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采用单因素考察法研究了椰油酸甲基单乙醇酰胺的合成工艺条件,最佳反应条件:n(椰子油)∶n(甲基单乙醇胺)=1∶1.05,反应温度90℃,反应时间5h,催化剂用量为0.3%;在此条件下,椰子油的转化率达93.5%,该工艺操作简便,满足工业化生产的需求。 相似文献
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《化学与生物工程》2017,(5)
以蓖麻油酸和乙二醇丁醚为原料,经酯化、酰化两步反应合成了乙酰化蓖麻油酸丁氧基乙酯。运用正交实验与单因素实验确定酯化和酰化反应的最佳条件:酯化反应中,蓖麻油酸与乙二醇丁醚物质的量比为1∶1.15,催化剂一水合硫酸氢钠用量为蓖麻油酸质量的2%,反应时间为5h,反应温度为90℃,蓖麻油酸丁氧基乙酯的酯化率可达98.8%;酰化反应中,蓖麻油酸丁氧基乙酯与醋酐物质的量比为1∶1.2,催化剂对甲苯磺酸用量为蓖麻油酸丁氧基乙酯质量的3%,反应温度为80℃,反应时间为2h,酰化率达93.2%。采用红外光谱(FTIR)、质谱(HRMS)表征并确认了合成产物的化学结构。 相似文献
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对以乙二醇单丙醚和氯化亚砜为原料合成2_ 正丙氧基氯乙烷的合成研究和中试开发。求取了优惠条件,收率为97% 。 相似文献
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Jingcan Sun Jin Hua Chin Weibiao Zhou Bin Yu Philip Curran Shao-Quan Liu 《Journal of the American Oil Chemists' Society》2012,89(11):1991-1998
Lipase (Lipozyme TL IM)-mediated biocatalysis in a solvent-free system was effectively employed to convert coconut oil and fusel oil to flavor-active octanoic acid esters (mainly ethyl-, butyl-, isobutyl- and (iso)amyl octanoate). Response surface methodology based on five-level-three-factor central composite design was applied to investigate the effects of single and multiple interactive factors on the conversion. Results indicated that the studied independent parameters including reactant molar ratio, enzyme loading and shaking speed were all significant factors that affected the formation of octanoic acid esters during transesterification reaction. According to the developed polynomial model (R 2?=?0.947), the optimum transesterification conditions were determined as follows: molar ratio of 3.25:1 (alcohol/oil), enzyme loading of 16.7?% (wt%) and shaking speed of 160?rpm. Under the optimized reaction conditions an average conversion of 62.0?% was achieved which was in reasonable agreement with the predicted value of 64.1?% and about 9.4?mg of ethyl octanoate, 14.4?mg of isobutyl octanoate, 0.3?mg of butyl octanoate and 49.2?mg of (iso)amyl octanoate were produced per gram of coconut oil. 相似文献
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B. K. De T. Chatterjee D. K. Bhattacharyya 《Journal of the American Oil Chemists' Society》1999,76(12):1501-1504
Synthesis of geranyl and citronellyl esters of mixed fatty acids has been investigated by alcoholysis of coconut oil (CNO)
using Rhizomucor miehei lipase. CNO fatty acid esters of geraniol and citronellol have unique mild flavors that can be used in food materials. Both
geraniolysis and citronellolysis of CNO produce flavor esters in good yield. Depending on substrate concentration the molar
yield is more than 50%. The optimized reaction conditions were: pressure, atmospheric; temperature, 50°C; incubation period,
5 h; and Lipozyme, 10% (w/w). 相似文献
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Deoxygenation of methyl esters and triglycerides was studied for production of either α-olefins or diesel components. The reactions were carried out in a reactive distillation fashion in which products are quickly removed from the reaction mixture in flowing He. The effects of He flow rate, reaction temperature, active component and support were studied. PtSnK supported on silica was found to be the best catalyst for selective production of α-olefins. Palm kernel oil and coconut oil were also deoxygenated to produce α-olefins or diesel components, depending on reaction conditions. 相似文献
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J. S. Pai S. S. Lomanno W. W. Nawar 《Journal of the American Oil Chemists' Society》1979,56(4):494-497
Fresh coconut oil was heated under different conditions for 48 hr at 180 C. The heat treatments included heating in vacuo,
heating in air and heating in air and water. The samples were distilled under high vacuum and the volatiles thus obtained
were analyzed by combined gas chromatography-mass spectrometry. In all heated samples, a series of n-alkanes and I-alkenes,
n-alkanals, methyl alkanones, alkenals, gamma-and delta-lactones, methyl and ethyl esters and free fatty acids were identified.
The relative amounts of these compounds varied with the type of heat treatment to which the coconut oil was subjected. 相似文献
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响应面法优化酶催化酯交换反应研究 总被引:7,自引:0,他引:7
为了利用植物油生产可再生的绿色能源——生物柴油,文章利用Novo435固定化脂肪酶,在无有机溶剂存在下催化菜籽油与甲醇酯交换合成生物柴油。利用响应面实验设计和分析方法对菜籽油的酯交换反应条件进行优化,得到了最佳工艺条件:醇油摩尔比1.5∶1,反应温度52℃,搅拌转速200 r/min,脂肪酶与油脂的质量比为10%,反应时间10 h,在此工艺条件下油脂的酯交换率达到48%(理论为50%)。理论甲醇量分3批加入,反应36 h后菜籽油的总酯交换率达到95%(理论酯交换率为100%)。每批试验后利用有机溶剂对脂肪酶进行清洗,然后继续反应,连续使用10个批次,油脂的酯交换率基本未变。 相似文献