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1.
Lars Gunnarsen 《Indoor air》1997,7(2):116-120
Abstract Experiments were performed using small-scale climate chambers, including the new Chamber for Laboratory Investigations of Materials Pollution and Air Quality (CLIMPAQ), to gain knowledge about the influence of ventilation rate per plane specimen area (specific ventilation rate) on emission rates. Emissions from pieces of linoleum, waterborne acrylic paint, nylon carpet, and sealant were quantified at different specific ventilation rates. A trained sensory panel used the decipol scale and chemical analysis quantified some major Volatile Organic Compounds (VOCs) after the specimens had been conditioned in the chambers for six days. The results showed that the specific ventilation rate (L/s m2) may influence the emission rates. In both sensory and chemical terms, emission rates increased when ventilation was increased. At low specific ventilation rates the emission rate was proportional to the specific ventilation rate. For higher ventilation rates the emission rates stabilized and became independent of ventilation. The chemical measurements showed that only the emissions from the tested paint were influenced by ventilation rates above those comparable to 0.5 h?1 in a typical room. The emissions quantified by the sensory panel continued, however, to be influenced by ventilation even at rates higher than 5 h-1.  相似文献   

2.
The emissions of volatile organic compounds (VOCs) from building materials may significantly contribute to indoor air pollution, and VOCs have been associated with odor annoyance and adverse health effects. Wood materials together with coatings are commonly used indoors for furniture and large surfaces such as walls, floors, and ceilings. This leads to high surface-to-volume ratios, and therefore, these materials may participate remarkably to the VOC levels of indoor environment. We studied emissions of VOCs and carbonyl compounds from pinewood (Pinus sylvestris) boards of 10% and 16% moisture contents (MC) with three paints using small-scale test chambers (27 L). The emissions from uncoated pinewood and paints (on a glass substrate) were tested as references. The 28-day experiment showed that the VOC emissions from uncoated pinewood were lower from sample with 16% MC. Painted pinewood samples showed lower emissions compared to paints on glass substrate. Additionally, paints on 16% MC pinewood exhibited lower emissions than on drier 10% MC wood. The emissions from painted pinewood samples were dominated by paint-based compounds, but the share of wood-based compounds increased over time. However, we noticed differences between the paints, and wood-based emissions were clearly higher with the most permeable paint.  相似文献   

3.
Natural materials of biological origin degrade over time and may emit odorous chemical compounds that can influence the perceived indoor air quality. The objective of this study was to investigate how the perceived air quality is influenced by emissions from building products with linseed oil compared with similar conventional synthetic products without linseed oil. Two types of linoleum, two types of wall paint and two types of floor oil were selected as examples of natural products containing linseed oil. The selected synthetic products were PVC floor covering, a water-based paint, and a synthetic floor oil. The emissions from the products were monitored over a one-year period in small ventilated test chambers. The odorous emissions were evaluated by sensory panel assessments of odour intensity and acceptability and by chemical analysis of the odour-active volatile organic compounds (VOCs) and carbonyl compounds. Odour-active VOCs in the emissions from one floor oil with linseed oil and two pure linseed oils were detected by gas chromatography combined with olfactometry (GC-O) and attempted identified with mass spectrometry (MS). The products with linseed oil influenced the perceived air quality more negatively than the similar synthetic products and the odour was persistent over time. It was found that the products with linseed oil did not qualify for the Danish Indoor Climate Label, because of the persistency of the odour. The results of the GC-O/MS investigations and VOC measurements indicated that an almost constant emission of odour-active VOCs with low odour thresholds resulted in the persistency of the odour. The VOCs probably originated from oxidation products from the linseed oil used as raw material. The study indicates that the acceptability of the emissions from the floor oil was influenced by the linseed oil used as raw material. It is therefore suggested that systematic use of less odorous linseed oils may improve the acceptability of the emission from products with linseed oils. The applied combination of sensory assessment of perceived air quality and GC-O/MS seems to be a useful approach in the effort to eliminate unwanted odours from building products.  相似文献   

4.
Q. Zhang  P. L. Jenkins 《Indoor air》2017,27(2):386-397
Ground‐level ozone can cause serious adverse health effects and environmental impacts. This study measured ozone emissions and impacts on indoor ozone levels and associated exposures from 17 consumer products and home appliances that could emit ozone either intentionally or as a by‐product of their functions. Nine products were found to emit measurable ozone, one up to 6230 ppb at a distance of 5 cm (2 inches). One use of these products increased room ozone concentrations by levels up to 106 ppb (mean, from an ozone laundry system) and personal exposure concentrations of the user by 12–424 ppb (mean). Multiple cycles of use of one fruit and vegetable washer increased personal exposure concentrations by an average of 2550 ppb, over 28 times higher than the level of the 1‐h California Ambient Air Quality Standard for ozone (0.09 ppm). Ozone emission rates ranged from 1.6 mg/h for a refrigerator air purifier to 15.4 mg/h for a fruit and vegetable washer. The use of some products was estimated to contribute up to 87% of total daily exposures to ozone. The results show that the use of some products may result in potential health impacts.  相似文献   

5.
Time versus concentration data of selected volatile organic compounds (VOCs) emitted from four pre-conditioned building materials were measured in the Field and Laboratory Emission Cell (FLEC) at three air exchange rates, 171, 342, 684 h?1, respectively, during a period of 240 hours. The materials were a carpet, a linoleum, a water-borne paint, and a sealant. Modeling of the time versus concentration data for two air exchange rates showed that the emission of VOCs from the carpet were best described with a diffusion model in which the diffusion coefficient depends on the concentration gradient for all data (exponential diffusion model), while a reduced data set eliminating initial events also could be described with a first order decay incorporating a sink effect. The paint emission data of the polar semi-VOC, Texanol, could be described with a first order decay model incorporating a sink effect for all three air exchange rates. The emission rate constant doubled by doubling the air exchange rate. The emission data for VOCs from the sealant were best described for all three air exchange rates by the exponential diffusion model. The best model correlation fit was obtained for hexane, but satisfactory results were also obtained for 2-ethylhexanol and dimethyloctanols. The decay results of linoleum did not allow for modeling leading to the conclusion that an internal concentration gradient had not yet been established under the experimental conditions  相似文献   

6.
The odor of 13 linoleum samples was investigated by different methods. 1) Gas chromatography (GC) with sniffing was used to ensure that no significant odorant was overlooked. 2) Odor intensity evaluation of the linoleum samples was correlated with GC data from Part 1 of this study. Partial least squares regression yielded two factors capable of explaining 77% of the odor intensity variation. The most important classes of compounds were 2-alkenals and fatty acids. 3) Odor indexes of the individual VOCs were compared in order to evaluate their relative odor impact. 4) The odor of linoleum was simulated by a synthetic mixture compounded according to the GC data. It had an odor closely resembling that from certain varieties of linoleum.  相似文献   

7.
Abstract  The reaction of ozone with permethrin can potentially form phosgene. Published evidence on ozone levels and permethrin surface concentrations in aircraft cabins indicated that significant phosgene formation might occur in this setting. A derivatization technique was developed to detect phosgene with a lower limit of detection of 2 ppb. Chamber experiments were conducted with permethrin-coated materials (glass, carpet, seat fabric, and plastic) exposed to ozone under cabin-relevant conditions (150 ppb O3, 4.5/h air exchange rate, <1% relative humidity, 1700 ng/cm2 of permethrin). Phosgene was not detected in these experiments. Reaction of ozone with permethrin appears to be hindered by the electron-withdrawing chlorine atoms adjacent to the double bond in permethrin. Experimental results indicate that the upper limit on the reaction probability of ozone with surface-bound permethrin is ∼10−7. Extrapolation by means of material-balance modeling indicates that the upper limit on the phosgene level in aircraft cabins resulting from this chemistry is ∼1 μg/m3 or ∼0.3 ppb. It was thus determined that phosgene formation, if it occurs in aircraft cabins, is not likely to exceed relevant, health-based phosgene exposure guidelines.  

Practical Implications


Phosgene formation from ozone-initiated oxidation of permethrin in the aircraft cabin environment, if it occurs, is estimated to generate levels below the California Office of Environmental Health Hazard Assessment acute reference exposure level of 4 μg/m3 or ∼1 ppb.  相似文献   

8.
The volatile organic compounds (VOCs) emitted from 12 linoleum samples were measured by use of the “Field and Laboratory Emission Cell” (FLEC) with sampling on Tenax TA followed by thermal desorbtion and GC/FID or GC/MS analysis. Major VOCs were alkanals, alkenals and fatty acids. The emissions were measured after 24 h in FLEC and again after one month's storage in a well ventilated room. The emission profiles of hexanal, nonanal and propanoic acid were modeled for four linoleum samples using a new exponential diffusion model. The time required to reach 50% of the odor threshold concentrations in a standard room was from 113 to 2296 hours. The applicability of the diffusion model for modeling long-term emission needs to be further evaluated considering possible continuous oxidative emission.  相似文献   

9.
The health effects associated with exposure to ozone range from respiratory irritation to increased mortality. In this paper, we explore the use of three green building materials and an activated carbon (AC) mat that remove ozone from indoor air. We studied the effects of long-term exposure of these materials to real environments on ozone removal capability and pre- and post-ozonation emissions. A field study was completed over a 6-month period, and laboratory testing was intermittently conducted on material samples retrieved from the field. The results show sustained ozone removal for all materials except recycled carpet, with greatest ozone deposition velocity for AC mat (2.5-3.8 m/h) and perlite-based ceiling tile (2.2-3.2 m/h). Carbonyl emission rates were low for AC across all field sites. Painted gypsum wallboard and perlite-based ceiling tile had similar overall emission rates over the 6-month period, while carpet had large initial emission rates of undesirable by-products that decayed rapidly but remained high compared with other materials. This study confirms that AC mats and perlite-based ceiling tile are viable surfaces for inclusion in buildings to remove ozone without generating undesirable by-products. PRACTICAL IMPLICATIONS The use of passive removal materials for ozone control could decrease the need for, or even render unnecessary, active but energy consuming control solutions. In buildings where ozone should be controlled (high outdoor ozone concentrations, sensitive populations), materials specifically designed or selected for removing ozone could be implemented, as long as ozone removal is not associated with large emissions of harmful by-products. We find that activated carbon mats and perlite-based ceiling tiles can provide substantial, long-lasting, ozone control.  相似文献   

10.
People are an important source of pollution indoors, through activities such as cleaning, and also from “natural” emissions from breath and skin. This paper investigates natural emissions in high‐occupancy environments. Model simulations are performed for a school classroom during a typical summer in a polluted urban area. The results show that classroom occupants have a significant impact on indoor ozone, which increases from ~9 to ~20 ppb when the pupils leave for lunch and decreases to ~14 ppb when they return. The concentrations of 4‐OPA, formic acid, and acetic acid formed as oxidation products following skin emissions attained maximum concentrations of 0.8, 0.5, and 0.1 ppb, respectively, when pupils were present, increasing from near‐zero concentrations in their absence. For acetone, methanol, and ethanol from breath emissions, maximum concentrations were ~22.3, 6.6, and 21.5 ppb, respectively, compared to 7.4, 2.1, and 16.9 ppb in their absence. A rate of production analysis showed that occupancy reduced oxidant concentrations, while enhancing formation of nitrated organic compounds, owing to the chemistry that follows from increased aldehyde production. Occupancy also changes the peroxy radical composition, with those formed through isoprene oxidation becoming relatively more important, which also has consequences for subsequent oxidant concentrations.  相似文献   

11.
An uncomfortable smell was reported by employees of an IT office (information technological office) in a medical center. This problem started two years ago when the office was refurbished. The objectives of this study are to characterize the indoor air quality of this complaint area in terms of chemical pollutants and odor characteristics, and identify possible sources of this foul smell. Carbonyl chemicals and volatile organic compounds (VOCs) were investigated in this study, since these two groups are associated with odors and health effects. Additionally, the odor was evaluated by odor assessors (non-smokers) who recorded odor characters that appeared in offices. By comparing chemical measurements between complaint and non-complaint areas, calculating odor indices, and correlating odor and chemical measurements, we got results showing that a higher correlation coefficient is found between odor presence frequencies and VOC concentrations. Further investigating found nonanal and decanal are possible chemicals for malodors. The concentration levels of these two chemicals in the complaint area are higher than those in the non-complaint areas and exceeding odor thresholds. Possible sources of these long-chain aldehydes are formed during the oxidation degradations of fatty acids like linoleic acid, linolenic acid and oleic acid which are ingredients for many building products like linoleum and surface coating. In order to mitigate this malodor problem, extra and effective ventilation flow rate should be provided to reduce the concentrations of odorous chemicals and the precursors for these odorous chemicals.  相似文献   

12.
With the gradual reduction of emissions from building products, emissions from human occupants become more dominant indoors. The impact of human emissions on indoor air quality is inadequately understood. The aim of the Indoor Chemical Human Emissions and Reactivity (ICHEAR) project was to examine the impact on indoor air chemistry of whole-body, exhaled, and dermally emitted human bioeffluents under different conditions comprising human factors (t-shirts/shorts vs long-sleeve shirts/pants; age: teenagers, young adults, and seniors) and a variety of environmental factors (moderate vs high air temperature; low vs high relative humidity; presence vs absence of ozone). A series of human subject experiments were performed in a well-controlled stainless steel climate chamber. State-of-the-art measurement technologies were used to quantify the volatile organic compounds emitted by humans and their total OH reactivity; ammonia, nanoparticle, fluorescent biological aerosol particle (FBAP), and microbial emissions; and skin surface chemistry. This paper presents the design of the project, its methodologies, and preliminary results, comparing identical measurements performed with five groups, each composed of 4 volunteers (2 males and 2 females). The volunteers wore identical laundered new clothes and were asked to use the same set of fragrance-free personal care products. They occupied the ozone-free (<2 ppb) chamber for 3 hours (morning) and then left for a 10-min lunch break. Ozone (target concentration in occupied chamber ~35 ppb) was introduced 10 minutes after the volunteers returned to the chamber, and the measurements continued for another 2.5 hours. Under a given ozone condition, relatively small differences were observed in the steady-state concentrations of geranyl acetone, 6MHO, and 4OPA between the five groups. Larger variability was observed for acetone and isoprene. The absence or presence of ozone significantly influenced the steady-state concentrations of acetone, geranyl acetone, 6MHO, and 4OPA. Results of replicate experiments demonstrate the robustness of the experiments. Higher repeatability was achieved for dermally emitted compounds and their reaction products than for constituents of exhaled breath.  相似文献   

13.
An INdoor air Detailed Chemical Model was developed to investigate the impact of ozone reactions with indoor surfaces (including occupants), on indoor air chemistry in simulated apartments subject to ambient air pollution. The results are consistent with experimental studies showing that approximately 80% of ozone indoors is lost through deposition to surfaces. The human body removes ozone most effectively from indoor air per square meter of surface, but the most significant surfaces for C6‐C10 aldehyde formation are soft furniture and painted walls owing to their large internal surfaces. Mixing ratios of between 8 and 11 ppb of C6‐C10 aldehydes are predicted to form in apartments in various locations in summer, the highest values are when ozone concentrations are enhanced outdoors. The most important aldehyde formed indoors is predicted to be nonanal (5‐7 ppb), driven by oxidation‐derived emissions from painted walls. In addition, ozone‐derived emissions from human skin were estimated for a small bedroom at nighttime with concentrations of nonanal, decanal, and 4‐oxopentanal predicted to be 0.5, 0.7, and 0.7 ppb, respectively. A detailed chemical analysis shows that ozone‐derived surface aldehyde emissions from materials and people change chemical processing indoors, through enhanced formation of nitrated organic compounds and decreased levels of oxidants.  相似文献   

14.
Cain WS  Schmidt R  Wolkoff P 《Indoor air》2007,17(5):337-347
Young adult subjects who occupied a well-ventilated space with low background of level of ozone achieved via carbon-filtration could detect ozone odor at 7 ppb, lower than expected from archival compilations. The outcome was not inconsistent, however, with some observations of recognition, beyond mere detection, at about 15-20 ppb. Individual differences in sensitivity lay at or just below an order of magnitude, rare in olfactory testing and indicative of precision. In a study of d-limonene, subjects again showed high sensitivity and small individual differences. The subjects could detect the odor at 8 and 15 ppb, depending upon whether they occupied a space with or without carbon filtration, respectively. The results argue for use of carbon filtration to measure sensitivity most stringently, although absence of filtration seems not to incur a large penalty. The protocol used here, with collection of hundreds of judgments in a day, yet with little net exposure of the subject to odorant; with verifiably stable delivery; and with analytical confirmation of level should reduce tolerance for outcomes of large differences among subjects and among studies. PRACTICAL IMPLICATIONS: Humans manifested much higher sensitivity to ozone and D-limonene than commonly thought, a pattern revealing itself more broadly in olfactory studies as testing improves and analytical confirmation of delivery becomes more common. Published databases, with errors of +/-1000%, often badly underestimate sensitivity and can thereby encourage use of higher concentrations of compounds, particularly VOCs, than relevant in studies of reactive indoor chemistry.  相似文献   

15.
Examination of the exposure‐ and odour‐reducing characteristics of gypsum‐based building materials containing zeolite. Emissions of volatile organic materials (VOC) from building products are increasingly regarded as harmful. In Germany the AgBB scheme was developed, which describes the health assessment procedure for emissions of volatile organic compounds from building products and today offers the main basis for requirements relating to room air hygiene‐related properties of building products. This article describes studies on plasterboard containing zeolite.  相似文献   

16.
Sakr W  Weschler CJ  Fanger PO 《Indoor air》2006,16(2):98-110
Sensory evaluations were used to investigate the impact of sorption processes on indoor air quality. Experiments were carried out in four similar, adjacent, unfurnished offices. Samples of carpet, linoleum, painted gypsum board, and Semia (a specially designed high-sorbing fabric) were tested individually and in combination. Additionally, to investigate the interaction between the pollutants emitted from the building materials and the test room surfaces themselves, air streams polluted by two different building materials were vented into an empty test office. Each experiment lasted for either 1 week (adsorption stage only) or 10 days (adsorption and desorption stages). Untrained panels assessed the air quality at specified times after moving the materials into or out of the rooms. The results showed that, in comparison with air in a room with carpet or linoleum alone, the presence of painted gypsum board improved the perceived air quality. This improvement persisted throughout the 168 h of the 'adsorption stage' of the experiments. A mass balance model was used to quantify the improvement. Calculated results indicate that, for the conditions used in these experiments, pollutant removal via sorption to the relatively inert office surfaces was equivalent to an extra 0.4 air change per hour (ACH) of ventilation air, while sorption to painted gypsum board surfaces was equivalent to an extra 1-7 ACH of ventilation air. In the case of Semia, sorption was equivalent to an extra 16 ACH of ventilation air. During the 'desorption stage' of the experiments, after carpet or linoleum were taken out of a room, approximately 3 days were required before the air in the test office, ventilated at 0.8 ACH, was judged to be free of the sorbed pollutants. PRACTICAL IMPLICATIONS: Ventilation rates in non-industrial buildings are based largely on sensory pollution sources and a desired level of perceived air quality. This study documents that sorptive materials in a room influence the perceived air quality and should be considered when evaluating ventilation requirements. Indeed, it may be possible to deliberately use sorption/desorption to improve indoor air in a manner analogous to the way thermal storage/release is currently used in buildings as a means of conserving energy.  相似文献   

17.
Chemical reactions on the surface of building materials can lead to secondary emissions from these materials that influence indoor air quality. Many studies have been made on the physical processes that influence material emissions. However, there are only a few studies on secondary emissions resulting from exposure of building material surfaces to ozone or ultraviolet (UV) irradiation. Therefore, this study was aimed at elaborating on the emission of chemicals resulting from chemical reactions initiated by the exposure of the surface of flooring materials to ozone or UV irradiation. The laboratory tests were conducted to estimate gas-phase emissions from the flooring materials when they were exposed to ozone or various kinds of light irradiation (infrared, sunlight, UV-A and UV-B lamps). The infrared and sunlight lamps significantly increased the temperature of the test specimens and, in turn, increased the emission rate for various organic compounds. The flooring materials used in this study had been treated with UV-cured surface coatings during their manufacturing. As a result, when exposed to UV irradiation, chemical transformations occurred resulting in the emission of a number of secondary products, including formaldehyde, acetaldehyde, cyclohexanone and benzaldehyde. Ozone reacted with chemicals present in the flooring materials to increase the emission rates of formaldehyde and acetaldehyde. Hence, the exposure of ozone and UV irradiation increased the secondary emissions of formaldehyde, even though the low formaldehyde emission type of flooring material was employed.  相似文献   

18.
The impact of asthma, exposure period, and filter condition downstream of the mixing box of air‐conditioning system on building occupants' perceptual response, work performance, and salivary α‐amylase secretion during exposures to ozone and its initiated chemistry products is studied. The experiments were conducted in a field environmental chamber (FEC) (240 m3) simulating an office environment. Experiments were conducted during periods when the air‐handling system operated with new or used pleated panel filters at constant recirculation (7/h) and ventilation (1/h) rates. Average ozone and secondary organic aerosols (ozone‐initiated chemistry products) measured during non‐asthmatic and asthmatic subjects' 3‐h exposures in the FEC were in the ranges approximately 20–37 ppb and approximately 1.6–3 μg/m3, respectively. Asthmatic subjects' perceived odor intensity and sensory (eye, nose, and throat) irritation ratings were generally lower than those of non‐asthmatic subjects, possibly explaining why asthmatic subjects accept perceived air quality more than non‐asthmatic subjects. However, asthmatic subjects' perceived physiological‐like symptom ratings (flu, chest tightness, and headache) and concentrations of secreted salivary α‐amylase were generally higher than those of non‐asthmatic subjects. Asthmatic subjects had significantly lower accuracy than non‐asthmatic subjects in a task that required higher concentration although they had higher work speed. Filter condition did not make any significant difference for subjects' responses.  相似文献   

19.
Abstract Polyurethane products were subjected to chamber testing to determine their emission rates of 2,4- and 2,6-toluene diisocyanate (TDI). The polyurethane (PU) products included carpet padding, furniture cushions, sheet foam, varnishes, and sealants, as well as a commercially-applied water sealant product for concrete that contained up to 4 percent TDI by weight. The PU products were screened in a 9-L glass chamber, under elevated temperature and chamber loading conditions, using both a time-integrated sampling and analysis method specific for TDI and a continuous but non-specific real-time monitor for isocyanates. None of the products normally found in residences showed a positive response in the screening tests, indicating that TDI emissions and consequently toxic effects from such products are negligible. However, the commercially-applied water sealant gave a positive response in the screening test. Further testing of that product at realistic temperatures showed initial TDI emission rates of about 300,000 μg/m2/hr, with emissions lasting only one hour or less. At 21 and 27°C, about 1 percent and 5 percent, respectively, of the TDI content of the product was released to the air. The emitted TDI was predominantly the 2,6-isomer, although the TDI originally present in the product was predominantly the 2,4-isomer.  相似文献   

20.
The development of odor emission rates from EU6 classified glass fiber bag filters was studied in four air-handling units (AHU), and emissions from the same kind of filters with EU3 classified polyester prefilters were studied in two units. The filters were loaded in six AHU in downtown Helsinki. The pressure drop was measured, and the odors of the filters were evaluated by a trained panel under laboratory conditions (T = 20°C, face velocity 1.0 m/s) every sixth week. The odor emissions of simultaneous atmospheric dust samples were also studied. The odor emissions of the filters rose during the first three months to a level where every third person would be dissatisfied. The emissions from coarse prefilters were similar to those from the more efficient filters without prefilters, and the emissions of the main filters were significantly lower if used with prefilters. This result indicates that the prefilters effectively protected the fine filters from odor-causing particles. The results of tests made with atmospheric samples agree with this result. Relative odor emissions were the highest in coarse fractions (> 10.0 μm). The pressure drop increased with the particle mass collected on the ventilation filter, but it did not correlate well with the odor emission of the filter. Thus, pressure drop alone is not an adequate criterion for changing supply air filters when hygienic aspects are a concern.  相似文献   

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