DRYING PAPER IN SUPERHEATED STEAM

ABSTRACT

The industrial potential for drying paper in superheated steam has been investigated in a series of studies designed to treat paper properties - drying process relations as well as process engineering aspects. Properties measurements show that for paper made from mechanical pulps, drying in superheated steam produces a better bonded sheet which is thereby stronger and has a lower scattering coefficient. Surface properties of such steam dried paper are improved, including reduced tinting. Desorption equilibrium shows that completely dry paper can be obtained at very low superheats. Impingement drying rates can be about twice as high for drying in superheated steam as in air. A hybrid cycle was developed in which drying is partially by superheated steam impingement drying and partially by conventional cylinder drying. Preliminary design and techno-economic evaluation indicates that three factors, paper properties, dryer size and energy efficiency, in various combinations specific to each case, may provide industrial potential for this new technology for drying paper.     

Use of Superheated Steam Drying to Increase Strength and Bulk of Papers Produced from Diverse Commercial Furnishes

Studies from this laboratory have documented significant changes in properties when paper is dried in superheated steam rather than, as in all current processes, in air. Extending these investigations to additional important pulp types, to recycled pulps and to filled papers, using commercial furnishes from mills, has identified further grades of paper for which drying in superheated steam enhances key properties. For bleached chemithermomechanical pulps and blends with kraft pulp as used for tissue and toweling, strong paper resulted, with 10% higher bulk. Linerboard from 100% recycled old corrugated containers (OCC) is obtained with various strength properties increased by up to 21% with no densification, actually a 4% increase in bulk. Linerboard from high-yield (55-67%) virgin kraft pulps show 23 to 37% increase in strength and toughness. Filled papers containing 0-10% clay can be produced with the same brightness but about 23% higher tensile index when dried in superheated steam.     

DRYING WITH SUPERHEATED STEAM

The principle of drying with superheated steam is known for a long time already, and different designs have been worked out and partly realised. The principle of the steam drying described in this paper starts with superheated steam that is blown on to the products to be dried. The superheated steam transfers its sensible heat to the product and the water to be evaporated. The superheated steam acts both as heat source and as drying medium to take away the evaporated water. The majority of the superheated steam has to be recirculated and reheated. The excess steam from this process, corresponding to the evaporated water, can be used elsewhere in the process or plant, thus making an efficient energy recovery possible. Possible emissions from the drying process can be effectively removed by condensation. Drying by means of superheated steam impingement is one of the possible designs that are in progress now for the paper industry. Work is going on with respect to this type of drying for other materials, especially foodstuffs. At present experimental research at the laboratory steam dryer of TNO-MEP is carried out for vegetables, fries, herbs, cacao nuts, wheat, flour, etc. Besides the energy savings and environmental benefits, the oxygen free steam atmosphere and the higher product temperatures in the dryer appear to have positive effects on the product qualities. For foodstuffs combinations of steam drying with blanching, pasteurisation, sterilisation, etc. are possible and make the steam drying very attractive for food producers. Modelling of the processes in foodstuffs during steam drying is established, both on macro and micro scale. In this paper examples and results of research on steam drying for specific products will be presented.     

Enhancement of Properties of Diverse Grades of Paper by Superheated Steam Drying

Abstract:

Studies from this laboratory have documented significant changes in properties when paper is dried in superheated steam rather than, as in all current processes, in air. Extending these investigations to additional important pulp types, recycled pulps, and filled papers, and using commercial furnishes from mills, has identified further grades of paper for which drying in superheated steam enhances key properties. For bleached chemithermomechanical pulps and blends with kraft pulp, as used for tissue and toweling, strong paper resulted with 10% higher bulk. Linerboard from 100% recycled old corrugated containers (OCC) is obtained with various strength properties increased by up to 21% with no densification, actually a 4% increase in bulk. Linerboard from high-yield (55–67%) virgin kraft pulps shows a 23 to 37% increase in strength and toughness. Filled papers containing 0–10% clay can be produced with the same brightness but 23% higher tensile index when dried in superheated steam.     

Use of Superheated Steam Drying to Increase Strength and Bulk of Papers Produced from Diverse Commercial Furnishes

ABSTRACT

Studies from this laboratory have documented significant changes in properties when paper is dried in superheated steam rather than, as in all current processes, in air. Extending these investigations to additional important pulp types, to recycled pulps and to filled papers, using commercial furnishes from mills, has identified further grades of paper for which drying in superheated steam enhances key properties. For bleached chemithermomechanical pulps and blends with kraft pulp as used for tissue and toweling, strong paper resulted, with 10% higher bulk. Linerboard from 100% recycled old corrugated containers (OCC) is obtained with various strength properties increased by up to 21% with no densification, actually a 4% increase in bulk. Linerboard from high-yield (55–67%) virgin kraft pulps show 23 to 37% increase in strength and toughness. Filled papers containing 0–10% clay can be produced with the same brightness but about 23% higher tensile index when dried in superheated steam.     

Experimental Investigation and Practical Application of Superheated Steam Drying Technology for Softwood Timber

Due to several advantages, superheated steam drying of timber has attracted great attention. However, the technology is still restricted to some special cases, partly due to the lack of fully understanding of the drying process. In this work, experiments were conducted to dry radiata pine timber using superheated steam under vacuum and at pressure. In the first part of the experiments, softwood timber was dried in a superheated steam kiln with drying rates, steam temperature across the stack and wood temperature being measured during drying. In the second part of the work, experimental studies were performed to investigate potential applications of the superheated steam drying at ultra-high temperatures (UHT) and pressurized steam conditioning of kiln dried timber. Compared to normal drying temperatures, the UHT drying can reduce the drying time by a factor of 5 to 10 and it is also more energy efficient. The pressurized steam conditioning has been proven to be a promising technology to relieve drying stresses and to reduce twist of the dried timer.     

Experimental Investigation and Practical Application of Superheated Steam Drying Technology for Softwood Timber

Abstract

Due to several advantages, superheated steam drying of timber has attracted great attention. However, the technology is still restricted to some special cases, partly due to the lack of fully understanding of the drying process. In this work, experiments were conducted to dry radiata pine timber using superheated steam under vacuum and at pressure. In the first part of the experiments, softwood timber was dried in a superheated steam kiln with drying rates, steam temperature across the stack and wood temperature being measured during drying. In the second part of the work, experimental studies were performed to investigate potential applications of the superheated steam drying at ultra-high temperatures (UHT) and pressurized steam conditioning of kiln dried timber. Compared to normal drying temperatures, the UHT drying can reduce the drying time by a factor of 5 to 10 and it is also more energy efficient. The pressurized steam conditioning has been proven to be a promising technology to relieve drying stresses and to reduce twist of the dried timer.

     

不同喷雾干燥方式对粉末橡胶结构与性能的影响

采用热空气喷雾干燥和过热蒸汽喷雾干燥制备粉末橡胶,并研究其干燥胶粉的形态结构及性能。FT-IR表明,热空气喷雾干燥比过热蒸汽喷雾干燥更容易引入含氧基团,造成粉末橡胶氧化分解。SEM表明过热蒸汽喷雾干燥使物料干燥程度更高,有利于水分蒸发。GPC表明热空气喷雾干燥容易破坏橡胶分子链,降低橡胶分子量,过热蒸汽喷雾干燥更能保持橡胶原有分子链。     

褐煤干燥技术发展及应用现状

论述了国内外褐煤干燥提质技术的发展现状。针对传统热力干燥在褐煤电厂应用中存在的高能耗、高投资和低安全性等问题,开展了褐煤过热蒸汽干燥机理的试验研究和中试试验。结果表明：过热蒸汽的干燥效果优于常规热空气;中试试验系统能稳定、连续地对褐煤进行干燥,且干燥产品符合褐煤干燥实际工业应用的要求。最后提出了过热蒸汽预干燥低质煤提质洁净煤技术（SCU技术）,对其在节能、安全等方面的技术先进性作了具体的对比分析,结果表明：SCU技术节能节水、安全性高,符合中国可持续发展战略和节能减排的要求。     

Inversion Temperature and Pinch Analysis,Ways to Thermally Optimize Drying Processes

This work studies the compatibility and suitability of a combined inversion temperature and pinch analysis with the process selection for air and superheated steam spray drying of milk solids. The inversion temperature is a good starting point for an energy analysis because it is a simplified rate-based approach to comparing the steam and air drying systems. pinch analysis enables process integration, at least on a heat recovery and heat exchanger network level.

The resulting inversion temperature for the studied system was estimated as 182°C for the dryer inlet temperature. However, mass and energy balances showed that a minimum inlet temperature for spray drying of 184°C was required for the superheated steam dryer in order to ensure that the outlet solids temperature above the dew point temperature.

The inversion temperature is still very relevant in the early stages of a design process because it allows a quick assessment of which drying medium should result in a smaller dryer. It was evident that the steam system is better from an energy perspective because of the recoverable latent heat of the water vapor carried out of the dryer with the recycled steam. The steam system has between 82 and 92% of thermal energy recovery potential as condensable steam, compared with 13–30% energy recovery of the air system. However, other important design and operational factors are not discussed here in detail.

Combining the inversion temperature and pinch analysis suggests that superheated steam drying both gives better energy recovery and is likely to give smaller dryers for all operational conditions.     

COMBINED SUPERHEATED STEAM AND MICROWAVE DRYING OF SINTERED GLASS BEADS: DRYING RATE CURVES

A new drying method of combined superheated steam and microwave drying is being proposed. The drying rates of sintered glass beads in combined superheated steam and microwave drying are experimentally and theoretically investigated. Drying experiments have been carried out in a waveguide where a standing wave is formed to uniformly heat a small sample. Concerning drying rate curves in combined superheated steam and microwave drying, a distinct constant rate period has been observed. For the falling rate period, high drying rates have been observed. For both periods, the drying rates in combined superheated steam and microwave drying are higher than those in superheated steam alone. Also, in comparison with the results of combined nitrogen and microwave drying, the normalized drying rates in combined superheated steam and microwave drying are higher than those at less than the critical moisture content in combined nitrogen and microwave drying. Moreover, theoretical drying rates for the falling rate period (predicted by a modified receding evaporation front model) in combined superheated steam and microwave drying, are in good agreement with the observed drying rates. The combined superheated steam and microwave drying method can attain higher drying rates under mild external conditions.     

SUPERHEATED STEAM IMPINGEMENT DRYING OF TORTILLA CHIPS

ABSTRACT

Low-fat snack products are the driving forces for the drying of tortilla chips before frying. Super-heated steam impingement drying of foods has the advantage of improved energy efficiency and product quality. The temperature profile, drying curves, and the physical properties (shrinkage, crispiness, starch gelatinization and microstructure) of tortilla chips dried at different superheated steam temperatures and heat transfer coefficients were measured. Results indicated that the steam temperature had a greater effect on the drying curve than the heat transfer coefficient within the range of study. The microstructure of the samples after steam drying showed that higher steam temperature resulted in more pores and coarser appearance. The modulus of deformation and the shrinkage of tortilla chips correlated with moisture content. A higher steam temperature caused less shrinkage and a higher modulus of deformation. The pasting properties showed that samples dried under a higher steam temperature and a higher heat transfer coefficient gelatinized less during drying and had a higher ability to absorb water. Comparison of the superheated steam drying and air drying revealed that at elevated temperatures the superheated steam provided higher drying rates. Furthermore, there was a less starch gelatinization associated with air drying compared to superheated steam drying.     

COMPARISON OF SUPERHEATED STEAM AND AIR OPERATED SPRAY DRYERS USING COMPUTATIONAL FLUID DYNAMICS.

In this paper a numerical simulation of a spray dryer using the computational fluid dynamics (CFD) code Fluent is described. This simulation is based on a discrete droplet model and solve the partial differential equations of momentum, heat and mass conservation for both gas and dispersed phase.

The model is used to simulate the behaviour of a pilot scale spray dryer operated with two drying media : superheated steam and air Considering that there is no risk of powder ignition in superheated steam, we choosed a rather high inlet temperature (973 K). For the simulation, drop size spectrum is represented by 6 discrete droplets diameters, fitting to an experimental droplets size distribution and all droplets are injected at the same velocity, equal to the calculated velocity of the liquid sheet at the nozzle orifice.

It is showed that the model can evaluate the most important features of a spray dryer : temperature distribution inside the chamber, velocity of gas, droplets trajectories as well as deposits on the walls. The model predicts a fast down flowing core jet surrounded by a large recirculation zone. Using superheated steam or air as a drying medium shows only slight differences in flow patterns. Except for the recirculation which is tighter in steam.

The general behaviour of droplets in air or steam are quite the same : smallest droplets are entrained by the central core and largest ones are taken into the recirculation zone. In superheated steam, the droplets penetrate to a greater extent in the recirculation zone. Also, they evaporate faster. The contours of gas temperature reflect these differences as these two aspects are strongly coupled. In both air and steam there is a “cool” zone which is narrower in steam than in air. Finally, the panicle deposit problem seems to be more pronounced in air than in steam.

Adding to the inherent interest in using superheated steam as a drying medium, the model predicts attractive behaviour for spray drying with superheated steam. In particular. under the conditions tested with the model, a higher volumetric drying rate is obtained in superheated steam.     

SUPERHEATED STEAM IMPINGEMENT DRYING OF TORTILLA CHIPS

Low-fat snack products are the driving forces for the drying of tortilla chips before frying. Super-heated steam impingement drying of foods has the advantage of improved energy efficiency and product quality. The temperature profile, drying curves, and the physical properties (shrinkage, crispiness, starch gelatinization and microstructure) of tortilla chips dried at different superheated steam temperatures and heat transfer coefficients were measured. Results indicated that the steam temperature had a greater effect on the drying curve than the heat transfer coefficient within the range of study. The microstructure of the samples after steam drying showed that higher steam temperature resulted in more pores and coarser appearance. The modulus of deformation and the shrinkage of tortilla chips correlated with moisture content. A higher steam temperature caused less shrinkage and a higher modulus of deformation. The pasting properties showed that samples dried under a higher steam temperature and a higher heat transfer coefficient gelatinized less during drying and had a higher ability to absorb water. Comparison of the superheated steam drying and air drying revealed that at elevated temperatures the superheated steam provided higher drying rates. Furthermore, there was a less starch gelatinization associated with air drying compared to superheated steam drying.     

THE INFLUENCE OF THE DRYING MEDIUM ON HIGH TEMPERATURE CONVECTIVE DRYING OF SINGLE WOOD CHIPS

High temperature convective drying of single wood chips with air and superheated steam respectively is studied theoretically. The two-dimensional model presented describes the coupled transport of water, vapour, air and heat. Transport mechanisms included are the convection of gas and liquid, intergas as well as bound water diffusion. In the initial part of the drying process, moisture is transported to the surface mainly due to capillary forces in the transversal direction where evaporation occurs, As the surface becomes dry, the drying front moves towards the centre of the particle and an overpressure is simultaneously built up which affects the drying process

The differences between drying in air and steam respectively can be assigned to the physical properties of the drying medium. The period of constant drying rate which does not exist (or is very short) in air drying becomes more significant with decreasing amounts of air in the drying medium and is clearly visible in Dure superheated steam drying. The maximal drying rate is larger in air drying, and shorter drying times are obtained since the heat flux to the wood chip particle increases with increasing amounts of air in the drying medium. The period of falling drying rate can be divided into two parts: in the first, the drying rate is dependent upon the humidity of the drying medium whereas in the second, there is no such correlation.     

过热蒸汽干燥技术的研究进展

过热蒸汽干燥技术具有安全、节能、环保等诸多优点,越来越受到广泛关注。对过热蒸汽干燥技术进行了简介,分析了其优缺点。总结了过热蒸汽干燥的理论研究进展,并对过热蒸汽干燥技术在食品、木材、纸张、污泥和和褐煤等物料的应用现状进行了综合评述。总而言之,过热蒸汽干燥技术是一种先进的干燥技术,具有广阔的应用前景。     

油页岩过热蒸汽的干燥动力学

以油页岩颗粒作为干燥物料,以过热蒸汽和热空气分别作为干燥介质,进行了油页岩干燥实验的研究。当颗粒粒径减小时,油页岩干燥速率越大;过热蒸汽和热空气温度增大时,干燥速率也越大。对比相同条件下过热蒸汽和热空气干燥油页岩的平均干燥速率,发现当干燥介质温度超过逆转点温度时,过热蒸汽条件下的平均干燥速率大于热空气下的数值。实验得出粒径分别为9,7,5 mm的油页岩颗粒逆转点温度值分别是154,179,177℃;逆转点温度值是个变量,随颗粒粒径大小变化而变化。颗粒粒径越大时逆转点温度值越小,粒径较小时逆转点变化不大。采用薄层干燥模型对油页岩的干燥数据进行动力学模拟,可得修正Page模型(Ⅱ)干基水分比w模拟值与实验值的最大绝对偏差是12%,综合比较发现修正Page模型(Ⅱ)能较好地描述油页岩在过热蒸汽条件下的干燥过程。     

COMPARISON OF SUPERHEATED STEAM AND AIR OPERATED SPRAY DRYERS USING COMPUTATIONAL FLUID DYNAMICS.

ABSTRACT

In this paper a numerical simulation of a spray dryer using the computational fluid dynamics (CFD) code Fluent is described. This simulation is based on a discrete droplet model and solve the partial differential equations of momentum, heat and mass conservation for both gas and dispersed phase.

The model is used to simulate the behaviour of a pilot scale spray dryer operated with two drying media : superheated steam and air Considering that there is no risk of powder ignition in superheated steam, we choosed a rather high inlet temperature (973 K). For the simulation, drop size spectrum is represented by 6 discrete droplets diameters, fitting to an experimental droplets size distribution and all droplets are injected at the same velocity, equal to the calculated velocity of the liquid sheet at the nozzle orifice.

It is showed that the model can evaluate the most important features of a spray dryer : temperature distribution inside the chamber, velocity of gas, droplets trajectories as well as deposits on the walls. The model predicts a fast down flowing core jet surrounded by a large recirculation zone. Using superheated steam or air as a drying medium shows only slight differences in flow patterns. Except for the recirculation which is tighter in steam.

The general behaviour of droplets in air or steam are quite the same : smallest droplets are entrained by the central core and largest ones are taken into the recirculation zone. In superheated steam, the droplets penetrate to a greater extent in the recirculation zone. Also, they evaporate faster. The contours of gas temperature reflect these differences as these two aspects are strongly coupled. In both air and steam there is a “cool” zone which is narrower in steam than in air. Finally, the panicle deposit problem seems to be more pronounced in air than in steam.

Adding to the inherent interest in using superheated steam as a drying medium, the model predicts attractive behaviour for spray drying with superheated steam. In particular. under the conditions tested with the model, a higher volumetric drying rate is obtained in superheated steam.     

A Comparative Study of Pork Drying Using Superheated Steam and Hot Air

Drying with superheated steam and hot air were comparatively studied for pork. Transport, physical, and chemical properties, i.e., effective diffusivity, color, microstructure, and rehydration ability, were investigated. The experimental results have shown that the decrease of pork moisture content in an early drying time was more rapid in superheated steam than in hot air and appeared to be lower in a latter time. The pork surface as examined by SEM was noticeably different for the samples dried by superheated steam and hot air. The fewer pores at the surface of superheated steam-dried pork caused a slower water penetration into the interior during rehydration, in addition to the lower drying rate. The color of the product from superheated steam was a relatively more intense brown than that obtained from hot air as presented by a lower L? value and a higher a? value.     

A Comparative Study of Pork Drying Using Superheated Steam and Hot Air

Drying with superheated steam and hot air were comparatively studied for pork. Transport, physical, and chemical properties, i.e., effective diffusivity, color, microstructure, and rehydration ability, were investigated. The experimental results have shown that the decrease of pork moisture content in an early drying time was more rapid in superheated steam than in hot air and appeared to be lower in a latter time. The pork surface as examined by SEM was noticeably different for the samples dried by superheated steam and hot air. The fewer pores at the surface of superheated steam-dried pork caused a slower water penetration into the interior during rehydration, in addition to the lower drying rate. The color of the product from superheated steam was a relatively more intense brown than that obtained from hot air as presented by a lower L* value and a higher a* value.