共查询到15条相似文献,搜索用时 109 毫秒
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污泥焚烧底灰的处理处置与资源化利用是污泥焚烧过程中必须解决的难题。该文通过对两种不同的污泥焚烧底灰的粒径、抗剪、压缩固结性、渗透性以及重金属含量等理化性质进行了研究,并将其与原生污泥性质进行对比,分析焚烧处理对污泥理化性质的影响,并进一步根据焚烧底灰性质,探索其再利用途径。结果表明污泥焚烧底灰属于砂土,且抗剪强度较污泥焚烧前有明显增大,可达76.23~80.03kPa;重金属含量有所超标,但重金属浸出量均小于相应标准限定值,可进行路基材料、cO2捕集、填海造陆等再利用。 相似文献
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采用水热合成法,详细考察了凝胶碱度对P沸石及其膜的合成的影响,发现凝胶碱度变化对合成晶化产物结构具有决定性影响,确定在实验条件下最佳合成碱度为Na2O/H2O=0.0163~ 0.0212. 在长250 mm、平均孔径3~5 mm的a-Al2O3陶瓷管外表面经二次涂膜,直接原位合成出膜厚约10~12 mm的沸石膜;XRD, SEM及H2, N2单组分气体渗透表征测试表明,载体管上的晶粒均匀规整,互锁状生长,为典型的P型沸石膜, H2和N2在膜内外压差为60~60 kPa范围内(25oC时),渗透速率分别为(3.60~3.99)10-6和(1.13~1.24)10-6 mol/(sm2Pa),同时具有较好的H2/N2选择系数(3.19~3.33). 相似文献
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利用粉煤灰合成沸石的方法很多,其中水热法合成沸石因操作简单、能耗低被认为是将粉煤灰基沸石商业化最可行的手段。采用水热法将国内外不同产地的几种粉煤灰合成沸石,并通过X射线衍射(XRD)、X射线荧光光谱(XRF)、热重分析(TG-DTA)、扫描电镜(SEM)等手段对合成的沸石产品进行表征,并在同一水热合成参数下考察不同粉煤灰合成沸石在品质上的差异。XRD谱图表明,原料中有80%~90%的成分转化为沸石,且沸石主要结晶类型为Na-P1型,也有少量的A型;XRF分析表明,3种粉煤灰基沸石硅铝物质的量比分别为1.61、1.35、1.45,符合XRD谱图的分析结论;TG-DTA表明,合成沸石在500 ℃以上几乎没有质量损失,具有良好的热稳定性;由SEM照片可见,合成的沸石为非球形,表面的纹理可增加沸石比表面积,结晶状态好。整个实验过程简单、成本低、合成沸石样品品质较高,由此可见通过水热法将粉煤灰合成沸石产品具有巨大的商业化潜力。 相似文献
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用叶蜡石合成Y型沸石的研究 总被引:3,自引:0,他引:3
用福州叶蜡石,在适量补硅的条件下,可合成出Y型沸石产物,用XRD进行了表征,其硅铝比为4.1-5.0,每克叶蜡石可制出1.2克产品,对焙烧和合成过程进行分析和讨论,试验结果表明,叶蜡石作为合成Y型沸石的廉价原料,有良好的应用前景。 相似文献
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This research evaluated the use of sewage sludge and refuse incineration bottom ash to replace calcium sulfoaluminate cement(CS(_)A) in making controlled low-strength material(CLSM).Various properties of CLSM mixtures were characterized in terms of unconfined compressive strength,microstructure and leachability.It was found that the strength of tested CLSM mixtures ranged from 3.6 to 9.0 MPa,over the upper excavatable limit of 2.1 MPa.The micro-structural analysis revealed that sewage sludge and bottom ash were crystallochemically in-corporated within CLSM systems by forming the needle-like ettringite(C3A?3CS(_)?H32) with exiguous tubers via the typical Pozzolanic Reaction,leading to a dense and low-porosity microstructure.Furthermore,the toxicity charac-teristic leaching procedure evidenced that the cumulative leachable metals in the leachate were much below the regulatory thresholds.The potential for using sewage sludge and bottom ash in CLSM making was thus confirmed. 相似文献
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A single phase Na- X zeolite was synthesized from pretreated oil shale ash by alkaline fusion and hydrothermal treatment. Effects of the NaOH concentration,crystallization time and temperature on the formation of Na- X zeolite were studied in detail. The single phase Na- X zeolite powders can be prepared by alkaline fusion of pretreated oil shale ash at 600 ℃ for 1 h,and crystallization at 80- 100 ℃ for 8- 10 h with NaOH concentration of 3- 3. 5 mol · L- 1. Na- A zeolite appears when decreasing NaOH concentration, crystallization time or temperature,and an unnamed zeolite emerges when prolonging crystallization time or raising crystallization temperature. SEM micrographs suggest that the aggregates of Na- X zeolite particles have perfect dispersity and uniform granular with about 1. 5 μm in size,and most of the Na- X zeolite crystals display a regular octahedral structure with the size of about 500 nm. The specific surface area of the powders with single Na- X zeolite phase reaches the maximum value of 488. 163 2m2·g- 1,larger than that of multiple zeolite powders. 相似文献