Comparison of Various Packaging Films for Mango Export

This study compared the effects of the use of various types of packaging films in maintaining quality, preserving bioactive compounds and extending shelf life of the ‘Nam Dok Mai’ mango. The principal techniques for maintaining the quality of mangoes are based on modified atmosphere packaging using highly gas‐permeable films and an ethylene‐removing mechanism. The films studied were non‐perforated highly gas‐permeable film, non‐perforated ethylene‐absorbing highly gas‐permeable film (HNPE), micro‐perforated highly gas‐permeable films (HMP) and common non‐perforated polyethylene film (LNP). These films were compared with non‐packaging treatment, which served as a control (C). Gas composition (O₂, CO₂ and C₂H₄) in the package headspace was monitored during storage at 12°C. The quality of mangoes were assessed by weight loss, colour (L* a* b*), texture, total soluble solids, titratable acidity, total phenolics, total flavonoids, ethanol concentration and sensory quality. Equilibrium‐modified atmospheres of 5 kPaO₂ + 5 kPaCO₂ and 4 kPaO₂ + 5 kPaCO₂ were achieved in the non‐perforated highly gas‐permeable film and HNPE packs, respectively. Carbon dioxide accumulation was observed in the HMP and LNP packs where CO₂ reached 17 and 10 kPa, respectively, after storage for 10 days. The shelf life of mangoes was extended to 40 days with HNPE, 35 days with HNP, and 30 days with HMP, as compared with 20 days with control and 5 days with LNP. HNPE, the film incorporated with fine particles of mordenite framework inverted‐type zeolite with ethylene‐absorbing ability, could further extend the shelf life of mangoes in addition to modified atmosphere packaging alone. Copyright © 2011 John Wiley & Sons, Ltd.     

Effects of polylactic acid antimicrobial films on preservation of Chinese rape

Two antimicrobial agents of organic salicylic acid (SA) and inorganic nanosized titanium dioxide (TiO₂) were added into polylactic acid (PLA) respectively to prepare two different biodegradable packaging films. The antimicrobial properties of PLA-based films were then characterized and the film preservation effect on fresh vegetables had been exampled by evaluating the external appearance, headspace gas concentration, weight loss rate, decay rate and −a/b values of Chinese rape. The results showed that the antimicrobial rate of PLA/4%TiO₂ film was 91.3% against Staphylococcus aureus and 90.8% against Escherichia coli. In the case of PLA/6%SA film, its antimicrobial rate was 97.3% against S. aureus and 93.1% against E. coli. These two antimicrobial films were seen to obviously reduce the respiration rate of Chinese rape and exhibit lower decay rate and higher −a/b values of Chinese rape than those packaged in pure PLA bag, resulting in the extended shelf life for stored Chinese rape. These satisfactory performances suggest that the PLA-based antimicrobial films could be potentially suitable for the preservation of green vegetables.     

Effects of PP‐based Nanopackaging on the Overall Quality and Shelf Life of Ready‐to‐eat Salami

A total of 1% nanoclay containing polypropylene (PP)‐nanocomposite and 1% nanoclay plus 5% poly‐beta‐pinene (PβP) containing PP‐active‐nanocomposite materials were produced and tested for packaging of sliced salami. The sliced salami was packaged using both nanofilms and multilayer film of PP/PA/EVOH/PE under vacuum, modified atmosphere packaging under 50% CO₂ and 50% N₂ and air and stored at 4 °C for 90 days. During storage, headspace gas composition; microbial, physical and chemical analyses; and sensory evaluation were performed. The antimicrobial effect of PβP containing nanomaterial was pronounced under vacuum, and no bacterial growth was observed for 75 days. An a* value decreased notably in all applications during storage and preserved best by the multilayered material under vacuum and high CO₂. Thiobarbituric acid reactive substances (TBARS) were 0.63 mg MDA/kg after the processing and gradually increased at all applications during increased storage. TBARS values of all vacuum applications were lower than that of modified atmosphere packaging applications. Rancid taste development was determined by sensory panelists when TBARS values were higher than 0.80 mg MDA/kg on the 90th day. There was no significant moisture loss, and no increase in hardness was determined during the whole storage time. The longest shelf life was 75 days for the sliced salami under vacuum and high CO₂ using the multilayer material. PβP containing nanomaterial provided 50 days of shelf life under vacuum, which is commercially considerable. Copyright © 2017 John Wiley & Sons, Ltd.     

Quality changes of treated fresh‐cut tropical fruits in rigid modified atmosphere packaging containers

There has been increasing demand for various fresh‐cut tropical fruits. However, their short shelf‐life has limited the market increase of this product. Quality changes (firmness, colour, total soluble solids (TSS), titratable acidity (TA), sensory quality and microbial safety) of fresh‐cut mangoes, pineapples, melons and mixes of these fruits were evaluated. Chemical treatments to reduce browning, firmness loss and decay of fresh‐cut tropical fruits were investigated. The most effective agents for fresh‐cut mangoes, pineapples and melons were 0.1m ascorbic acid, 0.2m ascorbic acid and 0.2m ascorbic acid + 0.2m calcium chloride, respectively. Fresh‐cut tropical fruits were packaged in various rigid containers (PET, OPS and OPLA). Gas composition in the package headspace and time to reach steady‐state condition varied among fresh‐cut packaging systems and affected their quality and shelf‐life. The effects of package permeability of O₂ and CO₂ on quality and shelf‐life of the fresh‐cut products are discussed. Extended shelf‐life was observed in fresh‐cut mangoes, pineapples and mixes packaged in PET due to reduced O₂ and elevated CO₂ atmosphere. A modified atmosphere of 6% O₂ and 14% CO₂ achieved in PET extended the shelf‐life of fresh‐cut pineapples from 6 to 13 days. Accumulation of CO₂ may impart an off‐odour of fresh‐cut fruits. The results suggested that the shelf‐life of fresh‐cut fruits could be extended by using proper rigid containers. Suitable mixes to create optimal equilibrium modified atmosphere had a potential to extend shelf‐life of short shelf‐life fresh‐cut tropical fruits. Copyright © 2006 John Wiley & Sons, Ltd.     

Novel pineapple leaf fibre composites coating with antimicrobial compound as a potential food packaging

Biodegradable packaging coated with antimicrobial compounds has emerged as a new type of food packaging with potential to enhance food safety, extend shelf life and minimize plastic pollution. We have developed a polylactic acid (PLA) composite pineapple leaf fibre (PALF) biopolymer to fulfil the high demand of biodegradable materials for a potential use in food packaging. Our formulation with 10% pineapple fibre PLA/PALF composites exhibited enhanced melting temperatures and heat resistance, with a 44% reduction in the tensile strength and 2.7-fold reduction on the strain at the break when compared with neat PLA. To impart antimicrobial activity, the PLA/PALF was coated with crude supernatants isolated from Pediococcus pentosaceus PP04 containing 1.3% w/v of nisin. This material coated with the crude extract was shown to inhibit the growth of Bacillus cereus ATCC 11778, Salmonella enterica subsp. enterica serovar Typhimurium ATCC 13311, and Escherichia coli ATCC 8739 in culture conditions, as well as minimizing the number of the tested pathogens on coated material surfaces.     

The effectiveness of hexamethylenetetramine‐incorporated plastic for the active packaging of foods

The feasibility of LDPE films containing 0.2 or 0.5% (w/w) hexamethylenetetramine (HMT) as antimicrobial packaging material to inhibit microbial growth on the surface of foods was investigated. As HMT is allowed in Europe to be used as a preservative under certain conditions, and as it is mentioned on the list of additives notified to the European Commission as substances which may be used in plastics intended in contact with food products, this compound offers good opportunities for the manufacturing of an antimicrobial packaging material. In a first experiment, fresh orange juice was vacuum packaged in LDPE films containing 0, 0.2 and 0.5% (w/w) HMT and stored at 6°C for 39 days. Every day and later every 3 days, packages of orange juice were analysed for yeasts and lactic acid bacteria. The shelf‐life of orange juice, could not be prolonged significantly by packaging into a 0.2% or 0.5% (w/w) HMT‐containing film. In a second experiment, however, packaging of cooked ham in a 0.5% (w/w) containing LDPE film, significantly affected shelf‐life. After 20 days a significant reduction of total aerobic count and lactic acid bacteria was observed. In an additional migration test, it became clear that the level of HMT released into orange juice was close to the specific migration limit of 15 mg CH₂O/kg imposed by the EC. Copyright © 2000 John Wiley & Sons, Ltd.     

Development of multilayer films with improved aroma barrier properties for durian packaging application

The symmetrical A/B/A structure of multilayer blown films was fabricated in this study. The immiscible low‐density polyethylene/polylactic acid (LDPE/PLA) blend was set as a core (B) layer and LDPE was used as skin (A) layers. The compositions of PLA in the core layer were varied from 20 to 50 wt%. The thickness of each layer was 10 μm (total film thickness of ~ 30 μm). In a blown film co‐extrusion process, the morphology of the fiber/ribbon‐like structures of LDPE/PLA blend was developed. Such structures had interesting effects on gas permeability and aroma barrier properties of the films. For instance, multilayer LDPE films containing 40 and 50 wt% PLA (P40 and P50) showed the reduction of oxygen permeability (PO₂) approximately 20% and 43%, respectively, compared with the neat LDPE film. A long tortuous path for gas and aroma transportation through film thickness was created from the developed ribbon‐like structures of the PLA minor phase. For durian packaging application, fresh‐cut durian of 300 g was packed in the developed multilayer films, LDPE, and HDPE (Control), stored at 4°C for 7 days. Results demonstrated that the steady‐state condition of 10% to 13% O₂ and 8% to 10% CO₂ was achieved in all packages except in the HDPE. Moreover, the P40 and P50 films exhibited an outstanding aroma barrier property for three major durian volatiles : diethyl sulfide, ethyl propanoate, and 2‐ethyl‐1‐hexanol. Overall results clearly indicated that the multilayer LDPE films containing PLA exhibited a significantly improved aroma barrier performance with optimum gas permeability desirable for modified atmosphere packaging to retain quality of fresh‐cut durian throughout the storage period.     

Shelf life extension of fresh asparagus using modified atmosphere packaging and vacuum skin packaging in microwavable tray systems

Asparagus (Asparagus officinalis L.) is one of the most popular vegetables because it contains a wealth of fiber and several essential nutrients. It is a very perishable commodity due to its very high respiration rate. To maintain product quality and to satisfy consumer demand as a convenient food, modified atmosphere packaging (MAP), vacuum skin packaging (VSP), and microwaveable containers were used to extend the shelf life of fresh-cut asparagus as a ready-to-eat food product. The objective of this study was to determine the shelf life of fresh-cut asparagus packed in MAP and VSP microwaveable tray systems at commercial storage conditions, 4°C, 80% RH. Weight loss, moisture content, O₂/CO₂ concentration in the package headspace, product pH, microbial growth, and sensory evaluation were used to determine the product quality and shelf life. Moreover, the preference of product appearance and the quality of the cooked asparagus in both microwaveable tray systems at different cooking times and microwave power levels was also sensorially evaluated. During storage for 21 days, there was no significant difference (p > 0.05) in weight loss, moisture content, and pH. Sanitation and packaging techniques also helped to retard the microbial growth. Both techniques, combined with refrigeration, help to maintain the freshness and product shelf life up to 21 days for MAP and 18 days for VSP. On the basis of hedonic scale results, consumers preferred the appearance of both packaging types. Both microwavable tray systems, thus, can help to prolong the shelf life of fresh-cut asparagus and can be eaten directly from the package.     

Effect of hinokitiol impregnated sheets on shelf life and quality of “KEK‐1” tomatoes during storage

Hinokitiol (β‐thujaplicin, volatile oil extracted from the wood of Hiba arborvitae [Thujopsis dolabrata var. hondae], cypress family) is a natural preservative, antimicrobial, and chelating agent, used to prevent decay and extend the shelf life of fruits and vegetables. In the present study, we used nonwoven rayon sheets impregnated with hinokitiol to conduct packaging studies. Mature green tomatoes var. “KEK‐1” were packaged under three packaging conditions, ie, modified atmosphere packaging (MAP), MAP + hinokitiol (MH), and perforated film package (as control), and their quality attributes were compared during storage. The packaging materials used were low‐density polyethylene (LDPE) film (40 μm) and fresh sheets of nonwoven rayon impregnated with hinokitiol. O₂ in the MAP packaged tomatoes were retained throughout the storage period (3% to 5% O₂). Results showed that MH had slightly improved quality attributes throughout the storage period when compared with MAP alone. Expression levels of LeACS, LeADH, and LeTBG4 genes were higher in 5 and 9 days of control when compared with MAP and MH. “KEK‐1” tomatoes had longer shelf life under MAP and MH packaging and maintained the quality at 15°C. Hence, the effect of the MAP with bioactive packaging treatments could be effective in the future application for the extension of shelf life and quality of fruits and vegetables.     

Effect of light‐barrier property of packaging film on the photo‐oxidation and shelf life of cookies based on accelerated tests

The influences of intensity of ultraviolet (UV) light, light‐barrier property of packaging film on the fat photo‐oxidation and accelerated shelf life of cookies were studied. Unpacked cookies were stored at a temperature of 408C and a relative humidity (RH) of 50% for 10 to 65 days, with an intensity of the UV light of 0.3, 1.9 and 9.5 mW/cm². Meanwhile, the same batch of cookies was packed with oriented nylon/polyethylene, polyethylene terephthalate/oriented nylon/polyethylene and bi‐oriented polypropylene/vacuuming aluminized casting polypropylene and stored at the same temperature and RH and UV‐light intensity of 1.9 mW/cm² for more than 40 days. The peroxide values (POV) of cookies were measured under the storage conditions. The results showed that the intensity of the UV light and light‐barrier property of film had notable influence on the photo‐oxidation rate and accelerated shelf life of cookies. According to the threshold of POV, unpacked cookies were rancid less than 32 and 11 days when exposed in light of 1.9 and 9.5 mW/cm² in the accelerated test, respectively. In contrast, the shelf life of unpacked cookies in darkness, or cookies packed in high light‐barrier package was more than 75 days. Logarithm of POV and store‐time relationship under different UV‐light illumination was successfully fitted by linear regression under the same temperature, RH and the accelerated shelf‐life‐based oxide index was estimated. Copyright © 2008 John Wiley & Sons, Ltd.     

Flexible and Tough Poly(lactic acid) Films for Packaging Applications: Property and Processability Improvement by Effective Reactive Blending

This study demonstrates a practical means to overcome inherent brittleness problem of poly(lactic acid) (PLA) and make PLA feasible as packaging material. PLA with suitable processability is utterly required for package manufacturers, where flexible, tough PLA film is essential for packers and end users. Highly flexible PLA films with 60‐fold increase in elongation at break (Eb) over that of the neat PLA were successfully produced by integrating effective reactive blending and economical film blowing process. The ‘two‐step’ blending was used to prepare PLA compound; poly(butylene adipate‐co‐terephthalate) (PBAT – another biodegradable polymer) was first blended with 0.5–1% chain extender (epoxy‐functionalized styrene acrylic copolymer) (ESA), followed by subsequent blending with PLA in twin‐screw extruder. Blown films of reactive blend of PLA/PBAT/ESA (80/20/1) showed impressively high Eb of 250% versus a very low Eb of 4% for the neat PLA. Resulting blown films still possessed high modulus of 2 GPa, yield stress of 50–60 MPa and good toughness of ~100 MPa. Significant enhancement in the film's ductility was attributed to homogeneous blend with developed fine strand‐like structure as a result of effective in situ compatibilization and good interfacial adhesion between the PLA and PBAT. PLA/PBAT/ESA blend also offered improved processability. Resulting films had acceptable haze of ~10% for common packaging, and clearer film close to PLA (≤2%) could be obtained by designing PLA skin layers in multilayer structure. Films of PLA/PBAT/1%ESA exhibit potential as packaging material; their mechanical and optical properties are comparable with or even exceed some existing films used in the market. Copyright © 2015 John Wiley & Sons, Ltd.     

Modelling a modified atmosphere packaging system for fresh scallops (Argopecten purpuratus)

Seafood is a highly perishable food, which has a relative short shelf‐life. Modified atmosphere packaging (MAP) is a system that offers a way of extending the shelf‐life of seafood products, maintaining quality and inhibiting bacterial growth. The objective of this research was to study and determine the optimal conditions for packaging scallops in a modified atmosphere system, which includes CO₂/O₂/N₂ mixture, headspace:food ratio and storage temperature, utilizing an integrated mathematical model for MAP systems with its respective experimental validation. For validation purposes, two experiments were conducted, using gas mixtures of: (a) 45% CO₂/10% O₂/45% N₂; and (b) 60% CO₂/10% O₂/30% N₂. In addition, two experiments, at 6°C and 20°C, were conducted to obtain the shelf‐life model, utilizing the following gas mixtures: 30% CO₂/10% O₂/60% N₂; 45% CO₂/10% O₂/45% N₂; 60% CO₂/10% O₂/30% N₂; and 75% CO₂/10% O₂/15% N₂. Gas mixtures with CO₂ concentrations between 30% and 70% and different headspace:food ratios were tested during simulations. The optimal conditions for scallop storage were a 60% CO₂/10% O₂/30% N₂ gas mixture and a headspace:food ratio of 2:1. With these conditions, a simulated shelf‐life of 21 days was obtained. Optimal conditions consider maximum shelf‐life, an adequate film collapse criterion, and time to reach the pseudo‐equilibrium condition. The predictive mathematical model, coupled with experimental studies for specific products, can be efficiently utilized to evaluate packaging alternatives (size, material and selected thickness) for different temperatures and initial gas concentration scenarios of MAP products. Copyright © 2006 John Wiley & Sons, Ltd.     

Using Graphene Oxide to Enhance the Barrier Properties of Poly(lactic acid) Film

The ultra‐thin (polyethyleneimine/graphene oxide)_n [(PEI/GO)_n]multilayer films on poly(lactic acid) (PLA) were constructed via the layer‐by‐layer assembly. Here, the electrostatic interactions between PEI and GO were used to obtain the nanoscale composite membrane of (PEI/GO)_n on the surface of PLA film. With the number of assembling layers increased, the oxygen permeability (PO₂) of PLA film decreased substantially. As a 0.06 wt% GO solution was used with only four layers, the PO₂ decreased from 53.8 to 0.377 × 10^?4 cm³/m²/d/Pa, only 0.7% of the original PLA film. At the same time, the coated PLA film also presented a good transparency and better mechanical properties. It is a novel way to use GO on biodegradable packaging materials. Copyright © 2014 John Wiley & Sons, Ltd.     

Synthesis of multiblock thermoplastic elastomers based on biodegradable poly (lactic acid) and polycaprolactone

A new biodegradable (AB)_n type of multiblock copolymers derived from poly (ε-caprolactone) (PCL) and poly (lactic acid) (PLA) was prepared via the method of the chain extending reaction among PCL oligomers, PLA oligomers and hexamethylene diisocyanate (HDI). Fourier transform infrared spectra (FTIR), ¹H NMR, thermal gravity analysis (TGA) and derivative thermograms (DTG) were used to characterize the copolymers and the results showed that PCL and PLA were coupled by the reaction between –NCO groups and terminal –OH and –COOH groups of PCL and PLA, respectively. The material displayed enhanced mechanical properties: Young's modulus was as low as 2.7 ± 0.7 MPa and elongation at break value was above 790% at the composition of PCL/PLA = 80/20 (w/w). Moreover, according to SEM micrographs interfacial adhesion of the composites was improved. Thermal degradation temperature of the composites was higher than PLA but was lower than PCL, which is an advantage for industry process.     

Prediction of plastic film thickness based on gas permeability and validation with ‘Kyoho’ table grapes for optimal modified atmosphere packaging

Modified atmosphere packaging (MAP) storage has become a useful technique for extending the shelf life of fruit and vegetables. However, the success of MAP depends on many factors, including types of fresh products, storage conditions, and the characteristics of the packaging films. To achieve the optimal gas composition in the package headspace and improve the postharvest quality of fresh produce, the packaging film with appropriate barrier properties needs to be selected. This study aimed to predict the film thickness by applying produce respiration rate and package film permeability data measured in given product weight and storage conditions. An available film (eg, 25‐μm‐thick low‐density polyethylene) was used to pack fresh produce, and the respiration rate of fresh produce and in‐package O₂ and CO₂ concentrations at steady state were measured. Permeability of the film was calculated based on mass balance, and the thickness of the film could be predicted if the recommended target O₂ and CO₂ concentration was obtained from the literature. To validate the predicted thickness value, an experiment was conducted by packaging fresh table grapes in bags of the predicted thickness. The effect of packaging with different film thicknesses on the quality of the fruit was determined. The results showed good agreement between the predicted and the experimental in‐bag O₂ and CO₂ concentrations, and the MAP with predicted thickness (90 μm) film was more effective in maintaining postharvest quality of grapes during low‐temperature storage than the thinner films (30 and 60 μm) and the control.     

Low‐density Polyethylene Films Loaded by Titanium Dioxide and Zinc Oxide Nanoparticles as a New Active Packaging System against Escherichia coli O157:H7 in Fresh Calf Minced Meat

Antibacterial packaging is introduced as a new method to prevent microbial food spoilage. Antibacterial effects of TiO₂, ZnO and mixed TiO₂–ZnO nanoparticle‐coated low‐density polyethylene (LDPE) films on Escherichia coli PTCC1330 were investigated. Bactericidal efficiency of 0.5%, 1% and 2% TiO₂ and ZnO nanoparticles and also 1% mixed TiO₂–ZnO nanoparticles with ratios of 25/75, 50/50 and 75/25 were tested under ultraviolet (UV) and fluorescent lights at two states: films alone and fresh calf minced meat packed. Maximum colony‐forming unit (CFU) reduction of 99.8% and 99.7% were obtained using 1% and 2% ZnO nanoparticle‐coated LDPE film under fluorescent light for films alone as well as 99.8% and 99.6% for fresh calf minced meat packed. 90.3% and 51.8% CFU reduction were recorded for 1% TiO₂ nanoparticle‐coated LDPE films in the presence of UV light at direct contact with bacteria and fresh calf minced meat packed, respectively. Maximum CFU reductions of 96% and 64.1% were obtained using 50/50 ratio of TiO₂/ZnO nanoparticles at the presence of UV light for film alone and fresh calf minced meat packed, respectively. ZnO nanoparticle‐coated LDPE films were identified as the best case to improve shelf life and prevent E. coli growth in fresh calf minced meat.     

Effects of Packaging Liners on Cooling Rate and Quality Attributes of Table Grape (cv. Regal Seedless)

Table grapes are commonly packed in multi‐layered packages consisting of cardboard carton, plastic liners and carry bag/pouch to maintain product quality along the cold chain. Each liner is characterized by the number and the size of perforations, which influence the environmental conditions around the produce inside the package. This study investigated the effects of different carton liners on the cooling rate and quality attributes of ‘Regal Seedless’ table grapes. Fruit quality attributes measured include weight loss, stem dehydration and browning, SO₂ injury, decay, berry firmness and colour. Non‐perforated liners maintained relative humidity (RH) close to 100% during cold storage and during a 7 day shelf life period, which resulted in delaying the loss of stem quality but significantly (p ≤ 0.05) increasing the incidence of SO₂ injury and berry drop during storage, as compared with perforated liners. Perforated liners improved fruit cooling rates but significantly (p ≤ 0.05) reduced RH. Low RH in perforated liners resulted in significant (p ≤ 0.05) increase in stem dehydration and browning as compared with non‐perforated liners. Berry firmness decreased by 78% after 42 days of storage at ?0.5°C. Significant (p ≤ 0.05) differences in berry firmness between the different packages were observed only during the first 7 days of storage. Berry colour changed from greenish‐yellow to yellowish‐green in all types of plastic liner during the storage period. Fruit decay occurred in all packages after a 7 day shelf life, with the highest incidence of decay occurring in liners with less perforation. Copyright © 2011 John Wiley & Sons, Ltd.     

Preservation of strawberries by modified atmosphere packages with other treatments

The impact of modified atmosphere packaging (MAP), in combination with ozone treatment and an edible film coating, on the preservation of strawberries was studied. A combination of 2.5% O₂ with 15% CO₂ was the optimum gas composition for the MAP of strawberries and prolonged shelf‐life by 4–6 days. When the strawberries were pre‐treated with a 4.3 mg/m³ ozone water dip and an edible coating prior to packaging, the shelf‐life was extended to 8–10 days. The results showed that two treatments [No.1: polyvinyl alcohol 134 (2%); monostearatacylglycerol (0.5%); phytic acid (0.05%); sorbitol (0.05%); sodium alginate (0.1%); absolute alcohol (8%): No.2: polyvinyl alcohol 134(1%); soluble starch (1%); glucose (1%); sucrose (1%); sodium alginate (0.1%); sorbitol (0.05%)] gave the best effects on strawberry quality and shelf‐life. All treatments (Nos 1–4) were obviously superior to check experiments for soluble sugar, ascorbic acid, acidity and anthocyanin. Furthermore, the treatments gave superior results for browning index, commodity ratio and permeability of the cell membrane. Copyright © 2006 John Wiley & Sons, Ltd.     

Combined effect of chill storage and modified atmosphere packaging on mussels (Mytilus galloprovincialis) preservation

Changes in biochemical indices, microbial growth, headspace and sensory quality of mussels which had been packaged in two modified atmospheres [Modified atmosphere packaging (MAP) 1: 60% CO₂/20% N₂/20% O₂ and MAP 2: 60% CO₂/40% N₂] and under vacuum (VP) were studied for 14 days. The results showed better quality retention and greater shelf life of mussels packaged under MAP 1 as compared to MAP 2 and VP samples. Increase in total volatile basic nitrogen followed the order: MAP 1 < MAP 2, VP < air (control) samples while increase in trimethylamine nitrogen followed the order: MAP 1 < air < MAP 2 < VP. The 2‐thiobarbituric acid (TBA) values of MAP 1 and air samples were significantly higher (p < 0.05) than the TBA values of VP and MAP 2 samples. MAP 1 showed a greater (p < 0.05) inhibition effect on total viable count of mussel samples than all other packaging conditions. Based primarily on odour scores, the MAP 1 samples remained acceptable up to ca. 10–11 days, the MAP 2 and VP up to ca. 7–8 days while the air‐packaged samples up to ca. 5–6 days of storage. Copyright © 2007 John Wiley & Sons, Ltd.     

Preparation and ferroelectric properties of predominantly (100)-oriented SrBi4Ti4O15 ferroelectric thin film on Pt(111)/TiO2/SiO2/Si(100) substrate

A predominantly (100)-oriented SrBi₄Ti₄O₁₅ (SBTi) ferroelectric thin film (orientation factor f ₍₁₀₀₎ = 68%) was formed on Pt(111)/TiO₂/SiO₂/Si(100) substrate using a metal organic decomposition process combined with a sequential layer annealing method. The film exhibits a well saturated hysteresis loop with a remanent polarization of 25 μC/cm². Furthermore, the coercive field (E _c ) is as low as 80 kV/cm. The values of the dielectric constant (ε _r ) and dissipation factor (tan δ) at 100 kHz are estimated to be 380 and 0.08, respectively. 15% loss of P _r was observed after 10⁹ switching cycles in the predominantly (100)-oriented SBTi film. The growth mode of the predominantly (100)-oriented SBTi film is discussed based on the sequential layer annealing process and the anisotropic structure of SBTi.