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在对有机物中微量砷测定方法综合分析的基础上,选用了砷斑法与Ag-DDTC法相结合的方法检测有机物中的微量砷。重点对Ag-DDTC法的操作内容作了两处改进。实验表明,新方法检测有机物中的微量砷快速,准确。 相似文献
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本文在对有机物中微量砷测定方法综合分析的基础上,选用了砷斑法与Ag-DDTC法相结合的方法检测有机物中的微量砷,重点对Ag-DDTC法的操作内容作了两处改进,并做了对比实验,实验表明,本文设计的砷斑法与Ag-DDTC法相结合的方法检测有机物中的微量砷是一种快速,准确的分析方法,目前,在我国有推广意义。 相似文献
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电感耦合等离子体发射光谱法测定高纯磷中微量砷 总被引:7,自引:1,他引:6
研究了ICP-AES法测定高纯磷中的微量砷,实验结果表明,该法回收率为94.9%~101.5%,分析精密度(n=9)RSD%<2.0%,方法快速、准确度好。 相似文献
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研究测定磷矿石中微量砷的新方法,以硝酸银—乙酸—聚乙烯醇(PVA)—乙醇作为砷化氢吸收液,Zn-KI-SnCl2为还原体系的新银盐光度法测定砷。As3+质量浓度在0~7.5μg/5ml范围内服从Beer定律。方法回收率为96%~100.5%,分析含砷1.60×10-3%,RSD为1.23%,方法检出限为1.9×10-6g/L。 相似文献
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特纯五硫化二砷的制备韩汉民(安徽师范大学芜湖市241000)1前言特纯As_2S_5应用于科学技术的许多部门 ̄[1],而我国目前市售的As_2S_5最高纯度仅为98.0% ̄[2],因此,特纯As_2S_5的制备具有很强的实际意义。As_2S_5的制备... 相似文献
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CALIXE[4]ARENE AS A TEMPLATE FOR CONTROLLING REGIOCHEMISTRY OF PHOTODIMERIZATION OF 9-SUBSTITUTED AN
《感光科学与光化学》1995,(2)
CALIXE[4]ARENEASATEMPLATEFORCONTROLLINGREGIOCHEMISTRYOFPHOTODIMERIZATIONOF9-SUBSTITUTEDANTHRACENELIYI;TONGZHEN-HE(CHEN-HOTUNG... 相似文献
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本文在碱性介质中,研究了PMT(1-苯基-5-巯基四氮唑)存在时胶态金催化Co(NH_3)_6Cl_3氧化对苯二胺彩显剂(PPD)的动力学,反应跟踪是通过可见紫外分光光度计监测PPD的完全氧化产物,QDI的显色反应来进行的。结果表明,在pH为10.20,且胶态金的初始浓度一定时,PMT对反应初始速率有较大的影响:PMT的初始浓度[PMT]。较小时,对反应有抑制作用:而[PMT]。较大时,对反应有促进作用。通过在无PMT、低[PMT]。高[PMT]。时对上述反应动力学的测定,我们推测PMT对反应的抑制-促进作用是由于PMT在胶态金上吸附状态的变化造成的。实验表明,当胶态金的初始浓度一定时,PMT对[Co(NH_3)_5Cl]Cl_2氧化PPD的反应也有类似作用。 相似文献
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化妆品中微量铅、砷的极谱连续测定蔡卓,黄孚畅(广西大学化学系南宁530004)化妆品中有害元素铅、砷含量的高低,直接影响消费者的健康,对其进行检测十分必要。目前测定化妆品中微量铅的方法主要有双硫腙比色法和原子吸收光谱法 ̄[1]。双硫腙比色法所需试剂毒... 相似文献
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Groundwater in the area of eastern Croatia contains high concentrations of iron, manganese, ammonia, organic substances and arsenic. The appearance of inorganic arsenic in groundwater is mainly caused by arsenic from natural geological sources. Since the groundwater is the main source of drinking water for the population in this area, almost 200,000 people are daily drinking water with arsenic concentration ranging from 10 to 610 μg/L. The Croatian legislation recently revised the maximum concentration limit (MCL) for arsenic in drinking water to 10 μg/L. The population in the two towns (Osijek and Vinkovci) of this region is supplied with groundwater processed by coagulation-filtration method, but in the other towns and villages water treatment implies only rapid sand filtration. Both methods for water treatment have resulted with higher arsenic concentration than MCL, so the main goal of this study was determination of population exposure to arsenic via drinking water and possible improvement of drinking water quality. Population exposure to arsenic via drinking water is determined with hair analysis, since the hair arsenic concentration is one of three most commonly employed biomarkers used to identify or quantify overall arsenic exposure. During this study the preliminary analyses of hair arsenic concentrations in several towns and villages in eastern Croatia were provided. The positive correlation between heightened arsenic concentration in drinking water and hair arsenic concentration was determined. In order to improve drinking water quality e.g. arsenic removal from contaminated drinking water, different modified adsorbents were used and compared (zeolite–clinoptilolite, manganese greensand and cationic exchange resin). Adsorbents were chemically modified and saturated with Fe(III) ions, while the arsenic solutions were prepared by processed groundwater. 相似文献
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Mg-enriched kaolinite-bentonite ceramics prepared in this work exhibited very porous and non-uniform structures, with grain sizes ranging from 1 to 20 µm. During the interaction of this ceramics with aqueous solutions of Na2HAsO4·7H2O, it was observed that the concentrations of Na, K, Ca and Mg in the ceramics and arsenic concentration in the solution decrease. These changes of metals concentrations in the ceramics and arsenic concentrations in water solutions appear to be on the account of arsenic deposition into the ceramics surface. The interaction of the ceramic samples prepared at 600 °C and 800 °C with used arsenic aqueous solutions reduced their arsenic concentration about 70-90%. 相似文献
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在氢氧化钠-硼砂的底液体系中对金矿石进行极谱测定,在峰电位-0.35 V,砷的质量浓度在2~400μg/mL之间时砷的浓度与峰电流成线性关系。选用含有甘露醇的氢氧化钠硼砂的底液测定砷,精度好,准确度高,检出限为0.002μg/mL。 相似文献
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Arsenic emissions are currently considered to be one of foremost importance. Arsenic volatility is higher than most of trace elements, but its vaporization behaviour is strongly dependent on the atmosphere composition. In this sense, thermodynamic equilibrium calculations, using HSC-Chemistry 5.0 software, were performed to evaluate the influence of different compounds in the distribution and mode of occurrence of arsenic in co-combustion processes. The influence of different parameters influencing arsenic behaviour, such as temperature, pressure, trace element concentration and flue gas composition on equilibrium composition were also evaluated. Predicting arsenic species, based on combustion conditions and fuel composition, will be useful to choose the best available control technology to reduce arsenic emissions. Finally, the possible interactions between arsenic and different trace elements (TE), mercury, cadmium and antimony, relevant from an environmental point of view, have also been studied; these interactions are not usually considered in thermodynamic studies; however, TE’s interactions affects the behaviour of a single TE, not only as a result of the formation of new species, but also, because of the different reactivity of TEs towards different elements which may affect TE’s volatilization behaviours. From results obtained in this study it may be concluded that in most cases, arsenic is mainly captured in ashes as a result of the formation of thermally stable species both from interactions with bulk ash and TE’s interactions. Nevertheless, the presence of some compounds (silicon, chlorine and sulphur) may enhance arsenic volatilization. 相似文献
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Ming-Cheng Shih 《Desalination》2005,172(1):85-97
Management of hazardous wastes, such as arsenic, is one of major public concern. Arsenic is a naturally occurring metalloid, which is widely distributed in nature. Recently, arsenic in drinking water attracted attention because some of the drinking water resources contain considerable concentrations of arsenic which cause acute; and chronic symptoms in many countries, especially in Bangladesh, China, Mongolia, and Taiwan. In 2001, the USEPA promulgated a rule lowering the arsenic MCL from 5 μgL−1 to 10 μgL−1. This paper offers an overview of geochemistry, distribution, sources, regulations, acute and chronic symptoms, and applications of membrane technologies in the water treatment research that have already been realized or that are suggested on the basis of bench or lab scale research. These membrane technologies include RO, NF, UF, and MF. Most of theses applications have proven to be reliable in removing arsenic from water. The possible influence of some source water parameters, membrane material, membrane types, membrane processes on arsenic removal efficiency by membrane technologies are also explored. This review paper also offers data relating to regulations of arsenic standard, acute and chronic symptoms that are caused by the exposure of arsenic to explain why water treatments need to use the membrane technology to meet the MCL standard. 相似文献
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Effect of operating conditions in removal of arsenic from water by nanofiltration membrane 总被引:2,自引:0,他引:2
The removal of arsenic from synthetic waters and surface water by nanofiltration (NF) membrane was investigated. In synthetic solutions, arsenic rejection experiments included variation of arsenic retentate concentration, transmembrane pressure, crossflow velocity and temperature. Arsenic rejection increased with arsenic retentate concentration. Arsenic was removed 93-99% from synthetic feed waters containing between 100 and 382 μg/L as V, resulting in permeate arsenic concentrations of about 5 μg/L. Under studied conditions, arsenic rejection was independent of transmembrane pressure, crossflow velocity and temperature. In surface water, the mean rejection of As V was 95% while the rejection of sulfate was 97%. The co-occurrence of dissolved inorganics does not significantly influence arsenic rejection. The mean concentration of As in collected permeated was 8 μg/L. The mean rejection of TDS, total hardness and conductivity were 75, 88 and 75% respectively. 相似文献