On spontaneous nucleation in field-accessed bubble devices

The dependence ot the in-plane drive field at which bubble domains spontaneously nucleate in field-accessed bubble devices has been investigated as a function ofH_{k} - 4piM_{s}and of spacer thickness between the bubble film and permalloy propagation elements. The experiments were carried out on amorphous GdCoMo bubble films with T-bar and Y-bar structures. For a given structure and spacer thickness the nucleation field increases linearly withH_{k} - 4piM. Larger spacer thicknesses also lead to increased nucleation fields. A model based on the Stoner-Wohlfarth astroid is compared to these data and found to be useful in explaining the qualitative trends, but to be in poor quantitative agreement. It is concluded that since the drive field required in a device is proportional to4piM_{s}, Q - 1 = (H_{k} - 4piM_{s})/4piM_{s}must be greater than some minimum value for a given device structure and spacer thickness to permit reliable device operation.     

Uniaxial anisotropy by "radiomagnetic" treatment; controlling factors in a new process

A new process-an electron-"radiomagnetic" treatment-for obtaining high-remanence, low-coercive-force loops in magnetic alloys was recently announced. As an example, 2-MeV electron irradiation of 6-mil-thick ring laminations of polycrystalline 5-80 Mo Permalloy with 10¹⁷e/cm²in an applied circumferential magnetic field of 0.2 Oe atsim100degC produced record highs in remanence (∼6700 G) for this material. Additional studies of this process have been made to determine some of the controlling factors and the range of application. In particular, the effects of the dose (number of e/cm²) and of the preirradiation magnetic properties were examined. The results show that: 1) for a given dose of1.1 times 10^{17}2-MeV e/cm², the relative change in remanence (DeltaB_{r}/B_{r}) is always positive, ranging from 10 to 50 percent, but varies inversely with the preirradiation value of remanence (Br); 2) for the same dose, the relative change in coercive force (DeltaH_{c}/H_{c}) also depends upon the preirradiation value of remanence, but in a different way. ForB_{r} < 5000G,DeltaH_{c}/H_{c}is either negative or zero. ForB_{r} > 5000G,DeltaH_{c}/H_{c}is positive, ranging from 20 to 150 percent, and increases linearly withB_{r}; 3) if the dose is reduced tosim0.8 times 10^{17}e/cm², thenDeltaH_{c}/H_{c}is reduced to a tolerable level (∼10 percent) with no significant sacrifice in the positive gain in remanence and rectangularity. Hence, there are optimum dose ranges in the "radio-magnetic" treatments of alloys, where significant gains in remanence may be obtained without appreciable increases in coercive force.     

Static and anhysteretic magnetic properties of tapes

The anhysteretic remanencebar{M}_{ar}(H_{o},T)of solidified suspensions of magnetic particles with predominant shape anisotropy is calculated from first principles for small dc fields Hoand arbitrary temperatureT < T_{B}(blocking temperature), describing the particle interactions by a mean field and assuming constant decrement of the ac field,2H_{d}per cycle. ForH_{d}< 2H_{o}, the anhysteretic distribution of particle magnetizations is found to be subject to the condition that the net internal dc fieldbar{H}_{i}is a minimum, and, for small Ho, to the condition,bar{H}_{i} = 0. The theory yieldsbar{M}_{ar}(H_{o},T)as a unique function of independently measurable static magnetic material properties, i.e., it contains no adjustable parameters and is hence quantitatively related to experimental data. Further, according to theory, ifbar{M}_{ar}(H_{o},T,T_{m})denotesbar{M}_{ar}as acquired in Hoat T and measured atT_{m}, bar{M}_{ar}(H_{o},T,T_{m} = T)is independent ofTforH_{d} ll 2H_{o}, andbar{M}_{ar}(H_{o},T,T_{m} neq T) = [M_{s}(T_{m})/M_{s}(T)] cdot bar{M}_{ar}(H_{o},T,T_{m} = T). The thermoremanent magnetization acquired in Hoand measured at a temperatureT_{m} ll T_{B},bar{M}_{thr}(H_{o},T_{m}), is related tobar{M}_{ar}(H_{o},T = T_{m}, T_{m})bybar{M}_{thr}(H_{o},T_{m}) = [M_{s}(T_{m})/M_{s}(T_{B})]bar{M}_{ar}(H_{o},T=T_{m},T_{m}), where TBis the blocking temperature below whichbar{M}_{thr}becomes thermally stable. Up to a constant factor of about 2, the theoretical results agree quantitatively with the experimental data on all materials that correspond to the premises of the theory, i.e., solidified suspensions, tapes in particular, of particles having predominant shape anisotropy.     

Long term operation of low noise DC-SQUID coupled to a very high Q gravitational radiation detector

We have coupled a very low noise dc-SQUID to the gravitational radiation detector of the Rome group at CERN laboratories. The SQUID used is a multiloop thin-film device with an input inductance of 1.6 μH, loop inductance of 5 pH and coupling coefficient of 0.5. The gravitational radiation detector is composed by a 2.3 tons Aluminum cylinder mechanically coupled to a resonant capacitive transducer; this is matched to the SQUID by means of a large superconducting transformer. The signal to be detected is essentially composed by the two mode frequencies at about 1 kHz and with quality factors of the order of 4×10⁶. To operate in a closed feedback loop mode we have used a particular setup in order not to degrade the performance of the system. The system operated for seven months with some interruptions due to refilling of liquid helium and various tests on the apparatus. The flux noise obtained was 1.5 to3times10^{-6} Phi_{o}/sqrt{Hz}at 1 kHz with a linearity over 6 orders of magnitude and a long term stability of1.5 times 10^{-8} Phi_{o}/hour.     

Reevaluation of the Optically Pumped Cesium Frequency Standard NRLM-4 With an H-Bend Ring Cavity

The largest source of uncertainty of the optically pumped cesium (Cs) frequency standard (NRLM-4), i.e., the distributed cavity phase shift, was reduced by replacing the microwave cavity with a new ring-type one. An H-bend-type ring cavity is adopted for the first time. Due to the novel cavity and the improvement of the Cs beam alignment, the distributed cavity phase shift was significantly reduced from $2 times 10^{-14}$ to $1.4 times 10^{-15}$. The frequency stability was measured to be $8 times 10^{-13}tau^{-1/2}$ . The total uncertainty was reevaluated to be $6.7 times 10^{-15}$ , which is four times better than the previous value.      

The measurement of the anisotropy field of cylindrical thin magnetic films

The described method for the anisotropy field measurement uses two fields HLand HT. The deviation of magnetization from the easy direction, and hence also sense signals, are proportional to these fields. The ratio of two integrated sense signals atH_{L} = 0andH_{L} neq 0reaches a certain value (∼ 2.5) with fieldH_{T} = H_{k}. In this way, Hkmay be measured by a device designed for the coercive force measurement.     

Wide PRIME-current range for all-magnetic shift registers

In an all-magnetic resistance-type shift register, a PRIME current pulsei_{p}(t), of amplitude Ip, is applied to Npand Nbturns through the minor and major apertures, respectively. For given operation frequencyf, the ratioR = I_{p}^{max}/I_{p}^{min}, whereI_{p}^{min} < I_{p} < I_{p}^{max}is the PRIME range of bistable operation, is maximized by matchingN_{p}/N_{b}so thatI_{p}^{max}values determined by spurious ZERO buildup and ONE dropout are the same. For a rectangular (or dc)i_{p}(t), the matchedN_{p}/N_{b}is fixed by the core properties, and R^maxis limited (e.g., <7). However, ifi_{p}(t)rises gradually, the matchedN_{p}/N_{b}depends also on the rise time Trofi_{p}(t). The lowerfis, with corresponding larger Tr, the smaller is the matchedN_{p}/N_{b}, and the larger is R^max. Calculation ofRis carried for ramp and half-sinusoidali_{p}(t)waveforms. The latter, for instance, atT = 25degC yields R^maxvalues of 14.0 and 22.0 forfof 1.0 and 0.5 kc/s respectively. Such wide PRIME ranges permit reliable register operation in a wide temperature range without resorting to temperature compensation of Ip. Experimental results are in agreement with the calculation.     

Magnetic properties of evaporated CoCr films

Perpendicular magnetic CoCr films were prepared on glass substrates using electron beam evaporation. The magnetic properties depend strongly on the substrate temperature, Ts. The anisotropy field,H_{k}^{eff}, and the perpendicular coercivity, Hc(perp) show maximum values at Tsaround 250°C. In this case, the alignment of c-axis is optimal and the grain size is smallest. The lattice spacing of the c-planes increases wlth Tsuntil 300°C. When the films prepared below 200°C were annealed around 300°C in high vacuum, the saturation magnetization, Ms, increased. The value of Ms, however, decrease by annealing above 400°C. In spite of the decrease of Msdue to the annealing above 400°C,H_{k}^{eff}and Hc(perp) increase by annealing above 400°C. If the films were bombarded by argon ions during film growth, Msdecreased and the internal stress changed from tensile to compressive. For low substrate temperature (below 150°C),H_{k}^{eff}decreased due to ion bombardment.     

A new principle for fast DC-sensitive potential-independent current comparators

A new principle of operation makes feasible small, cheap potential-independent current comparators whose performance reaches or exceeds the best properties of bulky magnetic amplifiers of the second-harmonic type. Connection of a ferrite-core coil in parallel with a suitable negative resistance generates relaxation oscillationsg(t). Inherently, at large oscillations the coil (i,phi)- characteristic is perfectly symmetric about the origin:phi(-i) = -phi(i). Provided that the negative-resistance (i,u)- characteristic has the same symmetry:i(-u) = -i(u), the oscillationsg(t)are perfectly symmetrical in the sense thatg(t+T/2) = -g(t). Heregrepresents either the coil flux φ, the currentior the voltageu. The time istandTthe oscillation period. External magnetomotive force shifts the coil (i,phi)-characteristics, invalidating (1) and therefore (3). Consequently, the deviation from 50% duty-ratio of the oscillatingq(t)is a sensitive and extremely stable measure of this MMF. Neither core temperature, pressure nor magnetic creep cause any zero drift. Orders of magnitude reached experimentally are: Short-time zero instability and noise:leq 10^{-5}ampere-turn, time resolution:leq 10^{-4}s, zero drift from -70 to +100°C:< 10^{-4}ampere-turn.     

A sensitive magnetoresistive power amplifier

A small, sensitive, low noise, high gain power amplifier, using the anisotropic magnetoresistance effect in thin film permalloy, has been designed and its characteristics calculated. The minimum detectable input current is determined by Johnson noise and hence by input resistance and desired bandwidth. An example of theoretical performance is as follows. For an amplifier unit with approximate dimensions of300 times 300 times 2 mum and with input and load resistances of 50 Ω each the calculated noise at room temperature is equivalent to 10^-8A for a bandwidth (BW) of 1MHz or to 10^-7A for a BW of 100 MHz. At the 10^-8A input current level, the calculated power gain issim 600,000corresponding to a current gain of 775. Power gain decreases with input current asI^{-4/3}, reaching unity atI = 2.1 times 10^{-4}A. Hence, for a BW of 1 MHz, at room temperature, the input current operating range for both amplification and signal-to-noise ratio greater than one is fromI=10^{-8}A to2.1 times 10^{-4}A. To achieve high gain, the amplifier is configured so that the magnetization of the permalloy is biased to lie nominally along the hard axis, the sensing current in the permalloy makes an angle of 45° with the nominal magnetization direction, and the input current produces a magnetic field along the easy axis. This microsize, low noise, silicon compatible power amplifier will be useful in digital and FM applications and possibly as an amplifier for crosstie and bubble memories.     

Measurements of superconducting Nb3Sn cavities in the GHz range

Superconducting Nb3Sn Cavities have potential advantages over rf cavities with Nb surfaces To test possible applications and to improve the understanding of Nb3Sn coatings on Nb, rf cavities have been measured between 1.5 and 8K and between 0.1 and 7GHz. The temperature dependence of the surface resistance R(T) indicates weak superconducting spots with transition temperaturesTmin{c}max{ast} < 1K andTmin{c}max{ast} simeq 2.5K. The normal conducting spotsTmin{c}max{ast} lsim 1K cause the large rf residual lossesR'_{res} propto f^{2}observed up to date. The spots withTmin_{c}max_{ast} simeq 2.5K cause temperature dependences ofR'(T)between 2 and 6K, where RBCS(Nb3Sn) is still negligible. In line withR_{res} propto f^{2}, the lowest rf lossesR_{res} < 2.10^{-9}Omegaand the highest field strengthB_{crit} = 83 m^{T}(wedgeE_{peak} = 29have been observed at the lowest frequency 0.1GHz measured. Surface resistance and penetration depth measurements have shown that grain boundaries or hydrogen clusters do not cause the weak spots observed withTmin{c}max{ast} < 2.5K. The origin and the chemistry of the weak spots withTmin{c}max{ast} lsim 1K, which cause the largeR_{res} propto f^{2}and the lowB_{crit} (T) simeq const, are still not clear. They seem related to the Nb3Sn surface. The weak spots withTmin{c}max{ast} simeq 2.5K consist most likely of Nb6Sn5, which in cooling below 950°C precipitates due to the excess Sn present in Nb3Sn coatings grown in Sn vapor.     

The effect of temperature on the electric conductivity property of Bi3Zn2Sb3O14 pyrochlore type phase

The electric conductivity characteristic of ceramics was investigated by impedance spectroscopy in the frequency range from 5 Hz to 13 MHz. Electric measurements were performed at temperatures in the range from 25 to 700 °C. The phase type pyrochlore was synthesized by the polimeric precursors method. Ceramic presenting a relative density of 98% of the theoretical density was prepared. The data were presented in Nyquist diagrams form, from which the electric resistivity was determined. The electric conductivity followed the Arrhenius law with an apparent activation energy of the conduction process equal to 1.37 eV. The electric conductivity at room temperature was determined by extrapolation being equal to . Between 400 and 700 °C, the conductivity values were and , respectively.     

Permanent magnet utilization criteria in a DC motor

In a dc motor with permanent magnet stator, the mean no-load working point of the magnet material can, after stabilization by stall current, be represented by a pointB_{m},H_{m}on a recoil line inside the demagnetization curve. The point results from the application during stall of an effective mean field Hadue to armature reaction in addition to the self-demagnetizing field due to circuit reluctance. It is shown that the motor specification and sizes lead to a specific value forH_{m}/H_{a}. The limiting values of this ratio (Hmzero or Hazero) imply that the corresponding optimum magnet designs for minimum magnet volume should be based either on maximum recoil energy or on(BH)_{max}. In practice, the best extreme working point during stall should lie between the points for these two criteria, dependent on the actualH_{m}/H_{a}. In some existing motorsH_{m}/H_{a}has been found to be between 0.5 and 1.5. For such values ofH_{m}/H_{a}, the variation of Bmand ofB_{m},H_{m}with working point is illustrated for high coercivity ferrite and for two grades of cast alnico alloy. A note on design methods is appended     

Dependence of coercivity on driving field in multilayer films of nickel

The variation in the coercivity of magnetization loops of multilayer films of nickel was investigated as function of the rate of riserin the applied magnetic field. The films were prepared by deposition of nickel and copper alternately in a vacuum of2 times 10^{-6}mm of Hg on to substrates made of thin aluminium foils. The thickness of the nickel layersLvaried in the different films from 8 to 1000 angstroms. The loops were cycled with sinusoidal or triangular waveform driving fields, with a variety of amplitudes from 1 kOe to 4 kOe, with frequencies from 0.01 to 2 c/s. The measurements were performed from room down to liquid hydrogen temperatures. It was found that the coercive force could be expressed byH_{c} = H_{o} + Q(ln r - ln r_{o})/T^{1/2}for values ofrchanging from 1 to 5 Oe/ms, whereH_{o}, Aand rovaried slightly with temperatureT. The coercive force was a very sensitive function ofLand of the thickness δ of the copper layers, having the formH_{c} = A(L + delta) exp - BLwithBnearly constant in films deposited on a substrate at room temperature. The dependence of the coercivity onLwas displayed by a nonmonotonical function showing two peaks in Hccorresponding to values ofLof about 35 and 400 angstroms. The observed dependence of Hcon the rate of rise in the applied field, as well as on the thicknesses of the layers, can be discussed on the assumption of nonuniform magnetization within the thin layers as a result of their superparamagnetic properties and of the magneto-statical coupling between neighboring layers.     

Development of a New Selective Optical Sensor for Cd(II) Ions Based on 4-Hydroxy Salophen

A new sensor membrane based on immobilization of 4-hydroxy salophen on triacetyl cellulose has been developed for the determination of Cd(II) ions that displays excellent performance. The sensing membrane is capable of spectrophotometric determining of Cd(II) with an outstanding high selectivity over a dynamic range between 1.0$,times 10^{-6}$ and 5.0$,times 10^{-2}$ mol L$^{-1}$ with a limit of detection of 5.3 $,times 10^{-7}~$mol L $^{-1}$ (0.06 $mu$g mL $^{-1}$ The sensor shows a fast response time ($≪ {5}~$ min) and the membrane can be used for more than two months without observing any major deviation. The optode revealed very good selectivity with respect to many cations including alkali, alkaline earth, transition and heavy metal ions. The proposed sensor could be used to determine cadmium ions in water and waste water samples. Different experimental parameters such as variable affecting on sensor preparation and pH of the sample solution plus response time were studied. The optodes developed in the present work were found to be stable, cost effective, easy to prepare, and efficient for direct determination of Cd(II) in a variety of aqueous samples using spectrophotometry, with satisfactory results.      

Thermal and Tribological Properties of <Emphasis Type="Italic">Jatropha</Emphasis> Oil as Additive in Commercial Oil

The recent use that has been given to bio-oil as an additive, in a commercial engine oil, raises the necessity to study its physical properties. The present study is aimed to obtain thermal properties of blends made with Jatropha-Curcas L. Oil, Crude, and Refined, at different concentrations using SAE40W oil (EO) as a lubricant base. By using photothermal techniques, thermal effusivity and diffusivity were obtained. The obtained results show that thermal effusivity increases from 455 \(\hbox {Ws}^{1/2}{\cdot }\hbox {m}^{-2}{\cdot }\hbox {K}^{-1}\) to 520 \(\hbox {Ws}^{1/2}{\cdot }\hbox {m}^{-2}{\cdot }\hbox {K}^{-1}\) as the percentage of additive increases as well, whereas thermal diffusivity values range from \(7\times 10^{-8}\hbox {m}^{2}{\cdot }\hbox {s}^{-1}\) to \(10\times 10^{-8}\hbox {m}^{2}{\cdot }\hbox {s}^{-1}\). In the present study, four balls test was used in order to obtain friction coefficient and wear scar values for studied samples, the obtained results point out that in general refined Jatropha-Curcas L. oil presents smaller wear scars than the crude one.     

Mechanism of the reduction of carbon/alumina powder mixture in a flowing nitrogen stream

The mechanism of the reduction of carbon/alumina powder mixture in a flowing nitrogen stream was studied. Five steps were found to be involved in the overall reaction. $$\begin{gathered} Al_2 O_{3f} (s) + 2C_f (s)\mathop \to \limits^{k_1 } Al_2 O(g) + 2CO(g) \hfill \\ Al_2 O(g) + solid surface\mathop \rightleftharpoons \limits_{k_2^\prime }^{k_2 } [Al_2 O]_s \hfill \\ [Al_2 O]_s + CO(g) + N_2 (g)\mathop \to \limits^{k_3 } 2AlN(s) + CO_2 (g) \hfill \\ CO_2 (g) + C_f (s)\mathop \rightleftharpoons \limits_{k_4^\prime }^{k_4 } CO(g) + [O]_c \hfill \\ [O]_c \mathop \to \limits^{k_5 } CO(g) \hfill \\ \end{gathered}$$ The consumption rates of Al₂O₃ and carbon, and the production rate of AIN, were determined to be $$\begin{gathered} \frac{{d[Al_2 O_3 ]}}{{dt}} = - 143.88(1 + m)exp( - 290 580/RT) [Al_2 O_3 ][C]^2 / \hfill \\ \left\{ {1 + 5.83 x 10^{14} exp( - 427 497/RT)\frac{{[CO_2 ]}}{{[CO]}}} \right\}^2 kg mol s^{ - 1} m^{ - 3} \hfill \\ \frac{{d[C]}}{{dt}} = - 409.504 exp ( - 254 500/RT) [Al_2 O_3 ][C]^2 / \hfill \\ \left\{ {1 + 5.83 x 10^{14} \exp ( - 427 497/RT)\frac{{[CO_2 ]}}{{[CO]}}} \right\}^2 kg mol s^{ - 1} m^{ - 3} \hfill \\ \frac{{d[AlN]}}{{dt}} = 53.24(1 + m) exp( - 290 580/RT) [Al_2 O_3 ][C]^2 / \hfill \\ \left\{ {1 + 5.83 x 10^{14} exp( - 427 497/RT)\frac{{[CO_2 ]}}{{[CO]}}} \right\}^2 kg mol s^{ - 1} m^{ - 3} \hfill \\ \end{gathered}$$ in the temperature range 1648–1825 K.     

Photopyroelectric Calorimetry of \hbox {Fe}_{3}\hbox {O}_{4} Magnetic Nanofluids: Effect of Type of Surfactant and Magnetic Field

Five types of magnetic nanofluids, based on \(\hbox {Fe}_{3}\hbox {O}_{4}\) nanoparticles with water as the carrier liquid, were investigated by using the two photopyroelectric (PPE) detection configurations (back (BPPE) and front (FPPE)), together with the thermal-wave resonator cavity (TWRC) technique as the scanning procedure. The difference between the nanofluids was the type of surfactant: double layers of lauric (LA–LA), oleic (OA–OA), and miristic (MA–MA) acids and also double layers of lauric–miristic (LA–MA) and palmitic-oleic (PA–OA) fatty acids were used. In both detection configurations, the information was contained in the phase of the PPE signal. The thermal diffusivity of nanofluids was obtained in the BPPE configuration, from the scan of the phase of the signal as a function of the liquid’s thickness. Using the same scanning procedure in the FPPE configuration, the thermal effusivity was directly measured. The influence of a 0.12 kG magnetic field on the thermal effusivity and thermal diffusivity was also investigated. Because of different surfactants, the thermal effusivity of the investigated nanofluids ranges from \(1530\,\hbox {W}\cdot \hbox {s}^{1/2} \cdot \hbox { m}^{-2}\cdot \hbox { K}^{-1}\) to \(1790\,\hbox { W}\cdot \hbox {s}^{1/2}\cdot \hbox { m}^{-2}\cdot \hbox { K}^{-1}\) , and the thermal diffusivity, from \(14.54~\times ~10^{-8}\,\hbox { m}^{2}\cdot \hbox { s}^{-1}\) to \(14.79~\times ~10^{-8}\,\hbox { m}^{2}\cdot \hbox { s}^{-1}\) . The magnetic field has practically no influence on the thermal effusivity, and produces a maximum increase of the thermal diffusivity (LA–LA surfactant) of about 4 %.     

Comparison of a Multichip 10-V Programmable Josephson Voltage Standard System With a Superconductor–Insulator–Superconductor-Based Conventional System

We developed a 10-V dc programmable Josephson voltage standard (PJVS) using a multichip technique. The PJVS was based on $hbox{NbN/TiN}_{x}/hbox{NbN}$ junctions and operated using a 10-K compact cryocooler. We carried out an indirect comparison with a superconductor–insulator–superconductor-based conventional Josephson voltage standard (JVS) by measuring the voltage of a 10-V zener diode reference standard. The combined standard uncertainty of the comparison was $u_{c} = 0.03 muhbox{V}(k = 1)$, and the relative combined standard uncertainty was $3 times 10^{-9}$.      

Determination of thermodynamic interactions of poly(l-lactide) and biphasic calcium phosphate/poly(l-lactide) composite by inverse gas chromatography at infinite dilution

Inverse gas chromatography at infinite dilution was applied to determine the thermodynamic interactions of poly(l-lactide) (PLLA) and the composite of biphasic calcium phosphate and PLLA (BCP/PLLA). The specific retention volumes, $ V_{\text{g}}^{0} $ , of 11 organic compounds of different chemical nature and polarity (non-polar, donor or acceptor) were determined in the temperature range of 308–378 K for PLLA and 308–398 K for BCP/PLLA. The weight fraction activity coefficients of test sorbates, $ \Omega_{1}^{\infty } $ , and the Flory–Huggins interaction parameters, $ \chi_{12}^{\infty } $ , were estimated and discussed in terms of interactions of the sorbates with PLLA and BCP/PLLA. Also, the partial molar free energy, $ \Delta G_{1}^{\infty } $ , the partial molar heat of mixing, $ \Delta H_{1}^{\infty } $ , the sorption molar free energy, $ \Delta G_{1}^{\text{S}} $ , the sorption enthalpy, $ \Delta H_{1}^{\text{S}} $ , and the sorption entropy, $ \Delta S_{1}^{\text{S}} $ , were analyzed. A different chromatographic behavior of the two investigated samples, PLLA and BCP/PLLA, was observed. The values of $ \Omega_{1}^{\infty } $ indicated n-alkanes, diethyl ether, tetrahydrofurane (THF), cyclohexane, benzene, dioxane (except for 338 K), and ethyl acetate (EtAc) (except for 338 K) as non-solvents, and chloroform (CHCl₃) as good solvent (except for 378 K) for PLLA. For BCP/PLLA, CHCl₃, EtAc (for 378 K), dioxane (except for 378 K), and THF were indicated as good solvents.