Effect of nano-silica modification on the tensile property of SMA/GF/CF/epoxy super hybrid woven fabric composites

Tensile properties of epoxy casts together with shape memory alloy (SMA), glass (GF) and carbon (CF) woven fabric reinforced epoxy matrix super hybrid composites were investigated, respectively. In order to enhance the mechanical strength of this advanced material, two categories of modifications including matrix blending and fiber surface coating by nano-silica were studied. Scanning electron microscopy (SEM) and fiber pull-out tests were adopted to complement the experimental results, respectively. Experimental results reveal that the toughness of epoxy matrix is enhanced significantly by adding 2wt% nano-silica. The failure mechanism of SMA reinforced hybrid composites is different from that of GF/CF/epoxy composites. Compared with the matrix modification, the fibers modified by coating nano-silica on the surface have better tensile performances. Moreover, the fiber pull-out test results also indicate that composites with fiber surface modification have better interfacial performances. The modification method used in this paper can help to enhance the tensile performance of the mentioned composite materials in real engineering fields.     

混杂纤维增强高性能混凝土拉压比试验研究

研究了揭示钢纤维和聚丙烯纤维混杂后对高性能混凝土强度和拉压比的影响.参照国家标准和试验方法,按不同的纤维掺量设计了9组混杂纤维增强高性能混凝土试件以及3组钢纤维增强高性能混凝土对比试件和1组普通高性能混凝土对比试件,进行了大量立方体抗压强度试验和劈裂抗拉强度试验研究,并对拉压比进行回归分析.结果在高性能混凝土中掺加适量的钢纤维和聚丙烯纤维后:对抗压强度影响不明显,但可使抗拉强度提高10%~30%,使拉压比增大到0.06~0.068;钢纤维体积掺量为0.8%、聚丙烯纤维体积掺量为0.11%时,混杂纤维增强高性能混凝土拉压比为0.068;混杂纤维增强高性能混凝土的劈裂抗拉试验为近似于延性断裂破坏.结论掺加适量钢纤维和聚丙烯纤维后,高性能混凝土的抗拉强度和拉压比均有不同程度的提高,这有利于提高高性能混凝土的抗裂性能和抗震性能.     

玻璃纤维增强环氧树脂单向复合材料力学性能分析

采用连续玻璃纤维与环氧树脂相复合,通过金属模压成型工艺,制备出单向玻璃纤维／环氧树脂复合材料。通过三点弯曲实验论证单向纤维对树脂基体的增强作用,从而研究不同纤维含量下复合材料的弹性模量、纵向拉伸强度、纵向压缩强度的变化趋势。结果表明：随着纤维含量的增加,复合材料的力学性能均增强,当纤维体积含量为50％时,其各项性能均较好,弹性模量为40GPa,纵向拉伸强度为1200MPa,纵向压缩模量为700MPa。此外,对复合材料的其他常用力学性能参数进行检测。     

Effect of twisted fiber on flexural property and microstructure of woven fabric reinforced composite

Two kinds of 2.5D deep straight-joint structure ultra-high molecular weight polyethylene (UHMWPE) (twisted and original) fibers woven fabric reinforced epoxy resin composites were prepared by the hand lay-up method. Subsequently, the flexural property, microstructures, and failure mechanisms of the composites were also investigated. The average flexural strength of 2.5D deep bend-joint structure twisted fiber and original fiber woven fabric composites were 176.66 MPa and 204.45 MPa, respectively. The results of the characteristics indicated that the twist was the main factor which affected the flexural performance. Flexural property vitally relied on the strength of the fiber itself. Twist decreased the strength of the yarns, which meant that when the mechanical property of woven fabric reinforced composites was improved, the yarns must be kept straight in the woven fabric. The study are extremely valuable to guide the improvement of the mechanical property of the woven fabric reinforced composites.     

全金属组元铁基块体非晶的制备与性能研究

3D打印成型碳纤维接枝碳纳米管增强热塑性复合材料的强度提高

王婼楠¹，吴海宏^1，2，郭子月³，刘春太²，申长雨²

（1. 河南工业大学 机电工程学院，郑州450001; 2.郑州大学 橡塑模具国家工程研究中心，郑州450002; 3.中山大学 数学学院（珠海）,珠海519082）

创新点说明：

1) 研究了碳纤维定量接枝碳纳米管对热塑性复合材料的界面性能及拉伸性能的影响。

2) 用3D打印模压成型的工艺方法制备了热塑性复合材料。

研究目的：

研究碳纤维表面接枝不同含量的碳纳米管对复合材料微观结构、界面性能和力学性能的影响。

研究方法：

1) 采用溶液法，通过控制碳纳米管接枝反应时间，制备不同含量碳纳米管接枝碳纤维，然后用硝酸刻蚀法，去除残留溶剂，验证了碳纳米管接枝的可靠性。用扫描电镜观察碳纤维的微观形貌，用FTIR测试碳纤维表面官能团并用XPS对碳纤维的表面官能团进行分析。

2) 用扫描电镜观察碳纤维与基体的结合情况并用接触角测量仪测试碳纤维与基体的接触角。

3) 通过 3D打印成型法成型了热塑性复合材料样条，并用扫描电镜观察碳纤维热塑性复合材料的界面微观形貌。

4) 采用万能试验机测试3D打印成型热塑性碳纤维复合材料的拉伸性能，并观察复合材料断口形貌。

结果：

1) 溶液法.扫描电镜观察发现碳纳米管在碳纤维表面均匀分布，表明碳纤维与碳纳米管之间存在较强的键合关系。但随着接枝时间的增加，碳纤维表面的碳纳米管含量逐渐增加，但达到0.4%时，出现分散不均匀现象。碳纤维表面含有上浆剂和去掉上浆剂的对比发现，无上浆剂的碳纤维表面沟壑明显，这些沟槽可以增加碳纤维的比表面积和表面能，增强了基体与碳纤维的机械相互作用。用FTIR测试碳纤维表面官能团并用XPS对碳纤维的表面官能团进行分析，结果表明，经偶联剂改性后，C=O键含量明显增加，碳纤维表面引入含氧官能团。C1，O1S峰增强，表明碳纳米管接枝到了碳纤维表面。

2) 扫描电镜结果表明，与表面未接枝碳纳米管的碳纤维相比，接枝碳纳米管的碳纤维与基体PA6具有更好的润湿性。接触角测试结果对比发现，接枝碳纳米管的碳纤维与基体的接触角，明显小于未接枝碳纳米管的。

3) 通过扫描电镜观察复合材料的界面微观形貌，结果表明：纤维与基体之间存在一定厚度的界面层，界面层的存在可以减轻纤维与基体之间的力学性能突变引起的应力集中，并防止界面缺陷的扩展。

4）界面结合强度测试结果表明，当碳纳米管的质量分数增加到0.25%时，复合材料的界面结合强度比未接枝碳纳米管的碳纤维增强的PA6复合材料提高了20%，比表面有环氧的碳纤维复合材料提高了41.8%。然而当碳纳米管含量大于0.4%时，界面结合强度不再继续增加。力学测试表明碳纳米管含量为0.25%的复合材料具有最高的平均模量、拉伸强度和界面剪切强度。接枝碳纳米管的碳纤维复合材料断口形貌可以观察到界面处基体中的韧窝。表明基体树脂在拔出纤维前经历了较大的塑性变形，表明纤维与基体有很好结合性。

结论：

实验结果表明，碳纳米管可以提高表面的润湿性和CF表面粗糙度。碳纳米管接枝碳纤维增强PA6与环氧上浆的碳纤维复合材料相比，当碳纳米管的质量分数达到0.25%时，复合材料的界面结合强度增加了41.8%，拉伸强度提高了130%，界面剪切强度提高了238%。然而，随着碳纳米管含量的继续增加到0.4%时，界面结合强度和力学性能就会下降。

关键词：热塑性复合材料，界面结合强度，界面剪切强度，3D打印成型

     

碳纤维上电聚合噻吩对复合材料性能的影响

为了改善碳纤维与树脂基体之间的界面性能,以噻吩为单体,采用循环伏安法对碳纤维进行电化学聚合改性.利用扫描电子显微镜研究了电化学聚合改性前后碳纤维的表面结构变化,采用电脑伺服控制材料试验机测试了碳纤维增强环氧树脂复合材料的力学性能.结果表明,当噻吩浓度为0.4 mol/L时,峰值电流增加幅度最大,电聚合效果最佳.当循环次数达到60次时,碳纤维表面电化学聚合反应完全,碳纤维/环氧树脂复合材料的层间剪切强度可由13.46 MPa增加到23.79 MPa,提高约76.75%.电化学聚合后大量片层状聚噻吩聚合物在碳纤维表面聚集,碳纤维与环氧树脂基体紧密结合,界面性能明显提高.     

ZrB2基层状复合材料力学性能与应力影响分析

通过层压复合技术制备出Mo/ZrB2层状复合材料,该复合材料的抗弯强度达到471 MPa,同时具有高的断裂韧性7.64 MPa·m1/2.研究发现材料内部的残余应力引起裂纹扩展阻力增大,裂纹发生偏转,材料因此得到强韧化.采用非均匀应变模型分析层状复合材料的内部残余应力,结果表明:基体层受拉应力,最大为64 MPa,界面层受压应力,最大为320 MPa,同时在层间存在剪切应力,最大为1.149MPa.基体层和界面层的厚度比对材料内部应力分布影响较大.     

添加不同纤维的高性能混凝土力学性能试验

通过试验研究了弹性模量具有明显差异的3种纤维对于混凝土的力学性能改善所起的作用,以及钢纤维、碳纤维和聚丙烯纤维单掺或复掺对于混凝土的抗压强度、劈裂抗拉强度和弹性模量的影响。结果表明：添加0．5％高弹性模量的钢纤维对于混凝土的强度和弹性模量均有提高作用,复掺0．3％钢纤维和0．2％碳纤维的混凝土抗拉强度的提高大于抗压强度;添加0．5％钢纤维的混凝土HPC-2的弹性模量最大,比基准混凝土提高6．5％;添加0．2％聚丙烯纤维的混凝土HPC-3的弹性模量最小,且小于基准混凝土;此外,混凝土抗压强度的影响程度与纤维的弹性模量的关系更为直接,混凝土劈裂抗拉强度的改善与纤维的抗拉强度的关系更为直接,纤维的弹性模量与基体弹性模量的比值,对复合材料的弹性模量有直接的影响。     

MECHANICAL PROPERTIES OF CARBON/GLASS FIBER REINFORCED POLY (METHYL METHACRYLATE) COMPOSITES

Artificial bone carbon/glass fiber reinforced PM-MA composites have been prepared by hot press moulding ofpre-preg which monofilments of CF and GF impregnated byMMA prepolymer. When the PMMA volume fraction in com-posites is 50%, theoretical and experimental results show thatstrength and modules of these hybrid composites are in accordwith “rule of mixture”.The tensile and flexure strength are thelowest when the raletive volume fraction of carbon fiber in rein-forcements is 50%, SEM examinations further explained re-sults.     

钢纤维再生混凝土劈拉强度试验研究

通过钢纤维再生混凝土立方体试件的劈拉强度试验,研究了钢纤维体积分数(0.0%～2.0%)、3种钢纤维类型(MF,SF,BF)、再生粗骨料处理方式以及试件尺寸变化对再生混凝土劈拉性能的影响.结果表明:钢纤维的加入显著提高了再生混凝土的劈拉强度,当纤维体积分数超过1.5%后,钢纤维再生混凝土的劈拉强度接近甚至超过天然钢纤维混凝土;钢纤维类型对再生骨料钢纤维混凝土影响显著,钢纤维对再生混凝土和天然混凝土的增强效果比较接近,其中BF钢纤维增强效果最好;尺寸效应对钢纤维再生混凝土的影响比天然钢纤维混凝土显著;再生骨料处理方法对钢纤维再生混凝土的劈拉强度也有一定的影响;现行钢纤维混凝土劈拉强度计算公式仍适用于钢纤维再生混凝土.     

玄武岩纤维布增强环氧树脂复合材料研究

以玄武岩纤维平纹布 (BF) 加入到环氧树脂 (EP) 中,采用模压工艺制备BF／EP 复合材料,研究加入不同层数的玄武岩纤维布对复合材料力学性能和断裂韧性的影响。实验结果表明,BF/EP复合材料的弯曲强度、冲击强度和断裂韧性明显优于环氧树脂;与未加BF的环氧树脂相比,加入三层BF后复合材料的弯曲强度提高了2.76倍,缺口冲击强度提高了19.67倍,无缺口冲击强度提高了5.94倍,KIC提高了2.97倍。     

苎麻增强不饱和聚酯复合材料的力学性能

分别以苎麻原麻和碱处理的原麻（碱麻）为增强体,KH550为偶联剂,制备了苎麻增强不饱和聚酯复合材料．探讨了偶联剂用量和纤维含量对复合材料力学性能的影响,并用扫描电子显微镜对复合材料的断面进行了观察．实验结果表明,复合材料的力学性能得到了较大的提高．原彬不饱和聚酯复合材料的拉伸强度达132．6MPa,弯曲强度达364．6MPa;碱彬不饱和聚酯复合材料拉伸强度迭116．5MPa,弯曲强度达297．7MPa．     

混杂纤维对高性能混凝土拉压比的影响

为研究低掺量钢-聚丙烯混杂纤维对高性能混凝土拉压比的影响,采用正交试验法设计了18组混杂纤维高性能混凝土试件及1组普通高性能混凝土对比试件,通过标准试验方法进行立方体抗压强度和劈裂抗拉强度试验,试验中考虑的因素主要是钢纤维的特征参数(类型、体积率、长径比)和聚丙烯纤维体积率.分析各因素对高性能混凝土拉压比的影响,结果表明:混杂纤维高性能混凝土具有明显延性破坏特征,而普通高性能混凝土表现为脆性破坏,混杂纤维的掺入使高性能混凝土的拉压比最大提高了26.2%,平均提高了9.9%.在影响高性能混凝土拉压比的四个因素中,钢纤维类型的影响最大,其次是聚丙烯纤维的体积率,影响最小的是钢纤维长径比.高性能混凝土中掺入适量钢-聚丙烯混杂纤维后,拉压比显著提高,韧性得到明显改善.     

表面处理碳纤维对增强尼龙复合材料性能影响

采用空气氧化法对碳纤维进行表面处理 ,以注塑成型法制备碳纤维增强尼龙 1 0 1 0复合材料 .研究发现表面处理碳纤维可明显提高增强尼龙复合材料的拉伸强度和摩擦学性能 ,其中摩擦系数较未处理碳纤维增强降低了 3 0 %～ 5 0 % ,而耐磨性提高了 2～ 3倍 .用扫描电镜对拉伸断口和磨损表面形貌分析发现 ,表面处理可显著改善碳纤维和尼龙基体间的界面结合性能 .最后对影响表面处理碳纤维增强复合材料性能的作用机理进行了初步分析     

Effects of fibers on mechanical properties of high-performance concrete subjected to elevated temperatures

The compressive strength and ilexural toughness as well as fracture energy of fiber reinforced highperformance concrete （FRHPC） subjected to different high temperatures were studied. The results showed that after exposure at 300,600 and 900℃, the concrete mixes retained 88.1% , 41.3% and 10.2% of the original compressive strength on average, respectively. Steel fiber and polypropylene （PP） fiber were both effective in minimizing the damage effect of high temperatures on the compressive strength. The HPC reinforced with steel fibers showed higher flexural toughness and fracture energy before and after the high-temperature exposures. In comparison, PP fibers had minor beneficial effects on the flexural toughness and fracture energy. The mechanical properties of HPC reinforced with hybrid fibers （steel fiber ＋ PP fiber） were equivalent to or better than those of HPC reinforced with steel fibers alone. In addition, the failure pattern of FRHPC beams changed from pull-out of steel fibers at lower temperatures （20, 300 and 600℃） to tensile failure of steel fibers at higher temperature （900 ℃）.     

Electrical resistance behavior of vinylester composites filled with glass-carbon hybrid fibers

Vinylester (bismethacryloxy derivative of a bisphenol-A type EP resin, VE) composites with glass-carbon hybrid fibers (CF-GF) weight fraction of 50%, were prepared by the compress molding method. The distribution of carbon fiber in the hybrids was observed by stereomicroscope. The electrical resistance behavior of the composites filled with different carbon fiber (CF) weight contents (0.5% to 20%) was studied. The experimental results show that the electrical resistance behaviors of CF-GF/VE composites are different with those of CF/VE composites because carbon fibers’ conducting networks are broken by the glass fibers in the CF-GF/VE composites. The carbon fibers distribute uniformly in the networks of glass fibers (GF) like single silk and form the semi-continuous conducting networks. Composite filled with GF-CF hybrid has a higher percolation threshold than that filled with pure CF. At that time, the resistivity of CF-GF/VE composites varies little with the temperature increasing. The temperature coefficient of resistivity in GF-CF/VE composite is less than 317 ppm and the variation of the resistivity after ten thermal cycles from 20 °C to 240 °C is less than 1.96%. Funded by the Natural Science Foundation of Hubei Province (No. 2007ABA028)     

混杂纤维轻骨料混凝土的力学和抗冻性能研究

为了研究钢纤维和聚丙烯纤维对轻骨料混凝土性能的影响,共设计了16组轻骨料混凝土试件,其中有9组混杂纤维轻骨料混凝土,3组钢纤维轻骨料混凝土,3组聚丙烯纤维轻骨料混凝土和1组普通轻骨料混凝土试件。试验结果表明:当钢纤维体积率为1.0%,聚丙烯纤维体积率为0.05%时,混凝土的抗压强度最大为39.16 MPa,提高了17.92%;当钢纤维体积率为1.5%时,抗拉强度最大为4.77 MPa,提高了63.36%。50次冻融循环试验后混凝土的强度损失率最低的是Ssp3组,即钢纤维体积率为1.0%,聚丙烯纤维体积率为0.15%时,强度损失率最低为1.79%,降低了68.92%。     

碳纤维复合材料原位增材制造设备与工艺

为了实现碳纤维增强热塑性复合材料（CFRTC）高质高效原位增材制造,设计一种激光聚焦加热CFRTC原位增材制造平台,以单向连续碳纤维增强聚醚醚酮热塑性复合材料（T800 CF/PEEK UD）预浸带为原材料开展CFRTC成型工艺相关研究. 制备环形样件进行剪切强度测试表征,通过扫描电子显微镜观察样件的截面形貌,确立激光聚焦加热CF/PEEK的可行工艺参数窗口与较优工艺参数. 结果表明,CF/PEEK成型件强度受激光聚焦加热温度、成型速度影响较大,均表现出随激光聚焦加热温度与成型速度的增加,先增大后减小,当成型速度为30 mm/s和激光加热温度为450 ℃时,环形样件有较高的剪切强度,并且表现出较少的微观缺陷.     

The Mechanical Properties of Polypropylene Fiber Reinforced Concrete

The compressive, shear strengths and abrasion-erosion resistance as well as flexural properties of two polypropyenc fiber reinforced concretes and the comparison with a steel fiber reinforced concrete were reported. The exprimental results show that a low content of polypropylene fiber (0.91 kg/m^3 of concrete ) slightly decreases the compressive and shear strengths, and appreciably increased the flexural strength, but obviously enhances the toughness index and fracture energy for the concrete with the same mix proportion, coasequently it plays a role of anti-cracking and improving toughness in concrete. Moreover, the polypropylene mesh fiber is better than the polypropylene monofilament fiber in improving flexaral strength and toughness of concrete, but the types of polypropylene fibers are inferior to steel fiber. All the polypropylene and steel fibers have no great beneficial effect on the abrasion-erosion resistance of concrete.     

Evaluation of statistical strength of bamboo fiber and mechanical properties of fiber reinforced green composites

Green composites made from bamboo fibers and biodegradable resins were fabricated with press molding.On the basis of the Weibull distribution and the weakest-link theory,the statistical strength and distribution of bamboo fiber were analyzed,and the tensile strength of green composites was also investigated.The result confirms that the tensile statistical strength of fiber fits well with two-parameter Weibull distribution.In addition,the tensile strength of bamboo fiber reinforced composites is about 330 MP...