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以丙烯酸 (AA)和甲基丙烯酰氧乙基三甲基氯化铵 (DMC)为原料 ,在水中采用自由基共聚和制备了两性丙烯酸树脂复鞣剂。利用红外光谱 (FTIR)和核磁共振 (13 CNMR)对其结构进行了表征。分别采用浊度法和黏度法测定了该类聚合物的溶解性和黏度行为。应用试验表明 ,共聚物的复鞣性能与其组成和分子量大小有关 ,在丙烯酸聚合物鞣剂中引入阳离子基团 ,可以提高复鞣革的柔软度 ,克服败色现象。通过扫描电镜观测、X -衍射分析证实 ,两性丙烯酸树脂复鞣剂可以分散皮胶原纤维 ,降低胶原纤维的结晶度。 相似文献
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以水作溶剂,过氧化物为引发剂,用顺丁烯二酸酐和乙烯基类为单体。合成多元共聚物(PR—1)复鞣剂。PR—1属多官能团聚离子型复鞣剂,试产品经成都、四川、浙江、河南、山东、新疆等地制革厂家应用结果表明,PR—1是制造猪、牛、羊软革产品的优良复鞣剂。它具有使成革丰满、柔软、增厚明显。粒面细致、毛孔清晰、pH值使用范围宽,对染色影响小等优异性能。复鞣剂主要有天然聚合物及其改性产品和合成聚合物两大类。合成聚合物主要有聚丙烯酸类,聚氨酯类和顺丁稀二酸酐的共聚物。顺丁烯二酸酐与芳烃共聚物由于用芳烃作溶剂,有机过氧化物作引发剂,该产品不仅对环境带来污染而且成本高,使用受到限制。PR—1顺丁烯二酸酐与乙烯基单体共聚物采用水作溶剂,生产过程基本无三废,还具有原料成本低且性能优异的特点。 相似文献
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以丙烯酸和马来酸酐为原料合成出了一种共聚物。用该共聚物对磷脂进行酰化,制备出了一种新的加脂复鞣剂。应用研究结果表明,该加脂复鞣剂具有良好的乳化性能和乳液稳定性,用于铬复鞣或加脂工序,能增加革的丰满度、柔软度、抗张强度和伸长率。当用于铬复鞣工序时,还能大幅度提高铬的吸收率。 相似文献
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《皮革科学与工程》2017,(5)
采用硫酸化不饱和动植物混合油(简称硫酸化不饱和油)、(甲基)丙烯酸、丙烯酸酯作为共聚单体,通过乳液聚合制备改性丙烯酸树脂复鞣剂乳液(简称改性复鞣剂)。分别用FTIR、DSC、万能试验机、旋转黏度计、TEM,测试了复鞣剂成膜物及乳液的结构、热性能、力学性能、旋转黏度以及复鞣剂的形态。此外,通过实验研究了产品的物理性能和化学反应性。最后,还通过应用试验考察了丙烯酸树脂复鞣剂与本产品的复鞣性能。结果表明:纯化样品在1058~1062 cm~(-1)处出现S=O特征吸收峰,验证了硫酸化不饱和油与丙烯酸类聚合物进行了部分接枝共聚。引入硫酸化不饱和油可以适当降低复鞣剂成膜物的玻璃化转变温度(Tg),其Tg在pH 3~5时,随pH升高而升高。引入铬粉的复鞣剂成膜物Tg亦明显提高。吸湿后的成膜物弹性增强,柔软性良好。采用适量NaOH溶液中和会使产品抗张强度增大,断裂伸长率增加。该种复鞣剂微粒近似球形,粒度分布均匀,中和后平均粒径由72nm减小为66 nm。应用试验表明,改性复鞣剂综合性能较丙烯酸树脂复鞣剂乳液更佳。 相似文献
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以马来酸酐(MA)、丙烯酸(AA)和丙烯酸十八酯(SA)为原料,采用偶氮二异丁氰作为引发剂,在乙醇介质中,共聚生成了较高相对分子质量和高羧基电荷密度的聚马来酸酐-丙烯酸-丙烯酸十八酯(MA-AA-SA)三元共聚物PMAS,并将其用于腈纶织物染色后的皂洗工序中.通过探讨单体配比、引发剂用量、反应时间和皂洗剂用量等因素对皂洗性能的影响,得到优化的合成工艺条件为:m(MA)∶m(AA)∶m(SA)=2∶6∶2.5,ω(引发剂)=2.5%(相对于原料的质量分数),反应温度65℃,反应时间7h;应用试验表明,PMAS用量为2 g/L时,皂洗效果最佳,织物皂洗后湿摩擦牢度达4~5级,干摩擦牢度达5级,且具有良好的防沾色性能. 相似文献
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聚合型多元羧酸的合成及其在柞丝绸防皱整理中的应用研究 总被引:2,自引:0,他引:2
合成马来酸(MA)、依康酸(IA)共聚物(PMI),用于柞丝绸的抗皱整理,通过正交试验优选了其在柞丝绸防皱整理中的应用工艺,结果表明:织物经PMI整理后,湿弹性显著提高,耐洗性较好,对织物的白度和强度基本无影响。 相似文献
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The effectiveness of nisin, lactate salts, and high hydrostatic pressure to inhibit the growth of Listeria monocytogenes and Salmonella in sliced cooked ham was studied through a combination of PCR-based detection methods, most probable number, and classical microbial enumeration techniques (International Organization for Standardization protocols). A synergistic effect to inhibit a cocktail of Listeria monocytogenes CTC1010, CTC1011, and CTC1034 was observed between potassium lactate, high hydrostatic pressure (400 MPa, 17 degrees C, 10 min), and low storage temperature when sliced cooked ham was stored for 84 days at 1 degrees C. The high hydrostatic pressure treatment also proved to be useful to inhibit a cocktail of Salmonella enterica serotypes London CTC1003, Schwarzengrund CTC1015, and Derby CTC1022. 相似文献
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乙烯基类聚合物鞣剂共单体种类配比与应用性能相关性的研究 总被引:6,自引:0,他引:6
采用单因素二次回归正交试验研究了乙烯基类聚合物鞣剂共单体种类、配比与应用性能的相关性,通过比较不同共单体及其不同配比的乙烯基聚合物鞣剂复鞣革样与对比革样的性能,得到了不同共单体对鞣剂应用性能的贡献。结果表明:含极性基团的共单体有利于复鞣革样抗张强度、耐湿热稳定性的提高,但影响革样的柔软性和革样胶原纤维的柔韧性;共单体丙烯酰胺对复鞣革样的丰满性具有特殊的贡献,鞣剂分子中引入丙烯酸酯类共单体有利于复鞣 相似文献
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Georg Zurhelle M. Petz Erika Müller-Seitz Eike Siewert 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1999,208(4):299-300
4-Epimers of tetracycline (TC) and chlortetracycline (CTC) were formed in vivo in laying hens and excreted in substantial
amounts besides the residues of the administered parent compounds via the egg. The recent observation of isochlortetracycline
(i-CTC) and its 4-epimer as being the principal metabolites in eggs after feeding CTC could be confirmed. The ratio of 4-epimer
to parent compound of TC, CTC and i-CTC was lower in egg white and higher in yolk and did not change during medication with
TC or CTC. Further, yet unidentified, in vivo formed metabolites were observed.
Received: 27 July 1998 相似文献
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Mridul Hazarika Sukhomoy K. Chakravarty Pradip K. Mahanta 《Journal of the science of food and agriculture》1984,35(11):1208-1218
The formation of thearubigin pigments in prevalent commercial manufacturing systems such as orthodox roll, roll followed by curling, tearing, crushing (CTC), rotorvane combined with CTC and CTC alone was studied in the six Tocklai released clones TV-1, TV-2, TV-8, TV-9, TV-17 and TV-18. The contribution of the pigment composition, especially thearubigins of high, intermediate and low molecular weights as separated by a Sephadex LH 20 column, was examined on the basis of the types of leaves, degree of wither and roll, conditions of fermentation and the temperature and type of drying. It was apparent that the biochemical pathway in the black tea processing could be conveniently followed from the thearubigin formation. Further, the amount of high molecular weight thearubigin could determine the quantity of cream formed in a black tea brew. The thearubigin and concomitant pigments such as theaflavin have distinct organoleptic properties and their variation was reflected in the overall quality of the finished product. 相似文献
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Georg Zurhelle M. Petz Erika Müller-Seitz Eike Siewert 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1999,59(1):299-300
4-Epimers of tetracycline (TC) and chlortetracycline (CTC) were formed in vivo in laying hens and excreted in substantial amounts besides the residues of the administered parent compounds via the egg. The recent observation of isochlortetracycline (i-CTC) and its 4-epimer as being the principal metabolites in eggs after feeding CTC could be confirmed. The ratio of 4-epimer to parent compound of TC, CTC and i-CTC was lower in egg white and higher in yolk and did not change during medication with TC or CTC. Further, yet unidentified, in vivo formed metabolites were observed. 相似文献
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Pradip K. Mahanta Mridul Hazarika 《Journal of the science of food and agriculture》1985,36(11):1133-1139
Chlorophylls and concomitant pigments along with catechins were analysed in shoots from various Tocklai released clones with pronounced genetic variation and in the corresponding orthodox black teas. Comparison of these values with tasters' score showed that the shade of colour of an orthodox black tea is influenced mostly by pheophytin and thearubigins. The degradation of chlorophyll into pheophytin and pheophorbide was also studied in orthodox and crush - tear - curl (CTC) teas. The observations indicated that both pheophytin and pheophorbide are always higher in orthodox than in CTC teas made from the same leaf source. 相似文献
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Excretion of tetracycline and chlortetracycline in eggs after oral medication of laying hens 总被引:1,自引:0,他引:1
After dosing laying hens orally with tetracycline (TC) through either drinking water (0.25 and 0.5 g/l for 5 days) or feed (300 and 600 ppm for 7 days), and chlortetracycline (CTC) through feed (600 ppm) residues were determined by an agar plate diffusion technique in cylinders with Bacillus cereus as test-organism, separately for albumen and for yolk. The sensitivity threshold was 0.07 micrograms/g in albumen and 0.15 micrograms/g in yolk for TC and 0.01 micrograms/g in albumen and 0.06 micrograms/g in yolk for CTC. Drug excretion via egg was 3-fold higher for TC than for CTC. The drug was excreted preferentially into the yolk (about 75% of the total amount) and the elimination period lasted between 6 and 11 days for TC and 9 days for CTC, after treatment. Tetracycline use in laying hens is discussed, taking into consideration the proposals presented by the joint FAO/WHO Expert Committee on Food Additives. 相似文献
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Farzana Chowdhury Georg Langenkämper Manfred Grote 《Journal für Verbraucherschutz und Lebensmittelsicherheit》2016,11(1):61-69
A large source of antibiotic active compounds and resistant bacteria is livestock waste, distributed as fertilizer on fields, used for vegetable cultivation. Frequently consumed vegetable, contaminated by low levels of antibiotics, may contribute to the development of bacterial antibiotic resistance. The objective of this work was to estimate the possible role of red cabbage as reservoir and carrier of antibiotic contaminants into the food chain. Red cabbage was exposed to antibiotics in hydroponic cultures and farming conditions. Enrofloxacin (ENR), chlortetracycline (CTC), monensin (MON) and amoxicillin (AMO) were separately added to nutrient solutions. Analysed by sequential extraction and LC–MS/MS methods, the plants revealed a remarkable uptake of CTC and in particular ENR (old leaves 0.22 mg/kg fresh weight (fw) CTC, 6.0 mg/kg fw ENR; roots up to 215.0 mg/kg fw CTC, 14.6 mg/kg fw ENR). The uptake of MON was significantly lower and AMO was not detectable. Red cabbage was also grown on manure-fertilized plots. The pig manure contained defined amounts of CTC and ENR (50 and 150 mg/kg). At harvest the edible parts of cabbage had between 9.2 to 16.9 µg/kg fw ENR, while there was no evidence obtained for the uptake of CTC. Finally, production steps of canned red cabbage were examined for carry over effects. Traces of tetracycline (16.4–19.2 µg/kg fw) were detected in supplies of freshly harvested vegetable, grown conventionally, but not in the marketable final product. 相似文献