人工湿地深度处理医院污水的研究

以人工湿地系统处理医院污水处理站二级处理出水,以达到深度降解并去除TN的目的。设计总面积782 m2人工湿地系统,其中自由表面流型(FWS)人工湿地450 m2和潜流型(SSF)人工湿地186 m2,最后连接生态景观池面积146 m2,每日平均抽取30 m3污水(二级处理出水),水力负荷为0.05 m/d。早期运行结果显示,TN去除率为44%,NO3-—N去除率FWS湿地为15%,SSF湿地为34%。试验进行到稳定运行期,调高流量至70～100 m3/d,水力负荷为0.11～0.16 m/d,结果显示,NO3-—N去除率达68%;比较FWS与SSF湿地的NO3-—N的去除速率,FWS湿地为2.48 g/(m2.d),SSF湿地为3.61 g/(m2.d)。SSF湿地对NO3-—N的去除效能比FWS湿地好。     

一体化装置-潜流人工湿地处理生活污水的研究

采用一体化装置—潜流人工湿地工艺对生活污水的处理进行了研究。结果表明,一体化装置对CODCr、BOD5、氨氮及SS的去除率分别在60.68%、58.87%、63.69%和75.51%以上,人工湿地对CODCr、BOD5、氨氮及SS的去除率分别在49.97%、84.40%、70.77%和82.74%以上,该工艺对各污染物去除效果明显,具有工艺流程简单、运行费用低等特点。     

Treatment of high strength wastewater with vertical flow constructed wetland filters.

The aim of the present study was to evaluate the behaviour of vertical flow constructed wetlands to treat high strength wastewater. Influents were obtained mixing tap water with different percentages of MSW landfill leachate (5%, 10% and 20%). Phragmites australis seedlings were used as macrophytes. The reeds were nurtured during three spring months, before the start of the experimental period. Three and four days of detention time were adopted. Influent concentrations of 510-2,050 mg L(-1), 180-740 mg L(-1) and 65-260 mg L(-1) were obtained for COD, N-NH4(+) and N-NO3(-), respectively. The environmental temperature averaged around 31.0 +/- 1.4 degrees C. During the experimental period, all parameters showed an increasing removal efficiency trend. Best results in terms of COD removal were obtained for mixtures at lowest rate of landfill leachate; while, denitrification process showed an opposite behaviour; finally, the removal of ammonia nitrogen appeared to be independent upon influent concentrations. Analysis carried out on the reed tissues showed a theoretic maximum storage of TKN in the leaves of about 55 mg/g dry weight. A leachate percentage of about 35% was derived to be able to fully inhibit the growth of macrophytes.     

Domestic wastewater treatment by a constructed wetland system planted with rice

The experiments were conducted in four concrete laboratory scale free water surface constructed wetland units 1 m wide, 1.5 m long and 0.8 m deep. Paddy field soil was added to a depth of 0.4 m and rice seedlings (Oryza sativa L.) were transplanted into the units at a density of 25 plants/m(2). Domestic wastewater collected from Chiang Mai University was applied into each unit via two different modes to evaluate suitable conditions for wastewater treatment and rice yield. In the first experiment, the wastewater was fed intermittently (7 h/day) with a hydraulic loading rate of 2, 4, 6 and 8 cm/day. The maximum removal efficiencies for chemical oxygen demand, biological oxygen demand, total kjedahl nitrogen and suspended solids were only 49.1, 58.7, 64.0 and 59.4%, respectively, due to the short hydraulic retention time for the biodegradation of organic substances. In the second experiment, the wastewater in each unit was inundated to a depth of 15 cm for 10, 15, 20 and 25 days in each unit and then drained and re-flooded. Removal efficiencies of chemical oxygen demand, biological oxygen demand, total kjedahl nitrogen and suspended solids were greater than in the first experiment especially at the 25 day retention time and except for suspended solids met the Thai national effluent standard. The study revealed that apart from wastewater treatment, wastewater can replace natural water to grow rice in the dry season or throughout the year. Moreover, nutrients in wastewater can be a substitute for chemical fertilizers. Rice grain production was 4,700 kg/ha and only 6% less than the production from the conventional paddy field.     

Feasibility of a constructed wetland and wastewater stabilisation pond system as a sewage reclamation system for agricultural reuse in a decentralised rural area.

The performance of a constructed wetland (CW) and wastewater stabilisation pond (WSP) system for sewage reclamation and paddy rice irrigation in a decentralised rural area was examined using a feasibility study. The CW was satisfactory for sewage treatment, with good removal efficiency even in the winter period, but the effluent concentration was relatively high in the winter period owing to the high influent concentration. The CW effluent was further treated in a WSP and the WSP effluent was considered safe for crop irrigation with respect to sewage-borne pathogens. Reclaimed water irrigation did not adversely affect the yield of rice; on the contrary, it resulted in an approximately 50% greater yield than in controls. The chemical characteristics of the soil did not change significantly during the experimental period of irrigation with reclaimed water. In the winter, CW effluent could be stored and treated in a WSP until the spring; the water could then be discharged or reused for supplemental irrigation during the typical Korean spring drought. Overall, sewage treatment and agronomic reuse using a CW-WSP system could be a practical integrated sewage management measure for protecting receiving water bodies and overcoming water shortages in decentralised rural areas.     

Performance of constructed wetland treating wastewater from seafood industry.

Wastewater from seafood industry contains high concentrations of organic matter, nitrogen compounds, and solid matter. Constructed wetland can be used as tertiary treatment and for nutrient recycling. This research studied the performance of nitrogen and suspended solids removal efficiency of a constructed wetland treating wastewater from a seafood-processing factory located at Songkhla, southern Thailand. The existing constructed wetland has dimensions of 85 m, 352 m and 1.5 m in width, length and depth respectively, with an area of about 29,920 m2. The water depth of 0.30 m is maintained in operation with plantation of cattails (Typha augustifolia). Flow rate of influent ranged between 500-4,660 m3/d. Average hydraulic retention time in the constructed wetland was about 4.8 days. Influent and effluent from the constructed wetland were collected once a week and analyzed for pH, temperature, dissolved oxygen (DO), biochemical oxygen demand (BOD5), Suspended solid (SS), total Kjeldahl nitrogen (TKN), ammonia nitrogen (NH3-N), organic nitrogen (Org-N), nitrate (NO3-N), and nitrite (NO2-N). The average removal efficiencies of BOD5, SS, TKN, NH3-N, and Org-N were 84%, 94%, 49%, 52% and 82%, respectively. It was found that the constructed wetland acting as a tertiary treatment process provided additional removal of BOD5, SS and TKN from wastewater from the seafood industry.     

Nitrogen dynamics in a constructed wetland system treating landfill leachate.

A pilot scale treatment system was established in 2002 at the Laflèche Landfill in Eastern Ontario, Canada. The system consists of a series of treatment steps: a stabilisation basin (10,000 m3), a woodland peat trickling filter (5,200 m2), a subsurface flow constructed wetland planted in Phragmites sp. (2,600 m2), a surface flow constructed wetland planted in Typha sp. (3,600 m2) and a polishing pond (3,600 m2). The system operates from May to December with leachate being recycled within the landfill during the winter months. Hydraulic loading was increased three-fold over four operating seasons with nitrogen and organic mass loading increasing six-fold. Excellent removal efficiencies were observed with 93% BOD5, 90% TKN and 97% NH4-N removed under the highest loading conditions. Almost complete denitrification was observed throughout the treatment system with NO3-N concentrations never exceeding 5mg L(-1). The peat filter reached treatment capacity at a hydraulic loading of 4cm d(-1) and organic loading rate of 42 kg BOD ha(-1) d(-1), which is consistent with design criteria for vertical flow wetland systems and intermittent sand filters, The first order plug flow kinetic model was effective at describing TKN and ammonium removal in the SSF and FWS wetlands when background concentrations were taken into account. Ammonium removal k-values were consistent with the literature at 52.6 and 57.7 yr(-1) for the SSF and FWS wetlands, respectively, while TKN k-values at 6.9 and 7.7 yr(-1) were almost an order of magnitude lower than literature values, suggesting that leachate TKN could contain refractory organics not found in domestic wastewater.     

Potential of a tropical subsurface constructed wetland to remove phenol from pre-treated pulp and papermill wastewater.

The capacity of a pilot project subsurface flow constructed wetland in the tropics to remove phenol from pre-treated pulp and paper mill wastewater was studied under varying hydraulic retention times (HRT) with batch loading. Initial 15 months results indicate that removal efficiencies for phenol were variable but on average reached 60% at 5-day HRT and 77% at 3-day HRT. It was thought that the longer retention time might have caused oxygen and nutrient deficiencies, which may have reduced removal performance. Although phenol was sometimes not detectable in the wetland outflow, on average values over the experimental period did not meet set national guidelines. In the ongoing study, the impact of varying hydraulic retention time and/or loading rate on the removal of phenols will be evaluated and the main removal process established.     

Municipal wastewater treatment with pond-constructed wetland system: a case study.

The performance of a pond-constructed wetland system in the treatment of municipal wastewater in Kiaochow city was studied; and comparison with oxidation ponds system was conducted. In the post-constructed wetland, the removal of COD, TN and TP is 24%, 58.5% and 24.8% respectively. The treated effluent from the constructed wetland can meet the Chinese National Agricultural and Irrigation Standard. The comparison between pond-constructed wetland system and oxidation pond system shows that total nitrogen removal in a constructed wetland is better than that in an oxidation pond and the TP removal is inferior. A possible reason is the low dissolved oxygen concentration in the wetland. Constructed wetlands can restrain the growth of algae effectively, and can produce obvious ecological and economical benefits.     

厌氧—接触氧化渠—垂直潜流型人工湿地处理农村生活污水研究

选择厌氧—接触氧化渠—垂直潜流型人工湿地工艺处理农村生活污水,分析比较了各工艺段DO水平,接触氧化渠充氧效果明显.通过对COD、NH3—N和TP浓度及去除率的研究发现,厌氧池去除率较稳定,对各污染物去除率最高可达72％、49.54％和66.36％,接触氧化渠和人工湿地对各污染物也有较高去除率,但并不稳定.系统运行稳定后,出水水质整体可达到《城镇污水处理厂污染物排放标准》(GB 18918-2002)二级标准,部分时段可达一级B标准.     

A two-stage subsurface vertical flow constructed wetland for high-rate nitrogen removal.

By using a two-stage constructed wetland (CW) system operated with an organic load of 40 gCOD.m(-2).d(-1) (2 m2 per person equivalent) average nitrogen removal efficiencies of about 50% and average nitrogen elimination rates of 980 g N.m(-2).yr(-1) could be achieved. Two vertical flow beds with intermittent loading have been operated in series. The first stage uses sand with a grain size of 2-3.2 mm for the main layer and has a drainage layer that is impounded; the second stage sand with a grain size of 0.06-4 mm and a drainage layer with free drainage. The high nitrogen removal can be achieved without recirculation thus it is possible to operate the two-stage CW system without energy input. The paper shows performance data for the two-stage CW system regarding removal of organic matter and nitrogen for the two year operating period of the system. Additionally, its efficiency is compared with the efficiency of a single-stage vertical flow CW system designed and operated according to the Austrian design standards with 4 m2 per person equivalent. The comparison shows that a higher effluent quality could be reached with the two-stage system although the two-stage CW system is operated with the double organic load or half the specific surface area requirement, respectively. Another advantage is that the specific investment costs of the two-stage CW system amount to 1,200 EUR per person (without mechanical pre-treatment) and are only about 60% of the specific investment costs of the singe-stage CW system.     

Phosphorus mass balance in a surface flow constructed wetland receiving piggery wastewater effluent

This research was conducted to investigate the phosphorus forms present in water, soil and sediment and to estimate the phosphorus mass balance in a surface flow constructed wetland (CW). Water quality and sediment samples were collected from each cell along the hydrologic path in the CW from October 2008 to December 2010. At the same time, three dominant plant species (e.g. common reed and cattails) were observed through the measurement of the weight, height and phosphorus content. Based on the results, the orthophosphate constituted 24-34% of total phosphorus in water for each cell. The overall average phosphorus removal efficiency of the CW was approximately 38%. The average inflow and outflow phosphorus loads during the monitoring period were 1,167 kg/yr and 408 kg/yr, respectively. The average phosphorus retention rate was 65%, was mainly contributed by the settling of TP into the bottom sediments (30%). The phosphorus uptake of plants was less than 1%. The estimated phosphorus mass balance was effective in predicting the phosphorus retention and release in the CW treating wastewater. Continuous monitoring is underway to support further assessment of the CW system and design.     

Nitrogen removal and ammonia-oxidising bacteria in a vertical flow constructed wetland treating inorganic wastewater

Nitrogen removal performance and the ammonia-oxidising bacterial (AOB) community were assessed in the batch loaded 1.3 ha saturated surface vertical flow wetland at CSBP Ltd, a fertiliser and chemical manufacturer located in Kwinana, Western Australia. From September 2008 to October 2009 water quality was monitored and sediment samples collected for bacterial analyses. During the period of study the wetland received an average inflow of 1,109 m3/day with NH3-N = 40 mg/L and NO3-N = 23 mg/L. Effluent NH3-N and NO3-N were on average 31 and 25 mg/L, respectively. The overall NH3-N removal rate for the period was 1.2 g/m2/day indicating the nitrifying capacity of the wetland. The structure of the AOB community was analysed using group specific primers for the ammonia monooxygenase gene (amoA) by terminal restriction fragment length polymorphism and by clone libraries to identify key members. The majority of sequences obtained were most similar to Nitrosomonas sp. while Nitrosospira sp. was less frequent. Another two vertical flow wetlands, 0.8 ha each, were commissioned at CSBP in July 2009, since then the wetland in this study has received nitrified effluent from these two new cells.     

The effect of a vertical flow filter bed on a hybrid constructed wetland system.

Data from 18 sampling wells in Kodij?rve horizontal subsurface flow (HSSF) constructed wetland (CW) (South Estonia) is presented and differences in purification efficiencies inside the HSSF CW are calculated. Temporarily anaerobic conditions in the Kodij?rve HSSF system did not allow efficient removal of BOD7, NH4-N, Ntot and Ptot. In 2002 a vertical subsurface flow filter was constructed to enhance aeration. The design of the system was based simply on the oxygen demand of the wastewater and on the aeration potential of vertical flow wetlands. The vertical flow system has shown satisfactory results. The purification efficiency of BOD7 in the Kodij?rve CW has improved significantly and there has been a slight increase in purification efficiencies of NH4-N and Ntot. On the ohther hand, the removal efficiency of Ptot has decreased significantly. Although, the mass loading rates have increased, mass removal rates of all four parameters have improved significantly. Nevertheless, optimization of the constructed wetland system is essential in order to meet effluent standards during wintertime.     

Effects of effluent recirculation in vertical-flow constructed wetland on treatment efficiency of livestock wastewater.

Enhancing the treatment efficiency of livestock wastewater by effluent recirculation is investigated in a pilot-scale vertical-flow constructed wetland. The wetland system is composed of downflow and upflow stages, on which narrow-leaf Phragmites communis and common reed Phragmites typhia are planted, respectively; each stage has a dimension of 4 m(2) (2 m x 2 m). Wastewater from the facultative pond is fed into the system intermittently at a flow rate of 0.4 m(3)/d. Recirculation rates of 0, 25%, 50%0, 100% and 150% are adopted to evaluate the effect of the recirculation rate on pollutants removal. This shows that with effluent recirculation the average removal efficiencies of NH4-N, BOD5 and SS obviously increase to 61.7%, 81.3%, and 77.1%, respectively, in comparison with the values of 35.6%o, 50.2%, and 49.3% without effluent recirculation. But the improvement of TP removal is slight, only from 42.3% to 48.9%. The variations of NH4-N, DO and oxidation-reduction potential (ORP) of inflow and outflow reveal that the adoption of effluent recirculation is beneficial to the formation of oxide environment in wetland. The exponential relationships with excellent correlation coefficients (R(2) > 0.93) are found between the removal rates of NH4-N and BOD5 and the recirculation rates. With recirculation the pH value of the outflow decreases as the alkalinity is consumed by the gradually enhanced nitrification process. When recirculation rate is kept constant at 100%, the ambient temperature appears to affect NH4-N removal, but does not have significant influence on BOD5 removal.     

Use of headspace solid-phase microextraction to characterize odour compounds in subsurface flow constructed wetland for wastewater treatment.

A headspace solid-phase microextraction (HS-SPME) preconcentration method was applied to the analysis of some of the major odorous compounds occurring in wastewater using GC/MS or GC/NPD detection. The detection limit for volatile amines, volatile fatty acids, and volatile alkylsulphides ranged from 3 to 100, 2 to 150, and 0.0006 to 0.035 microg/L, respectively. The SPME method was used to examine the fate of odorous compounds in the subsurface flow constructed wetlands (SFCW) operated under different hydraulic loading rate (HLR), bed aspect ratio, and granular medium size. Among the experimental conditions evaluated in the SFCW beds, HLR was found to be the most important factor influencing the evolution of the studied compounds. There were also significant differences among bed types in the behaviour of ammonia (NH3), acetic acid (Ac), isovaleric acid (IsoA), propionic acid (PrA), and dimethylsulphide. Aspect ratio and medium granular size were minor factors influencing SFCW performance. The major odour compounds by mass in the effluent of SFCW with different operational conditions were NH3 and Ac. Further removal of these two compounds is considered as very important from the viewpoint of chemical composition. On the other hand, Relative Odour Intensity (ROI: ratio between the absolute concentration to the odour threshold concentration) suggested that PrA and IsoA were the two major compounds responsible for odour intensity. Thus, further removal of these two compounds is viewed as very important for the effluent deodorization, especially for PrA. From our results, this compound appears to be produced by processes occurring in the SFCW.     

Water quality in a surface-flow constructed treatment wetland polishing tertiary effluent from a municipal wastewater treatment plant

Constructed treatment wetlands (CTWs) are unique ecotechnologies that can sustainably treat a range of wastewaters. This study focused on a 0.23 ha vegetated surface-flow CTW polishing nitrate-rich (3-6 mg-N/L) tertiary effluent from a municipal wastewater treatment plant. Water quality was monitored longitudinally in the fall of 2009 and 2010. The CTW cooled water by from around 20 °C to <15 °C in both years. Longitudinal temperature profiles were successfully modeled using an energy balance approach (2009 R(2) = 0.69; 2010 R(2) = 0.92). The magnitude of key model fitting parameters, including albedo (0.1-0.2) and convective transfer coefficient (0.1-0.9 MJ/m(2) d °C), were within ranges reported in the literature. In both years, dissolved oxygen decreased through the wetland from 6-7 mg/L to 3-4 mg/L, yielding an oxygen mass consumption rate of 0.08-0.09 g/m(2) d. Longitudinal nitrate profiles were well represented by the P-k-C* model (2009 R(2) = 0.88; 2010 R(2) = 0.92). First order removal rates were 20.2 m/yr in 2009 and 29.0 m/yr in 2010 at a P value of 6.0. Levels of ammonia and total phosphorus increased negligibly through the wetland, remaining below 0.25 mg/L. This study shows that vegetated surface-flow CTWs are well suited to cool and polish low-BOD nitrate-dominated tertiary effluents with little degradation of other water quality parameters of concern, including phosphorus and ammonia.     

Fenton-水解酸化-厌氧接触-接触氧化工艺处理高盐生产废水

高盐废水中的高含盐量对微生物的生长有较强的抑制作用,增加了其生物处理的难度.重庆某化工厂日排成分复杂的高盐高浓度生产废水,其CODCr51～63 g/L,氯化物75～91 g/L.通过驯化耐盐微生物作为主体菌种,采用Fenton-水解酸化-厌氧接触-接触氧化组合工艺,出水各项指标均达到<污水综合排放标准>(GB 897...     

Potential nitrification and denitrification and the corresponding composition of the bacterial communities in a compact constructed wetland treating landfill leachates.

Constructed wetlands can be used to decrease the high ammonium concentrations in landfill leachates. We investigated nitrification/denitrification activity and the corresponding bacterial communities in landfill leachate that was treated in a compact constructed wetland, Tveta Recycling Facility, Sweden. Samples were collected at three depths in a filter bed and the sediment from a connected open pond in July, September and November 2004. Potential ammonia oxidation was measured by short-term incubation method and potential denitrification by the acetylene inhibition technique. The ammonia-oxidising and the denitrifying bacterial communities were investigated using group-specific PCR primers targeting 16S rRNA genes and the functional gene nosZ, respectively. PCR products were analysed by denaturing gradient gel electrophoresis and nucleotide sequencing. The same degree of nitrification activity was observed in the pond sediment and at all levels in the filter bed, whereas the denitrification activity decreased with filter bed depth. Denitrification rates were higher in the open pond, even though the denitrifying bacterial community was more diverse in the filter bed. The ammonia-oxidising community was also more varied in the filter bed. In the filter bed and the open pond, there was no obvious relationship between the nitrification/denitrification activities and the composition of the corresponding bacterial communities.     

Performance of a combined eco-system of ponds and constructed wetlands for wastewater reclamation and reuse.

An on-site study on the operational performance of a combined eco-system of ponds and SF constructed wetland for municipal wastewater treatment and reclamation/reuse in Donging City, Shandong, China was carried out from January 2001 through October 2003. The removal efficiencies for various main parameters were: TSS 84.8 +/- 7.3%, BOD5 87.2 +/- 5.3%, CODCr 70.2 +/- 18.6%, TP 52.3 +/- 23.1%, and NH(3)-N 54.8 +/- 23.9% with effluent concentration of TSS 9.12 +/- 5.12 mg/l, BOD5 6.44 +/- 4.58 mg/l, CODCr, 42.8 +/- 6.7 mg/l, TP 0.94 +/- 0.27 mg/l and NH(3)-N 7.95 +/- 2.36 mg/l. In addition, the removal efficiencies for faecal coliforms and total bacteria were > 99.97% and > 99.998% respectively, which well meet Chinese National standards for effluent quality of municipal wastewater treatment plants. The composition of TSS was closely related to CODCr and BOD5 variations, and nitrification-denitrification is the major mechanism of nitrogen removal both in ponds and in wetlands. In addition, sedimentation also played an important role in the removal of TSS, nitrogen, phosphorus and BOD5. The removal efficiencies of various parameters, the number of species and biomass of biological community in the system increased gradually with the ecological maturation.