导电高分子材料的进展

论述了复合型及结构型导电高分子材料的导电机理,应用和研究进展     

共混复合型导电高分子材料研究进展

介绍了复合型导电高分子材料的概念及特点，重点讨论了共混复合型导电高分子材料的制备方法和影响共混复合型导电高分子材料导电性的主要因素。并对当前共混复合型导电高分子材料的应用及发展趋势作了简要介绍。     

导电高分子材料制备及应用研究进展

在介绍导电高分子材料导电机理的基础上,对目前最常见的两种导电高分子材料的制备方法进行综述;重点讨论了含大型离域π键导电高分子材料、化学掺杂型共轭结构导电高分子材料和新型本征导电高分子材料等本征型导电高分子材料的制备方法,并研究了金属及其氧化物、碳系纳米材料、有机组分以及新型导电填料等对填充型导电高分子材料导电性能的影响;同时对其在电子电器材料、生物医学以及环境保护等方面的应用进行了总结,展望了新型导电高分子材料未来的应用研究方向。     

复合导电高分子材料的改性及应用研究进展

介绍了复合导电高分子材料的主要构成和分类,综述了碳系复合导电高分子材料[如炭黑(CB)填料型、碳纳米管(CNTs)填料型和石墨烯填料型等]、金属系复合导电高分子材料和金属氧化物系复合导电高分子材料的改性进展。最后对复合导电高分子材料的应用和发展前景进行了展望。     

高分子基导电复合材料研究进展

高分子基导电复合材料凭借其导电性、稳定性、加工性等方面的明显优势,成为导电材料研究的热点。系统地介绍了复合型导电高分子材料的导电机理、制备方法并对导电复合材料的应用进行了总结,并展望了导电高分子复合材料的发展趋势。     

导电高分子材料在智能隐身技术中的应用

介绍了导电高分子材料的结构特点及导电机理。简要叙述了导电高分子材料在雷达波智能隐身、红外智能隐身、可见光智能隐身方面的应用情况。指出导电高分子材料在智能隐身领域的良好发展前景,及其作为智能隐身材料实用化应注意的问题。     

导电高分子材料探析

随着高分子材料在导电材料的领域的应用,不仅提高了导电材料的发展速度,还增加了很多以供选择的材料。对导电高分子进行研究后发现,其不仅在导电性能上比其他传统的材料有优势,在其他方面一样存在优势如材料特性。因而,在高分子材料的应用中,不仅要理解导电高分子的特点,还要了解它的应用领域等各个方面使导电高分子满足导电材料的发展需求。     

导电高分子在隐身材料中的应用

研究了导电高分子材料的导电机理,并结合隐身材料的相关理论,分析了导电高分子材料在雷达、红外隐身中的应用原理,论述了国内外隐身导电高分子材料的研究现状,最后分析了该类材料应用于隐身存在的问题及研究的方向。     

导电高分子材料的研究进展

与传统的导电材料相比较,导电高分子材料具有许多独特的性能,例如密度小、易加工、耐腐蚀、结构易变、半导体、可大面积成膜以及电导率可在大范围内调节等特点,显示出了其广阔的应用前景。着重综述了导电高分子材料的分类,并分别介绍了复合型和结构型两种导电高分子材料的制备以及导电机理,列举出了导电高分子材料在隐身技术、显示材料、电池、导体、药物释放、传感器方面的应用,并对导电高分子材料未来的发展前景做了展望。     

导电高分子材料制备及应用进展

导电高分子材料是一类具有导电性能的聚合物材料,通常是由一些有机单体聚合而成,由于其含有共轭的π-电子体系组成,使得电子能够在材料中进行自由移动,从而具有良好的导电性能。导电高分子材料在传感器技术、能源存储和转换、生物医学、电磁屏蔽材料、涂料和涂层等领域得到广泛的应用,主要综述了近几年来导电高分子材料最新研究进展,以及其在相关领域的应用。     

智能型高分子分离膜

本文把智能型高分子分离膜分为荷电型，接枝型，互穿网络型，聚电解质配合物型和导电聚合物型等五种类型，并介绍这一新领域已取得的一些进展和应用前景。     

导电高分子纳米复合材料研究进展

介绍了导电高分子纳米复合材料的特点,综述了导电高分子纳米复合材料的最新研究进展,展望了导电高分子纳米复合材料的发展前景。     

导电高聚物聚苯胺的开发应用

聚苯胺可应用于抗静电，电磁波屏蔽，防蚀，敏感元件有机晶体管，电致变色材料和微电子等领域，具有广阔的市场前景，目前国外已有ＰＡＮ的工业化产品，国内ＰＡＮ的研究开发尚处于实验阶段。     

高分子PTC材料及其器件电阻稳定性研究概况

综述了高分子基ＰＴＣ（正温系数）导电材料及其器件开发中最关键的技术－电阻稳定性的研究现状及 进展,分析了影响电阻稳定性和重要性的因素,提出了辐照交联等方法,并从原理上作了简单介绍。     

新型导电高分子抗静电剂进展

本征型导电高分子抗静电剂是目前发现的使用效果最好的抗静电剂之一．本文简要综述了本征型导电高分子抗静电剂的工作原理、特点、国内外发展现状及发展趋势，其中重点介绍了聚(3，4-二氧乙基噻吩)／聚对苯乙烯磺酸，以及它在感光材料中作为抗静电剂显示的重要作用．     

Conducting Polymer Nanostructures: Template Synthesis and Applications in Energy Storage

Conducting polymer nanostructures have received increasing attention in both fundamental research and various application fields in recent decades. Compared with bulk conducting polymers, conducting polymer nanostructures are expected to display improved performance in energy storage because of the unique properties arising from their nanoscaled size: high electrical conductivity, large surface area, short path lengths for the transport of ions, and high electrochemical activity. Template methods are emerging for a sort of facile, efficient, and highly controllable synthesis of conducting polymer nanostructures. This paper reviews template synthesis routes for conducting polymer nanostructures, including soft and hard template methods, as well as its mechanisms. The application of conducting polymer mesostructures in energy storage devices, such as supercapacitors and rechargeable batteries, are discussed.     

ABTS•+ scavenging activity of polypyrrole,polyaniline and poly(3,4‐ethylenedioxythiophene)

Although many methods are available for the evaluation of the antioxidant capacity of samples presented in the liquid state, typically food and beverages, to date only the 2,2′‐diphenyl‐1‐picrylhydrazyl (DPPH) assay has been applied to the measurement of the antioxidant capacity of solid samples such as active packaging materials. A modified 2,2′‐azino‐bis(3‐ethylbenzothiazoline‐6‐sulfonic acid) diammonium salt (ABTS) assay has been successfully developed for the measurement of the antioxidant capacity of conducting polymer powders. The ABTS^?+ radical scavenging activity of polypyrrole (PPy), polyaniline (PANI) and poly(3,4‐ethylenedioxythiophene) (PEDOT) powders was compared. The ranking order for greatest antioxidant capacity among the conducing polymer powders was PANI > PPy > PEDOT. The reduced forms of all the three conducting polymer samples were found to show greater radical scavenging activity than their as‐prepared partially oxidized forms. The modified ABTS assay is a simple, rapid and sensitive method for evaluating the antioxidant capacity of conducting polymer powders. The method is also suitable for composite antioxidant materials comprising a conducting polymer and a conventional packaging polymer. Copyright © 2010 Society of Chemical Industry     

导电聚合物复合材料技术进展

本文介绍了导电聚合物复合材料的种类及其特性,重点讨论了填充和共混型导电聚合物复合材料的制备方法、研究现状及最新进展,并且展望了它们的发展方向和应用前景。     

导电高分子研究概述

主要介绍了聚乙炔、聚苯胺、聚吡咯、聚噻吩这几类导电高分子在近年来的研究进展 ,集中体现在进一步提高导电高分子的电导率 ,改善其溶解性及可加工性 ,制备缺陷少、结构规整、性能好的高品质导电高分子。同时还展望了导电高分子有待发展的方向     

Mixed electron and proton conductivity of polyaniline films in aqueous solutions of acids: beyond the 1000 S cm−1 limit

BACKGROUND: The application potential of conducting polymers depends on their conductivity. It is generally assumed that the conductivity determined in the dry state is a parameter that unambiguously characterizes them. RESULTS: The conductivity of polyaniline (PANI) films immersed in aqueous solutions of sulfuric acid may be more than 1000 times higher compared with that obtained by measurement of dry films in air, and is estimated to reach a value exceeding 3300 S cm^?1 in 1 mol L^?1 sulfuric acid. This is explained by the reduction of conductivity barriers between conducting PANI islands. CONCLUSION: The organized polymer chains in the conducting islands of a PANI film are separated by disordered regions of low conductivity in the dry state. The penetration of sulfuric acid solution into the disordered areas increases the overall conductivity of the PANI film by improving the electrical contact between the islands through ionic charge transport. The electronic conductivity of the PANI film in the dry state thus converts to mixed electron–proton conduction in acidic aqueous solutions, electron conductivity being dominant in ordered regions and ionic conductivity in disordered regions separating them. Weakly bound protons are the most important ionic charge carriers hopping along the PANI chains. Copyright © 2009 Society of Chemical Industry