Attenuation of Roadway-Derived Heavy Metals by Wood Chips

Wood chips were evaluated for their ability to attenuate heavy metals in roadway runoff. Column experiments with controlled synthetic runoff composition and flow rate were used to assess effects of flow rate (intercepted sheetflow from a 3-m wide roadway section), runoff salt concentration, wood exposure to alternating wetting and drying cycles, wood aging, competition among dissolved heavy metals, and removal of particle-associated heavy metals. Overall, wood chips damped the “pulse” of copper in the synthetic runoff such that the effluent was characterized by lower concentrations (3–25% of input) over longer periods of time, but with little retention of the total copper mass. The most effective treatment was wood chips aged up to 9 months. Increased aging and chip water content reduced effluent concentrations, relative to no treatment. Flow rate had no effect on effluent concentrations. The presence of salt (>2?mS/cm) or dissolved lead (500?μg/L) in the runoff caused greater copper effluent concentrations than the no treatment case. Removal of suspended particles (and associated contaminants) was greater than 85% with an estimated capacity of 0.16?g/gwood. Field evaluation with concentrated flow to a gutter containing a wood chip treatment showed little effect on total or dissolved copper and zinc runoff concentrations and indicated that wood chips may be a source of contaminants in subsequent storm events. Applications of wood chips to treat roadway runoff would not provide a significant decrease in total maximum daily load contributions (e.g., kg/d); however, there may be some scenarios for which wood chip treatments to decrease peak storm water concentrations of dissolved heavy metals in sheetflow runoff is desirable.     

Impact of Storm-Water Runoff on Clogging and Fecal Bacteria Reduction in Sand Columns

Storm-water runoff has been identified as a major cause of coastal water quality degradation. Storm-water outfalls, common in many coastal towns, convey bacteria and other pollutants into the ocean and estuaries. In an effort to minimize this impact, the Town of Kure Beach, North Carolina, installed Dune Infiltration Systems (DIS) at two storm-water outfalls to receive storm-water runoff and allow infiltration beneath the beach dunes. A laboratory column experiment was performed to supplement this installation and determine the potential hydraulic and bacterial removal efficiency of the sand comprising the Kure Beach dunes. Columns constructed using sand collected at different depths of the dune were used to analyze the affect of bacteria application on infiltration and to examine the changes in bacteria removal that occur as infiltration rates are affected by bacteria-laden water application. Sand columns were loaded over a 60-day period with either bacteria-free storm water or storm water spiked with Escherichia coli. The seepage rate for the bacteria-spiked storm-water treatment was significantly lower (p<0.05) than the seepage rate of the bacteria-free treatment, particularly toward the end of the study. Bacteria application likely compounds the impact of sediment clogging at the sand/storm-water interface. This study indicates the need for maintenance when implementing a DIS or similar sand filter to maintain design infiltration rates, especially if reduced infiltration rates are not planned for in the design. However, a decrease in seepage rate was correlated with a decrease in effluent bacteria concentration in the bacteria-spiked storm-water sand columns. Thus, optimization is required to provide maximum infiltration of storm-water while maintaining bacteria removal efficiency.     

Zero-Valent Iron-Assisted Autotrophic Denitrification

Porous reactive?barriers containing metallic iron and hydrogenotrophic denitrifying microorganisms may potentially be suitable for in-situ remediation of nitrate-contaminated groundwater resources. The main objective of the research described here was to determine the type and concentration of metallic iron to be used in such reactive?barriers so that ammonia formation through metallic iron-assisted abiotic nitrate reduction was minimized, while a reasonable rate of biological denitrification, sustained by hydrogen produced through metallic iron corrosion, was maintained. Initial experiments included the demonstration of autotrophic denitrification supported by externally supplied hydrogen, either from a gas cylinder or generated through anaerobic corrosion of metallic iron. Next, the effect of iron type on abiotic nitrate reduction was studied, and among those types of iron tested, steel wool, with its relatively low surface-area-to-weight ratio, was identified as the material that exhibited the least propensity to abiotically reduce nitrate. Further, long-term experiments were carried out in batch reactors to determine the effect of steel?wool surface area on the extent of denitrification and ammonia production. Finally, experiments carried out in up-flow column reactors containing sand and varying quantities of steel wool demonstrated biological denitrification occurring in such systems. Based on the results of the final set of experiments, it appeared that to minimize ammonia production, the steel-wool concentration up-flow columns must be even below the lowest value—0.5 g steel wool added to 125?cm3 of sand—used during this study. To counter any detrimental effect of lowered steel wool concentration on the extent of hydrogenotrophic denitrification, increase of the retention time in the columns to values higher than 13 days (the maximum value investigated in this study) may be necessary.     

Multiyear Performance of a Pervious Concrete Infiltration Basin BMP

The use of infiltration storm-water best management practices (BMPs) has become a more commonly used approach as a means of reducing postdevelopment runoff volumes in many areas throughout the United States. Although studies regarding the performance of infiltration BMPs are emerging, much remains to be learned about their design, construction, and operation. The increase in knowledge will improve the performance and longevity of these BMPs. The performance of one such infiltration basin over a 2-year cycle is presented in this paper. The study site is a pervious concrete infiltration basin BMP built in 2002 in a courtyard common area at Villanova University. The system consists of three linked infiltration beds lined with geotextile filter fabric, filled with coarse aggregate, and overlaid with pervious concrete. The natural soil beneath the infiltration BMP is a silty sand. The BMP is extensively instrumented to facilitate water quantity and quality research. Both water-quantity and -quality results are presented. The water-quantity analysis showed that the performance of the basin was directly related to its infiltration characteristics. The infiltration rate of the silty sand is cyclic, with higher rates during warmer periods and lower rates during colder periods. The water quality analysis investigated the pollutant reduction for chloride, copper, nitrogen, and phosphorus from the inlet to the surface-water outlet of the structure, as well as differences in pollutant concentration levels between the basin, surrounding ground, and varying soil layer elevations beneath the basin. In general, the pollutant reduction to the surface waters was greater than 90% from inlet to outlet, primarily influenced by the infiltration of the storm water into the natural soils below the BMP. The pollutant concentration of the infiltrating runoff was found to be higher than expected in the area adjacent to the bed when compared to concentration levels found at a similar depth beneath the infiltration bed. Comparison of pollutant concentration levels, as the water moved from within the storage bed to the soil beneath the bed, were shown to vary, with statistical differences found for mean concentration levels of both pH and copper levels; and no statistical differences were found for conductivity, total phosphorous, and chloride at each elevation.     

Phosphorus Retention by Bioretention Mesocosms Using Media Formulated for Phosphorus Sorption: Response to Accelerated Loads

Recent research indicates that phosphorus (P) retention by bioretention systems comprising sandy media may not be effective for even a decade of urban runoff loads. To improve P retention for longer durations, this paper present findings from bioretention mesocosms using media amended with red mud (RM), a by-product of bauxite processing; water treatment residuals (WTRs), a by-product of water treatment; or Krasnozem soil (K), a highly aggregated clay soil. All treatments were vegetated except for one (K20nv). All treatments had outlets to restrict outflows except for one (WTR-Knr). To simulate the effect of long-term nutrient loads, the mesocosms were loaded weekly with secondary treated effluent with P concentrations averaging 3.3??mg-L-1. Over 80 weeks, this comprised hydraulic loads from 24.5 to 29.3??m-year-1 at a flow-weighted average between 2.8 and 3.2??mg-L-1 PO4-P, or mass loads from 1,115 to 1,284??kg-ha-1 PO4-P. These cumulative P loads represent the equivalent of over three decades of runoff loads. After 80 weeks, cumulative PO4-P retention in the K and RM soil treatments ranged from 79% to 95%, whereas PO4-P retention in the WTR treatments ranged from 95% to 99% of the input load. At 6-month intervals, the treatments were dosed with at least four sequential dosing runs of synthetic storm water with concentrations less than 0.8??mg-L-1 PO4-P. After 56 weeks of effluent loading, removal of PO4-P from storm water was negative 109% in the unvegetated K20nv treatment, compared with 33% retention in the corresponding vegetated K20 treatment. The K40 treatment with the most K retained 69% PO4-P, while the RM10 treatment with the most RM retained 78% PO4-P. After 80 weeks of effluent loading, removal of PO4-P from storm water was negative in both the K20nv and vegetated K20 treatments. The K40 treatment retained 76% PO4-P, and the RM10 treatment retained 55% PO4-P, while the total dissolved P (TDP) retention was 72% and 52%, respectively. After 110 weeks of effluent loading comprising 1,598??kg-ha-1 PO4-P, equivalent to 48?years of bioretention loads, PO4-P retention from storm water by the K40 treatment increased to 85%, and retention by the RM10 treatment increased to 91%. TDP retention also increased to 78% and 75%, respectively. These observations of P retention increasing after exposure to additional loads are uncharacteristic of typical sorption responses. After 80 weeks of effluent loading equivalent to 32?years of bioretention loads, the flow-restricted WTR-K treatment removed 99% of the storm-water PO4-P load while the corresponding free-discharge WTR-Knr treatment retained 94%. The WTR-K treatment was less effective than the WTR-Knr treatment in the earlier storm-water runs. The restricted outlet WTR30 treatment, which contained the most WTRs, retained 99% of the storm-water PO4-P load. These high rates of P retention from storm water after accelerated P loads indicate that these amendments can provide effective P retention for the expected lifetime of bioretention facilities.     

Influence of Supplemental Acetate on Bioremediation for Dissolved Polycyclic Aromatic Hydrocarbons

The influence of supplemental acetate on in situ bioremediation for the removal of dissolved polycyclic aromatic hydrocarbons (PAHs) in groundwater was evaluated in laboratory sand columns. Sand columns, inoculated with a soil enrichment culture, were fed with dissolved PAHs (9 mg/L naphthalene, 0.8 mg/L phenanthrene, 0.09 mg/L pyrene), nutrients, and hydrogen peroxide to sustain aerobic microbial growth. Pore water PAH concentration profiles were obtained during the study. Determinations of viable biomass, carbohydrate, and PAH sorption capacity were obtained at the conclusion of the experimental runs. Pore water profiles indicated that PAH biodegradation capability became more quickly established after 45 days in sand columns amended with acetate versus the unamended control. The endpoint pore water PAH concentration profiles were similar for both acetate-amended and unamended columns. Higher biomass in acetate-amended columns increased the overall sorption capacity of the sand medium for PAHs by 24–47%. Supplemental acetate resulted in minimal biofouling of the sand medium as the final hydraulic conductivity of the acetate-amended treatments was 36–72% of the clean sand value.     

Evaluation and Optimization of Bioretention Media for Treatment of Urban Storm Water Runoff

Bioretention is a relatively new urban storm water best management practice. The objective of this study is to provide insight on media characteristics that control bioretention water management behavior. Eighteen bioretention columns and six existing bioretention facilities were evaluated employing synthetic runoff. In columns, the runoff infiltration rate through different media mixtures ranged from 0.28 to 8.15?cm/min at a fixed 15 cm head. For pollutant removals, the results showed excellent removal for oil/grease (>96%). Total lead removal (from 66 to >98%) decreased when the total suspended solids level in the effluent increased (removed from 29 to >96%). The removal efficiency of total phosphorus ranged widely (4–99%), apparently due to preferential flow patterns, and both nitrate and ammonium were moderate to poorly removed, with removals ranging from 1 to 43% and from 2 to 49%, respectively. Two more on-site experiments were conducted during a rainfall event to compare with laboratory investigation. For bioretention design, two media design profiles are proposed; >96%?TSS, >96%?O/G, >98%?lead, >70%?TP, >9%?nitrate, and >20%?ammonium removals are expected with these designs     

Feasibility Study and Conceptual Design for Using Coagulants to Treat Runoff in the Tahoe Basin

Fine particles entrained in storm-water runoff are likely to pass through storm-water treatment basins because of their slow settling velocities and the natural biotic and abiotic mixing processes common to ponds and basins. In Lake Tahoe, targeting fine particles <20?μm in diameter is critical to abating turbidity and phosphorus inputs disproportionately responsible for reducing the lake clarity and impacting regional water quality goals. Iron- and aluminum-based coagulant dosing has been commonly used in water and wastewater treatment plants for removal of fines, turbidity, and dissolved organic carbon. However, application of these coagulants for treating storm water is not common. This study used settling columns to show the feasibility of coagulant dosing to target fine particle removal from storm water in shallow treatment basins and wetlands. Coagulation reduced mean turbidity and phosphorus by 85–95% within 10 h of dosing, compared to 20 and 55% reductions in turbidity and phosphorus, respectively, for nontreated storm water over the same amount of time. To achieve equivalent treatment levels, an order of magnitude increase in time was required for the nontreated storm water. These results have important implications on approaches to treat storm water in the Tahoe Basin. First, these findings suggest that whereas most treatment basins and wetlands will not effectively remove fines and total phosphorus within a 24-h hydraulic residence time, those which utilize coagulant dosing should effectively remove fines and total phosphorus. Second, coagulant dosing relies on mechanical equipment such as pumps and flow meters. These equipments cannot accommodate normal variations in storm-water flow which can range over four orders of magnitude. Thus, to fully leverage the investment of this technology, modifications in hydrologic designs are necessary. We suggest equalization basins upstream of treatment basins to shift treatment from storm water entering a treatment complex to that leaving the equalization basin. This configuration buffers flows at the coagulant dosing location and increases the storage capacity of the storm-water treatment complex. Finally, given the paucity of available acreage in the Tahoe Basin and its high cost, coagulant dosing systems could be retrofitted to existing treatment basins and wetlands, enabling these treatment areas to be more effective in targeting phosphorus and fines, service drainage areas two or three times greater than currently, and reduce land area needed for treating storm water. We present a conceptual layout, a process and instrumentation diagram, and cost estimates to implement this technology at a larger scale. We believe that this technology should receive serious consideration for its application at a field or pilot scale where other potential issues can be further investigated and addressed.     

Effect of Metallic Iron Concentration on End-Product Distribution during Metallic Iron-Assisted Autotrophic Denitrification

The main objective of this study was to determine the optimum composition of a reactive porous medium containing sand and metallic iron, to be used for Fe(0)-assisted hydrogenotrophic denitrification. This determination is important to ensure that the end-product distribution after such treatment is acceptable, i.e., ammonia formation due to abiotic nitrate reduction by metallic iron in such media is minimized, while a reasonable rate of biological denitrification is maintained. Based on a previous study it was established that steel wool, with its relatively low specific surface area, exhibited the least propensity to abiotically reduce nitrate. It was also established that to achieve acceptable end-product distribution, the steel wool concentration in the reactive porous media has to be lowered even below the lowest value, i.e., 4.0?g steel wool/m3 of sand, used during that study. It was further hypothesized that to counter any detrimental effect of lower steel wool concentration on biological nitrate removal rate, increase of the retention time in porous media to values higher than 13 days, the maximum value investigated in that study, may be necessary. In the present study, experiments were conducted in batch reactors containing denitrifying microorganisms and various concentrations of steel wool and in semibatch reactors containing sand seeded with denitrifying microorganisms and various concentrations of steel wool. Based on the results of the semibatch experiments, it appears that to achieve acceptable end-product distribution, the steel wool concentration in the reactive porous media has to be maintained around 2.0?g steel wool/m3 sand and the corresponding retention time in the reactive media must be around 26 days.     

In Situ Partial Exfiltration of Rainfall Runoff. II: Particle Separation

Metal elements or other constituents transported in urban and transportation land use rainfall runoff are often adsorbed on or incorporated with entrained particles that are ubiquitous in such runoff. Infiltration–exfiltration can be an effective in situ particle separation and quantity control structural best management practices or low impact development practices allowing runoff to return to soil after passive physical-chemical treatment. The in situ partial exfiltration reactor (PER), which combined the surface straining of the cementitious porous pavement (CPP) layer with filtration of oxide coated sand media beneath, provided control of water quantity and quality. Particle analyses were carried out for both influent and effluent to examine filter efficiency as a function of particle size and hydrology. Influent dm/dp ratios suggest that the dominant PER particle separation mechanisms were unsaturated physical–chemical filtration with the CPP layer functioning as a straining surface. Particle size distributions were modeled based on a two-parameter cumulative power-law function. The performance of the PER as a filter is shown to be a function of the unsteady site hydrology. Temporal variation in the filter coefficient and the volumetric particle fraction remaining were directly related to the unsteady influent loading rate. Particle removal efficiency by the PER based on concentration ranged from 71 to 96% on a mass-based concentration and 92–99% on a number based concentration. Results suggest that a properly designed PER can provide effective in situ control for particles and could be combined with or function separately from source control (i.e., pavement cleaning or a mass trading framework).     

Urban Runoff Quality Characterization and Load Estimation in Saskatoon, Canada

The improvement in the effluent quality of the treated sanitary sewage entering the South Saskatchewan River at Saskatoon, Canada, and the impending change in provincial legislation governing urban runoff, provided the impetus for Saskatchewan Environment to initiate the stormwater runoff quality study reported in this paper. Among others, the study involved a field program for characterizing the urban runoff water quality from four catchments, each representing a different type of land use. Both a site mean concentration approach and a multiple variable regression analysis approach were used to quantify the pollutant load contained within the runoff. Thereafter, using the runoff water quality characterizations developed in the study, rainfall–runoff pollutant loads from the entire city were estimated and compared with two local point sources to the receiving stream. On the basis of this analysis, it was found that urban runoff contributes more total suspended solids and total Kjeldahl nitrogen load, similar chemical oxygen demand load, and slightly less total phosphorus load than the two local point sources.     

Quality of Runoff Leachate Collected from Biosolids and Dairy-Manure Compost-Amended Topsoils

Compost amendment of pavement shoulder subgrades was attempted to mitigate shrinkage cracking, which otherwise would result in severe distress to adjacent pavement infrastructure systems. Two types of composts, biosolids and dairy-manure composts, were evaluated. As a part of this application, the runoff leachate emanating from the compost soils needs to be environmentally assessed as this leachate potentially ends up in storm sewer collection systems. As a part of the research, runoff collection systems were placed in both dairy-manure and biosolids compost-amended soil sections and a control untreated soil section. The collected water samples at various time intervals were then subjected to various chemical and environmental tests, including total suspended and dissolved solids, biochemical and chemical oxygen demand, total Kjeldahl nitrogen (TKN), and phosphorous measurements. This paper presents a summary of these test results from both sections and their comparisons with similar results from another leachate collected from a control or untreated section. These test results are also compared with a few local studies conducted on highway runoff samples and EPA benchmark values. Possible causes for chemical contaminant concentration differences in the leachate samples from both composts are also explained.     

Natural Catchments as Sources of Background Levels of Storm-Water Metals, Nutrients, and Solids

A key challenge in managing water quality and meeting compliance standards is accounting for both the anthropogenic and natural contributions of a range of water quality constituents. This study quantified levels of solids, metals, and nutrients in storm-water runoff from 18 sites across 11 watersheds representing a range of natural conditions in southern California. Constituent concentration and flux were measured over the course of a variety of storms in order to investigate temporal and spatial patterns in constituent levels, and to identify the most important environmental attributes affecting background water quality. Metals and nutrient concentrations from the natural catchments were typically one to two orders of magnitude lower than those from developed catchments. In contrast, total suspended solids levels were comparable to those found in urban storm water from Los Angeles. Geologic setting had the greatest effect on constituent levels at natural sites. Unlike urban systems, natural catchments do no appear to exhibit a first flush phenomenon, with a substantial portion of the constituent load occurring later in the storm. Ratios of particulate to dissolved metals concentrations changed considerably over the course of storms suggesting that bioavailability of constituents from natural areas may vary over storm duration.     

Nitrate Removal with Sulfur-Limestone Autotrophic Denitrification Processes

Nitrate removal using sulfur and limestone autotrophic denitrification (SLAD) processes was evaluated with four laboratory-scale fixed-bed column reactors. The research objectives were (1) to determine the optimum design criteria of the fixed-bed SLAD columns; and (2) to evaluate the effects of biofouling on the SLAD column performance. A maximum denitrification rate of 384 g NO3?-N/(m3?day) was achieved at a loading rate between 600 and 700 g NO3?-N/(m3?day). The effluent nitrite concentration started to rise gradually once the loading rate was above 600 g NO3?-N/(m3?day). A loading rate between 175 and 225 g NO3?-N/(m3?day) achieved the maximum nitrate-N removal efficiency (～95%). Biofouling was evaluated based on tracer studies, the measured biofilm thickness, and modeling. The porosities of the columns fluctuated with time, and the elongation of the filter media was observed. Biofouling caused short-circuiting and decreased nitrate removal efficiency. A SLAD column will require backwashing after 6 months of operation when the influent is synthetic ground water but will foul and require backwashing within 1–2 months when the influent is real ground water.     

Orthophosphate Adsorption Equilibrium and Breakthrough on Filtration Media for Storm-Water Runoff Treatment

Total phosphorus (TP) in storm-water runoff is a common regulatory target for maintaining the quality of receiving surface water. Previous storm-water treatment studies show that it is difficult to consistently achieve TP removal higher than 40%, whereas regulatory goals of 50–65% removal are becoming common. To meet these goals, storm-water filtration technologies utilizing an expanding array of filtration media are being deployed, especially in areas with protected water bodies such as Puget Sound and Chesapeake Bay. One challenge is that if the media has no adsorption capacity, particulate phosphorus can redissolve into solution and form liberal orthophosphate (Ortho-P), resulting in lower overall TP removal. Therefore, effective Ortho-P adsorption capacity in filtration media is crucial to meet more stringent TP removal goals. Additional media characteristics that should be considered include gradation, permeability, surface area, morphology, cost, and toxicity. In response to these requirements, an engineered media (EM) was developed and evaluated by Ortho-P adsorption isotherms and breakthrough in typical storm-water runoff conditions. Three other media, perlite, zeolite, and granular activated carbon (GAC), widely used in storm-water treatment, were also investigated under the same experimental conditions. With adsorption isotherms, EM showed the highest adsorption capacity of 7.82??mg/g, nearly seven times that of GAC (1.16??mg/g). In adsorption breakthrough testing, overall removal efficiency decreases as the number of treated empty bed volumes (EBVs) increases. To reach 50% overall removal, EM provided 838 EBVs, whereas GAC could only treat 12 EBVs. In addition, for the lifetime of media, EM outlasted GAC with 2,297 EBVs, compared to 1,000 EBVs, respectively. Results indicate that EM is an adsorptive filtration media for treating storm-water phosphorus.     

Temperature Effects on the Infiltration Rate through an Infiltration Basin BMP

Infiltration Best Management Practices (BMPs) are becoming more readily acceptable as a means of reducing postdevelopment runoff volumes and peak flow rates to pre-construction levels, while simultaneously increasing recharge. However, the design, construction, and operation of infiltration basins to this point have not been standardized due to a lack of understanding of the infiltration processes that occur in these structures. Sizing infiltration BMPs to hold and store a predetermined volume of runoff, typically called the Water Quality Volume, has become a widely accepted practice. This method of sizing BMPs does not account for the infiltration that is occurring in the BMP during the storm event; which could result in significantly oversized BMPs. The objective of this study was to develop a methodology to simulate varying infiltration rates observed from a large scale rock infiltration basin BMP. The results should aid in improved design of such structures. This methodology is required to predict the performance of these sites using single event and continuous flow models. The study site is a Pervious Concrete Infiltration Basin BMP built in 2002 in a common area at Villanova University. The system consists of three infiltration beds filled with coarse aggregate, lined with geotextile filter fabric, overlain with pervious concrete and underlain by undisturbed silty sand. The BMP is extensively instrumented to facilitate water quantity and quality research. The infiltration performance of the site is the focus of the study. Recorded data indicates a wide variation of linear infiltration rates for smaller storm events. A model was developed using the Green–Ampt formula to characterize the infiltration occurring in the basin for small storm events characterized by an accumulated depth of water in the infiltration bed of less than 10?cm. The effectiveness and accuracy of the model were measured by comparing the model outputs with observed bed water elevation data recorded from instrumentation on site. Results show that for bed depths of <10?cm, hydraulic conductivity is the most sensitive parameter, and that the storm event measured infiltration rate is substantially less then the measured saturated hydraulic conductivity of the soil. The governing factor affecting hydraulic conductivity, and subsequently, infiltration rate is temperature; with higher rates occurring during warmer periods, affecting the infiltration rate by as much as 56%.     

Prediction of Nutrient Concentrations in Urban Storm Water

Excessive quantities of nutrients in urban storm-water runoff can lead to problems such as eutrophication in receiving water bodies. Accurate process based models are difficult to construct due to the vast array of complex phenomena affecting nutrient concentrations. Furthermore, it is often impossible to successfully apply process based models to catchments with limited or no sampling. This has created the need for simple models capable of predicting nutrient concentrations at unmonitored catchments. In this study, simple statistical models were constructed to predict six different types of nutrients present in urban storm-water runoff: ammonia (NH3), nitrogen oxides (NOx), total Kjeldahl nitrogen, total nitrogen, dissolved phosphorus, and total phosphorus. Models were constructed using data from the United States, collected as a part of the Nationwide Urban Stormwater Program more than two decades ago. Comparison between the models revealed that regression models were generally more applicable than the simple estimates of mean concentration from homogeneous subsets, separated based upon land use or the metropolitan area. Regression models were generally more accurate and provided valuable insight into the most important processes influencing nutrient concentrations in urban storm-water runoff.     

Establishing Storm-Water BMP Evaluation Metrics Based upon Ambient Water Quality Associated with Benthic Macroinvertebrate Populations

Storm-water experts agree that the currently used best management practice (BMP) percent removal methodology metric has many flaws, and some have suggested using a BMP effluent concentration metric. This case study examines establishing an effluent target concentration for BMPs that relates to the health of macroinvertebrates in the receiving water. In North Carolina, 193 ambient water quality monitoring stations were paired with benthic macroinvertebrate health ratings collected in very close proximity. Water quality for the sites ranged from excellent to poor and was divided into three distinct ecoregions: Mountain, Piedmont, and Coastal. Statistically significant relationships were found in one or more ecoregions for dissolved oxygen, fecal coliform, NH3, NO2?3?N, total Kjeldahl nitrogen, total nitrogen (TN), and total phosphorus (TP). BMPs can then be selected and designed to meet these target effluent concentrations. Based upon this research, a development, and therefore set of BMPs, in Piedmont North Carolina could be required to release TN and TP effluent concentrations of 0.99 mg/L and 0.11 mg/L, respectively. These concentrations are both associated with “good” benthos health. The new method was most effective in the Piedmont ecoregion, however with more data collection, the Mountain and Coastal ecoregions may also benefit.     

Volumetric Filtration of Rainfall Runoff. II: Event-Based and Interevent Nutrient Fate

This study examines in situ phosphorus treatment using a combined unit operation and process, a volumetric clarifying filter (VCF). Urban rainfall-runoff transports phosphorus in dissolved and particulate phases with the latter phase distributed across the particulate matter (PM) gradation. From a clean initial condition, the VCF was monitored across 19 events without maintenance, to examine partitioning and phosphorus distribution on PM. For the monitoring period, site influent total phosphorus (TP) is 0.342 mg/L of which 0.081 mg/L is dissolved; and subsequently reduced to 0.095 and 0.031 mg/L, respectively, by the VCF. PM-bound phosphorus is categorized as suspended, settleable and sediment fractions based on PM size and separation behavior. Site influent PM-based concentrations (mg/g) are 0.22 for sediment, 0.42 for settleable and 3.27 for the suspended fraction with each fraction further enriched in the VCF, based on effluent monitoring. A categorical analysis and odds ratio testing of PM-based phosphorus specific capacities (mg/g) indicate that a significant fraction of phosphorus can bind to suspended PM preferentially over settleable and sediment PM as a PM-based concentration. At the end of the event-based monitoring the inter-event change in phosphorus and nitrogen, chemistry is examined as a function of runoff storage time. Runoff retention generates nitrate reduction and ammonia (NH3+NH4+) production; predominately as ammonium. Phosphorus partitioning is stable during runoff storage with a dissolved fraction between one fourth to one-third of TP. Predominant species are H2PO4? for a pH<7 and HPO42? for a pH>7.     

Field Evaluation of Four Level Spreader–Vegetative Filter Strips to Improve Urban Storm-Water Quality

An assessment of the performance of four level spreader–vegetative filter strip (LS-VFS) systems designed to treat urban storm-water runoff was undertaken at two sites in the Piedmont of North Carolina. At each site, a 7.6-m grassed filter strip and a 15.2-m half-grassed, half-forested filter strip were examined. Monitored parameters included rainfall, inflow to, and outflow from each LS-VFS system. A total of 21 and 22 flow-proportional water quality samples were collected and analyzed for the Apex and Louisburg sites, respectively. All studied LS-VFS systems significantly reduced mean total suspended solids (TSS) concentrations (p<0.05), with the 7.6 and 15.2-m buffers reducing TSS by at least 51 and 67%, respectively. Both 15.2-m VFSs significantly reduced the concentrations of total Kjeldahl nitrogen (TKN), total nitrogen (TN), organic nitrogen (Org-N), and NH4-N (p<0.05), whereas results were mixed for the 7.6-m VFSs. Significant pollutant mass reduction was observed (p<0.05) for all nine pollutant forms analyzed in Louisburg, which was caused by infiltration in the VFSs. The effects of VFS length and/or vegetation type are very important for pollutant removal, as effluent pollutant concentrations were lower (with one exception) for the 15.2-m VFSs. The median effluent concentrations for TN and total phosphorus (TP) for the four LS-VFSs were nearly always better than fair water quality benchmarks for the Piedmont of North Carolina, but only met good water quality metrics in one-half of the studied storm events.