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由SiO2/3Y-TZP包裹复合粉体制备ZrSiO4/3Y-TZP细晶陶瓷 总被引:1,自引:0,他引:1
对湿化学法制备的SiO2/3Y-TZP包裹复合粉体进行了热压烧结研究,并利用X射线衍射和透射电镜表征了烧结体的物相和显微结构.在低于1300℃,复合粉体发生瞬时粘性烧结,材料密度迅速提高;随着烧结温度的升高,SIO2和ZrO2发生反应生成ZrSiO4.在1500℃热压条件下,制备了平均晶粒尺寸为350nm的ZrSiO4/3Y-TZP细晶复相材料.我们认为,在烧结过程中形成的第二相ZrSiO4,特别是SiO2包裹层对抑制基体晶粒长大起主要作用. 相似文献
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非均相沉淀法制备Al2O3-YAG复相陶瓷 总被引:1,自引:0,他引:1
本文测量了YAG粉体的ξ电位,通过调节pH值获得均匀分散的YAG水悬浮液.采用非均相沉淀方法获得YAG分布均匀的Al2O3-YAG复合粉体.通过热压烧结得到致密烧结体,YAG的加入对烧结温度的影响不大.Al2O3-5vol%YAG复相陶瓷的抗弯强度为485MPa,断裂韧性为4.2MPa·m1/2,均高于单相Al2O3陶瓷,数据的重复性好于球磨混合所制备的样品.通过TEM观察,YAG颗粒均匀分布于整个样品中,表明通过非均相沉淀制粉可以获得YAG颗粒分布均匀的Al2O3-YAG复相陶瓷. 相似文献
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用化学共沉淀法制备了Y2O3含量不同的两种Y-TZP纳米粉体;采用了不同压力不冷等静压成形制备素坯;研究了Y2O3含量,素坯成型压力及烧结温度对Y-TZP陶瓷体密度,组织结构及机械性能的影响。 相似文献
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N. Mizutani T. Ogihara M. Kondo M. Ikeda K. Shinozaki 《Journal of Materials Science》1994,29(2):366-372
Monodispersed TiO2 particles were used to prepare a uniformly packed green compact with a high relative density by slip casting. A suspension consisting of monodispersed TiO2 particles, solvent and binder was cast in the mould. The sintering behaviour of the green compact was investigated. The green compact could be sintered to a relative density of > 99% by treatment at 1050 °C for 120 min. The average grain size of the sintered body was 1.26 m without abnormal grain growth. The green sheet cast on a glass board could be densified with no grain growth. The experimentally obtained relation between densification rate and grain size indicated a volume diffusion mechanism according to Coble's equation. 相似文献
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快速烧结制备纳米Y-TZP材料 总被引:29,自引:1,他引:28
研究了快速热压烧结和放电等离子快速烧结(SPS)制备纳米Y-TZP材料.利用快速热压烧结和 SPS快速烧结,可在烧结温度为 1200℃、保温9~10min条件下,制得相对密度超过99%的 Y-TZP材料.研究发现:虽然快速热压烧结和 SPS烧结都可使Y-TZP在相同温度下的密度高于普通热压烧结,但两种快速烧结所得Y-TZP的晶粒都大于无压烧结所得;另外,快速热压烧结所得样品的结构不够均匀,而SPS烧结的样品的均匀性较好.文章对产生这些现象的原因进行了理论探讨. 相似文献
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热压烧结制备纳米Y-TZP材料 总被引:9,自引:0,他引:9
本文研究了热压烧结制备纳米Y-TZP材料的过程.研究结果表明:热压烧结纳米Y-TZP材料有一些新的特点,主要是纳米Y-TZP材料在热压烧结时,由于软团聚未能有效地破碎;造成烧结过程中团聚体内部首先致密化,与基体之间产生张力,导致裂纹状大气孔的出现.同时因石墨模具的限制,热压时的外压不足以克服塑性滑移产生所需的“阈值”,因此大气孔无法“压碎”,使材料的烧结密度比相同温度下无压烧结还低.针对热压烧结纳米Y-TZP材料的局限性,采用热煅压烧结,可在1100℃的低温下获得致密的纳米Y-TZP材料,晶粒大小仅85nm左右。 相似文献
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Hwan-Cheol Kim In-Jin Shon In-Kyoon Jeong In-Yong Ko Z. A. Munir 《Journal of Materials Science》2007,42(22):9409-9414
High-frequency induction heated sintering (HFIHS) is utilized to consolidate ultra-fine grain tetragonal zirconia stabilized
with 3 mol%Y2O3 (3Y-SZ) ceramics. Densification to near theoretical density in a relatively short time can be accomplished using this method.
Samples of 3Y-SZ with a relative density of up to 99.5% and an average grain size of about 170 nm could be obtained by sintering
at 950 °C for 5 min under a pressure of 100 MPa pressure. The influence of sintering temperature and mechanical pressure on
the final density and grain size of the sintered products was investigated. The sintered materials had fracture toughness
and hardness values of 4.4 MPa m1/2 and 10.7 GPa, respectively. 相似文献
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Eduardo J. Gonzalez Bernard Hockey Gasper J. Piermarini 《Materials and Manufacturing Processes》1996,11(6):951-967
The effects of pressure on the compaction and subsequent sintering of nano-size Y- γ-Al2O3 powder were studied. Pressures up to 5 GPa were used to compact the powder in a WC piston/cylinder type die and also in a diamond anvil cell. The green body compacts obtained from both methods of compaction were pressureless sintered at temperatures between 1000°C to 1600°C. Results demonstrated that green body density was enhanced with increased compaction pressure. For compaction pressures less than 3 GPa, microstructures containing significant porosity developed at all sintering temperatures studied and is due to the development of a highly porous or vermicular structure during the y too phase transformation, occurring at temperatures between 1000°C and I I50°C. At compaction pressures greater than 3 GPa, however, the formation of the vermicular structure did not occur and near theoretical densities with grain size = 150 nm were obtained. 相似文献
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以D50为0.171μm和0.432μm的α氧化铝粉为原料,采用不同的成型压力制得生坯,并在1450℃进行烧结,研究了粉体粒径和成型压力对α氧化铝粉体烧结行为的影响.D50为0.432μm的粉体,烧结活性较差,成型压力从100 MPa提升到300 MPa,生坯相对密度从54.1%增加到56.6%,烧结体相对密度从93.2%增加到94.9%.D50为0.171μm的粉体,烧结活性较好,成型压力从100 MPa提升到300 MPa,生坯相对密度从51.3%增加到53.8%,但烧结体密度始终在98.6%~98.8%之间,并未产生大的变化.结果表明,提升成型压力对Al2O3粉体烧结行为影响有限,减小粉体粒径、提高粉体烧结活性,才是提高Al2O3陶瓷密度、降低烧结温度的关键. 相似文献
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Jiang L Liao Y Wan Q Li W 《Journal of materials science. Materials in medicine》2011,22(11):2429-2435
The aim of this study was to evaluate the effects of sintering temperature and particle size on the translucency of yttrium
stabilized tetragonal zirconia polycrystals (Y-TZP) dental ceramic. Eighty disc-shaped and cylindrical specimens were fabricated
from zirconia powers of particle size 40 and 90 nm. These specimens were sintered densely at the final sintering temperature
1350, 1400, 1450 and 1500°C, respectively. The visible light transmittance, sintered density and microstructure of the sintered
block were examined. The results showed that the sintered densities and transmittances increased with the temperature from
1,350 to 1,500°C. Y-TZP could gain nearly full density and about 17–18% transmittance at the final sintering temperature of
1,450–1,500°C. The 40-nm powders had higher sintered density and transmittance than the 90-nm. The translucency of Y-TZP dental
ceramic could be improved by controlling the final sintering temperature and primary particle size. 相似文献
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预热粉体爆炸烧结单相纳米氧化铝陶瓷的研究 总被引:13,自引:1,他引:12
采用预热粉体爆炸烧结技术制备单相纳米陶瓷,用40nm的α-Al2O3粉体作原料进行烧结试验,用高倍扫描电镜,X射线衍射分析等手段对试验结果进行了测试。最近的研究表明:纳米粉体分别经600-800度预热后进行爆炸烧结,可以得到密度为96-100%理论密度,晶粒大小在100nm以下的单相氧化铝纳米陶瓷,随着预热温度的递增,陶瓷晶粒生长有加快趋势,与常温下爆炸烧结相比,本研究的陶瓷晶粒无明显晶格变形,对陶瓷质量的影响因素及其改善途径也进行了分析。 相似文献