Performance enhancement in latent heat thermal storage system: A review

Phase change material (PCM) based latent heat thermal storage (LHTS) systems offer a challenging option to be employed as an effective energy storage and retrieval device. The performance of LHTS systems is limited by the poor thermal conductivity of PCMs employed. Successful large-scale utilization of LHTS systems thus depends on the extent to which the performance can be improved. A great deal of work both experimental and theoretical on different performance enhancement techniques has been reported in the literature. This paper reviews the implementation of those techniques in different configurations of LHTS systems. The influence of enhancement techniques on the thermal response of the PCM in terms of phase change rate and amount of latent heat stored/retrieved has been addressed as a main aspect. Issues related to mathematical modeling of LHTS systems employing enhancement techniques are also discussed.     

Numerical simulation of a multi-layer latent heat thermal energy storage system

A computational model for the prediction of the thermal behaviour of a compact multi-layer latent heat storage unit is presented. The model is based on the conservation equations of energy for the phase change material (PCM) and the heat transfer fluid (HTF). Electrical heat sources embedded inside the PCM are used for heat storage (melting) while the flow of an HTF is employed for heat recovery (solidification). Parametric studies are performed to assess the effect of various design parameters and operating conditions on the thermal behaviour of the unit. Results indicate that the average output heat load during the recovery period is strongly dependent on the minimum operating temperature, on the thermal diffusivity of the liquid phase, on the thickness of the PCM layer and on the HTF inlet mass flowrate and temperature. It is, on the other hand, nearly independent of the wall thermal diffusivity and thickness and of the maximum operating temperature. Correlations are proposed for the total energy stored and the output heat load as a function of the design parameters and the operating conditions. © 1998 John Wiley & Sons, Ltd.     

Numerical simulations on performance enhancement of a cross-flow latent thermal energy storage heat exchanger

基于列管式换热器具有传热面积大、结构紧凑、操作弹性大等优点,使其在相变储能领域具有广阔的应用前景。本文建立一种新型列管式相变蓄热器模型,在不考虑自然对流的情况下,利用Fluent软件对相变蓄热器进行二维储热过程的数值模拟。本文主要研究斯蒂芬数、雷诺数、列管排列方式、肋片数以及相变材料的导热系数对熔化过程的影响,并对熔化过程中固液分界面的移动规律进行了分析。模拟结果表明,内肋片强化换热效果明显,特别是对应用低导热系数相变材料[导热系数小于1 W/(m·K)]的列管式蓄热器,相对于无肋片结构,加入肋片（N_fn=2）可缩短熔化时间52.6%。     

High temperature latent heat thermal energy storage using heat pipes

A thermal network model is developed and used to analyze heat transfer in a high temperature latent heat thermal energy storage unit for solar thermal electricity generation. Specifically, the benefits of inserting multiple heat pipes between a heat transfer fluid and a phase change material (PCM) are of interest. Two storage configurations are considered; one with PCM surrounding a tube that conveys the heat transfer fluid, and the second with the PCM contained within a tube over which the heat transfer fluid flows. Both melting and solidification are simulated. It is demonstrated that adding heat pipes enhances thermal performance, which is quantified in terms of dimensionless heat pipe effectiveness.     

Analytical solution of heat transfer in a shell-and-tube latent thermal energy storage system

An analytical solution of a latent heat storage unit (LHSU) consisting of a shell-and tube was obtained by using the Exponential Integral Function and the variables separation technique. The working fluid (water) circulating by forced convection inside the inner tube charges and discharges the storage unit. The comparison between analytical predictions and experimental data shows good agreement. Extensive parametric studies were conducted in order to examine the effect of the pertinent parameters (such as natural convection, mass flow rate of HTF, outer tube radius, pipe length etc.) on the melting and solidification processes of paraffin as a PCM. In order to provide guidelines for system performance and design optimisation, unsteady temperature distributions within PCM during melting/solidification, energy stored, position of moving interface and thermal efficiency have been obtained by a series of numerical calculations and represented graphically.     

Thermal conductivity enhancement in a latent heat storage system

Latent heat storage systems especially those employing organic materials have been reported to exhibit a rather slow thermal response. This is mainly due to the relatively low thermal conductivity of organic latent heat materials. In this study, experiments were carried out to investigate a method of enhancing the thermal conductivity of paraffin wax by embedding aluminum powder in it. The size of the aluminum powder particles was 80 μm. The tested mass fractions in the PCM-aluminum composite material were 0.1, 0.3, 0.4, and 0.5 of aluminum. The used mass fraction in the experimental work was 0.5.The experiments were conducted by using a compact PCM solar collector. In this collector, the absorber-container unit performed the function of absorbing the solar energy and storing the phase change material (PCM). The solar energy was stored in the PCM and was discharged to cold water flowing in pipes located inside the PCM. Charging and discharging processes were carried out. The propagation of the melting and freezing fronts was studied during the charging and the discharging processes. The time wise temperatures of the PCM were recorded during the processes of charging and discharging. The solar intensity was recorded for the charging process. It was found that the charging time was reduced by approximately 60% by adding aluminum powder in the wax. In the discharging process, experiments were conducted for different water flow rates of 9-20.4 kg/h. It was found that the useful heat gained increased when adding aluminum powder in the wax as compared to the case of pure paraffin wax. The heat transfer characteristics were studied.     

Low temperature latent heat thermal energy storage: Heat storage materials

Heat-of-fusion storage materials for low temperature latent heat storage in the temperature range 0–120°C are reviewed. Organic and inorganic heat storage materials classified as paraffins, fatty acids, inorganic salt hydrates and eutectic compounds are considered. The melting and freezing behaviour of the various substances is investigated using the techniques of Thermal Analysis and Differential Scanning Calorimetry. The importance of thermal cycling tests for establishing the long-term stability of the storage materials is discussed. Finally, some data pertaining to the corrosion compatibility of heat-of-fusion substances with conventional materials of construction is presented.     

Numerical analysis on the thermal behavior of high temperature latent heat thermal energy storage system

High temperature latent heat thermal energy storage technology is a promising option for future cost reduction in parabolic trough or tower power plant. However, low thermal conductivity of phase-change material (PCM) is the major shortage of latent heat thermal energy storage. This paper proposed a new thermal energy storage system (TESS) that metal foam and fins were used to enhance the effective conductivity of PCM. Three-dimensional physical model was established for representative element extracted from TESS. Considering the natural convection in the liquid part of PCM, volume-averaged mass and momentum equations were employed with the Brinkman–Forchheimer extension to Darcy law to simulate the porous resistance. A local thermal equilibrium model was developed to obtain temperature field. The governing equations were solved with finite-volume approach and enthalpy method was employed to account for phase change. The model was firstly validated against low temperature experiments from the literature and then used to predict the charging and discharging behavior of the present TESS. The position of solid/liquid interface was explored and the effects of design parameters, including that of metal foam pore density and porosity, configuration of fin and Rayleigh number, on melting and solidifying rate and energy stored in each time step were revealed and discussed. The results indicate that metal foam and fins can effectively improve the heat transfer performance for thermal storage system and decrease charging and discharging time.     

Analysis and optimization of a latent thermal energy storage system with embedded heat pipes

Latent thermal energy storage system (LTES) is an integral part of concentrating solar power (CSP) plants for storing sun’s energy during its intermittent diurnal availability in the form of latent heat of a phase change material (PCM). The advantages of an LTES include its isothermal operation and high energy storage density, while the low thermal conductivity of the PCM used in LTES poses a significant disadvantage due to the reduction in the rate at which the PCM can be melted (charging) or solidified (discharging). The present study considers an approach to reducing the thermal resistance of LTES through embedding heat pipes to augment the energy transfer from the heat transfer fluid (HTF) to the PCM. Using a thermal resistance network model of a shell and tube LTES with embedded heat pipes, detailed parametric studies are carried out to assess the influence of the heat pipe and the LTES geometric and operational parameters on the performance of the system during charging and discharging. The physical model is coupled with a numerical optimization method to identify the design and operating parameters of the heat pipe embedded LTES system that maximizes energy transferred, energy transfer rate and effectiveness.     

Exergetic and performance analyses of two-layered packed bed latent heat thermal energy storage system

In concentrating solar power (CSP) plant, a novel method involving the use of thermocline can be employed to augment the capability of the thermal energy storage system (TES). The rate of thermocline degradation can be reduced by packing encapsulated phase change material (PCM) in the TES. The thermal performance of the packed bed latent heat thermal energy storage system (PBTES) can be further enhanced by employing different diameters of PCM capsules arranged in multiple layers. In this paper, the thermal and exergetic performance of single-layered and two-layered PBTES is evaluated for varying mass flow rate, PCM capsule diameter and bed height of larger PCM capsules using a dynamic model based on simplified energy balance equations for PCM and heat transfer fluid (HTF). The single-layered PBTES has a lower TES latent charging rate than the two-layered PBTES. The charging efficiency and charging time of two-layered PBTES are increased by 15.85% and 16.85%, respectively for reducing the HTF mass flow rate by 14.29%. A higher stratification number can be achieved by using a two-layered PBTES instead of a single-layered PBTES filled with the corresponding larger diameter PCM capsules. The second law efficiency of the two-layered PBTES is found to be less than that of the single-layered PBTES. A decrease in the bed height of larger PCM capsules decreases the exergetic efficiency of the two-layered PBTES by 3.27%. The findings from this study can be used in further designing and optimising the multi-layered PBTES.     

潜热储热系统强化传热研究进展

近年来,潜热储热系统在太阳能和工业废能的利用中发挥着极其重要的作用,因此用于潜热储热的相变材料受到普遍关注.文章对国内外潜热储热系统众多强化传热技术进行了综述与讨论.     

Solar multi-mode heating system based on latent heat thermal energy storage and its application

为克服太阳能间断性和不稳定性的缺点进而实现太阳能集热与采暖的能量供需调节和全天候连续供热,提出了基于相变储热的太阳能多模式采暖方法（太阳能集热直接采暖、太阳能集热采暖+相变储热、太阳能相变储热采暖）,并在西藏林芝市某建筑搭建了太阳能与相变储热相结合的采暖系统,该系统可根据太阳能集热温度和外界供热需求实现太阳能多模式采暖的自动控制和自动运行。实验研究表明：在西藏地区采用真空管太阳能集热器可以和中低温相变储热器很好地结合,白天储热器在储热过程中平均储热功率为10.63 kW,储热量达到92.67 kW·h,相变平台明显;晚上储热器在放热过程中供热量达85.23 kW·h,放热功率和放热温度平稳,储放热效率达92%,其储热密度是传统水箱的3.6倍,可连续供热时间长达10 h,从而实现了基于相变储热的太阳能全天候连续供热,相关研究结果对我国西藏地区实施太阳能采暖具有一定的指导作用。     

Numerical simulation of a shell-and-tube latent heat thermal energy storage unit

A theoretical model was developed to predict the transient behavior of a shell-and-tube storage unit with the phase change material (PCM) on the shell side and the heat transfer fluid (HTF) circulating inside the tubes. The multidimensional phase change problem is tackled with an enthalpy-based method coupled to the convective heat transfer from the HTF. The numerical predictions are validated with experimental data. A series of numerical experiments are then undertaken to assess the effects of various thermal and geometric parameters on the heat transfer process and on the behavior of the system. Results show that the shell radius, the mass flow rate, and the inlet temperature of the HTF must be chosen carefully in order to optimize the performance of the unit.     

Heat transfer characteristics of the latent heat thermal energy storage capsule

The characteristic variation of the rate of heat transfer to and from a latent heat thermal energy storage capsule was investigated analytically and experimentally. Basic experiments were carried out to simulate a solar energy storage capsule, using a horizontal cylindrical capsule (300 mm length, 40 mm o.d.) filled with naphthalene as the phase change material. The variation of heat flux during the processes of heat storage and removal was measured by a heat flow meter wrapped around the capsule, as the capsule was subjected to stepwise variations of the surface temperature. Finite difference calculations based on heat conduction were also carried out to compare with the experimental results. For the heat removal process, the experimental results and the calculated heat flux agreed well with each other. They showed different characteristic trends for the heat storage process, due to the effects of natural convection.     

Performance enhancement of finned heat pipe assisted latent heat thermal energy storage system in the presence of nano-enhanced H2O as phase change material

In this research, Latent Heat Thermal Energy Storage Systems (LHTESS) containing Nano-Enhanced Phase Change Material (NEPCM) in the presence of novel shape finned heat pipe is numerically investigated from the viewpoint of discharging process. In recent years, LHTESS have been used to establish a balance between energy supply and demand. Since conventional PCMs are characterized with high latent heat and low thermal conductivity, these systems are capable of storing large amount of energy, but storage and retrieval processes cannot be achieved in the desired time duration. In this paper, CFD simulation and multi-objective Response Surface Method (RSM) optimization is used simultaneously to find the optimum configuration of novel shaped fin, which is then attached to a heat pipe and immersed into the LHTESS. The performance of finned heat pipe assisted LHTESS is compared to the LHTESS containing NEPCM, and LHTESS with other common fin structures. Since the immersion of finned heat pipe into the system decreases the amount of employed PCM, the maximum energy storage capacity of the LHTESS drops subsequently. Thus, energy storage capacity, as one of the objectives of optimization procedure of this research is studied quantitatively, which is proposed as the novelty here. Results indicate that employing maximum energy storage capacity as an evaluation parameter, leads to efficient design of LHTESS. Also it is inferred that immersing finned heat pipe into LHTESS as a heat transfer enhancement technique is superior to nanoparticles dispersion.     

A semi-analytical solution for time-varying latent heat thermal energy storage problems

Latent heat thermal energy storage (LHTES) problems include a lot of boundary conditions that could not be solved by exact solution, so new approaches to solving such problems could revolutionize the advanced energy storage devices. This paper focuses on reformulating the generalized differential quadrature method (GDQM) for a one-dimensional solidification/melting Stefan problem as a fundamental LHTES problem and solves some practical cases. Convergence and comparisons demonstrate that the proposed approach is sufficiently reliable. By checking the accuracy of the proposed approach for the LHTES problem (where Stefan number is below 0.2), it was demonstrated that for all Stefan numbers, the maximum error is less than 3.81% for temperatures. As the usual range of thermal energy storages, for Stefan numbers up to 0.2 the solution yields errors less than 0.2%. Then, the proposed approach is very ideal for such applications. In comparison, GDQM has a more accurate response than an integral solution for Stefan numbers less than 0.2. When this priority of GDQM comes with its low computational cost, it would undoubtedly be preferable.     

Numerical simulation of porous latent heat thermal energy storage for thermoelectric cooling

Porous latent heat thermal energy storage for thermoelectric cooling is simulated via a matrix-based enthalpy formulation, having the temperature as unknown, in a three-dimensional domain. The system is made up of two aluminum containers; the inner one contains the cooling objective in water suspension and the outer one the phase change material (PCM) in a porous aluminum matrix. The system’s charging and discharging processes are simulated for constant thermoelectric module cold side temperature under different porosities of the aluminum matrix. The mathematical modeling approach simplifies the analysis while the metal matrix in the PCM greatly improves performance. A direct application of the studied system is vaccine conservation in solar powered thermoelectric cooling systems.     

Review on heat transfer analysis in thermal energy storage using latent heat storage systems and phase change materials

Thermal energy storage (TES) is a technology that stocks thermal energy by heating or cooling a storage medium so that the stored energy can be used later for heating and cooling applications and for power generation. TES has recently attracted increasing interest to thermal applications such as space and water heating, waste heat utilisation, cooling, and air conditioning. Phase change materials (PCMs) used for the storage of thermal energy as latent heat are special types of advanced materials that substantially contribute to the efficient use and conservation of waste heat and solar energy. This paper provides a comprehensive review on the development of latent heat storage (LHS) systems focused on heat transfer and enhancement techniques employed in PCMs to effectively charge and discharge latent heat energy, and the formulation of the phase change problem. The main categories of PCMs are classified and briefly described, and heat transfer enhancement technologies, namely dispersion of low‐density materials, use of porous materials, metal matrices and encapsulation, incorporation of extended surfaces and fins, utilisation of heat pipes, cascaded storage, and direct heat transfer techniques, are also discussed in detail. Additionally, a two‐dimensional heat transfer simulation model of an LHS system is developed using the control volume technique to solve the phase change problem. Furthermore, a three‐dimensional numerical simulation model of an LHS is built to investigate the quasi‐steady state and transient heat transfer in PCMs. Finally, several future research directions are provided.     

Heat transfer enhancement in medium temperature thermal energy storage system using a multitube heat transfer array

An experimental energy storage system has been designed using an horizontal shell and tube heat exchanger incorporating a medium temperature phase change material (PCM) with a melting point of 117.7 °C. Two experimental configurations consisting of a control unit with one heat transfer tube and a multitube unit with four heat transfer tubes were studied. The thermal characteristics in the systems have been analysed using isothermal contour plots and temperature time curves. Temperature gradients along the three directions of the shell and tube systems; axial, radial and angular directions have been analysed and compared. The phase change in the multitube system was dominated by the effect of convective heat transfer compared to conductive heat transfer in the control system. The temperature gradient in the PCM during phase change was greatest in the radial direction for both the control and multitube systems. The temperature gradients recorded in the axial direction for the control and multitube systems during the change of phase were respectively 2.5 and 3.5% that of the radial direction, indicating essentially a two-dimensional heat transfer in the PCM. The onset of natural convection through the formation of multiple convective cells in the multitube system significantly altered the shape of the solid liquid interface fluid flow and indicates the requirement for an in-depth study of multitube arrangements.     

Numerical investigation of heat transfer enhancement in a multitube thermal energy storage heat exchanger using fins

The application of a phase change material (PCM) as thermal energy storage observed unprecedented growth due to its large latent heat storage capacity at a constant temperature. However, the design of an energy storage heat exchanger is a challenging task because of the poor thermal conductivity of PCMs. In an effort to improve the heat exchanger design, this paper presents a numerical performance investigation of a PCM-based multitube heat exchanger incorporated with two new fin configurations. The analysis of the results shows that the placement of fins is one of the important aspects, which needs to be cogitated in the design of heat exchangers.