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光引发剂对UV喷墨油墨固化过程流变行为的影响 总被引:1,自引:1,他引:0
UV喷墨油墨由颜料、预聚物、活性单体、光引发剂及各种助剂组成,光引发剂是影响UV喷墨油墨固化的关键因素之一。为了研究光引发剂对油墨固化需要的能量及固化速度的影响,使用TPO、907、ITX3种引发剂,运用配方设计原理制备了7种青色油墨,用紫外光照射使油墨固化,测试油墨样品在受到紫外光照射时发生固化反应过程中的流变学行为,通过测试油墨样品的动态弹性率G’、损耗弹性率G”等流变学参数随固化程度而变化的规律,探讨用流变学参数评价UV喷墨油墨固化速度的方法。研究结果表明:含有907和ITX的引发剂体系出现凝胶的时间短,固化快,对实验所制备油墨的引发效果最佳。 相似文献
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《功能材料与器件学报》2015,(5)
光引发剂是紫外光(UV)感光树脂固化体系的重要组分,是决定固化速率和固化程度的主要因素之一,对光固化体系起决定性作用。本研究以二苯甲烷、α-溴代异丁酰氯为起始原料,高效、绿色的制备出一种α-羟基酮双官能团光引发剂。目标化合物的结构通过核磁、红外光谱和质谱完全表征,同时利用高效液相色谱分析了其质量。 相似文献
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一种新型脂环族环氧树脂丙烯酸酯的紫外光固化 总被引:6,自引:0,他引:6
研究了阳离子引发剂的用量对脂环族环氧树脂紫外光固化的影响.并以脂环族环氧树脂为原料合成了一种新的用于紫外光固化的脂环环氧丙烯酸酯,研究了不同的引发剂对这种树脂固化反应速率的影响,测定了不同体系固化后的体积收缩率和线收缩率.对该树脂及不同体系的固化膜进行了FT-IR表征,表明所合成的新树脂含有两种官能团;用DSC对不同体系的固化膜进行了分析,结果证明加入自由基-阳离子混杂光引发剂的体系固化后具有较高的玻璃化温度. 相似文献
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目前,对紫外光(UV)固化氟醇改性环氧树脂的报道较少。通过溶液聚合法合成了环氧丙烯酸酯(EAA)和一种可UV固化的氟醇改性环氧树脂——十三氟环氧丙烯酸酯(F13-EAA),将F13-EAA、活性稀释剂、EAA按不同质量比混合,加入光引发剂配制涂料后涂覆于马口铁表面,采用UV固化成膜。通过测定凝胶率和吸水率,研究了稀释剂种类、光引发剂种类和含量、F13-EAA含量、涂膜厚度及光照时间对F13-EAA/活性稀释剂/EAA体系涂膜光固化速率及吸水率的影响。结果表明:当F13-EAA∶HDDA(1,6-己二醇双丙烯酸酯)∶EAA质量比为30∶20∶50时,在3%Daroeur光引发剂下,UV照射20 s后,凝胶率达87.6%,吸水率仅为0.5%,硬度为4 H,附着力为3级,耐冲击性为600 N·cm,性能优异,满足使用要求。 相似文献
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Kemin Wang Yuhui Lu Penghui ChenJingsong Shi Hongning WangQiang Yu 《Materials Chemistry and Physics》2014
Benzophenone (BP) is a common initiator which is often used in the UV-curing production and related fields. However, the shortcomings such as toxicity, odor, and migration always limit the development of the traditional BP photoinitiator. Polymeric benzophenone photoinitiator (PEG-BP) was synthesized basing on polyethylene glycol (PEG), succinic anhydride, 4-hydroxybenzophenone and epichlorohydrin. The structure of PEG-BP was characterized by IR and 1H NMR. The radiation absorption of PEG-BP was detected by UV spectrophotometer with the maximum absorption wavelength at 283 nm in acetonitrile solvent, undergone significant redshift corresponding to small molecule photoinitiator BP, thus enhanced the photosensitive efficiency of UV-curing system in the long wavelength region. Besides, PEG-BP has better water solubility than BP, thus could be used in both oil and aqueous solution. The obvious advantage of this initiator was the elimination of amine based hydrogen donors and to provide alternative hydrogen donors with easily availability and non-toxicity. The effects of molecular weights of PEG-BP, photoinitiator concentration, UV-radiation intensity and different monomers on photopolymerization kinetics were investigated in detail. The synthesized polymeric photoinitiators are attractive to be used as type II photoinitiators. 相似文献
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Photocatalytic degradation of Remazol Red F3B using ZnO catalyst 总被引:9,自引:0,他引:9
The photocatalytic degradation of aqueous solution of a commercial azo-reactive textile dye, Remazol Red F3B, has been investigated in a batch slurry reactor, in the presence of ZnO catalyst using two different UV light sources emitting at 254 nm and 365 nm. The effects of various process variables on degradation performance of the process have been investigated. The results showed that decolourization and total organic carbon (TOC) removal are both affected in the same manner by the solution pH in the pH range 6-10, showing maxima at pH 7 and pH 10. They are inversely related to the dye concentration, they increase in power-law with the light intensity. Decolourization is faster with 365 nm UV. TOC removal is not affected by UV wavelength in the initial period up to 20 min, after which it progresses faster under 365 nm UV radiation. These results indicate that the UV wavelength influences especially the degradation rate of the intermediate products generated during the initial period of the photocatalytic process. Finally, catalyst loading affects both efficiencies in the same trend, which are maximized at about 2 g/l catalyst loading. 相似文献
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采用干混法制备了掺TiO2水泥砂浆,测试了砂浆力学性能,研究了TiO2掺量、水化龄期、光源类型及光强等因素对罗丹明B降解性能的影响。结果表明,随TiO2掺量增加,砂浆对罗丹明B的降解率增加,而砂浆强度则呈先增加后降低规律。在相同TiO2掺量条件下,砂浆对罗丹明B的降解率随水化龄期延长而降低。与水化3 d试件相比,水化28、180 d掺5%TiO2水泥砂浆对罗丹明B的降解率分别降低7.84%、11.21%。砂浆对罗丹明B的总降解率随光源类型、光强的变化不明显,但其降解速率随紫外线光强的增大而显著提高。在波长(λ=365 nm)、光射时间(60 min)均相同的条件下,与20 W紫外灯相比,200 W紫外灯照射下的掺5%TiO2水泥砂浆对罗丹明B的降解率提高约80%。与太阳光相比,200 W紫外灯照射60 min砂浆对罗丹明B的降解率为85.54%,仅降低约1.46%。 相似文献
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UV curing behavior of a highly branched polycarbosilane 总被引:1,自引:0,他引:1
Houbu Li Litong Zhang Laifei Cheng Haitao Kang Yiguang Wang 《Journal of Materials Science》2009,44(4):970-975
The UV curing behavior of a highly branched polycarbosilane (HBPCS) was studied by differential scanning photo calorimeter
(DPC) measurements. 2-Hydroxy-2-Methyl-Phenyl-Propane-1-one (Photocure-1173) was selected as photoinitiator. In order to accelerate
the curing reaction rate of polycarbosilane, acrylic reactive diluent tripropane glycol diacrylate (TPGDA) was also added
to the polymer system. The effect of TPGDA content, photoinitiator concentration, temperature, light intensity, and the curing
atmosphere was investigated. The results indicated that the TPGDA greatly enhanced the reaction rate of the HBPCS system.
The TPGDA content, photoinitiator concentration, temperature, and light intensity had their own optimal values to get the
maximum ultimate conversion percentage and the reaction rate. The oxygen atmosphere helped to increase the final conversion
percentage though it could retard the reaction rate. 相似文献
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An automated column fabrication technique that is based on a ultraviolet (UV) light-emitting diode (LED) array oven, and provides precisely controlled "in-capillary" ultraviolet (UV) initiated polymerization at 365 nm, is presented for the production of open tubular monolithic porous polymer layer capillary (monoPLOT) columns of varying length, inner diameter (ID), and porous layer thickness. The developed approach allows the preparation of columns of varying length, because of an automated capillary delivery approach, with precisely controlled and uniform layer thickness and monolith morphology, from controlled UV power and exposure time. The relationships between direct exposure times, intensity, and layer thickness were determined, as were the effects of capillary delivery rate (indirect exposure rate), and multiple exposures on the layer thickness and axial distribution. Layer thickness measurements were taken by scanning electron microscopy (SEM), with the longitudinal homogeneity of the stationary phase confirmed using scanning capacitively coupled contactless conductivity detection (sC(4)D). The new automated UV polymerization technique presented in this work allows the fabrication of monoPLOT columns with a very high column-to-column production reproducibility, displaying a longitudinal phase thickness variation within ±0.8% RSD (relative standard deviation). 相似文献
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以2-羟基-2-甲基-1-苯基丙酮、异佛尔酮二异氰酸酯和丙烯酸羟乙酯合成了一种可聚合紫外光引发剂。用红外光谱、核磁共振谱和紫外-可见吸收光谱对合成产物进行了分析和表征。通过综合热分析仪(Photo-DSC)研究了合成产物和2-羟基-2-甲基-1-苯基丙酮在光固化体系中的引发效率及其固化后的相对迁移率。结果表明,合成的产物为目标可聚合紫外光引发剂,将其添加在紫外光固化体系中,随着添加量从3%增加到15%,引发效率逐渐增强。按照相同自由基浓度条件计算,12%合成产物的引发效率接近于5%1173,但是其固化过程中的迁移率却不到1173的10%。 相似文献
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S掺杂ZnO薄膜光电特性的研究 总被引:1,自引:0,他引:1
采用射频磁控溅射法,在玻璃基片上生长了ZnO:S薄膜。XRD测试表明所制薄膜为六角纤锌矿结构,具有明显的(002)衍射峰。室温下的透射光谱测量结果表明,随着S掺入量的增加,ZnO:S合金薄膜的吸收边向长波长方向移动,但在可见光部分有较高的透过率。在此基础上计算了各样品的禁带宽度,结果表明,在S掺入量小于8%的范围内,随着S掺入量的增加,禁带宽度减小。样品紫外光电导特性明显,在波长365nm、功率4000μW/cm2紫外光源照射下,紫外光与可见光所对应光电流响应之比可达3。 相似文献
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Baek KS Sadasivam KG Lee YG Song YH Jeong T Kim SH Kim JK Kim SH Jeon SR Lee JK 《Journal of nanoscience and nanotechnology》2011,11(8):7495-7498
380 nm ultraviolet (UV) light emitting diodes (LEDs) were grown on patterned n-type GaN substrate (PNS) with silicon dioxide (SiO2) nano pattern to improve the light output efficiency. Wet etched self assembled indium tin oxide (ITO) nano clusters serves as dry etching mask for converting the SiO2 layer grown on n-GaN template into SiO2 nano patterns by inductively coupled plasma etching. Three different diameter of ITO such as 200, 250 and 300 nm were used for SiO2 nano pattern fabrication. PNS is obtained by n-GaN regrowth on SiO2 nano patterns and UV LEDs were grown on PNS template by MOCVD. Enhanced light output intensity was observed by employing SiO2 nano patterns on n-GaN. Among different PNS UV LEDs, LED grown on PNS with 300 nm ITO diameter showed enhancement in light output intensity by 2.1 times compared to the reference LED without PNS. 相似文献
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The thermoluminescence (TL) characteristics of KCl:Eu2+ irradiated with solar and monochromatic ultraviolet (UV) light have been investigated. The glow curves exhibit at least five TL peaks between room temperature and 673 K. The low temperature peaks (<500 K) are very sensitive to the UV radiation, but their intensities practically do not depend on the duration of solar irradiation and are determined by the ratio between the creation rate by UV and the bleaching rate by visible light. The high temperature 650 K peak is not so sensitive, but it is more stable under optical bleaching and its intensity increases supralinearly as exposure time increases. The creation spectrum of the 650 K peak presents a broad band with a maximum at 230 nm that extends in the long wavelength range at least up to 360 nm. The results obtained are discussed in relation to the development of a UV dosemeter with wavelength sensitivity dependence close to the action spectra of UV-related biological effects. 相似文献