共查询到20条相似文献,搜索用时 0 毫秒
1.
Kwang Joo Kim Kwang‐Young Lim Young‐Wook Kim 《Journal of the American Ceramic Society》2013,96(11):3463-3469
The electrical properties of β‐SiC ceramics were found to be adjustable through appropriate AlN–Y2O3 codoping. Polycrystalline β‐SiC specimens were obtained by hot pressing silicon carbide (SiC) powder mixtures containing AlN and Y2O3 as sintering additives in a nitrogen atmosphere. The electrical resistivity of the SiC specimens, which exhibited n‐type character, increased with AlN doping and decreased with Y2O3 doping. The increase in resistivity is attributed to Al‐derived acceptors trapping carriers excited from the N‐derived donors. The results suggest that the electrical resistivity of the β‐SiC ceramics may be varied in the 104–10?3 Ω·cm range by manipulating the compensation of the two impurity states. The photoluminescence (PL) spectrum of the specimens was found to evolve with the addition of dopants. The presence of N‐donor and Al‐acceptor states within the band gap of 3C–SiC could be identified by analyzing the PL data. 相似文献
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Effects of Annealing on Dielectric Loss and Microstructure of Aluminum Nitride Ceramics 总被引:1,自引:0,他引:1
Shoichi Kume Masaki Yasuoka Naoki Omura Koji Watari 《Journal of the American Ceramic Society》2005,88(11):3229-3231
The effect of annealing on tan δ and microstructures of aluminum nitride (AlN) ceramics were explored. Yttria was added as a sintering additive to AlN powders, and the powders were pressureless-sintered at 1900°C for 2 h in a nitrogen flow atmosphere. In succession to sintering, AlN samples were annealed at 720, 970 and 1210°C for 2 and 4 h. Very low tan δ values between 2.6 and 6.0 × 10−4 at 28 GHz were obtained when the AlN samples were annealed for 4 h at all the annealing temperatures. 相似文献
3.
John A. Hanigofsky Karren L. More W. J. Lackey Woo Y. Lee Garth B. Freeman 《Journal of the American Ceramic Society》1991,74(2):301-305
The composition and microstructure of dispersed-phase ceramic composites containing BN and AIN as well as BN and AIN single-phase ceramics prepared by chemical vapor deposition have been characterized using X-ray diffraction, scanning electron microscopy, electron microprobe, and transmission electron microscopy techniques. Under certain processing conditions, the codeposited coating microstructure consists of small single-crystal AIN fibers (whiskers) surrounded by a turbostratic BN matrix. Other processing conditions resulted in single-phase films of AIN with a fibrous structure. The compositions of the codeposits range from 2 to 50 mol% BN, 50 to 80 mol% AIN with 7% to 25% oxygen impurity as determined by electron microprobe analysis. 相似文献
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Fang Zheng Renzhang Yuan Xingjiao Li Zaiguang Li Xingzhi Tao Qiguang Zheng Chang-Guo Zhan 《Journal of the American Ceramic Society》1998,81(9):2443-2448
Electronic ceramics of the Al2 O3 -WO3 system were synthesized by using a high-powered CO2 laser. It was shown that these ceramics can be used as linear thermistor materials. The linear temperature range of the Al2 O3 -WO3 system was ~200°C, the nonlinear deviation epsilon was <2%, the thermistor constant B was <103 , and the temperature coefficient was between -0.2%/°C and -0.8%/°C. These parameters could be adjusted by changing the composition of the samples and the laser-synthesis parameters. The present study showed that the materials should be encapsulated if they are to be used in an oxidizing atmosphere. The current-voltage curves of the present materials were symmetrical around the coordinate origin, which also is a necessary condition for judging whether or not a thermistor is linear. 相似文献
6.
Shifeng Liu Yu-Ping Zeng Dongliang Jiang Shifeng Liu 《International Journal of Applied Ceramic Technology》2009,6(5):617-625
Mullitized porous oxidation-bonded SiC (OBSC) ceramics were fabricated with and without preheat-treated aluminosilicate by an in situ reaction-bonding process. The effects of the preheat-treated aluminosilicate on the phase development, microstructure, and mechanical properties of porous SiC ceramics were investigated. With 5.0 wt% preheat-treated aluminosilicate addition, the process of mullitization was significantly promoted. Owing to the enhancement of neck growth by the preheat-treated aluminosilicate, a high flexural strength of 86.9 MPa was achieved at an open porosity of 35.3%, and the porous SiC ceramics maintained good thermal shock resistance. With 5.0 wt% preheat-treated aluminosilicate addition, the average pore size of porous SiC ceramics was enlarged from 2.8 to 4.0 μm. The effects of preheat-treated aluminosilicate content on the oxidation degree of SiC, open porosity, and flexural strength of porous SiC ceramics were also investigated. 相似文献
7.
氧化铬对无水泥刚玉浇注料矿相、显微结构和强度的影响 总被引:1,自引:0,他引:1
以电熔白刚玉颗粒及细粉为主要原料,以α-氧化铝微粉和水合氧化铝为结合剂,研究了加入氧化铬对无水泥刚玉基浇注料矿相、显微结构和抗折强度的影响.结果表明: 氧化铬1100℃开始向刚玉中固溶,随温度升高固溶程度增加,使浇注料各组分间的结合不断增强,明显提高了浇注料≥1400℃烧后的强度.氧化铬质量含量由0增加到4.0%时,1400℃烧后的热态抗折强度由5.1MPa增大到14.2MPa.1600℃烧后氧化铬通过固相和气相2种传质方式,在刚玉颗粒表面形成环状的固溶带,将刚玉彼此连接在一起,形成了较强的结合.加入质量分数2.0%的氧化铬可使1600℃烧后刚玉基浇注料在1400℃下的热态抗折强度由不含氧化铬的9.7MPa增大到18.6MPa. 相似文献
8.
Paul M. Sheedy Hugo S. Caram Helen M. Chan Martin P. Harmer 《Journal of the American Ceramic Society》2005,88(8):2046-2052
The reaction-bonded aluminum oxide (RBAO) process is an attractive alternative to the conventional processing of Al2 O3 -based ceramics. The most attractive features of the process are the high strengths, densities, and easy machinability of the green powder compacts, and the low shrinkage and high strengths of the sintered ceramics. These advantages result from the presence of aluminum in the green bodies and are enhanced further with increasing aluminum contents. However, it is apparent that ZrO2 -containing RBAO powders with higher aluminum contents (>45 vol%) are increasingly more difficult to densify, as the start of densification is delayed (shifted to higher temperatures) and the densification rates are decreased. Ultimately, this results in a decrease in the limiting density to which the RBAO ceramic may be sintered. In this study, the cooperative effects of ZrO2 and aluminum contents on the sintering of RBAO ceramics are discussed in terms of densification behavior and microstructural analysis. 相似文献
9.
Yukio Takeda Kousuke Nakamura Kunihiro Maeda Yasuo Matsushita 《Journal of the American Ceramic Society》1987,70(10):266-C
Effects of various elemental additives on the electrical resistivity of hot-pressed SiC ceramics were studied. The electrical resistivity at room temperature of dense SiC ceramics varied greatly depending on the additives used. SiC ceramics with added Be had an extremely high electrical resistivity of 3 × 1012 °.cm. On the other hand, SiC ceramics with added B and Al had electrical resistivities of 2 × 10 and 0.8 °cm, respectively. The differences in the electrical resistivity of the dense SiC ceramics were considered to be due to different solubilities of the additives in SiC grains. SiC ceramics with added Be had a low level of impurities in the SiC grains as a result of the low solubility of Be in these grains. 相似文献
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The effect of transition metal oxides and the sintering temperature on the strength parameters of cordierite ceramics synthesized using mechanical activation is investigated. It is established that an introduction of oxide additives improves the strength of ceramics. 相似文献
12.
氮化物添加对钛酸钡半导瓷电阻—温度曲线之影响 总被引:2,自引:0,他引:2
本文研究了氮化物添加对钛酸钡半导瓷电阻-温度曲线之影响,实验表明,除NB外TiN、Si3N4、AlN也可以给出较平坦的电阻极大值,在适当的工艺条件下没有氮化物添加同样可以得到类似结果。 相似文献
13.
H. P. R. FREDERIKSE A. H. KAHN A. L. DRAGOO W. R. HOSLER 《Journal of the American Ceramic Society》1985,68(3):131-135
The dc conductivity of hexagonal boron nitride (BN) and BN-containing composites was measured as a function of temperature up to 2400°C. The results confirm that at high temperatures BN is an intrinsic semiconductor with an energy gap of 0.99 ± 0.06 aJ (6.2 ± 0.4 eV) at T = 0 K. Extrapolated values for the resistivity of BN in the range 2600° to 3000°C are used to analyze the absorption, reflectivity, and transmissivity of a BN window when subjected to microwave radiation under atmospheric reentry conditions. It appears that the transmissivity is of the order of 1 to 10% at these temperatures due mainly to the high conductivity in a very thin, very hot surface layer. The transmissivity can be improved by using a composite made of boron nitride and silica. 相似文献
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Hiroyasu Tamai Takashi Hamauzu Akihito Ryumon Kaoru Aoki Kohei Oda Tetsuo Yoshio 《Journal of the American Ceramic Society》2000,83(12):3216-3218
The hydrothermal corrosion and strength degradation of aluminum nitride (AlN) ceramics were investigated. The weight gain in AlN ceramics after corrosion occurred because of the formation of boehmite. The reaction kinetics of AlN with water were diffusion controlled through the boehmite product layer. At 180°C, immersion in water caused no strength degradation, and water vapor caused a 20% strength degradation. At 300°C, immersion in water caused a 20% strength degradation, and water vapor caused a 30% strength degradation. 相似文献
16.
Development and Microstructural Characterization of High-Thermal-Conductivity Aluminum Nitride Ceramics 总被引:2,自引:0,他引:2
YASUHIRO KUROKAWA KAZUAKI UTSUMI HIDEO TAKAMIZAWA 《Journal of the American Ceramic Society》1988,71(7):588-594
The effect of several additives, such as CaC2 , CaO, Y2 O3 , and C, on thermal conductivity of hot-pressed AlN ceramics was investigated. The addition of CaC2 reductant was found to be useful for achieving high thermal conductivity of 180 W/(m·K) at room temperature. The characterization of AlN ceramics with CaC2 additive was performed by chemical analysis of Ca, C, and O and microstructural analysis using transmission electron microscopes equipped with an energy-dispersive X-ray analyzer and an electron energy loss spectrometer. The major influence on high thermal conductivity is the disappearance of a thermal barrier caused by oxygen impurities at the grain boundary. 相似文献
17.
加入SiC、SiAlON对刚玉-SiC-SiAlON材料组成、结构和力学性能的影响 总被引:2,自引:2,他引:0
以刚玉和8%Si粉为原料,1500℃埋碳烧后得刚玉-SiC-SiAlON复合材料.本文研究在加入8%Si粉基础上,另加入0~10%SiC或SiAlON粉对刚玉-SiC-SiAlON复合材料组成、结构和力学性能的影响.结果表明:加入SiC或SiAlON首先可促进Si反应完全,生成更多非氧化物使试样微膨胀量增加,重量增加;同时使试样的显气孔率提高,常温抗折强度降低;加入SiC使试样的结构疏松,高温力学性能下降;但由于生成较多O-SiAlON以及气孔率提高使试样的抗热震性明显提高;加入SiAlON,试样中生成较多的SiC,并有粒状的β-SiAlON存在,可明显提高试样的高温力学性能. 相似文献
18.
You Zhou Kiyoshi Hirao Motohiro Toriyama Yukihiko Yamauchi Shuzo Kanzaki 《Journal of the American Ceramic Society》2001,84(7):1642-1644
Based on the processing strategy of improving the mechanical properties of liquid-phase-sintered materials by modifying the secondary phase chemistry, four rare-earth oxides (RE2 O3 , RE = La, Nd, Y, and Yb), in combination with alumina, were used as sintering aids for a submicrometer-size β-SiC powder. Doped with 5 vol% RE2 O3 + Al2 O3 additives, all specimens were hot-pressed to near full-densities at 1800°C, and they exhibited similar microstructures and grain size distributions. The SiC grains in all specimens revealed a core-rim structure after being plasma-etched, indicating that they were densified via the same solution-reprecipitation mechanism. It was found that a decrease in the cationic radius of the rare-earth oxides was accompanied by an increase in Young's modulus, hardness, and flexural strength of the SiC ceramics, whereas the fracture toughness was improved by incorporating rare-earth oxides of larger cationic radius. The changes in the mechanical properties were attributed to the difference in the chemistry of the intergranular phases in the four ceramics. 相似文献
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Takeshi Yagi Kazuo Shinozaki Nobuo Ishizawa Nobuyasu Mizutani Masanori Kato Akihiko Tsuge 《Journal of the American Ceramic Society》1988,71(7):334-C
The thermal diffusivity of AlN ceramics was significantly decreased by the addition of SiO2 . The AlN ceramics with 4 wt% SiO2 could not be densified by pressureless sintering in the temperature range 1400° to 1800°C. The thermal diffusivity of these samples was very low because of their porous structure. The AlN ceramics containing 2, 4, and 8 wt% SiO2 were densified by hot-pressing and also had low thermal diffusivity. In these samples, the grains of the 27R polytype that resulted from the reaction between AlN and SiO2 were dispersed, obstructing the conduction of heat. The relation between the amount of 27R polytype and the thermal diffusivity of the AlN ceramics was determined. 相似文献