Extension and evaluation of the integral model for transient pyrolysis of charring materials

In most numerical simulations of fire growth and fire spread, pyrolysis models are required to calculate the reaction of the solid material to an incident heat flux. Important results of the pyrolysis model are the mass release rate of combustible pyrolysis gases and the surface temperature. In this paper an integral model is evaluated for the prediction of pyrolysis of charring materials. An existing integral model is extended with a finite and semi‐infinite cooling state. In this state both char and virgin material are present but the pyrolysis reactions have been interrupted due to insufficient heat supply. The results show that such a cooling state can occur in flame spread calculations. Simulations with the integral model are further compared with the results of a moving grid model, which has the same physical basis. Unlike the integral model, the moving grid model does not require any assumption for the temperature profile in the solid. The influence of the quadratic assumed temperature profile in the integral model on the accuracy of the predictions of the mass release rate of pyrolysis gases is evaluated for several cases. It is shown that the integral model has problems with sudden variations of the external heat flux. Copyright © 2005 John Wiley & Sons, Ltd.     

Demonstration of the effect of softening and fire resistance of materials on burning characteristics

An important observation during full-scale fires was that burning behaviour is often determined by softening characteristics as well as ignitability, flame spread, etc. Examples include stacking chairs where thermoplastics give a rapid rate of fire growth and suspended ceilings where thermoplastics reduce fire hazard. A test rig has been progressively developed at RAPRA to reproduce the mechanisms and fire growth rates of stacked chairs and to evaluate the role of softening in fire growth. Although the ignitability of fire-retarded materials is less than that of non-fire-retarded grades, the fire growth rate in stacks is similar and may be related to the softening behaviour determined by exposing sheets of material to radiant heat. The rate of fire growth in stacks may be significantly reduced by modifying the softening behaviour of materials, e.g. by using asbestos-reinforced thermoplastics which can form an integral, non-melting felt or by using non-melting materials such as SMC or wood.     

阻燃硬质聚氨酯泡沫塑料垂直火蔓延特性研究

通过一步合成法制备了阻燃硬质聚氨酯泡沫,自主搭建保温材料火蔓延实验台,采用中小尺寸实验对比研究了阻燃及非阻燃硬质聚氨酯的垂直火蔓延特性,分析了火焰结构特性、火蔓延速度、火焰温度、质量损失速率等参数的变化规律。结果表明,火蔓延过程中,材料表面均出现了炭化现象,垂直双面燃烧过程中聚氨酯纯样RPUF燃烧最剧烈,阻燃剂膨胀石墨(EG)、次磷酸铝(AHP)和二乙基次膦酸铝(ADP)的加入,抑制了材料的燃烧和蔓延,使材料燃烧的火蔓延速度、质量损失速率及温度等参数都相应降低。RPUF/AHP5垂直双面火蔓延过程中,火焰稳定性差,在20 s后出现熄灭现象,原因是阻燃剂次磷酸铝(RPUF/AHP5)受热挥发出难燃气体。AHP降解后形成的含磷化合物可促进聚氨酯分子链成炭,导致产生熄灭现象。而RPUF/ADP5火蔓延过程中,同样出现了熄灭现象,其熄灭的程度低于阻燃剂次磷酸铝(RPUF/AHP5)试样。RPUF/EG5火蔓延过程中试样表面温度存在两个峰值,由于RPUF/EG5燃烧生成的炭层不稳定所致。当温度高于400℃时炭层被迅速氧化,热量穿透炭层使内部未燃样品热解,生成温度的第二个峰值。     

Computational fluid dynamics modeling of biomass catalytic fast pyrolysis in bubbling fluidized reactor: Effects of catalyst parameters on process performance

In this study, a computational fluid dynamics mathematical model has been developed for catalytic fast pyrolysis (CFP) of biomass based on multiphase flow, transfer process, and biomass pyrolysis reactions in a bubbling fluidized bed reactor. The multiphase fluid flow, and the inter-phase momentum and energy transfer processes are modeled with Eulerian multiphase formulas, representing the flows of gases and solids (catalyst and biomass) within the reactor. The biomass CFP reactions are described by using a two-stage, semi-global model. Specified secondary tar catalytic cracking process, which considers both intrinsic reaction rates and mass-transfer process, is embedded to the developed model by user-defined function. The model simulation results of pyrolysis product yield and distribution are compared with the experimental data with close agreement. The model is then employed to investigate the effects of structural properties of catalyst, such as specific internal area, average size of active sites, pore diameter, and tortuosity, on products yields and composition. The tar cracking process by the selected catalyst is proposed and the influences of adsorption capability of tar molecule on catalyst surface and external film mass transfer are also analyzed. The developed model can be solved with short computational time and thus it can be employed for further research and engineering designs of the catalytic pyrolysis of carbonaceous materials.     

CFD modeling approach of smoke toxicity and opacity for flaming and non‐flaming combustion processes

Current engineer's methods of fire safety design include various approaches to calculate the fire propagation and smoke spread in buildings by means of computational fluid dynamics (CFD). Because of the increased computational capacity, CFD is commonly used for prediction of time‐dependent safety parameters such as critical temperature, smoke layer height, rescue times, distributions of chemical products, and smoke toxicity and visibility. The analysis of smoke components with CFD is particularly complex, because the composition of the fire gases and also the smoke quantities depends on material properties and also on ambient and burning conditions. Oxygen concentrations and the temperature distribution in the compartment affect smoke production and smoke gas toxicity qualitatively and quantitatively. For safety designs, it can be necessary to take these influences into account. Current smoke models in CFD often use a constant smoke yield that does not vary with different fire conditions. If smoke gas toxicity is considered, a simple approach with the focus on carbon monoxide is often used. On the basis of a large set of experimental data, a numerical smoke model has been developed. The developed numerical smoke model includes optical properties, production, and toxic potential of smoke under different conditions. For the setup of the numerical model, experimental data were used for calculation of chemical components and evaluation of smoke toxicity under different combustion conditions. Therefore, averaged reaction equations were developed from experimental measurements and implemented in ANSYS CFX 14.0. Copyright © 2015 John Wiley & Sons, Ltd.     

Evaluating methods for preventing smoke spread through ventilation systems using fire dynamics simulator

Fires in enclosures equipped with mechanical ventilation remain one of the key issues for fire safety assessment in multifamily homes and industries. Therefore, a wide variation of methods for preventing smoke spread through the ventilation system exist and are applied, in performance‐based designs. Through the use of the heating, ventilation and air conditioning (HVAC) model in the fire dynamics simulator, several different common and less common methods for preventing smoke spread in the ventilation system were tested. The effects on smoke spread with changing building leakage and fire growth rates were also investigated. The results were evaluated by determining the total soot spread from the fire room to other compartments connected to the ventilation system, as well as soot/thermal load on the fans and system in general. The maximum and average heat release rate was also of interest and hence compared between systems. It was found that, while many methods perform similar, a few proven methods, such as fire and smoke dampers, performed very well with very little smoke spread to the rest of the system. The study should be considered as an introduction to implementing a similar methodology in specific cases because different ventilations systems will present very different challenges and weaknesses. Copyright © 2016 John Wiley & Sons, Ltd.     

石油储罐消防安全设计

消防系统分为灭火系统和安全疏散系统。随着人们对火灾安全重视度的提高及科技的不断发展,我们在灭火系统设计,设备研究,疏散软件研发及性能化防火等方面都有了很大的提升。其目的就是为了确保消防设施在工业企业中能真正有效的应用,起到预防,灭火,减少损失的作用。石油化工企业在生产过程中存在着一系列的安全问题,因为其生产过程中常伴随着高温、高压、氧化、还原或临氢等化学反应。如果遇到操作不当或失误,引起的火灾和爆炸的危险性比非化工企业要大,容易发生更为严重的安全事故。根据多起消防火灾案例及消防法规,结合国内外油品防火设计思路,我们从石油储罐的危险性研究和消防系统布置为主进行了合理化设计。     

Effect of shielding rates on upward flame spread over extruded polystyrene foam in vertical channel and heat transfer mechanism

Fire hazard of extruded polystyrene (XPS) thermal insulation materials has aroused public concern. In order to develop flame spread theory and the guideline for fire risk assessment of XPS, an experimental study on upward flame spread behavior and heat transfer mechanism of XPS in a vertical channel with different frontal shielding rates was conducted. Maximum temperature at the place 2 cm from XPS surface and at the center of channel first increase and then decrease as the shielding rate rises. The former is higher than the latter. Experimental value of average flame height rises as the shielding rate increases. A model for predicting the flame height is built, and the predicted results are consistent with the experimental results. Moreover, the relation between flame height and pyrolysis height under different shielding rates is obtained. The flame spread rate rises as the shielding rate increases. A prediction model of flame spread rate is established, and its prediction results are more accurate compared with those from previous models. The model also predicts that radiative heat transfer is the dominant heat transfer mode, accounting for 93% of the total heat transfer. This work is beneficial for fire risk assessment and fire safety design of building façade.     

PYROLYSIS AND CHLORINATION OF SMALL HYDROCARBONS

The bases of the kinetic modeling of Chlorine containing systems are addressed in this article

A kinetic scheme, involving more than 300 elementary reactions and 46 molecular and radicalic species, has been developed based on general thermochemical kinetic theories as well as the consolidated know-how in the field of hydrocarbon pyrolysis

Several comparisons with commercial and laboratory experimental data indicate a fair agreement in a wide area of lower and higher pressures (up to 30atm) also covering the high temperature range of methylchloride pyrolysis (1000°C). Mathematical model of EDC pyrolysis furnaces already allows to evaluate process performances and alternatives accounting for fouling rates and on-stream times

The kinetic scheme can be applied to study the methane chlorination reaction system and the dichloroethane (EDC) pyrolysis system. The kinetic scheme is coupled with a furnace model and appropriate mathematical techniques to solve the resulting system of material, energy and momentum conservation equations. A coking model has also been incorporated as fouling of coils determines the run length of the furnaces. Simulation of the pyrolysis of EDC to produce vinyl chloride shows that the results are in reasonable agreement with observed values and trends. Application of the model for the design of coils and evaluation of process alternatives is discussed.     

Investigation of polymeric materials using the cone calorimeter

The use of polymeric materials in building or construction applications is steadily increasing. Therefore, the potential for these materials to be exposed to fire is also increased. The understanding of the pyrolysis characteristics of these materials is thus a necessity. There are many standard tests used to evaluate materials. Unfortunately, the correlation between these tests and large scale fire is less than desirable. A new bench scale rate of heat release apparatus, the Cone Calorimeter, is now being used more frequently in pyrolysis testing of polymeric materials. This apparatus has been shown to correlate much better between room scale testing and large scale fire testing. The cone Calorimeter provides a pyrolysis profile of a material under ambient oxygen conditions. Characteristics such as ignition time, total heat release, maximum rate of heat release, mass loss during pyrolysis, CO₂, CO, and smoke production are determined. In this work several almost neat polymers are examined and the general pyrolysis characteristics of these polymers are discussed. The objective of this work is to provide information of basic polymeric pyrolysis properties of these materials. Variations in the material, i.e., molecular weight, polydispersity, and residual catalysis, along with changes in testing procedures, can have dramatic effects on results. Obviously the addition of flame retardant and flame retardant packages to any of these materials will have dramatic effects on results.     

Study of vertical upward flame spread on charring materials—Part II: Numerical simulations

Simulation results, obtained by means of application of an enthalpy‐based pyrolysis model, are presented. The ultimate focus concerns the potential of the model to be used in flame spread simulations. As an example we discuss vertically upward flame spread over a charring material in a parallel plate configuration. First, the quality of the pyrolysis model is illustrated by means of cone calorimeter results for square (9.8 cm × 9.8 cm exposed area), 1.65 cm thick, horizontally mounted MDF samples. Temperatures are compared at the front surface and inside the material, for different externally imposed heat fluxes (20, 30 and 50 kW/m²), for dry and wet samples. The mass loss rate is also considered. Afterwards, vertically upward flame spread results are reported for large particle board plates (0.025 m thick, 0.4 m wide and 2.5 m high), vertically mounted face‐to‐face, for different horizontal spacings between the two plates. The simulation results are compared to experimental data, indicating that, provided that a correct flame height and corresponding heat flux are applied as boundary conditions, flame spread can be predicted accordingly, using the present pyrolysis model. Copyright © 2010 John Wiley & Sons, Ltd.     

Effect of Melting Behaviour on Upward Flame Spread of Thermoplastics

The effect of melting behaviour on upward flame spread of thermoplastic materials when subjected to small ignition sources and considered to suffer no external flux was studied using large-scale tests. For moderate fire conditions the cone calorimeter was utilized, with the sample set in a vertical orientation to study the melting behaviour of the specimens. Under these conditions the results indicate that the melting behaviour significantly affects upward flame spread behaviour. A pool of the melt which formed at the base of the vertically oriented sample tested creates a pool fire which then controls the fire growth and flame spread. In contrast, it was found that some thermoplastic materials which have higher glass transition temperatures or undergo a special pyrolysis process such as depolymerization, intumescing or charring do not experience significant melting behaviour when exposed to the same thermal insult. As a result, they behave very differently in terms of upward flame spread. The study also indicates that the melting behaviour of thermoplastic materials is an important characteristic in fires which should be taken into account in the development of modelling, in particular for upward flame spread models. © 1997 by John Wiley & Sons, Ltd.     

Predicting HCl concentrations in fire enclosures using an HCl decay model coupled to a CFD‐based fire field model

The amount of atmospheric hydrogen chloride (HCl) within fire enclosures produced from the combustion of chloride‐based materials tends to decay as the fire effluent is transported through the enclosure due to mixing with fresh air and absorption by solids. This paper describes an HCl decay model, typically used in zone models, which has been modified and applied to a computational fluid dynamics (CFD)‐based fire field model. While the modified model still makes use of some empirical formulations to represent the deposition mechanisms, these have been reduced from the original three to two through the use of the CFD framework. Furthermore, the effect of HCl flow to the wall surfaces on the time to reach equilibrium between HCl in the boundary layer and on wall surfaces is addressed by the modified model. Simulation results using the modified HCl decay model are compared with data from three experiments. The model is found to be able to reproduce the experimental trends and the predicted HCl levels are in good agreement with measured values. Copyright © 2006 John Wiley & Sons, Ltd.     

Validation of the lumped parameter code COCOSYS against large‐scale OECD PRISME 2 fire experiments

Fire safety analysis is a major issue for nuclear power plants (NPPs) in the context of deterministic safety assessments as well as of probabilistic safety analyses. Oil reservoirs and cables represent major fire loads. Therefore, simulations of oil and cable fires are of interest for quantifying the risk of such internal hazards in NPPs. To investigate the applicability of lumped parameter (LP) modelling, validations against fire experiments are required. In this way, results obtained with the LP code COCOSYS for simulations of oil and cable fire experiments conducted in the OECD PRISME 2 Project are presented. The PRISME 2 VSP (vertical smoke propagation) tests involving oil fires in a confined and mechanically ventilated facility were used to assess the ability of the LP code to simulate smoke propagation through a horizontal opening from the fire compartment to a compartment on top of it. As it was already identified in the “International Collaborative Fire Modelling Project (ICFMP),” this type of opening might cause problems in fire simulations, particularly for zone or LP fire models. In these simulations, attention has been paid to the coupling between the fire and the surrounding environment due to the decrease of oxygen concentration. Furthermore, different cable materials have been tested in the PRISME 2 CORE (completing and repeating) test campaign. By simulating the CFS‐3 (cable fire spreading) test with confined underventilated conditions, the applicability of the COCOSYS cable fire model with input parameters deduced from open atmosphere fire tests (CORE‐2) was analysed. Results show that the applicability of a LP fire model to predict the pyrolysis rate is partly limited for both oil and cable fires, in confined environment. However, simulations with prescribed pyrolysis rates show encouraging results in good agreement with the experimental data and underline the capability of the LP code COCOSYS to simulate the interaction between the thermal hydraulics inside compartments and the fire source.     

Thermal modelling of gypsum plasterboard assemblies exposed to standard fire tests

Gypsum plasterboards are widely used for compartmentation and for retarding the spread of fire in buildings. Although numerous heat transfer studies have been conducted, literature indicates there are extensive differences in the thermal properties used in these studies. Comprehensive experimental and numerical analyses have been conducted to elucidate the leading factor in the ablation of a gypsum board system when it is exposed to the standard fire resistance test. A methodology based on both simultaneous thermal analysis and computational modelling is proposed to understand the behaviour of a gypsum plasterboard when the boundary temperature increases quickly as one side of the wall is subjected to the standard ISO 834. Finally, four different wall assemblies made of a commercial fireproof plasterboard system are exposed to the standard test. The temperature on the unexposed face is examined to validate the computational model of the plasterboard. Copyright © 2015 John Wiley & Sons, Ltd.     

Reconstruction of Grenfell Tower fire. Part 1: Lessons from observations and determination of work hypotheses

The Grenfell Tower fire occurred on 14 June 2017, killing 72 people. The pattern and speed of vertical and horizontal fire spread characterize this catastrophic event. Plentiful video and photographic data of the fire spread available has been carefully verified and concatenated into a database. The verified data have been superimposed on a projection of the Grenfell Tower in order to track the development of the fire. The surface that is unburnt, burning, or extinguished, as well as the presence of internal fire at any given location, is thus recorded for the duration of the fire. An analysis of the results showed that the initial vertical propagation can be divided into three phases. After the façade ignited at the fourth floor, vertical propagation over time is linear, with a vertical fire spread rate of around 3.5 m/min until the fire reached the sixth floor. Then fire propagation decelerated. Finally, fire spread accelerated with a power four dependence. The maximum vertical fire spread rate was around 8 m/min as the fire reached the crown at the top of the building. Horizontal spread proved to be greatest at the level of the crown (0.293 ± 0.005 m/min). There is a linear relationship between speed of horizontal fire spread and height. These correlations and observations yield important conclusions, and eight different hypotheses capable of explaining the global behaviour of the fire are suggested.     

A New Approach to Contact Drying Modelling

This paper deals with contact drying modelling. The more general models of granular material contact dryers are based on assumptions proposed by Schlunder and al. (1.21. In this paper, a sensitivity study of the models is presented in order to find and to explain the influence of the different arameters.

A new approach, based on the same Schlunder's assumptions, but with less restrictive hypothesis, which can be applied to drying in the presence of an inert gas as well as vacuum drying and which take into account phenomena which were ignored untill now such as the local grain dehydration kinetics or the vapour diffusion inside the bed has been developped.

This new model has been compared uith some experimental results found in the litterature. A good agreement between the calculated and the experimental results has been observed. Moreover, this model is able to justify some assumptions made by Schlunder, which have not been so untill now.     

Reconstruction of the Grenfell Tower fire – Part 4: Contribution to the understanding of fire propagation and behaviour during horizontal fire spread

The tragic events at Grenfell Tower in 2017, involving a combustible façade system, have raised concerns regarding the fire risk that these systems pose. In this series of articles, so far published, fire development inside the initial apartment has been investigated using an appropriate computational fluid dynamics (CFD) model. Several scenarios including different fire sources and ventilation conditions were addressed. Fire propagation through the window to the external façade and to higher apartments was modelled. This model was validated by comparing the numerical results with the visual observations reported in the Grenfell Inquiry. A CFD model of the complete east face of the Grenfell Tower was then created. This paper details CFD modelling of the complete Grenfell Tower façade during the late horizontal phase of fire spread. As the physics of lateral flame spread is different from that for upward flame spread, it is important to assess the validity of the model, thus far developed, for this configuration. Fire propagation over the whole façade is modelled and compared with observations from the real disaster. This provides a better understanding of its fire behaviour and of the contribution of architectural details and their impact on fire spread.     

Prediction of unburned carbon and NOx in a tangentially fired power station using single coals and blends

Coal blends are now widely used by the power generation industry and the general characteristics are well known. Attention is still directed to the emission of NO_x, which is subject to more stringent regulation, and to the amount of carbon in ash. The latter is increased when low NO_x burners are employed, which is the norm now. It is also increased as a result of additional air staging when over-fire air is added in furnaces, especially tangential fired systems. Such a furnace is studied here. Two approaches can be employed for prediction of NO_x and unburned carbon. The first approach uses global models such as the ‘slice’ model which requires the combustor reaction conditions as an input but which has a detailed coal combustion mechanism. The second involves a computational fluid dynamic model that in principle can give detailed information about all aspects of combustion, but usually is restricted in the detail of the combustion model because of the heavy computational demands. The slice model approach can be seen to be complimentary to the CFD approach since the NO_x and carbon burnout is computed using the slice model as a post-processor to the CFD model computation. The slice model that has been used previously by our group is applied to a commercial tangentially fired combustor operated in Spain and using a range of Spanish coals and imported coals, some of which are fired as blends. The computed results are compared with experimental measurements, and the accuracy of the approach assessed. The CFD model applied to this case is one of the commercial codes modified to use a number of coal combustion sub-models developed by our group. In particular it can use two independent streams of coal and as such it can be used for the combustion of coal blends. The results show that both model approaches can give good predictions of the NO_x and carbon in ash despite the fact that certain parts of the coal combustion models are not exactly the same. However, if a detailed insight into the combustor behaviour is required then the CFD model must be used.