花生衣天然染料对亚麻织物染色性能研究

以60%乙醇提取花生衣染料,对亚麻织物进行染色。采用直接染色、铁预媒染及铝预媒染3种不同染色方法,研究染色温度和染料用量对亚麻织物染色性能的影响。通过测试染色后织物的K/S以及L、a、b得出最佳染色温度为:直接染色为120℃,Fe⁽²⁺⁾预媒染为110℃,Al(2+)预媒染为110℃,Al⁽³⁺⁾预媒染为120℃。媒染染色织物颜色差异较大,在相同染色条件下,Fe(3+)预媒染为120℃。媒染染色织物颜色差异较大,在相同染色条件下,Fe⁽²⁺⁾预媒染织物K/S值最大。直接染色亚麻织物K/S值高达6,表明花生衣染料对亚麻织物染色潜力大。在最佳染色条件下,染色亚麻织物的色牢度、抗紫外性能优良,Al(2+)预媒染织物K/S值最大。直接染色亚麻织物K/S值高达6,表明花生衣染料对亚麻织物染色潜力大。在最佳染色条件下,染色亚麻织物的色牢度、抗紫外性能优良,Al⁽³⁺⁾预媒染织物各项色牢度可达4级以上,Fe(3+)预媒染织物各项色牢度可达4级以上,Fe⁽²⁺⁾预媒染织物抗紫外性能为原布样的11.8倍。染色后织物荧光性能明显提升,而直接染色最佳。     

核桃青皮醇提取物对棉织物染色性能的研究

为解决天然染料核桃青皮染色色调单一的问题,以颜色特征值和染色牢度为指标,通过单因素和正交实验优化了影响染色效果的温度、时间、p H值及核桃青皮色素染液的质量浓度等条件,比较了单金属盐的不同媒染方法、复合金属盐复配的不同配方对纯棉织物染色性能的影响。结果表明:核桃青皮色素染色的优化条件为温度90℃、质量浓度71.40 g/L、染浴p H=4.0、时间140 min。核桃青皮提取液染色棉织物色谱范围广,染色深度(k/s值)分布范围从2.55到16.09,耐摩擦牢度均在4级以上;单金属盐媒染的耐皂洗牢度后媒预媒同浴直接染色,复合金属盐复配及Fe3+、Fe2+、Cu2+、Al3+、Cr6+等单金属盐媒染的耐皂洗色牢度均能达到3级以上。X-射线衍射及紫外透过率测试结果表明:棉织物内部结构未受影响,Fe3+、Fe2+、Cr6+、Sr2+、Na+和K+等单金属盐和Fe2+/Cu2+、Fe2+/Ti4+、Cu2+/Ti4+、Cu2+/Sn2+、Al3+/Cr6+、Cr6+/Ti4+和Cr6+/Sn2+等复合金属盐媒染后的棉织物紫外线防护能力增强。     

栀子染料染棉针织物的染色工艺研究

以栀子染料染得更深、牢度更好的棉针织物为出发点,主要研究了栀子染料的提取,金属离子Fe^2＋,Al^3＋对棉针织物媒染效果,并通过单因素优化、正交实验确定栀子染料金属铝预媒染的最佳工艺。结果表明：铝离子预媒染用于棉针织物染色的最佳工艺为：浴比1：25,温度75℃,染液pH值5,媒染剂用量6％（owf）,染料用量45％（owf）。     

改性姜黄素对棉织物染色性能初探

利用硼氢化钠对姜黄素进行还原改性,将改性后的姜黄溶液作为染液,对纯棉布进行染色,同时研究了用壳聚糖、壳聚糖季铵盐、三氯化铝、稀土(硝酸亚铈-柠檬酸)作为媒染剂在不同pH下的上染效果。研究表明:改性姜黄素溶液对纯棉布的染色色差与上染率随着pH的降低而增大;在弱酸性时染色效果最好,预媒处理会显著提高染色效果。总的来说,用稀土作为媒染剂进行媒染处理的染色效果最好。     

核桃青皮醇提物对棉织物染色性能的研究

为解决天然染料核桃青皮染色色调单一的问题,以颜色特征值和染色牢度为指标,通过单因素和正交实验优化了影响染色效果的温度、时间、pH值及核桃青皮色素染液的质量浓度等因素,比较了单金属盐的不同媒染方法和双金属盐复配对纯棉织物染色性能的影响。结果表明,核桃青皮色素染色的优化条件为：温度90oC、质量浓度71.40 g/L、染浴pH=4.0、时间140 min。核桃青皮提取液染色棉织物色谱的范围广,耐摩擦牢度好;耐皂洗牢度上单金属盐媒染是后媒＞前媒＞同浴＞直接染色,双金属盐复配及Fe3+、Fe2+、Cu2+、Al3+、Cr6+等单金属盐媒染的耐皂洗色牢度均能达到3级以上。X-射线衍射分析表明棉织物内部结构未受影响,Fe3+、Fe2+、Cr6+、Sr2+、Na+和K+等单金属盐和Fe2+/Cu2+、Fe2+/Ti4+、Cu2+/Ti4+、Cu2+/Sn2+、Al3+/Cr6+、Cr6+/Ti4+和Cr6+/Sn2+等双金属盐媒染后的棉织物紫外线防护能力增强。     

栲胶对丝绸染色的工艺研究

论文以栗木和余柑作为染料对丝绸染色进行研究。用这两种栲胶(水解类)对丝绸进行直接染色,并配合不同媒染剂进行后媒染和预媒染染色。通过对比试验,性能测试,确定栲胶最佳染色工艺条件:栗木采用配合媒染剂SnCI2后媒染法,酸固色pH 3.5,染色时间30 min;余柑为直接染色,酸固色pH 6.5,染色时间30 min。     

西藏本土天然植物蕞提取液对氆氇染色工艺的研究

采用超声波提取法对西藏本地植物蕞进行提取,而后用提取液对氆氇进行媒染染色,探讨了染料提取方法、提取工艺、染色工艺、媒染剂种类、媒染剂用量、提取液用量、染液pH、染色温度和时间对氆氇染色性能的影响,并测试了染色氆氇的染色牢度。结果表明：采用超声波提取法提取染液,染色工艺为前媒染色法;染料用量50m L/L,硫酸亚铁（0.5g/L）,染色时间为120min,染浴的p H值为5,染色温度为85℃。此时,染色氆氇的耐水洗色牢度可达3～4级,耐摩擦色牢度可达4级及以上。     

天然茶染料用于棉织物浸染工艺研究

以硫酸铜为媒染剂,研究了天然茶染料对棉织物的浸染工艺。结果表明,以硫酸铜为媒染剂,对棉织物进行浸染处理,可以得到较好的染色效果,同时还得到最佳的染色工艺:媒染剂Cu2+的浓度为12 g/L,温度为80℃,时间为100 min;以硫酸铜为媒染剂染色的棉织物经高温焙烘固色后,棉织物的干摩擦牢度和湿摩擦牢度都得到了提高。     

青海红花用于藏毯羊毛染色的研究简

通过设计正交试验,对二乙胺预处理过的羊毛进行染色工艺研究.重点考察了植物红花染料对羊毛的直接染色和同媒染色中时间、温度、媒染剂种类、以及媒染剂的用量等因素对染色效果的影响.结果表明同媒染色优于直染,且同媒染色的最佳条件为：染色温度60℃,染色时间30 min,媒染剂用量8％（o.w.f）,媒染剂Fe2＋.     

玫瑰红色素对羊毛和蚕丝的媒染性能

以FeSO4和ZnSO4·7H2O为媒染剂,采用玫瑰红提取液对羊毛和蚕丝进行染色,探讨了媒染温度、时间、媒染剂用量、玫瑰红提取液用量对媒染性能的影响,以及染色织物的牢度。结果表明,媒染剂FeSO4和ZnSO4·7H2O用量为2g／L、提取液用量为10mL、羊毛和蚕丝织物均为2g时,染色织物具有较深的色泽和良好的色牢度。     

Electrostatic self‐assembly dyeing of cotton fabrics

A new approach to the dyeing of cotton fabrics using an electrostatic self‐assembly method was evaluated. Cotton fabrics were pretreated with 2,3‐epoxypropyltrimethylammonuium chloride and cationic charges were produced on the fabric surfaces. For the dyeing of cotton fabric, reactive and acid dyes were used. Oppositely charged anionic reactive/acid dyes and cationic poly(diallyldimethylammonium chloride) were alternately deposited on the surface of cationised cotton fabrics. Ten multilayer films of dye/poly(diallyldimethylammonium chloride) were deposited on the cotton fabric surfaces using a padder. The build‐up of the multilayer films and the level of colour strength (K/S) achieved are discussed. Samples of cotton fabrics were also dyed with the same dyes, but using the exhaust method, and both types of dyed samples were compared. The washing, rubbing and light fastness properties were evaluated for the dyed fabrics.     

竹/棉混纺织物活性染料染色使用代用碱固色的工艺探讨

通过代用碱TF-221和常规纯碱对活性染料浸染固色的对比实验,测定了碱剂在染色浴固着反应中pH值的动态变化值。通过染色K/S值、各项色牢度、上染速率的对比实验,讨论了代用碱TF-221在活性染料染色中代替纯碱作为固色剂的作用效果,并测定两种工艺染色后织物的强力变化,找到合适的固色工艺。实践证明:代用碱TF-221完全可以代替纯碱用于活性染料染色对竹/棉混纺织物染色时的固色,其固着浴pH值稳定范围符合活性染料的染色特征,可以获得与使用纯碱相当或高于的K/S值和染色牢度,且上色缓慢,起到匀染作用;染色后织物的强力无明显下降。     

Application of polycarboxylic acid sodium salt in the dyeing of cotton fabric with reactive dyes

In this study, the effects of polycarboxylic acid sodium salt on the dyeing of cotton with reactive dyes were evaluated by measuring and comparing the K/S values and dyeing fastnesses of the dyed cotton fabric samples. Results showed that the K/S value and dyeing fastness of cotton fabrics dyed with polycarboxylic acid sodium salt, substituting inorganic salts as exhausting agent were close to that of with sodium chloride when dip‐dyeing process was used. While, in pad‐dry dyeing, the K/S value of cotton fabric samples dyed with polyacid salts as exhausting agent was higher than that of with sodium sulfate, and the dyeing fastnesses of these samples were nearly the same. The dyeing mechanism of cotton fabric with reactive dye, using polycarboxylic acid sodium salt as exhausting agent was analyzed. The dyeing exhausting mechanism of reactive dye seems different when the inorganic salt and polycarboxylic acid sodium salt were used as exhausting agent in the dyeing of cotton fabric with reactive dye. The polycarboxylic acid sodium salt, as weak electrolyte, increased the dye‐uptake of reactive dye on cotton fabric not only by screening negative charges on cotton surface, but also by the effect of salting‐out or hydrophobic combination. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Pretreatment of cotton fabrics with polyamino carboxylic acids for salt‐free dyeing of cotton with reactive dyes

In this study, polyamino carboxylic acids have been used to improve the dyeability of cotton in a salt‐free reactive dyeing process. These polyamino carboxylic acids were prepared by partial carboxylation of polyvinylamine. Cotton fabric was pretreated with polyamino carboxylic acids and dyed with reactive dyes. The colour strengths of the dyed fabrics were evaluated by measuring the K/S values. The fastness properties (washing, rubbing and light fastness) of the dyed cotton fabrics were also measured. The pretreatment of cotton with polyamino carboxylic acids creates positive charges on the fabric surface. In this way, salt‐free reactive dyeing of cotton or dyeing with only a small amount of electrolyte is possible.     

A method for dyeing cotton fabric with anthocyanin dyes extracted from mulberry (Morus rubra) fruits

For the first time, the natural anthocyanin dyes (mainly consisting of cyanidine 3‐glycoside) extracted from mulberry (Morus rubra) fruits has been successfully used to dye cotton fabric, with a dyeing property performance good enough for potential commercial applications. In this study, succinic acid was firstly incorporated into cotton fabrics by esterification to the hydroxyl groups of cellulose, forming an anionic site for the dyes. The performance of the modified material was characterised by Fourier transform infrared spectroscopy and tensile strength. Results showed that the tensile strength of cotton fabrics was mostly retained after modification. The anthocyanin extracts from mulberry fruits were used to study the dyeability of the control and modified cotton fabrics. Red and deep purple (aubergine) are two main shades of cotton fabrics dyed with mulberry fruit extracts. Most importantly, aubergine shade is rare in cotton fabrics dyed with natural dyes. Modification with succinic acid clearly increased the colour strength of the dyed cotton fabric. The colour strength of dyed cotton fabric was improved from 2.7 to 5.3 in the case of dyeing without mordants, and from 3.2 to 6.9 in the case of dyeing with tin mordanting. Meanwhile, the colour fastness was improved by 0.5–2 grades with increasing succinic acid concentration in the finish solution. The colour fastness to perspiration, crocking, light, and washing of fabric dyed with simultaneous tin mordanting and modified with 30 g l^?1 of succinic acid was found to be acceptable, with a grey scale grade of at least 3. As for home laundering, neutral soapy solution was more acceptable than alkaline soapy solution.     

Dyeing natural fibres in supercritical carbon dioxide using a nonionic surfactant reverse micellar system

A reverse micellar system in supercritical carbon dioxide has been developed as a dyeing medium. Water-soluble dyes such as reactive dyes and acid dyes could be sufficiently solubilised in the interior of a specially constituted reverse micelle. Protein fabrics, silk and wool, were satisfactorily dyed even in deep shades with conventional acid dyes without any special pretreatment. Cotton cellulose fabric was also dyed with conventional reactive dyes when the electrostatic force of repulsion between dye and cotton was eliminated. Compared to previously proposed supercritical dyeing methods, dyeing of fabrics with this system could be performed at low temperatures and pressures in a short time.     

Using carbon black nanoparticles to dye the cationic‐modified cotton fabrics

Carbon black (CB) aqueous dispersion was prepared and used to dye the cationic‐modified cotton fabrics through exhaust dyeing process. The effects of CB concentration, CB nanoparticles size, dyeing bath pH, dyeing time and dyeing temperature were investigated. The color yields of dyed fabrics were evaluated on Kubelka‐Munk value K/S. The surface morphologies of cationic modified and nonmodified cotton fabrics were measured by video microscope. The fabrics presented 18.9 of the color yield with the dyeing conditions: the dyeing solution contained 2% o.w.f. CB and dyeing at 80°C for 30 min with pH 13 using a 50 : 1 liquor ratio. The images of the video microscope demonstrated a clear surface profile for the cationic‐modified cotton fabrics dyed with smaller CB particle size solutions. These results indicated that CB nanoparticles were suitable for dyeing the cotton fabrics. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011