Field‐induced photo‐reactive alignment technology for the vertical‐alignment liquid‐crystal mode

Abstract— An advanced vertical‐alignment liquid‐crystal (VA‐LC) technology based on field‐induced photo‐reactive alignment (FPA) as an advanced alignment mode for VA is proposed. FPA realizes uniform alignment and a faster rising response time, especially at high voltage. This technology can generate a pre‐tilt angle only by using photo‐reactive alignment material so that the tact time is shorter and the long‐term reliability is higher than that of conventional photo‐reactive processes, which require additional photo‐reactive monomers. The advanced hybrid FPA was developed by adopting both the tilted alignment with a pre‐tilt angle and conventional vertical alignment. By using an advanced hybrid structure, the response time and contrast ratio can be further improved.     

EO characteristics for a photoaligned VA‐1/4 π cell on a photopolymer layer

The generation of a liquid‐crystal (LC) tilt angle on a copolymer with chalconyl and cholesteryl moiety characteristics was performed, and the electro‐optical (EO) performance of the photoaligned vertical‐alignment (VA) 1/4 π cell by polarized UV exposure on a homeotropic photopolymer surfaces was studied. The LC tilt angles decreased as UV exposure time increased on the copolymer surfaces. A tilt angle of 87° in NLC was observed with an UV exposure of 3 min on the photoalignment‐2 surface. The LC tilt angle is attributed to increased chalcone moiety with increasing UV exposure time. Excellent voltage‐transmittance (V‐T) curves of the photoaligned VA 1/4 π cell by polarized UV exposure on the photopolymer surface for 3 min containing a cholesteryl moiety of 8% were obtained. The V‐T and response‐time characteristics can be improved by the presence of a cholesteryl moiety in the photopolymer.     

Review Paper: Emerging vertical‐alignment liquid‐crystal technology associated with surface modification using UV‐curable monomer

Abstract— The recent development of polymer‐induced pretilt angle in multi‐domain vertical‐alignment liquid‐crystal (LC) structures is reviewed. To create a small but well‐defined pretilt angle, ～0.1 wt.% of a photo‐curable monomer was mixed in an LC host and a bias voltage was applied to reorient the LC directors within each domain. The monomers are polymerized near the substrate surfaces by UV exposure. The formed polymer layers change the surface pretilt angle of the LC from 90° to about 89° with a defined azimuthal orientation. Consequently, within each domain the LC reorientation direction responding to the external field is well‐defined which leads to faster rise time and higher transmittance. This new technology overcomes the long standing problems of conventional MVA devices and is therefore expected to play a dominant role in the future.     

Polymer‐stabilized pretilt angle on the surface of nanoparticle‐induced vertical‐alignment surface for multi‐domain vertical‐alignment liquid‐crystal display

Abstract— By introducing polyhedral oligomeric silsesquioxane (POSS) nanoparticles along with a controlled amount of UV‐curable reactive mesogen (RM) into a liquid‐crystalline (LC) medium, a multi‐domain vertical‐alignment LC device was successfully demonstrated. The device, possessing a vertically aligned LC director in four different azimuthal directions, exhibited a fast response time and wide‐viewing‐angle characteristics, in the absence of conventional polymer‐type vertical‐alignment layers. Electro‐optic characteristics of the fabricated device, before and after UV curing of the cell, were studied. The surface morphology of the substrate surfaces were analyzed by using field‐emission scanning electron microscopy (FESEM). The experimental results show that the technology will possibly be applicable to cost‐effective vertical‐alignment liquid‐crystal devices and is suitable for green‐technology liquid‐crystal displays.     

Local dimming light‐guiding plate type backlight system using alignment‐controlled polymer‐dispersed liquid crystals

A new technology which enables a local brightness control according to the displayed images has been expected in the thin and lightweight backlight systems to improve a contrast ratio and power consumption of the liquid crystal displays (LCDs). In this paper, we have proposed a novel local‐dimming backlight system using alignment‐controlled polymer‐dispersed liquid crystals as a light‐guiding plate and investigated the forming conditions of polymer‐dispersed liquid crystals to achieve both a high‐luminance ratio and a fast response speed. As a result, we found that a luminance ratio and response speed of the backlight system can be improved by using bifunctional LC monomer materials and forming fine and rigid polymer network in the LCs, and achieved high luminance ratio of 16:1 and fast response time less than 0.5 ms. In addition, we fabricated the twisted nematic‐mode LCD using the local dimming light‐guiding plate‐type backlight based on this design, and successfully realized eight times higher contrast ratio than that of the traditional twisted nematic‐mode LCD.     

Frictional properties of VA‐mode alignment‐film surfaces studied by frictional force microscopy

Abstract— The surface‐friction characteristics of the post‐bake temperature were compared to that of the rubbing condition on VA‐mode alignment films (AFs) using frictional force microscopy (FFM). The surface roughness and the surface frictional force increased when the temperature was elevated. However, the frictional asymmetry could not be detected by the frictional loop due to the instability of the side‐chain molecular arrangement. For the inter‐influences of the total friction and surface roughness, the density of the side chain was changed and it was intentionally rubbed for evaluation. The results showed that the total friction was higher when the rubbing was stronger and side‐chain density lower, and the surface roughness also increased in the same manner. This can be explained by the potential interaction due to the curved structure of the side‐chain surface that establishes the probe that is scanned and the top surface layer. In order to confirm the influence of the pre‐tilt angle on the tilt of the side chain, a test cell was produced under the same conditions and evaluated. The results showed that the pre‐tilt‐angle decreased according to the difference in density of the side chain and strength of rubbing after injecting liquid‐crystal (LC).     

A novel polarizer‐free dye‐doped polymer‐dispersed liquid crystal for reflective TFT displays

Abstract— A novel preparation method for dichroic dye‐doped polymer‐dispersed liquid crystals has been developed. This was achieved by creating a porous polymer matrix first by washing out the liquid crystal from a polymer‐dispersed liquid crystal (PDLC), which is then refilled with dye‐doped liquid crystal. Optimizing the liquid crystal used in the refilling results in decreased turn‐on voltage and faster response time. Poster‐standard reflectivity and newspaper‐standard contrast was demonstrated with a 3.8‐in. QVGA reflective TFT display with a drive voltage of 10 V.     

Simulation and fabrication of a fast fringe‐field switching liquid crystal with enhanced surface anchoring enabled by controlled polymer topology

We demonstrate a fringe‐field switching nematic liquid crystal with electro‐optical behavior modulated by both bulk and surface polymer stabilization. The polymer is formed by ultraviolet irradiation‐induced phase separation of various amounts of a reactive monomer in the planar‐aligned nematic liquid crystal. Simulation is carried out to verify the effect of anchoring energy. Experimental evidence validates the effect of monomer concentration on transmittance–voltage and response times curves of fringe‐field switching cells. The polymer‐stabilized alignment with a higher polymer concentration escalates the interaction between the liquid crystal and the polymer structure and increases the surface anchoring energy. The polymer stabilization also improves the dynamic response times of liquid crystal. The enabling polymer‐stabilized alignment technique has excellent electro‐optical properties such as a very good dark state, high optical contrast, and fast rise and decay times that may lead to development of a wide range of applications.     

Medical displays by using plasma‐beam‐alignment technology

Abstract— Novel anode layer plasma within minimum chamber space was developed for non‐contact alignment process. The plasma‐treated polyimide (PI) surface showed no particle contamination and no micro‐scratches. Surface morphology was investigated by using scanning electron microscope (SEM), an atomic force microscope (AFM), and X‐ray photoemission spectroscopy. The different oxygen‐to‐carbon ratio ([O]/[C] ratio) for XPS spectra indicated a composition change after plasma treatment. Surface pretilt angles were varied from 0 to 2.1° under different plasma exposure times. Finally, a prototype 20.8‐in. QXGA IPS‐mode gray‐scale medical liquid‐crystal display was successfully demonstrated with high contrast ratio, excellent uniformity, and wide viewing angle using this new plasma‐beam‐alignment technique.     

Azo‐dye aligning layers for liquid‐crystal cells

Abstract— The photo‐induced alignment of liquid crystal onto a photochemical stable azo‐dye film was studied for liquid‐crystal display (LCD) applications. The photo‐aligning of azo dye takes place due to the pure reorientation of the molecular absorption oscillators perpendicular to the UV‐light polarization. The order parameters S = ?0.4 (80% of the maximum absolute value S_m = ?0.5) was measured at a wavelength of 372 nm from the polarized absorption spectra. The temperature‐stable pretilt angle of 5.3° was obtained by a two‐step exposure of azo‐dye film using normally incident polarized light followed by oblique non‐polarized light. The azimuthal anchoring energy of the photo‐aligned substrate was A_? > 10^?4 J/m², which is of the same magnitude as the anchoring of the rubbed PI layer. The VHR value of the photo‐aligned LC cell was also found to be very high (98–99%) at room temperature and more than 95% at T=80°C. The thermal stability of the photo‐aligned azo‐dye layers is sufficiently high, while UV stability has to be improved, _e.g., by polymerization. The new LCD aligning technology based on photochemical stable azo‐dye layers is envisaged.     

Fast switching and high‐contrast polymer‐stabilized IPS liquid crystal display

We demonstrated that polymer stabilization can significantly improve the response time of in‐plane‐switching liquid crystal display. We carried out a systematic study of the effect of polymer networks on the performance of in‐plane‐switching liquid crystal display. The polymer network has a strong aligning effect on the liquid crystal and has the advantage of reducing the switching time of the display but may have the disadvantage of ruining the contrast ratio because of its scattering effect. Through optimization, we successfully improve the switching time (less than 6 ms) and reduce the scattering and thus retain high contrast ratio (higher than 1000:1).     

A reflective polarizer‐free display using dye‐doped polymer‐stabilized blue‐phase liquid crystals

Abstract— A reflective polarizer‐free display using dye‐doped polymer‐stabilized blue‐phase liquid crystal (DDPSBP‐LC) has been demonstrated. The mechanism is a combination of electrically tunable light absorption and Bragg reflection. In this paper, the influence of light absorption in DDPSBP‐LC by changing the dye concentration and absorption paths has been studied. Increased dye concentration can improve the contrast ratio of DDPSBP‐LC; however, the response time is the tradeoff. Increasing the cell gap can improve the contrast ratio of DDPSBP‐LC; however, the response time remains the same. The study of DDPSBP‐LC can help in shutter‐glass applications of 3‐D displays and electronic paper.     

Properties of azo‐dye alignment layer on plastic substrates

Abstract— The alignment properties of the azo‐dye photo‐alignment material SD‐1/SDA‐2 on plastic substrates are investigated. Important liquid‐crystal cell parameters, such as azimuthal and polar anchoring energy, pretilt angle, voltage holding ratio, and the corresponding electro‐optical properties are presented. Excellent alignment with high anchoring energy can be achieved with a polarized UV dose less than 1.0 J/cm². A reflective six‐digit flexible passive‐matrix‐driven TN‐LCD for smart‐card applications showing excellent electro‐optical properties is demonstrated.     

A 15‐in. XGA thresholdless antiferroelectric LCD addressed by TFTs and using the quasi‐dc driving method

Abstract— A 15‐in. TFT‐LCD with XGA resolution using thresholdless antiferroelectric liquid crystal (TLAF) has been developed. TLAF materials show V‐shaped switching and enable display of analog gray scale, wide viewing angle, and fast response. However, in the case that high‐resolution TFT‐LCDs using materials with large spontaneous polarization such as TLAF were driven by the conventional method, alternating current (ac) driving, the obtained contrast ratio was limited because of a sharp decline of holding voltage due to the growth of a depolarization field. In order to enhance the contrast ratio, a novel driving method referred to as quasi‐dc driving was proposed. In the quasi‐dc driving, the polarity of the applied voltage to liquid crystals inverts at certain intervals of several seconds. Moreover, the applied voltage and the charging time at the time of polarity inversion are increased more than the intended signals. By this method, the 15‐in. TFT‐LCD using TLAF with high contrast ratio (more than 100:1) and wide viewing angle was realized.     

Ultra‐FFS TFT‐LCD with super image quality,fast response time,and strong pressure‐resistant characteristics

Fringe‐field‐switching (FFS) devices using liquid‐crystal (LC) with a negative dielectric anisotropy exhibit high transmittance and wide viewing angle simultaneously. Recently, we have developed an “Ultra‐FFS” thin‐film‐transistor (TFT) LCD using LC with a positive dielectric anisotropy that exhibits high transmittance, is color‐shift free, has a high‐contrast ratio in a wide range, experiences no crosstalk and has a fast response time of 25 msec. In this paper, the device concept is discussed, and, in addition, the pressure‐resistant characteristics of the devices compared with that of the twisted‐nematic (TN) LCD is discussed.     

Low voltage fast response display using dual π‐cells with quarter‐wave thickness

In this paper, a design for a fast response display consisting of dual π‐cells is investigated. The thickness of each liquid crystal cell layer is only half of a single LC cell device with the same retardation change, which results in about one quarter of the response time for a single π‐cell device. While this result is obviously anticipated, an additional advantage is that a good viewing angle can be achieved by using negative C plates, which allows a lower cost device with a more uniform black state across the area of the display than the case of a single cell compensated by a discotic compensator. We also propose a solution to solve parallax issue from two‐layer structure of liquid crystal cell, and it opens a window of opportunity for a device with two‐layer structure.     

Moving‐image‐sticking phenomenon induced by an outside force in liquid‐crystal displays

Abstract— Image deformation caused by an outside force is observed to remain for hours at high gray levels for liquid‐crystal displays (LCDs) in the multi‐domain (MD) vertical‐alignment (VA) mode. This so‐called moving‐image‐sticking phenomenon demonstrated a non‐symmetric luminance profile for the left and right viewing direction for MDVA‐mode LCDs which have original symmetric viewing‐angle characteristics. The generation of a stable reverse‐tilt domain by an outside force was assumed to be the cause of this phenomenon, and the stability of a reverse‐tilt domain under an electric fringe field was calculated by changing the electric‐fringe‐field distribution which determines the LC tilt direction. The domain of a given tilt direction is calculated to change to other tilt direction induced by a fringe field at a low gray condition, but to remain unchanged at a high gray condition. This agrees with the observed trends of duration time of the moving‐image‐sticking phenomenon.     

Fast‐response nematic liquid‐crystal mixtures

Abstract— High birefringence and relatively low‐viscosity isothiocyanate‐based liquid‐crystal compounds and mixtures were developed. A high figure‐of‐merit (FoM), which implies a fast response time of the described liquid crystals was observed. Using the new UCF mixture in a 2‐μm cell, a submillisecond response time was obtained. The UV stability dilemma is discussed as a common concern for high‐birefringence LC materials.     

Switchable transmissive and reflective liquid‐crystal display using a multi‐domain vertical alignment

Abstract— A wide‐view transflective liquid‐crystal display (LCD) capable of switching between transmissive and reflective modes in response to different ambient‐light conditions is proposed. This transflective LCD adopts a single‐cell‐gap multi‐domain vertical‐alignment (MVA) cell that exhibits high contrast ratio, wide‐viewing angle, and good light transmittance (T) and reflectance (R). Under proper cell optimization, a good match between the VT and VR curves can also be obtained for single‐gamma‐curve driving.     

Optimization of photo‐aligned ferroelectric liquid‐crystal display under passively addressed driving

Abstract— A ferroelectric liquid‐crystal (FLC) passively addressed 64 × 64 display based on the photo‐alignment technique has been developed. The display matrix has dimensions of 33 × 33 mm², and the FLC layer thickness is about 5 μm. Asymmetric boundary conditions, when only one of ITO surfaces of the display matrix is covered with the photo‐aligning layer while another one is not, have been used for providing both high contrast ratio and steady multiplex operation. The electro‐optical performance of the 5‐μm FLC display is presented, including bistable switching in static operation, optimization in multiplexing operation, and gray‐scale generation.