Electric field-enhanced metal-induced lateral crystallization and P-channel poly-Si TFTs fabricated by it

The poly-Si thin film was obtained by electric field-enhanced metal-induced lateral crystallization technique at low temperature. Raman spectra, X-ray diffraction (XRD) and scan electron microscope (SEM) were used to analyze the crystallization state, crystal structure and surface morphology of the poly-Si thin film. Results show that the poly-Si has good crystallinity, and the electric field has the effect of enhancing the crystallization when DC electric voltage is added to the film during annealing. Secondary ion mass spectroscopy (SIMS) shows that the metal Ni improves the crystallization by diffusing into the a-Si thin film, so the crystallization of the lateral diffused region of Ni is the best. The p-channel poly-Si thin film transistors (TFTs) were fabricated by this large-size grain technique. The I_DS−V_DS and the transfer characteristics of the TFTs were measured, from which, the hole mobility of TFTs was 65 cm²/V s, the on and off current ratio was 5×10⁶. It is a promising method to fabricate high-performance poly-Si TFTs at low temperature for applications in AMLCD and AMOLED.     

镍硅化物诱导横向晶化制备高性能多晶硅薄膜晶体管

提出一种新的采用镍硅化物作为种子诱导横向晶化制备低温多晶硅薄膜晶体管的方法。分别采用微区Raman、原子力显微镜和俄歇电子能谱对制备的多晶硅薄膜进行结构和性能表征,并以此多晶硅薄膜为有源层制备了薄膜晶体管,测试其I-V转移特性。测试结果显示,制备的多晶硅薄膜具有较低的金属污染和较大的晶粒尺寸,且制备的多晶硅薄膜晶体管具有良好的电学特性,可以有效地减小漏电流,同时可提高场效应载流子迁移率。这主要是由于多晶硅沟道区中镍含量的有效降低使得俘获态密度减少。     

多晶硅薄膜的两步激光晶化技术

采用两步激光晶化技术获得了多晶硅薄膜，分析计算了激光晶化时薄膜中的温度分布及表面温度与激光功率密度的关系，利用计算结果并优化了激光晶化时的工艺参数，采用该技术制备了性能优良的顶栅多晶硅薄膜晶体管，测量了薄膜晶体管的转移特性与输入输出特性，从多晶硅薄膜的制备工艺上分析了提高薄膜晶体管性能的原因。     

Improving hydrogenation efficiency of polycrystalline silicon thin film transistors by a new approach

In this paper, a new hydrogenation process of poly-Si thin film for the fabrication of poly-Si thin film transistors (TFTs) is proposed. In the new approach, the hydrogenation of TFTs is performed before deposition of contact metal. N-channel and p-channel poly-Si TFTs with various channel lengths and widths were fabricated with the new and conventional processes for comparison. The results verified that the efficiency of hydrogenation has been improved remarkably by the new process. The field-effect mobility of carriers, the on state current, threshold voltage and the on/off states current ratio have been greatly improved, and the trap state density has been reduced significantly.     

多晶硅薄膜的等离子氢化新工艺

根据多晶硅薄膜氢化的微观机理,提出改进氢化效果的工艺方法。在不增加设备投资的情况下,采用该方法能够明显提高多晶硅薄膜的氢化效果,从而提高薄膜晶体管的性能,ＩＯＮ／ＩＯＦＦ从１０＾３量级增加到１０＾５量级,氢化工艺的处理时间也相应缩短。     

多晶硅薄膜的新型激光晶化制备方法

采用两步激光晶化方法制备了多晶硅薄膜 ,其晶粒尺寸为 1.1μm,比用传统单步晶化制备的薄膜晶粒尺寸大 ,表明该方法对扩大晶粒尺寸很有效。拉曼光谱分析表明 0 .30 J/ cm2晶化的薄膜结晶程度已很高     

准分子激光晶化制备TFT多晶硅薄膜的研究进展

对准分子激光晶化制备TFT用多晶硅薄膜的研究进展进行了综述。介绍了晶化过程中的超级横向生长现象。主要结合各种基于光束调制和光刻技术的人工控制超级横向生长方法,讨论了获得大晶粒尺寸优质多晶硅薄膜的途径。     

High-quality polycrystalline Si TFTs fabricated on stainless-steelfoils by using sputtered Si films

We have developed a low-temperature fabrication process (⩽ 200°C for high-quality polycrystalline Si thin-film transistors (poly-Si TFTs) on flexible stainless-steel foils. The fabrication processes is realized through sputter deposition of thin films, including active-Si and gate-SiO₂ films, crystallization of Si films by KrF excimer laser irradiation, and inductively coupled plasma hydrogenation. High-quality n- and p-channel poly-Si TFTs are successfully fabricated without suffering from problems of substrate bending, film ablation, or cracking in films. The resulting n- and p-channel poly-Si TFTs showed mobilities of 106 and 122 cm²/V·s, respectively. This paper describes the deposition and properties of the sputtered Si films and the fabrication process and electrical characteristics of the poly-SiTFTs     

自缓释镍源的横向诱导晶化多晶硅薄膜晶体管

以镍硅合金靶作为溅射源,采用磁控溅射方法制备了一种自缓释镍源. 控制合适的自缓释镍源的准备条件,以单一方向横向晶化条件对非晶硅薄膜进行再晶化,可以获得低残余镍含量、大晶粒、高薄膜质量的多晶硅. 以此多晶硅为有源层进行了薄膜晶体管研究. 制备的p型TFT器件具有良好的特性,可有效地减小漏电流,同时具有很好的均匀性和稳定性.     

A new polycrystalline silicon TFT with a single grain boundary inthe channel

A new excimer laser annealing method, which results in large lateral polysilicon grains exceeding 1.5 μm, has been proposed and polycrystalline silicon thin film transistors (poly-Si TFTs) with a single grain boundary in the channel have been successfully fabricated. The proposed method employs a lateral grain growth phenomenon obtained by excimer laser irradiation on an amorphous silicon layer with pre-patterned aluminum film. The aluminum patterns act as a masking layer of the incident laser beam for the selective melting of the amorphous silicon layer. Uniform and large grains are obtained near the edge of the aluminum patterns. When two aluminum patterns are separated by a 2 μm space, the solidified region (i.e., poly-Si channel) exhibits a single grain boundary. The n-channel poly-Si TPT fabricated by the proposed method shows considerably improved I-V characteristics, such as high field effect mobility exceeding 240 cm²/Vs     

多晶硅薄膜晶体管的表面氮钝化技术

采用N2O和NH3等离子钝化技术对多晶硅薄膜表面和栅氧表面进行了钝化处理。实验结果表明,该技术能有效降低多晶硅薄膜的界面态密度,提高多晶硅薄膜晶体管性能,二次离子质谱分析表明在p-Si/SiO界面有氮原子富积,说明生成了强的Si-N键。     

A high-performance polycrystalline silicon thin film transistorwith a silicon nitride gate insulator

We have fabricated a high performance polycrystalline silicon (poly-Si) thin film transistor (TFT) with a silicon-nitride (SiN_x ) gate insulator using three stacked layers: very thin laser of hydrogenated amorphous silicon (a-Si:H), SiN_x and laser annealed poly-Si. After patterning thin a-Si:H/SiN_x layers, gate, and source/drain regions were ion-doped and then Ni layer was deposited. This structure was annealed at 250°C to form a NiSi silicide phase. The low resistive Ni silicides were introduced as gate/source/drain electrodes in order to reduce the process steps. The poly-Si with a grain size of 250 nm and low resistance n⁺ poly-Si for ohmic contact were introduced to achieve a high performance TFT. The fabricated poly-Si TFT exhibited a field effect mobility of 262 cm²/Vs and a threshold voltage of 1 V     

Hot carrier effects in polycrystalline silicon thin-film transistors: analysis of electrical characteristics and noise performance modifications

Hot-carrier effects on both the electrical characteristics and the noise performance in polycrystalline silicon thin film transistors are analysed. The devices were fabricated by using a combined solid phase crystallization (SPC) and excimer laser annealing (ELA) process, combining the beneficial aspects of the two techniques. Hot-carrier degradation results in the formation of both interface states, which have been evaluated through the analysis of the sheet conductance and of oxide traps near the insulator/semiconductor interface, as evidenced by the 1/f noise measurements. Oxide traps are calculated evaluating the flat band voltage spectral density associated with interface charge fluctuations in the damaged part of the interface. A strong correlation between interface state and oxide trap densities has been found, suggesting a common origin for the generation mechanism of the two types of defects.     

Fabrication of Poly—Si TFT by Al—induced Lateral Crystallization at Low Temperature

Using a new low-temperature process (<600 ℃), the poly-Si TFT was fabricated by metal-induced lateral crystallization (MILC). An ultrathin aluminum layer was deposited on a-Si film and selectively formed by photolithography. The films were then annealed at 560 ℃ to obtain laterally crystallized poly-Si film, which is used as the channel area of a TFT. The poly-Si TFT showed an on/off current ratio of higher than 1×10 6 at a drain voltage of 5 V. The electrical properties are much better than TFT fabricated by conventional crystallization at 600 ℃.     

Low temperature poly-Si thin-film transistor fabrication bymetal-induced lateral crystallization

A new low temperature crystallization method for poly-Si TFTs was developed: Metal-Induced Lateral Crystallization (MILC). The a-Si film in the channel area of a TFT was laterally crystallized from the source/drain area, on which an ultrathin nickel layer was deposited before annealing. The a-channel poly-Si TFTs fabricated at 500°C by MILC showed a mobility of 121 cm²/V·s, a threshold voltage of 1.2 V, and an on/off current ratio of higher than 10⁶ . These electrical properties are much better than TFTs fabricated by conventional crystallization at 600°C     

A high-performance polysilicon thin-film transistor using XeClexcimer laser crystallization of pre-patterned amorphous Si films

A high-performance polysilicon thin-film transistor (TFT) fabricated using XeCl excimer laser crystallization of pre-patterned amorphous Si films is presented. The enhanced TFT performance over previous reported results is attributed to pre-patterning before laser crystallization leading to enhanced lateral grain growth. Device performance has been systematically investigated as a function of the laser energy density, the repetition rate, and the number of laser shots. Under the optimal laser energy density, poly-Si TFT's fabricated using a simple low- temperature (⩽600°C) process have field-effect mobilities of 91 cm²/V·s (electrons) and 55 cm²/V·s (holes), and ON/OFF current ratios over 10 ⁷ at V_Ds=10 V. The excellent overall TFT performance is achieved without substrate heating during laser crystallization and without hydrogenation. The results also show that poly-Si TFT performance is not sensitive to the laser repetition rate and the number of laser shots above 10     

连续氩氪离子激光晶化非晶硅薄膜的研究

为了研究连续激光晶化非晶硅薄膜中激光功率密度对晶化效果的影响,利用磁控溅射法制备非晶硅薄膜,采用连续氩氪混合离子激光器对薄膜进行退火晶化,用显微喇曼光谱测试技术和场发射扫描电子显微镜研究了薄膜在5ms固定时间下不同激光功率密度对晶化效果的影响,并对比了普通玻璃片和石英玻璃两种衬底上薄膜晶化过程的差异。结果表明,在一定激光功率密度范围内(0kW/cm2~27.1kW/cm2),当激光功率密度大于15.1kW/cm2时,普通玻璃衬底沉积的非晶硅薄膜开始实现晶化;随着激光功率密度的增大,晶化效果先逐渐变好,之后变差;激光功率密度增大到24.9kW/cm2时,薄膜表面呈现大面积散落的苹果状多晶硅颗粒,晶粒截面尺寸高达478nm ;激光功率密度存在一个中间值,使得晶化效果达到最佳;石英衬底上沉积的非晶硅薄膜则呈现与前者不同的结晶生长过程,当激光功率密度为19.7kW/cm2时,薄膜表面呈现大晶粒尺寸的球形多晶硅颗粒,并且晶粒尺寸随着激光功率密度的增大而增大,在 27.1kW/cm2处晶粒尺寸达到最大5.38m。研究结果对用连续激光晶化法制备多晶硅薄膜的研究具有积极意义。     

High-mobility poly-Si thin-film transistors fabricated by a novelexcimer laser crystallization method

High-mobility poly-Si thin-film transistors (TFTs) were fabricated by a novel excimer laser crystallization method based on dual-beam irradiation. The new method can reduce the solidification velocity of the top Si layer by heating the bottom Si layer of the Si/SiO₂/Si/glass substrate structure by means of laser irradiation not only from the front side but also from the back side. The grain size of poly-Si film was enlarged up to 2 μm. The field-effect mobilities of the TFT exceeded 380 cm²/V-s for electrons and 100 cm²/V-s for holes     

The metal-induced crystallization of poly-Si and the mobility enhancement of thin film transistors fabricated on a glass substrate

In this study, we report on the fabrication of poly-crystalline silicon (poly-Si) using the metal-induced crystallization (MIC) method and its application to thin film transistors (TFTs). The top gate of the p-type TFTs, whose active layer used MIC poly-Si annealed for 1 h at 650 °C, showed a field effect mobility (μ_FE) of 7.5 cm²/V s. By increasing the crystallization time to 5 h, the quality of the MIC poly-Si was improved. The μ_FE increased from 7.5 to 15 cm²/V s. In order to enhance the channel mobility, the Si dangling bonds, which were produced during the transformation from the amorphous phase to the poly-crystalline phase of silicon (Si), were reduced by using plasma hydrogenation. Measurements show that the μ_FE reached 45 cm²/V s after passivation by an inductively coupled plasma chemical vapor deposition (ICPCVD) system.     

Microcrystalline Structure and Luminescence of ZnS Thin Films

The electroluminescence thin films doped with erbium, fabricated by thermal evaporation with two boats, are analyzed by X-ray diffraction(XRD).The relationship between electroluminescence brightness and microstructure of the thin films is obtained.The results reveal that the large grain size in high index plane of deposited microcrystalline film has an effect on electroluminescence characteristics of the film devices.