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核壳聚合物增韧环氧树脂的进展 总被引:7,自引:0,他引:7
核壳聚合物(CSP)现已用于增韧环境树脂,它具有许多优点:预先设计的CSP在环氧基体中的形态、大小和分散状态与固化规范无关;在提高环氧树脂韧性的同时不降低玻璃化温度。本文综述了CSP/环氧共混物的性能和增韧机理。主要的增韧机理是CSP粒子空穴化,释放裂缝附近的三轴度,继而产生膨胀形变和剪切屈服。 相似文献
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丙烯酸酯核壳纳米粒子的合成及其改性环氧树脂 总被引:5,自引:2,他引:3
以丙烯酸丁酯(BA)为软单体、甲基丙烯酸甲酯(MMA)为硬单体和甲基丙烯酸缩水甘油脂(GMA)为官能单体,采用乳液聚合法合成出具有活性结构的BA/MMA/GMA核壳纳米粒子,并以此作为环氧树脂(EP)的增韧改性剂。研究结果表明:当w(核壳粒子)=10%、m(BA):m(MMA):m(GMA)=80:20:10时,与纯EP体系相比,改性EP体系的断裂伸长率提高了42.5%,剥高强度提高了近3倍,25℃和150℃时的剪切强度分别提高了48.6%和31.2%,坡璃化转变温度变化不大;红外光谱(FT-IR)证实,该核壳纳米粒子具有典型的特征吸收峰;透射电镜(TEM)观察结果表明,合成粒子具有纳米级核壳结构。 相似文献
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核-壳弹性粒子改性E-44/DDM的研究 总被引:3,自引:0,他引:3
PBA/PMMA型复合粒了能有效地降低环氧E-4/DDM体系的内应力,提高力学性能。改性体系的分散相的尺寸由预制结构的复合粒子所控制。 相似文献
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用负离子聚合技术合成出聚丁二烯,将其乳化成核,再用乳液聚合法与甲基丙烯酸甲酯接枝,合成了以聚丁二烯为核,聚甲基丙烯酸甲酯为壳的核-壳结构聚合物粒子。 相似文献
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用负离子聚合技术合成聚丁二烯,将其乳化成核,再用乳液聚合法与甲基丙烯酸甲酸接枝,合成了以聚丁二烯为核,聚甲基丙烯酸甲酯为壳的核-壳结构聚合物粒子。 相似文献
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环氧树脂含量对氰酸酯热学性能的影响研究 总被引:1,自引:0,他引:1
采用示差扫描量热法(DSC)和热失重分析法(TGA)研究了环氧树脂含量对氰酸酯树脂固化反应特性、热稳定性以及热膨胀系数的影响。结果表明,环氧树脂的加入可有效降低改性体系的固化反应活化能,同时体系的热稳定性和尺寸稳定性有不同程度的削弱。当环氧树脂质量分数达到20%时,改性体系的表观活化能为65.4 kJ/mol,耐热温度指数为174℃,较纯氰酸酯树脂分别降低了25.8%和21.4%。当环氧树脂质量分数达到50%时,改性体系的热膨胀系数为65.3 922×10-6/℃(25~150℃),较纯氰酸酯树脂提高了8.13%。 相似文献
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The effective thermal conductivity, elastic modulus, and coefficient of thermal expansion of epoxy resins filled with ceramic fillers like silica, alumina, and aluminum nitride were determined. The data obtained was compared with theoretical and semitheoretical equations in the literature that are used to predict the properties of two phase mixtures. It was found that Agari's model provided a good estimate of the composite thermal conductivity. The Hashin‐Shtrikman lower bound for composite modulus fits the modulus data fairly well at low concentrations of the filler. Also, it was found that the coefficients of thermal expansion of the filled composites lie in between Schapery's upper and lower bounds. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 3396–3403, 1999 相似文献
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由于封装材料与电子元件线膨胀系数差异大,成型后造成开裂、空洞和离层等缺陷,采用化学固相分步法制备的高纯度负热膨胀材料钨酸锆(ZrW2O8)颗粒作为填料,制备ZrW2O8/E-51及SiO2/E-51电子封装材料,测试了不同种类和含量的填料下封装材料线膨胀系数、显微硬度、玻璃化转变温度及磨损性能。实验结果表明:随ZrW2O8含量的增加,ZrW2O8/E-51材料线膨胀系数不断下降,显微硬度不断提高。ZrW2O8/E-51材料的磨损性能优于SiO2/E-51材料,磨损机理主要是粘着磨损和疲劳剥落,后期发生了磨粒磨损。 相似文献
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Tatsuya Hirata Peng Li Fan Lei Spencer Hawkins Michael J. Mullins Hung-Jue Sue 《应用聚合物科学杂志》2019,136(26):47703
Control of the coefficient of thermal expansion (CTE) of polymeric materials is critical in many applications, particularly the electronics industry where CTE mismatches have caused failures. In theory, adding exfoliated nanoplatelets with high aspect ratios would offer an effective solution for reducing CTE, but reported results have not been compelling due to poor dispersion. In this study, α-zirconium phosphate (ZrP) nanoplatelets, along with organic surfactants, were added to epoxy thermosets. The CTE reduction and glass-transition temperature (Tg) were measured while the molecular weight of the surfactant was varied. High-molecular-weight surfactants are effective for ZrP exfoliation and dispersion, but they can also lead to a reduction in Tg and hinder the drop in CTE. A combination of two low-molecular-weight tetrabutylammonium hydroxide and 2-methoxyethylamine surfactants for exfoliation of ZrP were found to give a CTE reduction of 40% with just 3.5 vol % of ZrP added. This CTE reduction correlates well with theory. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47703. 相似文献
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A hydroxyl‐functionalized hyperbranched polymer (HBP, H30) is used to modify 4,4′‐diaminodiphenylsulfone‐cured bisphenol‐A type epoxy resin and a separate phase structure of modified epoxy resins is observed. The effects of the H30 second phase size on the mechanical properties of modified epoxy systems are investigated systematically. The dependence of the toughening mechanisms on the HBP particle size is reported for the first time. It is shown that the nanosized H30 second phase is superior over microsized counterparts in modifying brittle epoxy resin. The tensile strength is slightly enhanced by the introduction of nanosized H30 second phase, whereas the strength is significantly reduced by the addition of microsized H30 phase. The failure strain and impact strength are obviously enhanced by the introduction of nanosized H30 second phase at low contents, whereas these properties are reduced by the addition of microsized H30 second phase at high contents. Finally, differential scanning calorimetric and thermogravimetric analyses are conducted to examine the effects of the HBP content on the glass transition temperature and the thermal stability, respectively. The glass transition temperature is slightly reduced while the thermal stability is not obviously influenced by the introduction of H30 second phase. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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有机硅改性双酚F环氧树脂热性能研究 总被引:2,自引:0,他引:2
以TMA和TGA研究了含酚羟基的有机烷氧基硅烷及3,3′,3″-三羟基苯氧基硅烷三缩水甘油醚等多种自行设计、合成的有机硅改性剂改性双酚F环氧树脂的热性能。研究结果表明,有机硅可降低改性树脂的线胀系数,但端环氧基脂肪族聚硅氧烷及含酚羟基的二官能度有机硅的加入均使固化物玻璃化温度降低10℃以上;含环氧基的多官能度有机硅改性剂3,3′,3″-三羟基苯氧基硅烷三缩水甘油醚的加入可使线胀系数降低约20%,内应力指数降低约20%,抗开裂指数提高50%以上,固化物玻璃化温度基本不变,热分解温度有较大幅度的提高,是一种理想的环氧树脂增韧改性剂,可用于电子封装等行业用环氧树脂的改性。 相似文献
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