The Bonding Properties of Solid Steel to Liquid Aluminum

The bonding of solid steel plate to liquid aluminum was studied using rapid solidification. The relationship models of interfacial shear strength and thickness of interfacial layer of bonding plate vs bonding parameters ( such as preheat temperature of steel plate, temperature of aluminum liquid and bonding time ) were respectively established by artificial neural networks perfectly. The bonding parameters for the largest interfacial shear strength were optimized with genetic algorithm successfully. They are 226℃ for preheating temperature of steel plate, 723℃ for temperature of aluminum liquid and 15.8s for bonding time, and the largest interfacial shear strength of bonding plate is 71.6MPa. Under these conditions, the corresponding reasonable thickness of interfacial layer (10.8μm) is gotten using the relationship model established by artificial neural networks.     

Thickness of compound layer in steel-aluminum solid to liquid bonding

The bonding of solid steel plate to liquid aluminum was studied using rapid solidification. The surface of solid steel plate was defatted, descaled, immersed (in K2ZrF6 flux aqueous solution) and stoved. In order to determine the thickness of Fe-AI compound layer at the interface of steel-aluminum solid to liquid bonding under rapid solidification, the interface of bonding plate was investigated by SEM (Scanning Electron Microscope) experiment. The relationship between bonding parameters (such as preheat temperature of steel plate, temperature of aluminum liquid and bonding time) and thickness of Fe-AI compound layer at the interface was established by artificial neural networks (ANN) perfectly. The maximum of relative error between the output and the desired output of the ANN is only 5.4%. From the bonding parameters for the largest interfacial shear strength of bonding plate (226℃for preheat temperature of steel plate, 723℃ for temperature of aluminum liquid and 15.8 s for bonding time), the reasona     

Interfacial mechanical property of steel-mushy Al-20Sn bonding

The bonding of a steel plate to Al-20Sn slurry was conducted using the casting rolling technique. The surface of the steel plate was defatted, descaled, immersed (in K2ZrF6 flux aqueous solution) and stored. Al-20Sn slurry was prepared using the electromagnetic mechanical stirring method. The interfacial mechanical property of the bonding plate was researched to determine the relationship between the diffusion time and the interfacial shear strength. In order to identify the mechanism of bonding, the interfacial structure of the bonding plate was studied. The results show that at a preheat temperature of the steel plate of 505℃ and a solid fraction of Al-20Sn slurry of 35%, the relationship between the interfacial shear strength S and the diffusion time t is S=28.8 4.3t-0.134t^2 0.0011t^3. When the diffusion time is 22 s, the largest interfacial shear strength is 70.3 MPa, and the corresponding interface is a new one which is made up of Fe-Al compound and Fe-Al solid solution alternatively and in a right proportion.In this interfacial structure, the interfacial embrittlement does not happen and Fe-Al compound can play its role in strong combination adequately.     

The Influence of Preheat Temperature of Steel Plate on Steel-mushy Cu-graphite Bonding

The pressing bonding of steel plate to QTi3.5-3.5 graphite slurry was conducted. Under the conditions of 530 ℃ for the preheat temperature of dies, 45% for the solid fraction of QTi3.5- 3.5 graphite slurry, 50 MPa for the pressure and 2 min for the pressing time, the relationship between the preheat temperature of steel plate and interfacial mechanical property of bonding plate was studied. The results show that when the preheat temperature of steel plate is lower titan 618 ℃ , the interfacial shear strength of bonding plate increases with the increasing of the preheat temperature of steel plate. When the preheat temperature of steel plate is higher than 618 ℃ , the interfacial shear strength decreases with the increasing of the preheat temperature of steel plate. When the preheat temperature of steel plate is 618 ℃ , the highest interfacial shear strength of bonding plate of 127.8 MPa can be got.     

Immersing Treatment of Steel Plate Surface in Steel-Aluminum Solid to Liquid Bonding

The interfacial status of the steel-aluminum solid to liquid bonding plates (their steel plate surfaces were or were not immersed in flux aqueous solution) were measured by using SEM (Scanning Electron Microscope) and X-ray diffraction . The results showed that the layer of flux (the minimum thickness was 15 μm on the steel plate surface) could protect the steel plate surface from oxidizing effectively at high temperature in solid to liquid bonding. The melt temperatUre of the flux should be lower than 580 ℃ so that it could be melted and removed completely. No. 1 flux (patent product made by the author) made up of halogeindes could also force liquid aluminum to infiltrate into steel plate surface and thus the interfacial shear strength of the bonding plate was rather large.     

Semi—solid Processing of Steel—Al—7 Graphite BInding Plate

The bonding of steel plate to Al-7 graphite slurry was studied for the first time.The relationship model about preheat temperature of steel plate,solid fiaction of Al-7 graphite slurry,rolling speed and nterfacial shear strength of bonding plate could be established by artificial neural networks perfectly.This model could be optimized with a genetic algorthm.The optimum bonding parameters are :516℃ for preheat temperature of steel plate,32.5% for solid fraction of Al-7 graphite slurry and 12mm/s for rolling speed,and the largest interfacial shear strength of bonding plate is 70.6MPa.     

Experimental Study of Fluid Flow in Thin Slab Continuous Caster Mould with Water-Model

The interfacial status of the steel-alu-minum solid to liquid bonding plates (their steel plate surfaces were or were not immersed in flux aqueous solution) were measured by using SEM (Scanning Electron Microscope) and X-ray diffraction. The results showed that the layer of flux (the minimum thick-ness was 15 m on the steel plate surface) could protect the steel plate surface from oxidizing effectively at high temperature in solid to liquid bonding. The melt temperature of the flux should be lower than 580 ℃ so that it could be melted and removed completely. No.1 flux (patent product made by the author) made up of halogenides could also force liquid aluminum to infiltrate into steel plate surface and thus the interfacial shear strength of the bonding plate was rather large.     

Ratio of Fe-Al compound at interface of steel-backed Al-graphite semi-solid bonding plate

The ratio of Fe-Al compound at the bonding interface of solid steel plate to Al-7graphite slurry was used to characterize the interfacial structure of steel-Al-7graphite semi-solid bonding plate quantitatively. The relationship between the ratio of Fe-Al compound at interface and bonding parameters (such as preheat temperature of steel plate, solid fraction of Al-7graphite slurry and rolling speed) was established by artificial neural networks perfectly. The results show that when the bonding parameters are 516 ℃ for preheat temperature of steel plate, 32.5% for solid fraction of Al-7graphite slurry and 12 mm/s for rolling speed, the reasonable ratio of Fe-Al compound corresponding to the largest interfacial shear strength of bonding plate is obtained to be 70.1%. This reasonable ratio of Fe-Al compound is a quantitative criterion of interfacial embrittlement, namely, when the ratio of Fe-Al compound at interface is larger than 70.1%, interfacial embrittlement will occur.     

Study on Bonding of Steel-mushy Al-7graphite

The bonding of steel-mushy Al-7graphite was studied. The relationship between interfacial shear strength of bonding plate and solid fraction of Al-7graphite mushy was obtained, and the interfacial structure of bonding plate was determined. The results showed that: under the condition of 500℃ for preheat temperature of steel plate and 10mm/s for rolling speed, the largest interfacial shear strength of bonding plate was 70.1 MPa when solid fraction of Al-7graphite mushy was 34.6%.     

Effect of Interface on Mechanical Property of Steel-mushy Ak-20Sn Bonding Plate

The ratio of Fe-Al compound at interace, which could determine the quarttity of Fe-Al compound at the interace of steel-mushy Al- 20 Sn bonding plate, was used to characterize the interfacial structure of steel-mushy Al-20 Sn bonding plate quantitatively. The effect of ratio of Fe-Al compound at interface on interacial shear strength was investigated perfectly. The results show that the relationship between ratio of Fe-Al compound at interace and interfacial shear strength is S = 3.3 ＋ 1.91 t - 0.0135t^2 （ where t is ratio of Fe-Al compound at in- terface and S is interfacial shear strength ）. When the ratio of Fe-Al compound at interface is 71%, the largest interfacial shear strength 70.9 MPa is got. This reasonable ratio of Fe-Al compound at interface is a quarttitative criterion of interfacial embrittlement. When the ratio of Fe-Al compound at interface is higher than 71% , interfacial embrittlement will occur.     

受火后混凝土黏钢界面的剪切性能研究

针对不同的受火温度(250,350,450和550℃)和不同的混凝土强度(C25,C30和C35),进行了混凝土高温受火后黏钢界面剪切性能的试验研究.结果表明,当混凝土受火温度相同时,随着混凝土强度的提高,黏钢界面黏结剪切强度逐渐增大,平均增大幅度在3%左右,最大增大幅度近8%.当混凝土强度等级相同时,界面的黏结剪切强度随着受火温度的升高逐渐降低.当受火温度为450℃时,黏结剪切强度为常温的50%;当受火温度为550℃时,黏结剪切强度仅为常温的38%左右.得到了钢-混凝土黏结剪切强度与混凝土强度的比值随混凝土受火温度升高的退化规律.     

Interfacial microstructure and properties of Ti(C,N)/Ni bonded by transient liquid-phase diffusion

Effects of the main process parameters(temperature and time) on microstructure and properties of Ti(C, N)/Ni interface bonded by (Cu+Nb) interlayer in a vacuum diffusion bonding device were investigated. The interfacial microstructures consisted initially of Ni₃Nb metallic compound and eutectic of Ni₃Nb+CuNi_SS, and finally transformed to (Ti, Nb) (C, N)+Ni₃Nb near Ti (C, N) and NiCu_SS+Ni₃Nb near Ni when diffusion bonding temperature was 1 523–1 573 K. It was clear that Cu was a constituent in the transient liquid phase (TLP) into which Ni was dissolved by forming Cu-Ni transition liquid. Nb was dissolved in Cu-Ni transition liquid rapidly. Ti (C, N) conld be wetted by resultant Ni-Nb-Cu transient liquid phase which was followed by a little (Ti, Nb) (C, N) solid solution formed at interface. This increased the interface combining capability. Ultimately the interface shear strength was able to reach 140 MPa. The theoretle analysis and experimental results show that the growth of interfacial reaction layer Ni₃Nb accords with parabola law, and the activation energy of diffusion reaction is 115.0±0.5 kJ/mol, while the diffusion reaction speed constant is 12.53 mm/s^1/2. Funded by the National Natural Science Foundation of China (No. 50074017/E0408)     

Influence of aluminum solid fraction on property of steel-mushy aluminum bonding plate

The interfacial shear property of steel-mushy aluminum bonding plate was studied, and the relationship between aluminum solid fraction and the interfacial shear strength of bonding plate was determined. The results showed that when aluminum solid fraction is 34.3 %, the maximum interfacial shear strength of bonding plate is 71 .0 MPa.     

铝合金板与混凝土的粘贴粘结强度研究

为了在提高加固钢筋混凝土梁承载力的同时具有很好的延性和耗能能力,特别是满足侵蚀环境及寒冷环境中加固工程的需要,采用铝合金板加固钢筋混凝土梁是一个很好的解决办法。铝合金板通过粘贴层将力传给钢筋混凝土梁,故铝合金板与混凝土的粘贴粘结性能决定了铝合金板加固钢筋混凝土梁的效果。铝合金板与混凝土的粘贴粘结强度作为铝合金板加固钢筋混凝土梁连接设计的基础,对其开展试验和理论研究。开展105个试件的铝合金板与混凝土面内单剪试验发现：对粘贴界面没有进行粗糙处理的试件发生了界面剥离破坏,其他试件均发生了混凝土层剥离破坏;界面剥离破坏的粘结性能远差于混凝土层剥离破坏,说明了对粘贴界面进行处理的必要性。通过试验得到铝合金板和混凝土连接的极限粘结荷载,根据铝合金板正应力的变化率与粘贴界面剪应力的关系,得到剪应力的分布曲线和有效粘结长度;假设剪应力沿有效粘结长度处处相等,得到了铝合金板与混凝土的粘贴试验粘结强度,并基于此讨论了界面处理、混凝土强度、铝合金板宽度、厚度和粘贴长度等因素对试验粘结强度的影响。结合试验数据的统计回归分析,提出计算铝合金板与混凝土的粘贴粘结强度的修正Niedermeier模型,得到了铝合金板与混凝土的有效粘结长度和粘贴粘结强度的理论计算公式,其理论值和试验值吻合较好,误差最大值为8.98%,平均值为0.004,标准差为0.041。研究成果为铝合金板加固钢筋混凝土梁的粘贴设计提供了理论基础。