Effect of geometry on crashworthiness parameters of natural kenaf fibre reinforced composite hexagonal tubes

The effect of geometry on energy absorption capability and load-carrying capacity of natural kenaf fibre reinforced composite hexagonal tubes had been investigated experimentally. A series of experiments were carried out for composite hexagonal tubes with different angles from a range of 40–60° in 5° steps. This range is suitable for obtaining a regular hexagonal shape. Kenaf fibre mat form was used in this work due to several advantages such as low cost, no health risk, light weight and availability. The kenaf density was usage 0.17 g/cm³ with thickness of 4 mm. Results demonstrated that structures failed in few distinct failure modes. Precisely in progressive failure mode and fragmentation failure associated with longitudinal cracks. The composite tube with β = 60° exhibited local buckling failure mode and displayed the highest specific energy absorption capability equal to 9.2 J/g. On the other hand, new crashworthiness parameter has been introduced as catastrophic failure mode indicator (CFMI). Furthermore, typical load–deformation histories were presented and discussed.     

Microstructure and transport properties of [0 0 1]-tilt bicrystal grain boundaries in iron pnictide superconductor,cobalt-doped BaFe2As2

Relationships between microstructure and transport properties of bicrystal grain boundary (BGB) junctions were studied in cobalt-doped BaFe₂As₂ (BaFe₂As₂:Co) epitaxial films grown on [0 0 1]-tilt bicrystal substrates of MgO and (La, Sr)(Al, Ta)O₃ with misorientation angles θ_GB = 3–45°. The θ_GB of BaFe₂As₂:Co BGBs were exactly transferred from those of the bicrystal substrates. No segregation of impurities was detected at the BGB junction interfaces, and the chemical compositions of the BGBs were uniform and the same as those in the bulk film regions. A transition from a strongly-coupled GB behavior to a weak-link behavior was observed in current density–voltage characteristics under self-field around θ_GB ～ 9°. The critical current density decreased from (1.2–1.6) × 10⁶ A/cm² of the intragrain transport to (0.7–1.1) × 10⁵ A/cm² of θ_GB = 45° because supercurrent becomes more governed by Josephson current with increasing θ_GB.     

An investigation into the damage development and residual strengths of open-hole specimens in fatigue

An extensive experimental program was carried out to investigate and understand the sequence of damage development throughout the life of open-hole composite laminates loaded in tension–tension fatigue. Quasi-isotropic carbon/epoxy laminates, with stacking sequence [45₂/90₂/−45₂/0₂]_S, [45/90/−45/0]_2S and [45/90/−45/0]_4S were examined. These were selected on the basis that under quasi-static loading the [45₂/90₂/−45₂/0₂]_S configuration exhibited a delamination dominated mode of failure whilst the [45/90/−45/0]_2S and [45/90/−45/0]_4S configurations showed a fibre dominated failure mode, previously described as “pull-out” and “brittle” respectively. Specimens were fatigue loaded to 1 × 10⁶ cycles or catastrophic failure, which ever occurred first. A number of tests were interrupted at various points as the stiffness dropped with increasing cycles, which were inspected using X-ray computed tomography (CT) scanning. A static residual strength program was carried out for run-out specimens of each configuration.     

Post-impact compressive strength of curved GFRP laminates

Low velocity impacts to fibre reinforced plastic composites cause a pattern of damage consisting in general of delamination, fibre breakage and matrix cracking. Such damage is accidental and may go unnoticed; therefore composite structures must be designed assuming impact damage exists. Previous work on flat composite laminates has resulted in a reasonable understanding of the mechanisms of compressive strength reduction. There are, however, many instances where curved laminates are used in structures where impact is likely. Furthermore, due to the mechanisms of strength reduction, it may be expected that curvature would have a significant effect on the behaviour of the laminates.The work described here consists of experimental measurement of the post-impact compressive strength of curved GFRP laminates. The laminates were of 8 plies of 0.3 mm thick pre-impregnated glass fibre/epoxy tape in a (0, ±45, 0°)_s lay-up. Each laminate was 200 mm in length by 50 mm wide with the plane of curvature normal to the length. Laminates were impacted on the convex surface of the laminate by dropping a steel mass from 1 m vertically above it.Impacted laminates were loaded in compression and the out-of-plane displacements of the top and bottom surfaces were recorded. Final failure was typically due to fibre breakage occurring through the centre of the impacted area of the laminate. Possible differences in the impact response, and measurable differences in the sizes of the impact damage area, were found to arise from these curvatures, and differences were observed in their post-impact buckling behaviour. However, perhaps unexpectedly, the post-impact compressive strength for a curved laminate was found to be similar to that for a flat laminate. The failure loads for the impact damage laminates are shown to be comparable with those for laminates containing artificial delaminations.     

Effects of winding angle on the behaviour of glass/epoxy pipes under multiaxial cyclic loading

The effects of winding angle on the behaviour of glass/epoxy composite tubes under multiaxial cyclic loading were investigated. The performance of such composite tubes was studied using an indigenous automated test procedure that is compatible with the internal qualification requirements of the composite pipe manufacturers. Glass fibre reinforced epoxy (GRE) composite pipes with three winding angles, namely, [± 45°]₄, [± 55°]₄, and [± 63°]₄, were tested. A novel automated test rig was fabricated to accommodate five stress ratios, ranging from pure axial to pure hoop loadings. The cyclic pressure test was conducted until droplets of water were seen on the outer surface of the pipe. Failure envelopes were then constructed based on the first ply failure (FPF) points determined from the axial stress to hoop strain response at five stress ratios. Three functional failure modes, namely, tensile axial, weepage, and local leakage failures, were observed during the tests. The results indicate that each winding angle dominates a different optimum pressure loading condition, namely, [± 55°]₄ for pure hydrostatic loading, [± 45°]₄ for hoop to axial loading, and [± 63°]₄ for quad hoop to axial loading. The envelopes show a strong dependence on the stress ratio and winding angle.     

Preparation,phase structure and microwave dielectric properties of CoLi2/3Ti4/3O4 ceramic

A new low loss microwave dielectric ceramic with composition of CoLi_2/3Ti_4/3O₄ was prepared by a conventional solid-state reaction method. The compound has a cubic spinel structure [Fd-3m (227)] similar to MgFe₂O₄ with lattice parameters of a = 8.3939 Å, V = 591.42 Å³, Z = 8 and ρ = 4.30 g/cm³. This ceramic has a low sintering temperature (～1050 °C) and good microwave dielectric properties with relative permittivity of 21.4, Q × f value of 35,000 GHz and τ_f value of ?22 ppm/°C. Furthermore, the addition of BaCu(B₂O₅) (BCB) can effectively lower the sintering temperature from 1050 °C to 900 °C and does not induce much degradation of the microwave dielectric properties. Compatibility with Ag electrode indicates that the BCB added CoLi_2/3Ti_4/3O₄ ceramics are good candidates for LTCC applications.     

The influence of martensite,bainite and ferrite on the as-quenched constitutive response of simultaneously quenched and deformed boron steel – Experiments and model

This paper examines the relationship between as-formed microstructure and mechanical properties of a hot stamped boron steel used in automotive structural applications. Boron steel sheet metal blanks were austenized and quenched at cooling rates of 30 °C/s, 15 °C/s and 10 °C/s within a Gleeble thermal–mechanical simulator. For each cooling rate condition, the blanks were simultaneously deformed at temperatures of 600 °C and 800 °C. A strain of approximately 0.20 was imposed in the middle of the blanks, from which miniature tensile specimens were extracted. Depending on the cooling rate and deformation temperature imposed on the specimens, some of the as-quenched microstructures consisted of predominantly martensite and bainite, while others consisted of martensite, bainite and ferrite. Optical and SEM metallographraphic techniques were used to quantify the area fractions of the phases present and quasi-static (0.003 s⁻¹) uniaxial tests were conducted on the miniature tensile specimens. The results revealed that an area fraction of ferrite greater than 6% led to an increased uniform elongation and an increase in n-value without affecting the strength of the material for equivalent hardness levels. This finding resulted in improved energy absorption due to the presence of ferrite and showed that a material with a predominantly bainitic microstructure containing 16% ferrite (with 257 HV) resulted in a 28% increase in energy absorption when compared to a material condition that was fully bainitic with a hardness of 268 HV. Elevated strain rate tension tests were also conducted at 10 s⁻¹ and 80 s⁻¹ and the effect of strain rate on the ultimate tensile strength (σ_UTS) and yield strength (σ_Y) was shown to be moderate for all of the conditions. The true stress versus effective plastic strain (flow stress) curves generated from the tensile tests were used to develop the “Tailored Crash Model II” (TCM II) which is a strain rate sensitive constitutive model that is a function of effective plastic strain, true strain rate and area fraction of martensite, bainite and ferrite. The model was shown to accurately capture the hardening behaviour and strain rate sensitivity of the multiphase material conditions examined.     

Impact strength of a few natural fibre reinforced cement mortar slabs: a comparative study

This paper presents the experimental investigations of the resistance to impact loading of cement mortar slabs (1:3, size: 300 mm × 300 mm × 20 mm) reinforced with four natural fibres, coir, sisal, jute, hibiscus cannebinus and subjected to impact loading using a simple projectile test. Four different fibre contents (0.5%, 1.0%, 1.5% and 2.5%—by weight of cement) and three fibre lengths (20 mm, 30 mm and 40 mm) were considered. The results obtained have shown that the addition of the above natural fibres has increased the impact resistance by 3–18 times than that of the reference (i.e. plain) mortar slab. Of the four fibres, coir fibre reinforced mortar slab specimens have shown the best performance based on the set of chosen indicators, i.e. the impact resistance (R_u), residual impact strength ratio (I_rs), impact crack-resistance ratio (C_r) and the condition of fibre at ultimate failure.     

Fatigue behavior and failure mechanism of basalt FRP composites under long-term cyclic loads

This paper studies the fatigue behavior of basalt fiber reinforced epoxy polymer (BFRP) composites and reveals the degradation mechanism of BFRP under different stress levels of cyclic loadings. The BFRP composites were tested under tension–tension fatigue load with different stress levels by an advanced fatigue loading equipment combined with in-situ scanning electron microscopy (SEM). The specimens were under long-term cyclic loads up to 1 × 10⁷ cycles. The stiffness degradation, S–N curves and the residual strength of run-out specimens were recorded during the test. The fatigue strength was predicted with the testing results using reliability methods. Meanwhile, the damage propagation and fracture surface of all specimens were observed and tracked during fatigue loading by an in-situ SEM, based on which damage mechanism under different stress levels was studied. The results show the prediction of fatigue strength by fitting S–N data up to 2 × 10⁶ cycles is lower than that of the data by 1 × 10⁷ cycles. It reveals the fatigue strength perdition is highly associated with the long-term run-out cycles and traditional two million run-out cycles cannot accurately predict fatigue behavior. The SEM images reveal that under high level of stress, the critical fiber breaking failure is the dominant damage, while the matrix cracking and interfacial debonding are main damage patterns at the low and middle fatigue stress level for BFRP. Based on the above fatigue behavior and damage pattern, a three stage fracture mechanism model under fatigue loading is developed.     

Translaminar fracture toughness: The critical notch tip radius of 0° plies in CFRP

The relationship between translaminar fracture toughness measured at initiation and specimen initial notch root radius is investigated for the translaminar failure mode of cross-ply IM7/8552 carbon/epoxy laminates. Compact tension specimens with four sizes of notch root radii were tested; the true initiation toughness of the laminate was measured from specimens with notch tip radii of ρ ? 250 μm. Testing of specimens with larger notch root radii, ρ = 750 μm, yielded an apparent toughness that was found to be 30% higher than the true toughness of the laminate. The propagation toughness corresponding to the R-curve plateau was found not to be affected by the initial notch tip radius. Investigation of the fracture surfaces of failed specimens revealed that there is no interaction between the 0° and 90° ply failure mechanisms, and that the critical notch radius is a property intrinsic to the 0° plies of the laminate.     

Effect of BaCu(B2O5) on the sintering temperature and microwave dielectric properties of BaO–Ln2O3–TiO2 (Ln = Sm,Nd) ceramics

BaCu(B₂O₅) (BCB) ceramic powder was used to decrease the sintering temperatures of BaSm₂Ti₄O₁₂ (BST) and BaNd₂Ti₅O₁₄ (BNT) ceramics. The sintering temperature of the BST and BNT ceramics was reduced from approximately 1350 °C to 850 °C by the addition of BCB. The bulk density of the specimens increased and reached the saturated value with increasing BCB content. The variation of the dielectric constant (ɛ_r) was similar to that of the bulk density and, thus, the relative density plays an important role in determining the ɛ_r value of the specimens. The Q-value initially increased with the addition of BCB but decreased considerably when a large amount of BCB was added because of the presence of the liquid phase. Good microwave dielectric properties of Qxf = 4500 GHz, ɛ_r = 60 and τ_f = −30 ppm/°C were obtained for the 16.0 mol% BCB-added BST ceramics sintered at 875 °C for 2 h.     

Optimization of CVD growth of CNT-based hybrids using the Taguchi method

Taguchi method, extensively applied for the optimization of multifactor processes in the most diverse fields, is for the first time applied to the synthesis of hybrids based on C nanotubes by iron-catalyzed chemical vapor deposition in 1:1 i-C₄H₁₀ + H₂ atmosphere. For this purpose, assumed synthesis-temperature (500 °C, 600 °C or 700 °C), support-material (alumina, magnesia or Na⁺-exchanged K10 montmorillonite), calcination (450 °C, 600 °C or 750 °C) and reduction (500 °C, 600 °C or 700 °C) temperature of the iron catalysts as the four factors of importance in the process, nine suitably designed experiments are conducted and the influence is evaluated of the four three-level factors on the issue of the process in terms of selectivity toward nanotubes, catalytic yield and content of carbonaceous and metallic impurities in the C nanotubes. By this procedure, the configurations giving optimal results are predicted, and tested by carrying out new experiments.     

Carbon/epoxy composite delamination analysis by acoustic emission method under various environmental conditions

New multifunctional materials for aerospace industry with exceptional properties must be tested under various environmental conditions to find out possible scatter factors for evaluated properties. Delamination is a typical damage mode observed for laminated composites. Therefore, reliable information regarding the delamination growth behaviour is needed for all operational environments of an aircraft operated at cryogenic and elevated temperatures. In this paper, delamination crack growth monitoring in a climatic chamber on double-cantilever beam (DCB) specimens using optical devices and acoustic emission (AE) techniques is described. A relationship between cumulative AE energy, events localization, clusters, and crack growth in a plain-weave carbon fibre–reinforced epoxy is investigated under constant displacement rate loading at + 80 °C, and − 55 °C. Test results are evaluated for specimens with multi-walled carbon nanotubes (MWCNT) in the microstructure and for a reference material. The mechanical properties during delamination are represented by fracture toughness G_IC, and they are also correlated with the AE data. The elevated test temperature caused a decreased rate of released AE energy. The crack growth in material with more significant fibre breakage caused increase of the AE release rate.     

Modeling quasi-static and high strain rate deformation and failure behavior of a (±45) symmetric E-glass/polyester composite under compressive loading

Quasi-static (1 × 10⁻³–1 × 10⁻² s⁻¹) and high strain rate (∼1000 s⁻¹) compressive mechanical response and fracture/failure of a (±45) symmetric E-glass/polyester composite along three perpendicular directions were determined experimentally and numerically. A numerical model in LS-DYNA 971 using material model MAT_162 was developed to investigate the compression deformation and fracture of the composite at quasi-static and high strain rates. The compressive stress–strain behaviors of the composite along three directions were found strain rate sensitive. The modulus and maximum stress of the composite increased with increasing strain rate, while the strain rate sensitivity in in-plane direction was higher than that in through-thickness direction. The damage progression determined by high speed camera in the specimens well agreed with that of numerical model. The numerical model successfully predicted the damage initiation and progression as well as the failure modes of the composite.     

Powder synthesis and properties of LiTaO3 ceramics

The LiTaO₃ powders with sub micrometer grade grain size have been synthesized successfully using a molten salt method. Lithium tantalate began to form at 400 °C reaction temperature and transformed to pure phase without residual reactants when it was processed at 500 °C for 4 h in static air. The undoped LiTaO₃ ceramics with a Curie temperature about 663 °C were obtained by pressureless sintering at 1300 °C for 3 h. The relative dielectric constant (ɛ_r) increases from 50 to 375 at temperature ranging from 30 to 663 °C and then decreases quickly as the temperature increases above 663 °C. The ceramics shows a relative dielectric constant of 49.4, a dielectric loss factor (tan δ) of 0.007, a coercive field (Ec) of 28.66 kV/cm and a remnant polarization (Pr) of 32.48 μC/cm² at room temperature.     

Diffusion bonding of titanium alloy to micro-duplex stainless steel using a nickel alloy interlayer: Interface microstructure and strength properties

In the present study, diffusion bonding of titanium alloy and micro-duplex stainless steel with a nickel alloy interlayer was carried out in the temperature range of 800–950 °C for 45 min under the compressive stress of 4 MPa in a vacuum. The bond interfaces were characterised by scanning electron microscopy, electron probe microanalyzer and X-ray diffraction analysis. The layer wise Ni₃Ti, NiTi and NiTi₂ intermetallics were observed at the nickel alloy/titanium alloy interface and irregular shaped particles of Fe₂₂Mo₂₀Ni₄₅Ti₁₃ was observed in the Ni₃Ti intermetallic layer. At 950 °C processing temperature, black island of β-Ti phase has been observed in the NiTi₂ intermetallics. However, the stainless steel/nickel alloy interface indicates the free of intermetallics phase. Fracture surface observed that, failure takes place through the NiTi₂ phase at the NiA–TiA interface when bonding was processed up to 900 °C, however, failure takes place through NiTi₂ and β-Ti phase mixture for the diffusion joints processed at 950 °C. Joint strength was evaluated and maximum tensile strength of ∼560 MPa and shear strength of ∼415 MPa along with ∼8.3% ductility were obtained for the diffusion couple processed at 900 °C for 45 min.     

The effects of interfacial adhesion strength on the characteristics of an aluminum/CFRP hybrid beam under transverse quasi-static loading

The effects of interfacial adhesion strength on the damage behavior and energy absorption characteristics of an aluminum (Al)/carbon fiber reinforced plastic (CFRP) short square hollow section (SHS) beam under three point bending loading was investigated. An Al SHS beam was wrapped by CFRP with a [0°/+45°/90°/−45°]_n (n = 1 or 2) stacking sequence, and four gradations of interfacial adhesion strength were caused by physical or chemical changes of the Al adherend with different mechanical abrasion and optimal Argon plasma treatment. A different level of appropriate interfacial adhesion strength existed for each hybrid specimen depending on the CFRP laminate thickness to obtain the highest energy absorption capability, and this was verified by detailed observation of the failure mechanism of the hybrid specimen. The specific energy absorbed (SEA) was improved by up to 57.2% in the Al/CFRP [0°/+45°/90°/−45°]₂ SHS beam compared to the Al SHS beam without compromising the crush force efficiency (CFE).     

Creep deformation and rupture behavior of Alloy 617

A series of creep data was obtained from creep tests at different applied stresses at the temperatures of 850 °C, 900 °C, and 950 °C for Alloy 617, which is a leading candidate material for high-temperature components in Gen-IV nuclear reactor systems. The creep deformation and rupture behavior were investigated in terms of Norton's power law, Monkman–Grant relation (MGR), modified Monkman–Grant relation (MMGR), creep damage tolerance factor (λ), Zener–Hollomon Parameter (Z), and fracture behavior. Alloy 617 did not exhibit textbook creep behavior and revealed somewhat differences from typical heat resistant steels. The MMGR provided improved correlation between creep rate and rupture life in Alloy 617. The Z parameter obeyed a good agreement for a function of Z = 2.30 × 10³³ (σ/E)^5.87, and the same creep mechanism was operative within the ranges tested in the present study. The value of λ for Alloy 617 was found to be 2.40, and this was in agreement with materials exhibiting typical cavitation damage. The creep failure analysis revealed a dominant intergranular fracture mode, which proceeds via initiation, linking, and incorporation of the cavities.     

Temperature influence on the voltage-controlled diffractive property of Mn-doped potassium sodium tantalate niobate crystal

We report the temperature influence on the voltage-controlled diffractive property of Mn-doped potassium sodium tantalate niobate crystal. The crystal was grown by the top seeded solution growth method. Its quadratic electro-optic coefficients achieved as high as R₁₁ = 3.50 × 10⁻¹⁵ m²/V² and R₁₂ = −0.44 × 10⁻¹⁵ m²/V² near the Curie temperature, while they declined with the increasing temperature. The external electric field which correspond to the maximum diffraction efficiency of photorefractive grating moved from 166 V/mm to 512 V/mm as the temperature increased from 25 °C to 32.5 °C. The maximum diffraction efficiencies all reached the maximum value of 60% at different temperatures. The results were discussed and compared with the theoretical equations.     

Influence of temperature and thickness on the off-axis behaviour of short glass fibre reinforced polyamide 6.6 – cyclic loading

This paper investigates the anisotropic properties of short glass fibre reinforced polyamide 6.6 (PA66-GF35) under tension–tension and tension–compression cyclic loading. Tensile fatigue tests were carried out on dog-bone specimens, machined out from injection-moulded plates 80 × 80 mm, of three different thicknesses t (1 and 3 mm) at three different nominal fibre orientation angles θ (0°, 30° and 90°). The tests were carried out at RT as well as at 130 °C.The Tsai–Hill failure criterion, modified to account for cyclic loading, is applied to the fatigue data for estimating the fatigue strength parameters of the material under investigation. Results are compared to the strength parameters obtained under quasi-static loading in a previous part of this work [De Monte M, Moosbrugger E, Quaresimin M. Influence of temperature and thickness on the off-axis behaviour of short glass fibre reinforced polyamide 6.6 – quasi-static loading. Composites: Part A, 2010;41(10):1368–79]. The experimental results highlight how specimen thickness remarkably affects mechanical properties: the thinner the specimen the higher will be the degree of anisotropy. Also temperature strongly reduces the fatigue strength under cyclic loading. The Tsai–Hill criterion allows for an adequate fitting of experimental data at the investigated temperatures and load ratios.