In-plane shear properties of unidirectional glass fiber (U)/random glass fiber (R)/epoxy hybrid and non-hybrid composites

The in-plane shear properties (shear strength τ_xy and shear modulus G_xy) of unidirectional glass fiber (U)/random glass fiber (R)/epoxy hybrid and non-hybrid composites have been investigated experimentally and theoretically. The effect of stacking sequence and random fiber relative volume fraction (V_fR/V_fT) in hybrid composites were reported. Laminates were fabricated by hand lay-up technique with a total of 5 plies, by varying the number and position of random glass layers so as to obtain four different hybrid laminates; i.e. [0.5R/U/U]_S, [U/0.5R/U]_S, [U/U/0.5R]_S, and [U/R/U/R/U]. All unidirectional fiber laminate [U]₅ and another of all random fiber laminate [R]₅ were also fabricated for comparison purpose. The average thickness of the manufactured laminates is 5.5 ± 0.2 mm and the total fiber volume fraction (V_fT) is 37%. Failure modes of all specimens were investigated. Results indicated that the in-plane shear properties (shear strength τ_xy and shear modulus G_xy) of unidirectional fiber composite can be considerably improved by incorporation of random glass fiber and forming hybrid composites.     

Monotonic properties of unidirectional glass fiber (U)/random glass fiber (R)/epoxy hybrid composites

The main objective of the present paper is to study the tensile and bending behaviors of unidirectional glass fiber (U)/random glass fiber (R)/epoxy hybrid composites with total fiber volume fraction (V_fT) = 37%. Six kinds of laminated composites of average thickness 5.5 mm were manufactured using hand lay-up technique; i.e. [R]₅, [U/R/U/R/U], [U/0.5R/U]_S, [0.5R/U/U]_S, [U/U/0.5R]_S, and [U]₅. In bending test, notched and unnotched specimens were tested. For this purpose different circular notch sizes (D = 3, 6, 9 mm) were drilled at the specimen center. Tensile strength, tensile modulus, Poisson’s ratio, bending strength and bending modulus were determined experimentally. The effect of stacking sequences, random fiber relative volume fraction (V_fR/V_fT), and notch diameter on the mechanical properties of the mentioned composite types were studied. Failure modes of all specimens were investigated.     

Improved cryogenic interlaminar shear strength of glass fabric/epoxy composites by graphene oxide

The cryogenic interlaminar shear strength (ILSS) at cryogenic temperature (77 K) of glass fabric (GF)/epoxy composites is investigated as a function of the graphene oxide (GO) weight fraction from 0.05 to 0.50 wt% relative to epoxy. For the purpose of comparison, the ILSS of the GF/epoxy composites is also examined at room temperature (RT, 298 K). The results show that the cryogenic ILSS is greatly improved by about 32.1% and the RT ILSS is enhanced by about 32.7% by the GO addition at an appropriate content of 0.3 wt% relative to epoxy. In addition, the ILSS of the composite at 77 K is much higher than that at RT due to the relatively strong interfacial GF/epoxy adhesion at 77 K compared to the RT case.     

Mechanical properties of carbon fiber/fullerene-dispersed epoxy composites

This study examined the effect of fullerene dispersion on the mechanical properties of carbon-fiber reinforced epoxy matrix composites (CFRPs). Mechanical properties such as tension, compression, open-hole compression, comparession after impact (CAI), binding, short beam shear, and interlaminar fracture toughness were evaluated for [0]₈, [90]₁₆, [45/0/?45/90]_2S laminates. Tension and compression strengths increased 2–12% by dispersing 0.5% of fullerene into the matrix resin. Furthermore, interlaminar fracture toughness of the composite was improved by about 60%. It was revealed that a small amount of fullerene (0.1–1 wt.%) increased the failure strain of epoxy resin itself, thereby improving the CFRP strength.     

Enhancement on interlaminar shear strength and tribological properties in water of ultra high molecular weight polyethylene/glass fabric/phenolic laminate composite by surface modification of fillers

The ternary laminate composite of ultra high molecular weight polyethylene (UHMWPE)/high strength glass fabric (S-glass fabric)/phenolic resin was prepared, in which UHMWPE microparticles were etched by chromic acid and S-glass fabrics were treated by silane coupling agent. The interlaminar shear strength (ILSS) and tribological properties of the composite in water environment were investigated, in comparison with those of the composite without any treatments on fillers and the composite with single treatment on UHMWPE. Results showed that the composite with the combined treatment exhibited the best interfacial bond, accordingly showing remarkably enhanced water repellency, ILSS and tribological properties under water lubrication. Furthermore, after experiencing 48 h water immersion, the composites with both single and combined treatment did not suffer any degradation of ILSS and water-lubricated tribological performances, showing excellent duration in water environment.     

Hygrothermal effects on the shear properties of carbon fiber/epoxy composites

The environmental factors, such as humidity and temperature, can limit the applications of composites by deteriorating the mechanical properties over a period of time. Environmental factors play an important role during the manufacture step and during composite’s life cycle. The degradation of composites due to environmental effects is mainly caused by chemical and/or physical damages in the polymer matrix, loss of adhesion at the fiber/matrix interface, and/or reduction of fiber strength and stiffness. Composite’s degradation can be measure by shear tests because shear failure is a matrix dominated property. In this work, the influence of moisture in shear properties of carbon fiber/epoxy composites (laminates [0/0]_s and [0/90]_s) have been investigated. The interlaminar shear strength (ILSS) was measured by using the short beam shear test, and Iosipescu shear strength and modulus (G ₁₂) have been determinated by using the Iosipescu test. Results for laminates [0/0]_s and [0/90]_s, after hygrothermal conditioning, exhibited a reduction of 21% and 18% on the interlaminar shear strenght, respectively, when compared to the unconditioned samples. Shear modulus follows the same trend. A reduction of 14.1 and 17.6% was found for [0/0]_s and [0/90]_s, respectively, when compared to the unconditioned samples. Microstructural observations of the fracture surfaces by optical and scanning electron microscopies showed typical damage mechanisms for laminates [0/0]_s and [0/90]_s.     

Influence of fiber content on the mechanical and dynamic mechanical properties of glass/ramie polymer composites

The combination of glass and ramie fibers with a polyester matrix can produce a hybrid material that is competitive to all glass composites (e.g. those used in the automobile industry). In this work, glass and ramie fibers cut to 45 mm in length were used to produce hybrid polymer composites by resin transfer molding (RTM), aiming to evaluate their physical, mechanical and dynamic mechanical properties as a function of the relative glass–ramie volume fractions and the overall fiber content (10, 21 and 31 vol.%). Higher fiber content and higher ramie fiber fraction in the hybrid composites yielded lower weight composites, but higher water absorption in the composite. The mechanical properties (impact and interlaminar shear strength) of the composites were improved by using higher fiber content, and the composite with 31 vol.% of reinforcement yielded the lowest value for the reinforcement effectiveness coefficient C, as expected. Although the mechanical properties were improved for higher fiber content, the glass transition temperature did not vary significantly. Additionally, as found by analyzing the adhesion factor A, improved adhesion tended to occur for the composites with lower fiber content (10%) and higher ramie fiber fraction (0:100) and the results for the adhesion factor A did not correspond to those found by the analysis of the tan delta peak height.     

Hybridization effect on the mechanical properties of curaua/glass fiber composites

The aim of this paper was to evaluate the effect of hybridizing glass and curaua fibers on the mechanical properties of their composites. These composites were produced by hot compression molding, with distinct overall fiber volume fraction, being either pure curaua fiber, pure glass fiber or hybrid. The mechanical characterization was performed by tensile, flexural, short beam, Iosipescu and also nondestructive testing. From the obtained results, it was observed that the tensile strength and modulus increased with glass fiber incorporation and for higher overall fiber volume fraction (%V_f). The short beam strength increased up to %V_f of 30 vol.%, evidencing a maximum in terms of overall fiber/matrix interface and composite quality. Hybridization has been successfully applied to vegetable/synthetic fiber reinforced polyester composites in a way that the various properties responded satisfactorily to the incorporation of a third component.     

An assessment of mechanical behavior and fractography study of glass/epoxy composites at different temperatures and loading speeds

Effect of loading rate on fracture and mechanical behavior of autoclave cured glass fiber/epoxy prepreg composite has been studied at various loading (striking) rates (0.01-10³ mm/min). The maximum load carrying capacity and strain at yield continuously increases with increasing loading speed. The interlaminar shear strength (ILSS) value is high at low loading speed and becomes low at high loading speed with the transition of loading rate at approximately 300 mm/min. The formation of steps, welt interfacial failure and cleavage formation on matrix resin i.e. localized plastic deformation processes were dominating mechanisms for specimens tested at low loading rates, while brittle fracture of fiber, fiber pull-out and impregnation were dominating mechanisms for specimens tested at loading rates of 800 mm/min or higher.     

Hygrothermal degradation of 977-2A carbon/epoxy composite laminates cured in autoclave and Quickstep

While there are reports concerning the processing and properties of materials using Quickstep technique, little attention has been paid to the hygrothermal degradation of the flexural, interfacial and glass transition behaviours of polymeric composites cured at a relatively high ramp rate of 10 K min^?1 (typical of Quickstep processing). Composite laminates were manufactured in an autoclave and using Quickstep and then conditioned in a climatic chamber at 70 °C and 85% RH until reaching the limit of saturation. The interfacial (interlaminar shear strength (ILSS)), flexural (flexural strength) and glass transition (T_g) properties of the conditioned and unconditioned panels were evaluated. The results demonstrated that the moisture absorption caused the deleterious effect on the properties and that the reduction in the flexural, interfacial and glass transition properties of Quickstep panels was comparable to that observed in autoclave cured panels. Thermal stability, reversible and irreversible effects of hygrothermal conditioning using TGA, DMTA and FT-IR spectroscopy was also investigated and discussed.     

The effect of thermal cycles on the mechanical properties of fiber–metal laminates

The effect of thermal-shock cycles on the mechanical properties of fiber–metal laminates (FMLs) has been evaluated. FML plates were composed by two AA2024 Al sheets (1.6 mm thick) and one composite ply formed by two layers of unidirectional glass fiber epoxy prepreg and two layers of epoxy adhesive tape of glass fiber reinforced epoxy adhesive. The set was manufactured by hand layup and typical vacuum bag technique. The curing cycle was in autoclave at 125 ± 5 °C for 90 min and an autoclave pressure of 400 kPa. FML coupons taken from the manufactured plate were submitted to temperature variations between −50 and +80 °C, with a fast transition between these temperatures. Tensile and interlaminar shear strength were evaluated on samples after 1000 and 2000 cycles, and compared to nonexposed samples. 2000 Cycles corresponds to typical C Check interval for commercial aircraft maintenance programs. It was observed that the thermal-shock cycles did not result in significant microstructural changes on the FML, particularly on the composite ply. Similarly, no appreciable effect on the mechanical properties of FML was observed by the thermal-shock cycles.     

Role of matrix modification on interlaminar shear strength of glass fibre/epoxy composites

Interlaminar shear properties of fibre reinforced polymer composites are important in many structural applications. Matrix modification is an effective way to improve the composite interlaminar shear properties. In this paper, diglycidyl ether of bisphenol-F/diethyl toluene diamine system is used as the starting epoxy matrix. Multi-walled carbon nanotubes (MWCNTs) and reactive aliphatic diluent named n-butyl glycidyl ether (BGE) are employed to modify the epoxy matrix. Unmodified and modified epoxy resins are used for fabricating glass fibre reinforced composites by a hot-press process. The interlaminar shear strength (ILSS) of the glass fibre reinforced composites is investigated and the results indicate that introduction of MWCNT and BGE obviously enhances the ILSS. In particular, the simultaneous addition of 0.5 wt.% MWCNTs and 10 phr BGE leads to the 25.4% increase in the ILSS for the glass fibre reinforced composite. The fracture surfaces of the fibre reinforced composites are examined by scanning electron microscopy and the micrographs are employed to explain the ILSS results.     

Effects of thermal treatment on the mechanical properties of poly(p-phenylene benzobisoxazole) fiber reinforced phenolic resin composite materials

Thermal degradation behaviors of the poly(p-phenylene benzobisoxazole) (PBO) fiber and phenolic resin matrix were investigated. The unidirectional PBO fiber reinforced phenolic resin composite material laminates were fabricated and exposed in a muffle furnace of 300 °C, 550 °C, 700 °C, and 800 °C for 5 min, respectively, to study the effects of thermal treatment on mechanical properties of the composites. After undergone thermal treatments at 300 °C, 550 °C and 700 °C for 5 min, the flexural strength was reduced by 17%, 37% and 80%, respectively, the flexural modulus was decreased by 5%, 14% and 48%, respectively, and the interlaminar shear strength (ILSS) was lowered by 12%, 48% and 80%, respectively. Thermal treatment at 300 °C, the phenolic resin began to pyrolyze and shrink resulted in the irreversible damage of the composites. After 550 °C thermal treatment, the phenolic resin pyrolyzed mostly but the PBO fiber had no obvious pyrolyze, the interface had sever broken. After 700 °C thermal treatment, the phenolic resin formed amorphous carbonaceous and PBO fiber pyrolyzed mostly so the mechanical properties dropped dramatically. At being heated at 800 °C for 5 min, the fiber was nearly totally pyrolyzed and and kept fibrous carbonaceous although the specimen became too brittle to stand any load thereon.     

Electrical conductivity and interlaminar shear strength enhancement of carbon fiber reinforced polymers through synergetic effect between graphene oxide and polyaniline

Utilizing synergetic effect of different ingredients is an important strategy to design new multi-functional composites. In this work, high-strength graphene oxide and conductive polyaniline were selected to dope into divinylbenzene to fabricate a new type carbon fiber reinforced polymer laminates, where a cooperative improvement of through-thickness electrical conductivity and interlaminar shear strength was observed. With addition of 15 wt% of PANI-GO at the optimized weight ratio of 60:1 in the CF/DVB-PANI-GO, 150% enhancement of the electrical conductivity compared to the CF/DVB-PANI, and 76% enhancement of the ILSS compared to the CF/DVB-GO were realized. Our laminates reach 66% in ILSS of that for the conventional CFRP made of epoxy, but the former features about 103 times higher AC conductivity. The mechanism for such a synergic enhancement for both electrical and mechanical performance was investigated by rheology measurement and scanning electron microscopy, where uniform 3-D network formed by PANI/GO has been clearly observed.     

Effect of intumescent ammonium polyphosphate (APP) and melamine cyanurate (MC) on the properties of epoxy/glass fiber composites

The effects of halogen-free flame retardants (FR) such as intumescent ammonium polyphosphate (APP) and melamine cyanurate (MC) on the flammability and mechanical properties of epoxy/glass fiber composite systems were studied. Overall, intumescent APP shows better flammability results compared with MC. The composite with 5 vol.% APP performed sufficiently well in the UL-94 test and LOI, whereas 20 vol.% MC is required to achieve similar results. The addition of 1 vol.% MC into 4 vol.% APP had shown some improvement on the composite flame resistance. The composite attains the maximum flexural strength at 15 vol.% while the dynamic mechanical analysis shows that the addition of flame retardants increased the storage modulus but did not change the glass transition temperature T_g.     

Influence of fiber orientation and thickness on the response of glass/epoxy composites subjected to impact loading

Composite laminates, made of glass/epoxy using compression molding technique, were subjected to impact loading. The ballistic limit and energy absorption capacity of the laminates were obtained. Experiments were carried out to study the effect of fiber orientation and thicknesses on ballistic limit and energy absorption of the laminates, by using a rigid conical bullet having 9.5 mm diameter and mass of 7.5 g in an air gun. Analytical expressions were obtained to find the ballistic limit, residual velocity and energy absorption capacity of the laminates. The expressions obtained by considering the various damage modes, which were involved in penetration, when laminates subjected to impact loading. The values obtained from analysis were compared with experimental results and good agreement was found. The strain rate sensitivity of the glass/epoxy composites was considered for analysis.     

Optimal design for the flexural behaviour of glass and carbon fibre reinforced polymer hybrid composites

A study on the flexural behaviour of hybrid composites reinforced by S-2 glass and T700S carbon fibres in an intra-ply configuration is presented in this paper. The three point bend test in accordance with ASTM D790-07 at various span-to-depth ratios was simulated using finite element analysis (FEA). For the purpose of validation, specimens of selected stacking configurations were manufactured following the hand lay-up process and tested in a three point bend configuration. The validated FEA model was used to study the effects of fibre volume fractions, hybrid ratio and span-to-depth ratio. It is shown that flexural modulus increases when the span-to-depth ratio increases from 16 to 32 but is approximately constant as the span-to-depth ratio further increases. A simple mathematical formula was developed for calculating the flexural modulus of hybrid composites, given the moduli of full carbon and full glass composites, and the hybrid ratio. Flexural strength increases with span-to-depth ratio. Utilisation of hybridisation can improve the flexural strength. A general rule is in order to improve flexural strength, the fibre volume fraction of glass/epoxy plies needs to be higher than that of carbon/epoxy plies. The overall maximum hybrid effect is achieved when the hybrid ratio is 0.125 ([0_G/0_7C]) when both V_fc and V_fg are 50%. The strength increases are 43.46% and 85.57% when compared with those of the full carbon and glass configurations respectively. The optimisation shows that the maximum hybrid effect is 56.1% when V_fc = 47.48% and V_fg = 63.29%.     

Grafting of nano-TiO2 onto flax fibers and the enhancement of the mechanical properties of the flax fiber and flax fiber/epoxy composite

In this article, a flax fiber yarn was grafted with nanometer sized TiO₂, and the effects on the tensile and bonding properties of the single fibers and unidirectional fiber reinforced epoxy plates were studied. The flax fiber yarn was grafted with nanometer sized TiO₂ through immersion in nano-TiO₂/KH560 suspensions under sonification. The measured grafting content of the nano-TiO₂ ranged from 0.89 wt.% to 7.14 wt.%, dependent on the suspension concentration. With the optimized nano-TiO₂ grafting content (∼2.34 wt.%), the tensile strength of the flax fibers and the interfacial shear strength to an epoxy resin were enhanced by 23.1% and 40.5%, respectively. The formation of Si–O–Ti and C–O–Si bonds and the presence of the nano-TiO₂ particles on the fiber surfaces contributed to the property enhancements. Unidirectional flax fiber reinforced epoxy composite (V_f = 35.4%) plates prepared manually showed significantly enhanced flexural properties with the grafting of nano-TiO₂.     

Water absorption behavior,mechanical and thermal properties of nano TiO2 enhanced glass fiber reinforced polymer composites

Nano TiO₂ particle is one of the promising inorganic nano fillers used in polymer matrix composites to enhance the mechanical properties. However, reliability of this type of nano composites is yet to be ensured in hydrothermal environment. The present work investigates the addition of nano TiO₂ filler on water sorption, residual strength and thermal properties of glass fiber reinforced polymer (GFRP) composites. The results revealed that addition of 0.1 wt% TiO₂ has reduced water diffusion coefficient by 9%, improved residual flexural strength by 19% and residual interlaminar shear strength by 18% among all the nano TiO₂ modified composites. The improvement of mechanical properties in hydrothermal environment creates opportunity and reliability to be used in different engineering applications. Weibull design parameters are evaluated and found a good agreement between Weibull stress-strain curves and experimental one. Fractographic analysis confirmed the various failures and strengthening mechanisms of nano composites in dry and hydrothermal environment.     

Processing a glass fiber reinforced vinyl ester composite with nanotube enhancement of interlaminar shear strength

Carbon nanotubes have been considered as a promising means of enhancing the properties of advanced composites in a range of polymer systems. Expected property enhancements include high strength and stiffness, improved toughness, impact and through-thickness properties. Z-axis properties like shear strength are of special interest for laminated composite structures subjected to transverse loads. This paper reports the processing of a glass fiber reinforced vinyl ester composite with nanotube integration and examines the reinforcement potential on interlaminar shear strength. Several sidewall functionalized nanotube derivatives were also prepared in order to obtain high dispersion and matrix bonding. Carbon nanotube enhanced vinyl ester/glass fiber composites were fabricated by a vacuum assisted resin transfer molding process. Overcoating the glass fiber weave with nanotubes and processing modification led to enhancement of the interface properties. A maximum of 45% increase in shear strength over control sample was observed on several types of nanotubes with a very small amount of nanotubes (0.015 wt%) coated in the midplane ply.