloys are within the range of 3.6–7.3 mg at speed 45 m/s and 2.0–4.1 mg at speed 34 m/s. The surface elasticity of the Fe–Mn–Si–Cr shape memory alloys is better than that of the 13Cr–5Ni–Mo stainless steel, and the effect of surface elasticity on cavitation damage increases with velocity. The excellent surface elasticity of the cavitation-induced hexagonal closed-packed (h.c.p.) martensite plays a key role in contribution of phase transformation to the cavitation erosion resistance of the Fe–Mn–Si–Cr shape memory alloys. The cavitation damage of the studied alloys at speed 45 m/s mainly depends on their surface elasticity, and the variation of 48 h cumulative mass loss (Δm) as a function of the elastic depth (h_e) can be expressed as Δm=2.695+[1371.94/(4(h_e−46.83)²+12.751)] with a correlation factor of 0.99345.     

Effect of heat treatment on the structure,cavitation erosion and erosion–corrosion behavior of Fe-based amorphous coatings

In this study, high-velocity oxygen-fuel sprayed amorphous coatings have been heat treated at various temperatures to form microstructures with crystalline phases. The structure, micro-hardness, cavitation erosion resistance and erosion–corrosion resistance of these coatings are compared. Crystalline phases are discovered in the coatings after heat treatments at 650 °C and 750 °C. The coating heat treated at 750 °C exhibits the poorest cavitation erosion resistance in 3.5 wt% NaCl solution among all coatings due to the degraded corrosion resistance. However, the hardness of the crystallized coating can reach 1000 Hv and the erosion–corrosion resistance of the heat treated coating is better than the untreated one.     

Effects of Strain-Induced Martensitic Transformation on the Solid Particle Erosion Behavior of Fe–Cr–C–Ni/Mn Austenitic Alloys

The effects of Ni and Mn concentrations and also the impact velocity on the solid particle erosion behavior of Fe?C12Cr?C0.4C?CxNi/Mn (x?=?5 and 10) alloys were investigated with respect to strain-induced martensitic transformation. The critical strain energy (CSE), which is defined as the energy required to initiate the martensitic transformation increased with increasing Ni and Mn concentrations. As the impact velocity decreased, the solid particle erosion resistance of the low CSE alloy improved compared to that of the high CSE alloy under the given ranges of impingement angles and impact velocities. This result was most likely due to an increase in the volume fraction of martensite that formed during the solid particle erosion test in the low CSE alloy when the impact velocity was decreased.     

Effects of Cr3C2 addition on the erosion–corrosion resistance of Ti(C,N)-based cermets in alkaline conditions

Effects of Cr₃C₂ on the erosion–corrosion behavior of Ti(C,N)-based cermets are studied in alkaline conditions. The results indicate that the erosion–corrosion resistance of cermets is improved with proper Cr₃C₂ content. Corrosion performance of cermets is deteriorated by Cr₃C₂ addition in NaOH solution. With the increase of Cr₃C₂, the erosion–corrosion behavior of Ti(C,N)-based cermets is classified to be erosion regime, erosion–corrosion regime, corrosion–erosion regime and corrosion regime. Materials degradation is determined by particles erosion for cermets with low Cr₃C₂ content, while for materials containing more Cr₃C₂ addition, binder corrosion and subsequent erosion are responsible for materials deterioration.     

The influence of Cu addition on precipitation in Fe–Cr–Ni–Al–(Cu) model alloys

Precipitation in Fe–Cr–Ni–Al–(Cu) model alloys was investigated after ageing for 0.25, 3, 10 and 100 h at 798 K. Characterization of nanoscale precipitates was performed using three-dimensional atom probe microscopy and transmission electron microscopy. The precipitates are found to be enriched in Ni and Al (Cu) and depleted in Fe and Cr. After 0.25 h of ageing the number density of precipitates is ∼8×10²⁴ m⁻³, their volume fraction is about 15.5% and they are near-spherical with an average diameter of about 2–3 nm. During further ageing the precipitates in the both alloys grow, but the coarsening behaviour is different for both alloys. The precipitates of the Cu-free alloy grow much faster compared with the Cu-containing alloy and their density decreases. Precipitates in Cu-free alloy change to plate shaped even after 10 h of ageing, whereas those of Cu-containing alloy remain spherical up to 10 h of ageing. The influence of Cu addition on precipitation in these model alloys is discussed with respect to the different coarsening mechanisms.     

Effects of electromagnetic stirring and rare earth compounds on the microstructure and mechanical properties of hypereutectic Al–Si alloys

In this paper, the effects of rare earth addition and electromagnetic stirring on the microstructure and the mechanical properties of hypereutectic Al–Si alloys have been reported. Hypereutectic Al–Si alloy was prepared using liquid metallurgy route and modified with the addition of cerium oxide. To control the structure, slurry of hypereutectic Al–Si alloy was subjected to electromagnetic stirring before pouring into the mould. It was observed that the addition of cerium oxide (0.2 wt.%) refined the primary silicon particles and modified the eutectic silicon particles. Further, the electromagnetic stirring of the hypereutectic Al–Si alloy reduced the average size of primary silicon particles, from 152?±?9 to 120?±?6 μm, and the length of β-intermetallic compounds decreased from 314?±?12 to 234?±?10 μm. Similarly, the application of electromagnetic stirring on cerium oxide-modified hypereutectic Al–Si alloy also reduced the average size of primary silicon particles from 98?±?5 to 76?±?4 μm and the average length of β-intermetallic compounds from 225?±?7 to 203?±?5 μm. Mechanical properties namely tensile strength, ductility and hardness of the alloys were improved with electromagnetic stirring and addition of cerium oxide appreciably.     

Microstructural and abrasive characteristics of high carbon Fe–Cr–C hardfacing alloy

A series of high carbon Fe–Cr–C hardfacing alloys were produced by gas tungsten arc welding (GTAW). Chromium and graphite alloy fillers were used to deposit hardfacing alloys on ASTM A36 steel substrates. Depending on the four different graphite additions in these alloy fillers, this research produced hypereutectic microstructures of Fe–Cr phase and (Cr,Fe)₇C₃ carbides on hard-facing alloys. The microstructural results indicated that primary (Cr,Fe)₇C₃ carbides and eutectic colonies of [Cr–Fe+(Cr,Fe)₇C₃] existed in hardfacing alloys. With increasing the C contents of the hardfacing alloys, the fraction of primary (Cr,Fe)₇C₃ carbides increased and their size decreased. The hardness of hardfacing alloys increased with fraction of primary (Cr.Fe)₇C₃ carbides. Regarding the abrasive characteristics, the wear resistance of hardfacing alloys were related to the fraction of primary (Cr,Fe)₇C₃ carbides. The wear mechanism was also dominated by the fraction of primary (Cr,Fe)₇C₃ carbides. Fewer primary carbides resulted in continuous scratches worn on the surface of hardfacing alloy. In addition, the formation of craters resulted from the fracture of carbides. However, the scratches became discontinuous with increasing fraction of the carbides. More primary carbides can effectively prevent the eutectic colonies from the damage of abrasive particles.     

Effect of strain amplitude and temperature on creep-fatigue behaviors of 9–12 % Cr steel

The creep-fatigue behaviors of P92 steel under strain range of 0.3 %–0.5 % and test temperature of 600–650 °C was studied carefully in this paper. With the increase of temperature, the creep-fatigue life is significantly reduced, and more vulnerable to temperature than strain amplitude. In addition, the dislocation density decreases with increasing creep fatigue, and the martensite laths become coarser. Furthermore, the increase of strain amplitude leads to more significant secondary cracks and fatigue striation. The higher temperature causes much deeper and larger dimples. During the test, the growth and accumulation of precipitates inevitably lead to stress concentration, resulting in material fracture and destruction. Finally, the linear cumulative damage (LCD), the modified ductility exhaustion (MDE) and the frequency separation life (FSL) model are used to predict the creep-fatigue life of P92 steel, and it is found that the frequency separation life model had the highest prediction accuracy among the threes.

     

Wear resistance of cast Fe–Cr–C steels with various combinations of structural constituents at high velocities of sliding

The positive effect of the additional alloying of cast Fe–Cr–C steels on the formation of a secondary structure in the steels and their tribological characteristics under boundary friction has been shown. This effect leads to a decrease in the wear rate of the cast steel 1.2–5.2 times compared to that of the commercial 95Kh18 steel depending on the alloying system of the steels.     

Effects of Chromium Addition on Microstructure and Abrasion Resistance of Fe–B Cast Alloy

This research work studies the effects of chromium on microstructure and abrasion resistance of Fe–B cast alloy. The results show that eutectic boride changes from continuous network to less continuous and matrix changes from pearlite to martensite with the increase in chromium content in the alloy. Meanwhile, an increase in chromium addition in the alloy leads to an increase in the chromium content in M₂B-type boride because chromium can enter boride by substituting for iron in Fe₂B. Under two-body wear, Fe–B cast alloy exhibits excellent wear resistance. When alloys are tested against soft abrasive, chromium can markedly improve the wear resistance of Fe–B cast alloy, whereas excessive chromium can reduce the wear resistance. The wear resistance of Fe–B cast alloy increases first and then decreases with the increase in chromium. But when tested against hard abrasive, since the hardness of SiC is much higher than that of M₂B boride, an increase in chromium content marginally increases the wear resistance. Weight losses of Fe–B cast alloy increase with the increase in the load and exhibit the linear relationship.     

Influence of the Addition of Vanadium Nitride on the Structure and Specifications of a Diamond–(Fe–Cu–Ni–Sn) Composite System

This article discusses the influence of the addition of vanadium nitride on the mechanical and operational properties of diamond composite material based on metallic bond comprised of iron, copper, nickel, and tin obtained by sintering in a mold at 800°C for 1 h with subsequent hot repressing. It has been established that the addition of vanadium nitride in the amount of 2 wt % to diamond–(51Fe–32Cu–9Ni–8Sn) increases the ultimate compressive strength from 846 to 1640 MPa and bending strength from 680 to 1120 MPa, as well as decreases the wear intensity of the composite material from 0.0069 to 0.0033 g/km. The mechanism of improving the tribological properties has been revealed.     

Optimizing the geometric parameters of chamfered edge for rough machining Fe–Cr–Ni stainless steel

Geometry of cutting edge has great influence on performance and reliability of modern precision cutting tools. In this study, two-dimensional finite element model of orthogonal cutting of Fe–Cr–Ni stainless steel has been built to optimize the geometric parameters of chamfered edge. A method to measure the chip curl radius has been proposed. The effect of cutting edge geometric parameters on tool stress and chip curl radius has been analyzed. Then, the chamfered edge parameters have been optimized based on numerical simulation results. It finds that, keeping the equal material removal rate, the optimal geometric parameters of chamfered edge for rough machining Fe–Cr–Ni stainless steel are that the rake angle is from 16° to 17°, and the chamfer length is from 60 to 70 μm. Small (large) rake angle combined with small (large) chamfer length is more reasonable to reduce the tool stress. When the length of land is approximately equal to undeformed chip thickness and the rake angle is larger than 15°, the chip curl radius is minimal. The groove type with large radio of width to depth should be used in the chip breaking based on the optimization results.     

The Influence of the Matrix Microstructure on Abrasive Wear Resistance of Heat-Treated Fe–32Cr–4.5C wt% Hardfacing Alloy

The abrasion wear resistance of Fe–32Cr–4.5C wt% hardfacing alloy was investigated as a function of matrix microstructure. In this study, the alloy was deposited on ASTM A36 carbon steel plates by the shielded metal arc welding (SMAW) process and the as-welded matrix microstructure was changed into ferrite, martensite, and tempered martensite by heat treatment processes. The Pin-on-disk test results show that under low (5 N) and high (20 N) load conditions, the wear resistance behavior of the as-welded matrix sample is 20 and 15% higher, respectively, than the martensitic matrix sample, although the bulk hardness of the as-welded matrix is 5% lower. The ferritic matrix sample has the poorest wear resistance behavior which is less than half of that of the as-welded matrix one. Micro-ploughing, micro-cutting, and micro-cracking are recognized as the micro-mechanisms in the material removal in which the proportion of micro-ploughing mechanism increased by increasing matrix toughness.     

Strain-Induced ε/α′ Martensitic Transformation Behavior and Solid Particle Erosion Resistance of Austenitic Fe–Cr–C–Mn/Ni Alloys

The strain-induced ε/α′ martensitic transformation behavior and resistance to solid particle erosion was investigated for austenitic Fe-12Cr-0.4C-xMn/Ni (x = 5, 7, and 10 wt%) alloys. The γ → α′ chemical driving force decreased with increasing Mn and Ni. The SFE values of 5Ni, 7Ni, and 10Ni alloys were 31.2, 41.5, and 45.8 mJ/m², respectively. Because Ni increased the SFE, γ → α′ phase transformation was suppressed in Fe-12Cr-0.4C-Ni alloys. The SFE values for 5Mn, 7Mn, and 10Mn alloys were 19.4, 16.6, and 10.5 mJ/m², respectively. Although Mn decreased the SFE, the fraction of transformed α′ decreased with increasing Mn concentrations due to γ → ε phase transformation and decreasing γ → α′ chemical driving force of higher Mn alloys. The solid particle erosion resistance was better in the phase transformable alloys than the non-phase transformed alloys. In particular, γ → α′ phase transformable alloys had better resistance to solid particle erosion than γ → ε phase transformable alloys.     

The influence of elastic strain on the early stages of decomposition in Cu–1.7 at% Fe

The initial stage of decomposition of homogenized Cu–1.7 at% Fe at 722 K was investigated by means of field ion microscopy (FIM), atom probe tomography (APT) and computer-assisted field ion image tomography (cFIIT). The agglomeration of atoms depending on time could be investigated and the growth of precipitates with a diameter of few nanometers was observed during ongoing nucleation.     

The Microstructure and Abrasive Wear Resistance of Fe–Cr–C Hardfacing Alloys with the Composition of Hypoeutectic,Eutectic, and Hypereutectic at $$ frac{Cr}{C} = 6 $$

In this investigation, three Fe–Cr–C hardfacing alloys with different carbon and chromium contents and in constant ratio of ( fracCrC = 6 ) left( {frac{Cr}{C} = 6} right) were fabricated by GTAW on AISI 1010 mild steel substrates. The OES, OM, SEM, and XRD techniques and Vickers hardness method were used for determining chemical composition, hardness, and studying the microstructure of the hardface alloys. The OES, OM, and XRD examination results indicated that different carbon and chromium contents of hardface alloys produced hypoeutectic/eutectic/hypereutectic structures. By increasing the carbon and chromium contents in the chemical composition of hardface alloys, the volume fraction of the total (Cr, Fe)₇C₃ is increased resulting to decreasing in total the austenite volume fraction and increasing the hardness of the surface. Studying the microstructure after wear test (ASTM G65) shows that at the edge of the worn surface, the transformation of austenite to martensite had occurred in all the samples. The wear test results indicate that the highest wear resistance is gained in the hypoeutectic structure with maximum hardness after the wear test. In addition, abrasive wear micromechanisms in hypoeutectic/eutectic/hypereutectic were recognized as: ploughing + cutting/ploughing + cutting + cracking/cracking + cutting, respectively.     

Effects of cold working and heat treatment on microstructure and wear behaviour of Cu–Be alloy C17200

The effects of cold work process between aging and solution heat treatment on the microstructure, hardness and the tribologic behaviour of a copper–beryllium (Cu–Be) alloy C17200 were investigated. The wear behaviour of the alloys was studied using ‘pin on disc’ method under dry conditions. The results show that the formation of fine grained structure and γ phase particles enhances the mechanical properties of the alloy; nonetheless, they do not reduce the wear rate. This is attributed to the capability of the softer specimens to maintain oxygen rich compounds during the dry sliding test.