Determination of creep behaviour of Ti60 alloy by small punch creep test

The small punch (SP) creep test has distinct advantages in the creep property assessment of materials at elevated temperatures. However, there are few creep properties of Ti alloys obtained by the SP creep test in the current literature. In this paper, the SP creep behaviour of Ti60 alloy has been evaluated under various loads in the range 550–800 N over a temperature range 873–973 K. The SP creep curves obviously indicated the primary, secondary and tertiary stages of creep. The test results have been compared with those of conventional creep tests. The European Code of Practice (CoP) for Small Punch Testing, Dorn equation and Monkman–Grant relationship have also been used to analyse the results of the SP creep tests. The ratio of load of the SP creep tests to equivalent stress of conventional creep tests, the load exponent value of steady deflection rate and activation energy for creep deformation were estimated from the SP creep tests. In conclusion, it was found that dislocation creep may be the main mechanism that dominates the SP creep deformation of Ti60 alloy in the range of load and temperature.     

High temperature fatigue behaviour of intermetallics

There would be considerable benefits in developing new structural materials where high use temperatures and strength coupled with low density are minimum capabilities. Nickel and titanium aluminides exhibit considerable potential for near-term application in various branches of modern industry due to the number of property advantages they possess including low density, high melting temperature, high thermal conductivity, and excellent environmental resistance, and their amenability for significant improvment in creep and fatigue resistance through alloying. Reliability of intermetallics when used as engineering materials has not yet been fully established. Ductility and fracture toughness at room and intermediate temperatures continue to be lower than the desired values for production implementation. In this paper, progress made towards improving strain-controlled fatigue resistance of nickel and titanium aluminides is outlined. The effects of manufacturing processes and micro alloying on low cycle fatigue behaviour of NiAl are addressed. The effects of microstructure, temperature of testing, section thickness, brittle to ductile transition temperature, mean stress and environment on fatigue behaviour of same γ-TiAl alloys are discussed.     

Creep behaviour of cast TiAl based intermetallics

Abstract

Constant load tensile creep tests were carried out on the cast TiAl based intermetallics Ti–47 Al–2Mn, Ti–47 Al–2Zr, and Ti–48Al (at.-%), prepared by plasma arc melting. Two microstructural conditions dependent on heat treatment were evaluated as follows: a fully lamellar (FL) scheme consisting of a fully transformed coarse lamellar structure with α₂ laths plus γ laths within the grain interiors; and a duplex scheme consisting of fine equiaxed grains of γ with α₂/γ lamellae. The steady state creep behaviour of both microstructural conditions, for each composition, was studied under stresses of 70–300 MN m^?2 in the temperature range 700–900°C. The microstructure was found to have a pronounced influence on the creep resistance. The FL microstructure exhibited superior creep resistance to the duplex microstructure. At temperatures and stress levels at which direct comparisons can be made, the steady state creep rates of the FL structures are an order of magnitude lower than those of the duplex structure. The apparent creep activation energies and stress exponents were measured for both microstructural conditions for each composition. The temperature and stress dependence of the steady state creep rate of both microstructures can be described by the power law creep equation, suggesting dislocation motion as the operative deformation mechanism.

MST/1962     

Toughening and creep in multiphase intermetallics through microstructural control

The lack of engineering ductility in intermetallics has limited their structural applications, in spite of their attractive specific properties at high temperatures. Over the last decade, research in intermetallics has been stimulated by the discovery of remarkable ductilisation mechanisms in these materials. It has however often been the case that the process of ductilisation or toughening has also led to a decrease in high temperature properties, especially creep. In this paper we describe approaches to the ductilisation of two different classes of intermetallic alloys through alloying to introduce beneficial, second phase effects. The Ti₂AlNb based intermetallics in the Ti-Al-Nb system can be ductilised by stabilising thebcc phase of titanium into the structure. The principles of microstructural and compositional optimization developed to achieve adequate plasticity, while retaining creep properties of these alloys, are described. An entirely different approach has been successful in imparting plasticity to intermetallics based on Fe₃Al. The addition of carbon to form the Fe₃AlC_0.5 phase imparts ductility, while enhancing both tensile and creep strength.     

Part 8: Steady-state creep and creep recovery for service and accident conditions

RILEM Technical CommitteesRILEM TC 129-MHT: Test Methods for Mechanical Properties of Concrete at High Temperatures Recommendations

Part 8: Steady-state creep and creep recovery for service and accident conditions     

Steady-state creep of single-phase crystalline matter at high temperature

Over the past 15 years important advances have been made in the experimental study of the microstructural changes occurring during the non-linear steady-state creep of single phase crystalline matter at elevated temperatures. Curiously, although the results of these painstaking studies have gone a long way toward elucidating the mechanism of this phenomenon, they have been largely ignored in favour of some simple dislocation mechanisms that are not only inconsistent with these observations, but are also unable to describe correctly the known phenomenology. This review concentrates primarily on the recent experiments on microstructural alterations occurring during creep; however, it also surveys the many mechanistic models that attempt to describe this phenomenon, and finds them all deficient.On leave from The Institute for Solid State Physics, The University of Tokyo, during 1974–1975.     

Transitions in creep behaviour

Attempts to identify the mechanisms operating during creep are often made by examining plots which yield apparent activation energies, or the stress or grain size-dependences of creep-rate. The forms of such plots are here examined and the ambiguities which arise near transitions from one regime to another are noted. The ranges of temperature, stress and grain size commonly used are inadequate and serious errors in interpreting the results of creep tests will continue to be made until a better understanding of the interaction of the basic processes is developed, so as to enable the positions of transitions to be predicted.At Dept. of Metallurgy, University of British Columbia, Vancouver 8, BC, Canada until 31 March 1970.     

Mechanical properties of recrystallized L12-type Ni3(Si,Ti) intermetallics

The mechanical properties of the Ni₃(Si, Ti) alloys undoped and doped with 50 p.p.m. boron, both of which were polycrystalline specimens prepared by recrystallization, were investigated by tensile testing. The yield stress was found to increase with increasing test temperature to a maximum at 800 K, followed by a decrease. The tensile elongation was highest at room temperature and tended to decrease with increasing temperature for both alloys, but was consistently higher in the boron-doped Ni₃(Si, Ti) alloys than in the undoped ones over all the test temperatures. The change in the ultimate tensile stress (UTS) with temperature was similar to that of tensile elongation. The transgranular fracture became dominant as the elongation increased, regardless of the alloys and the testing temperature. Thus, this work again verified that the alloying method proposed by the present authors is useful for improving the grain-boundary cohesion of L1₂-type ordered alloys.     

Non-linear creep behaviour of PET

The non-linear creep behaviour has been studied on PET films at room temperature. A particular value of the stress, _c, was used to characterize the change between the linear to the non-linear domain. The variations of the elastic modulus, the relaxed modulus and _c revealed great sensitivity to the morphology of the crystallization. A molecular model of non elastic deformation, assuming (i) hierarchical correlated molecular motion, and (ii) nucleation and expansion of sheared-microdomains, was used to analyse the role of stress on anelasticity. To take into account the two-phase structure of semicrystalline films, a phenomenological series/parallel model was applied to express the mechanical coupling between amorphous and crystalline phases. Quantitative agreement was found between theoretical predictions and experimental data for low and high stresses. However, there was a discrepancy in the rate of recovery because the model predicts a strain recovery slower than the experimental behaviour. Consequently, it is proposed to develop further the molecular model mentioned above by specifying the energy profile of a sheared-microdomain and its stress dependence. Then, the difference between creep and recovery strain rate could be explained.Nomenclature A Anelastic equilibrium compliance - A Parameter proportional to the relaxation strength - b Shear vector - Correlation parameter - _i Particular value in the distribution - _e Average value in the material ( = 0.27) - Correlation parameter characterizing the ability of chain orientation - d _a Amorphous density - d _c Crystalline density - Parameter of the mechanical mixing law - E Tensile modulus - E _c Crystalline Young's modulus - g _i Statistical weight in the distribution - G ₀ Shear modulus at 0 K - J _max Creep compliance at the end of the creep time - J _max(0) Value ofJ _max for low stresses - J _u Unrelaxed compliance - J _i( _i;A _i) Calculated compliance for a couple ( _i;A _i) - J _exp Experimental creep compliance - J _a Compliance of the amorphous part - J _c Compliance of the crystalline part - J _sc Compliance of the semi-crystalline material - k Boltzmann's constant - Parameter of the mechanical coupling law - R Radius of a shear micro domain - ₀ Stress necessary to cross the energy barrier only by mechanical activation - T _c Crystallization temperature - t _c Creep time - _mol Time for a translational motion of a structural unit over a distance comparable to its size - Particular value of _mol in the time distribution - Characteristic time for the secondary relaxation - ₀ Time proportional to the Debye time - t ₀ Scaling time parameter determined by the experimental value of _mol - U Activation energy for an elementary molecular motion - X _c Crystallinity ratio - V _a Volume fraction of the amorphous part - V _c Volume fraction of the crystalline part     

Tensile creep behaviour of a fibre-reinforced SiC-Si3N4 composite

The tensile creep behaviour of a SiC-fibre-Si₃N₄-matrix composite was investigated in air at 1350 C. The unidirectional composite, containing 30 vol % SCS-6 SiC fibres, was prepared by hot pressing at 1700 C. Creep testing was conducted at stress levels of 70, 110, 150 and 190 MPa. An apparent steady-state creep rate was observed at stress levels between 70 and 150 MPa; at 190 MPa, only tertiary creep was observed. For an applied stress of 70 MPa, the steady-state creep rate was approximately 2.5×10^–10 s^–1 with failure times in excess of 790 h. At 150 MPa, the steady-state creep rate increased to an average of 5.6×10^–8 s^–1 with failure times under 40 h. The creep rate of the composite is compared with published data for the steady-state creep rate of monolithic Si₃N₄.     

Laser-induced formation of intermetallics in multilayered Al/Ti nano-structures

In this study, multilayered structures consisting of eight (Al/Ti) bilayers deposited by d.c. ion sputtering onto Si (100) wafers, to a total thickness of ~300 nm were treated in air with a picosecond-pulsed Nd:YAG laser in a defocused regime. Irradiation was done with 200 successive pulses, at 1,064-nm wavelength, energy per pulse 15 mJ, the incidence angle of ~45°, covering an area of 2-mm in diameter. The samples were analyzed by scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. It was found that laser irradiation-induced melting and a progressed Al–Ti nanoalloying within the top four bilayers (up to a depth of ~150 nm), while the underlying part of the multilayered structure remained intact. Another interesting result is that of a regularly rippled surface topography (~1.4-μm period and 100-nm amplitude) developed throughout the zone of the melted and reacted material.     

The creep behaviour of isotropic polyethylene

Dead loading creep and constant strain rate yield experiments have been used to study the tensile creep behaviour of three grades of isotropic polyethylene. This has provided further evidence for the existence of two yield points in isotropic polyethylene. Two different models have been used to attempt to describe this behaviour. Although the results can be described by to both the two process model of Wilding and Ward and the co-operative jump model of Fotheringham and Cherry, it appears that the two process model provides a more convincing quantitative fit to the data. This revised version was published online in September 2006 with corrections to the Cover Date.     

Pressure induced structural behaviour in f-electron based AB, AB2 and AB3 intermetallics

The rare-earth and actinide based compounds are endowed with several exotic physical and chemical properties due to the presence of f-electrons. Under pressure, the nature of f-electrons can be changed from localized to itinerant, leading to significant changes in their structural, physical and chemical properties. The present review on these f-electron based binary intermetallics compounds is an outcome of a detailed literature survey as well as our own research` during the last one decade. It attempts to bring out the structural sequences observed among the various homologues and their correlations with their electronic structure. It is seen that the majority of the AB type compounds show the NaCl to CsCl type structural transformation; whereas the AB₃ type compounds stabilizing in cubic structure at STP, remain stable over a wide pressure range. However, the AB₂ type compounds exhibit a variety of structural transitions, which broadly fall into the following sequence: MgCu₂ →.......... → CeCu₂ → AlB₂ → ZrSi₂ → ThSi₂ → SmSb₂ →.......... Further, the structural transitions, the transition pressures and bulk modulii values in any homologous series are seen to follow a systematic trend with respect to the atomic numbers of their constituent elements.     

On the tensile creep behaviour of a directionally-solidified Ni3Al-based alloy

High temperature tensile creep behaviour of a directionally-solidified Ni₃Al-based alloy is presented. The study involved selection of nine alloy systems based on Ni₃Al. The alloys contained varying amounts of Cr and Ta, fixed amounts of 1·5 at.% Hf and 0·5 at.% Zr and doped with 0·2 at.% each of C and B. The alloys were vacuum arc-melted into buttons and homogenized at 1050°C for 68 h. The test pieces of the alloys were hot compression tested at 600, 700, 800 and 900°C. The yield strength data of some of the alloys were superior to conventionally cast Mar-M 200, a cast nickel-base superalloy widely used in gas turbine structural applications. The best alloy system was chosen based on consistent performance in the hot compression studies. The alloy so chosen was directionally solidified and vacuum-homogenization-treated for 20 h at various selected temperatures. Optimum creep properties were observed at 1120°C, 20 h treatment. The minimum creep rate data of the DS alloy showed relatively higher values even at lower temperatures and stress levels as compared to Mar-M 200. Hence, the alloy is less promising in replacing nickel-based superalloys used as structural materials in gas turbine applications.     

Kinetics of Oxidation Resistance of the Ti_3Al-base Intermetallic Alloys

1.IntroductionThe research of the TD1 and TD2 al-loys based on intermetallic compound Ti_3Al,which possesses high temperature capabilityfrom 650 to 700℃ was conducted.However,the limitation used at high temperature isimposed by oxidation and degradation ofcreep strength,and relatively little know-     

Effect of grain size on creep of Ti-53.4mol%Al intermetallics at 1100 K

Constant stress creep under compression stress, 100 to 316 MPa, at 1100 K was investigated on single-phase TiAl intermetallics. The material was ingot-cast, isothermally forged, and then annealed to produce stable equi-axed grain structures, whose average grain diameters were 25, 42 and 70m. Creep curves were very similar among the three specimens with different grain diameters and the creep rates at a given strain, as well as the minimum creep rates, depended little on grain size. Two regimes were observed on the stress dependence of the minimum creep rate. The stress exponent under high stresses was about 4.5, independent of grain size. Under stresses lower than about 150 MPa it became about 8.     

The creep behaviour of ultra-high modulus polypropylene

The creep and recovery behaviour of highly drawn polypropylene monofilaments has been studied over the temperature range 20 to 50° C. A range of samples was examined to identify the influence of draw ratio and molecular weight. It is concluded that the permanent flow creep arises from the presence of two thermally activated processes, one of which relates to the -relaxation process and is associated with the crystalline regions of the polymer, and the second with the molecular network.     

The creep behaviour of Synroc and alumina

The creep of Synroc C and alumina in four-point bending in argon was investigated in terms of the relaxed symmetric stress and the reference asymmetric stress; the alumina being used as a reference material. The creep tests were undertaken in the temperature range from 850°C to 1300°C. The rupture behaviour of Synroc at 950°C indicated a high stress exponent, and that the creep ductility was unusual in that the strain increased with increasing test time. A scanning electron miscroscopy examination of Synroc after creep revealed the development of defect-free oxidised surface layers. For Synroc, neither prior exposure to pre-heating in air, nor prior indentation affected the creep rate behaviour. This was attributed to the formation of the oxidised surface layers and the associated healing effects of the damage produced by the indentations.     

Environmental effect on mechanical properties of recrystallized L12-type Ni3(Si,Ti) intermetallics

The environmental effect on the mechanical properties of boron-doped and undoped Ni₃(Si, Ti) polycrystals was investigated by tensile testing in air from room temperature to 1073 K, and the results were compared with those obtained previously by tensile testing in vacuum. The environmental effect for the Ni₃(Si, Ti) alloys was significant at ambient temperatures whereas that for the boron-doped Ni₃(Si, Ti) alloys was considerable at elevated temperatures. When these samples at associated temperatures were tensile tested in air and also at low strain rate, intergranular fracture was dominant. It was suggested that the environmental embrittlements at low and high temperatures were due to hydrogen and oxygen absorbed from the air, respectively, and were caused by the weakening of the grain-boundary cohesion. It was proposed that boron competing with hydrogen, for site occupation or for its effectiveness at grain boundaries, has the effect of suppressing hydrogen embrittlement, whereas it was suggested that the low-melting phases, consisting of boron and oxygen (and/or constituent atoms), may be responsible for the ductility loss in the boron-doped Ni₃(Si, Ti) alloys.