冀中坳陷饶阳凹陷留西地区沙三上亚段层序地层与隐蔽油藏

根据层序地层学基本原理,利用地震、测井、岩相等资料,对冀中坳陷饶阳凹陷留西地区古近系沙三上亚段进行了层序地层学研究,建立了全区的层序地层格架。研究表明,沙三上亚段为一个完整的三级层序,可分为低位、湖侵和高位3个体系域。在此基础上,分析了层序格架内各体系域的沉积相平面展布特征。沙三上亚段主要发育辫状河三角洲沉积相,其中前缘亚相分布面积最广。区内低位体系域砂体与湖侵体系域烃源岩形成了十分有利的生储盖组合,具有优越的隐蔽圈闭发育条件。结合区域构造特征,综合分析认为中南部沙三上亚段低位体系域辫状河三角洲前缘砂体是下一步隐蔽油藏勘探的有利区域。     

涠西南凹陷(西部)古近系层序地层及沉积特征研究

在不同勘探阶段,运用层序地层学理论进行层序地层的沉积特征研究是当前石油行业各生产单位常用的工作方法。在勘探初期钻井稀少的情况下,充分利用钻井和地震资料,采用井—震结合进行三级层序沉积特征研究的思路和方法,探讨了涠西南凹陷(西部)古近系层序地层。通过钻井资料分析,进行单井及多井层序地层及沉积旋回解释。井震结合,进行地震剖面的地震地层学解释,建立层序地层格架并进行地震相及沉积相分析。结合构造背景和古地貌研究,在层序地层格架内进行研究区沉积相及沉积体系平面特征及沉积演化过程的分析和预测。     

华北油田地层-岩性油藏勘探发现与启示

在华北油田二连盆地的巴音都兰凹陷,按照寻找地层岩性油藏的新勘探思路,通过层序地层研究建立等时地层格架,根据构造与沉积综合研究确定有利勘探区块,依靠老井复查构建扇三角洲前缘砂体上倾尖灭岩性油藏成藏模式,发现了以岩性油藏为主的宝力格油田。在冀中坳陷,深化长洋淀潜山带成藏条件的研究,建立了"新生古储古堵"的潜山油藏成藏模式,使钻探获得新突破。     

霸县凹陷南洼槽沉积相研究及岩性地层圈闭识别

通过对霸县凹陷南洼槽构造、沉积特征和成藏条件研究,首次建立了该区古近系层序地层等时格架,将沙一下亚段—沙四段划分为7套三级层序,明确了沉积体系及沉积相在等时地层格架内的空间展布及特征,指出文安斜坡内带、"凹中隆"背斜构造带和洼槽带为3个岩性地层圈闭发育的有利区带。综合应用地震相分析、地震属性分析及地震反演等技术进行岩性地层圈闭的有效识别。构建了斜坡带、背斜带和洼槽区岩性地层油藏模式,对有利勘探目标进行精细落实优选,钻探文安1、文安11井均获成功,研究表明该区是岩性地层油藏规模勘探的有利区,对冀中坳陷富油气凹陷岩性地层油藏勘探具有一定指导作用。     

欢喜岭油田南部坡洼过渡带沙一、二段隐蔽油气藏预测

应用层序地层学理论,利用岩心、测井、录井等资料,建立了欢喜岭油田南部坡洼过渡带沙一、二段的高分辨率层序地层格架,将其划分为2个长期旋回、8个中期旋回和20个短期旋回。在此基础之上对各中期旋回的砂体、沉积相展布规律进行了分析,并根据层序、沉积发育特征预测了隐蔽油气藏有利发育区带,认为锦128以南架岭6以东及双203、锦110和锦310井之间为隐蔽油气藏勘探的有利地区。同时结合研究区的断裂与砂体发育特征,得出本区断裂下降盘构造岩性油气藏和低水位时期的砂岩尖灭油气藏应为隐蔽油气藏勘探的重点对象。     

南苏丹Melut盆地北部凹陷古进系及白垩系岩性地层油气藏勘探潜力

Melut盆地北部凹陷为富油气凹陷,具有岩性地层油气藏形成的基本条件。针对深层白垩系和岩性地层油气藏勘探尚未取得突破的现状,通过开展层序地层学和沉积相研究,建立了统一的层序地层格架,明确了Melut盆地北部凹陷源上、源内各主要层序岩性地层油气藏的勘探潜力与方向。研究表明:源上主要发育Yabus上段—Adar—Lau高位域,有利相带为河流、三角洲、扇三角洲,主要形成构造-岩性圈闭;源内主要发育Galhak—Algayger湖侵域,有利相带为三角洲前缘、滑塌浊积扇和洪水浊积扇,主要形成岩性和构造-岩性圈闭。综合分析认为,源内层序是寻找构造-岩性油气藏的主要勘探目标。在有利构造背景下发育良好的储盖组合是Melut盆地白垩系成藏的关键因素,辫状河三角洲前缘相带是白垩系油气成藏的优势相带,上白垩统Galhak组是白垩系油气成藏的主要目的层段。研究结果对Melut盆地北部凹陷下步勘探具有指导意义。     

渤海湾盆地廊固凹陷油气分布特征研究

渤海湾盆地廊固凹陷已全面进入了隐蔽油气藏勘探阶段,如何认识层序地层格架内各种类型油气藏的分布特征是指导本区下一步勘探方向的关键.通过深入研究廊固凹陷古近系地层层序特征,根据其分布组合特点,建立了不同构造单元沉积模式,进一步剖析了凹陷内不同沉积体系特征及其不同组合样式.从整体沉积背景、构造背景认识出发,厘清了层序格架内沉积体系的分布特征;建立了陡坡带、洼槽带及中央带各具特色的6类成藏模式.指出多期次的沉积体系组合、多期次的构造运动叠加、生油层—储集体—圈闭的时空匹配对廊固凹陷各种类型油气藏的分布和富集发挥了重要作用.      

南阳凹陷张店油田核二段沉积微相研究

沉积相研究是从成因的角度来研究砂体沉积特征和展布特征。通过对岩心、测井资料的综合分析,在南阳凹陷张店油田核桃园组识别出10余种岩石相类型和8种岩石相组合类型,确定了6种沉积微相类型。并在此基础上在核二段三角洲相地层建立了二维高分辨率地层对比格架,分析了不同的沉积时期各沉积微相的组合特征和平面分布特征。指出水下分流河道砂体、河口坝和重力流砂体为有利储集相带,为本区的勘探开发提供依据。     

南堡凹陷东营组层序地层格架及沉积相预测

黄骅坳陷南堡凹陷属走滑伸展型断陷，古近系东营组主要发育冲积扇-扇三角洲-湖相沉积体系。为了查明南堡凹陷油气分布规律及勘探前景，利用高分辨率层序地层学方法，结合岩心、测井和地震资料分析，识别南堡凹陷东营组各级层序界面和相序，建立等时地层层序格架和演化模式，综合预测层序地层格架下的沉积相和油气分布。研究认为：层序界面、最大湖泛面、层序格架下的沉积相分布和构造背景是有利砂体分布和油气富集的主控因素，东营组油气分布具有纵向相对集中和平面分带的特点，表现为油气主要富集于最大湖泛面之下的东三上亚段地层中，且多分布于凹陷第二走滑断阶带。图7参16     

南阳凹陷张店油田核二段沉积微相研究

沉积相研究是从成因的角度来研究砂体沉积特征和展布特征。通过对岩心、测井资料的综合分析，在南阳凹陷张店油田核桃园组识别出10余种岩石相类型和8种岩石相组合类型，确定了6种沉积微相类型。并在此基础上在核二段三角洲相地层建立了二维高分辨率地层对比格架，分析了不同的沉积时期各沉积微相的组合特征和平面分布特征。指出水下分流河道砂体、河口坝和重力流砂体为有利储集相带，为本区的勘探开发提供依据。     

重力流沉积研究综述

随着越来越多的以重力流沉积为主的油气田相继被发现,对于重力流类型及其沉积相模式的研究愈加深入。由于水下过程的复杂性,重力流的类型出现了多种分类方案,也引出了许多新的名词;另外,先前流行的多种浊积相模式现在看来存在很多问题,甚至有相互矛盾的地方。在对国内外重力流沉积研究成果进行分析总结的基础上,重点对重力流沉积的相关概念以及沉积相模式进行了对比分析,并对重力流沉积的勘探方法提出了一些建议。     

Diatomic Gaseous Sulfur Obtained at Low Temperature Catalytic Decomposition of Hydrogen Sulfide

Experimental evidences of occurrence of gaseous diatomic sulfur produced in the low temperature catalytic decomposition of hydrogen sulfide 2 H2S ←→ 2 H2 ＋ S2 （g） are summarized. The S2 molecule is suggested to be in the ground triplet state. Analysis of literature data allows concluding that the S2 metastable singlet state is realized in the thermal dissociation of hydrogen sulfide and solid sulfur. Arguments in favor of the hypothesis are been discussed.     

靖安低渗透裂缝性油藏泡沫辅助空气驱油试验效果分析

靖安油田五里湾ZJ53井区储层渗透率低,非均质性强,在前期注水开发过程中,受天然裂缝和人工裂缝影响,主向井裂缝性水淹特征明显,侧向井呈现高渗透带水淹特征,导致注水驱油效率低下。泡沫辅助空气驱将空气作为驱油剂,泡沫作为辅助调剖剂,可实现边调边驱,具有实施成本低,工艺简单的特点,特别对低渗透、裂缝见水油藏能有效改善平面水驱矛盾,扩大波及体积。现场试验应用表明,试验后该区19口油井中有11口明显见效,综合含水由58．3％下降到50．3％,日产油总量由见效前的47．3t上升到最高值62．1t,达到了增油降水目的。     

新型钢带边部预处理装置

为了克服钢带边部涂层材料对钢管焊接的影响,开发出了一种新型钢带边部预处理装置。该装置由AG Shepherd（machinery）有限公司（英国）、Universal Tube＆Roll Form公司（美国）和D＆E Precision Engineering公司（英国）联合开发制造,现已投入市场。     

Oxidative Dehydrogenation of Isobutane to Isobutene on FSM-16 Doped with Cr and Related Catalysts

The oxidative dehydrogenation of isobutane to isobutene was examined for the use in the preparation of FSM-16 and related compounds doped by chromium with expectations that a yield of isobutene of greater than 8% could be achieved. The activity depended on the molding procedure of the catalyst and the doping method of the chromium species. In the present study, 8.8% and 8.3% of the yield of isobutene were obtained at 0.75 h and 6 h on-stream for the catalyst （Cr-loading; 6.2 wt.%） molded using wet treatment hut not pressurization treatment, in which the chromium species were directly added into the aqueous solution containing raw FSM-16 （hydrated sodium silicate powder） at an initial stage of the catalyst preparation. The structure information was based on XRD （X-ray diffraction）, the specific surface area was determined using a conventional BET （Brunauer-Emmett-Teller） nitrogen adsorption and the loading of chromium was estimated using ICP （inductively coupled plasma）. All those parameters combined with the molding method indicated that the catalytic activity was more influenced by the loading of chromium into bulk but not on surface of the catalyst rather than by the hexagonal structure of FSM-16 and the surface area.     

SAPO-34催化剂上甲醇制烯烃反应动力学

A kinetic model of MTO process over the SAPO-34 catalyst considering the effect of water and coke deposition has been proposed.The model takes into account three steps of the MTO reaction in which the products cover 5 lumped components.The water in the feed not only reduces the concentration of methanol but also alleviates the deactivation of SAPO-34 catalyst.The kinetic parameters have been estimated by the least square method.It has been proved that the calculated values in the kinetic model are in good agreement with the experimental values.     

二次重建法制备具有大孔容高比表面的大孔-介孔γ-Al2O3

Through improving the aging process during synthesis of the support, γ-Al2O3 with large pore volume and high surface area was synthesized by a facile secondary reforming method. The synthesis parameters, such as the reaction temperature, the first aging temperature and the second aging temperature, were investigated. The textural properties of γ-Al2O3 were characterized by means of N2 adsorption-desorption isotherms, X-ray powder diffractometry(XRD), scanning electron microscopy(SEM), Fourier transform infrared(FTIR) spectroscopy and thermogravimetry(TG). The experimental results indicated that AACH and amorphous AlOOH were the precursors of alumina, which were formed via precipitation from solutions after reaction of aluminum sulphate with ammonium hydrogen carbonate. The precursor nanocrystallites grew and re-assembled during the secondary reforming process, which resulted in an increased pore size and pore volume and a decreased bulk density. The as-synthesized γ-Al2O3 materials featured meso/macroporosity, large pore volume(2.175 cm3/g), high surface area(237.8 m2/g), and low bulk density(0.284 g/mL).     

Geochemical Studies and Elemental Contaminants in the Bay of the City of Asuncion

Minor and trace elements composition of bottom sediments from the bay of Asunci6n on the Paraguay River have been investigated by XRF （X-ray fluorescence） techniques to determine their correlation as well as provenance. The analysis of complex spectra was performed by the AXIL software and the quantitative analysis by the QAES （quantitative analysis of environmental samples ） software. Analyzed trace elements were the refractory elements Rb, Sr, Y, Zr, Nb, Ba, La, Ce, Pr, Nd, Zr, Th and others with high field stabilization energy as Cr, Ni, Cu, together with Zn, As, Cd, Pb. Minor elements were Ti, Mn, Fe which are often to the above refractories related. According to their normalized spidergrams, two sets of sediments can be differentiated. Those that show LREE （light rare earth elements） enrichment, negative Nb and Ti anomalies and no spike at Zr and those that have spidergrams very alike, with strong negative anomalies at Nb, Nd and Ti whereas a of Fe versus the refractory elements except Fe-Zr in which correlation seem to be low. positive spike at Zr. In both set, there are strong correlations is negative. Potential hazards of toxic elements in sediments     

HZSM-5沸石上4-羟基-3-己酮催化脱水制备4-己烯-3-酮

A study on catalytic dehydration of 4-hydroxy-3-hexanone （HH） to 4-hexen-3-one （HO） was carried out through conversion of HH over HZSM-5 zeolite catalyst in a fixed-bed reactor （FBR） operating under almospheric pressure. The test indicated a relatively high activity of the HZSM-5 zeolite capable of achieving a HH conversion of 99.2% and a HO yield of 83.5%. Catalyst deactivation could be prevented by increasing the reaction temperature by 10 ＂C for every 20 h and adding 2.0% of piperidine in the feed. A catalyst stability test （for 100 h） in FBR showed that the catalyst was active even after 100 h of time-on-stream with HH conversion remaining at 99.2% and HO yield still reaching over 83.5%. Regenera- tion experiment showed that the regenerated catalyst demonstrated a catalytic performance comparable to the fresh one.     

Research progress on blending modification process of PP/PA6/2013,24 （5） ： 1-4

PP and PA6 are incompatible systems, so it＇ s necessary to add compatibilizer into the blends to improve the compatibility of the blends. However, the addition of compatibilizer affects the performance of the blend system. This paper analyzed the factors affecting the performance of PP/PA6 system, explained the influence of the blending process and inorganic filler on blend system, and indicated research direction of PP/PA6 blending modification process.